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RESEARCH PAPER · Chemical Society Reviews · 2021

Recent progress of zero-dimensional luminescent metal halides

Mingze Li, Zhiguo Xia

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Recent progress of zero-dimensional luminescent metal halidesOriginalBroadband light emitting zero-dimensional antimony and bismuth-based hybrid halides with diverse structures43Enhancement of the photoluminescence efficiency of hybrid manganese halides through rational structural design94Solvent-free mechanochemical syntheses of microscale lead-free hybrid manganese halides as efficient green light phosphors105Highly Efficient Cool-White Photoluminescence of (Gua) 3 Cu 2 I 5 Single Crystals: Formation and Optical Properties126Strongly Luminescent Dion–Jacobson Tin Bromide Perovskite Microcrystals Induced by Molecular Proton Donors Chloroform and Dichloromethane43Multimode dynamic luminescent switching of lead halide hybrids for anti-counterfeiting and encryption94An Overview for Zero‐Dimensional Broadband Emissive Metal‐Halide Single Crystals269Ultra-Broad-Band-Excitable Cu(I)-Based Organometallic Halide with Near-Unity Emission for Light-Emitting Diode Applications168Structural Dimensionality Modulation toward Enhanced Photoluminescence Efficiencies of Hybrid Lead‐Free Antimony Halides164Activation of Self‐Trapped Emission in Stable Bismuth‐Halide Perovskite by Suppressing Strong Exciton–Phonon Coupling154Phase Engineering of Cesium Manganese Bromides Nanocrystals with Color‐Tunable Emission144Excitation‐Dependent Emission Color Tuning of 0D Cs2InBr5·H2O at High Pressure81Sb 3+ ‐Doping in Cesium Zinc Halides Single Crystals Enabling High‐Efficiency Near‐Infrared Emission370Bulk Assembly of Zero-Dimensional Organic Copper Bromide Hybrid with Bright Self-Trapped Exciton Emission and High Antiwater Stability66Low Dimensional, Broadband, Luminescent Organic‐Inorganic Hybrid Materials for Lighting Applications57Photoluminescent ionic metal halides based on s2 typed ions and aprotic ionic liquid cations87Ultrafast Study of Exciton Transfer in Sb(III)-Doped Two-Dimensional [NH3(CH2)4NH3]CdBr4 Perovskite84Defect Passivation in Air‐Stable Tin(IV)‐Halide Single Crystal for Emissive Self‐Trapped Excitons85Multiexcitonic Emission in Zero-Dimensional Cs2ZrCl6:Sb3+ Perovskite Crystals275Te4+-doped Cs2InCl5·H2O single crystals for remote optical thermometry88Antimony‐Doped Lead‐Free Zero‐Dimensional Tin(IV)‐Based Organic–Inorganic Metal Halide Hybrids with High Photoluminescence Quantum Yield and Remarkable Stability720D Perovskites: Unique Properties, Synthesis, and Their Applications386Selective Luminescence Response of a Zero-Dimensional Hybrid Antimony(III) Halide to Solvent Molecules: Size-Effect and Supramolecular Interactions72Blue light-emitting diodes based on halide perovskites: Recent advances and strategies120Pressure‐Treated Engineering to Harvest Enhanced Green Emission in Mn‐Based Organic–Inorganic Metal Halides at Ambient Conditions110Highly emissive zero-dimensional antimony halide for anti-counterfeiting and confidential information encryption-decryption164Zero-Dimensional Lead-Free Halide with Indirect Optical Gap and Enhanced Photoluminescence by Sb Doping76Antimony -doped indium-based halide single crystals enabling white-light emission47Coordination units of Mn 2+ modulation toward tunable emission in zero-dimensional bromides for white light-emitting diodes94High-efficiency luminescent organic–inorganic hybrid manganese( ii ) halides applied to X-ray imaging70Self-trapped excitons in soft semiconductors97Two multifunctional stimuli-responsive materials with room-temperature phosphorescence and their application in multiple dynamic encryption51White-light defect emission and enhanced photoluminescence efficiency in a 0D indium-based metal halide54Component Engineering to Tailor the Structure and Optical Properties of Sb-Doped Indium-Based Halides86Dual‐Band‐Tunable White‐Light Emission from Bi 3+ /Te 4+ Emitters in Perovskite‐Derivative Cs 2 SnCl 6 Microcrystals144Light/Force‐Sensitive 0D Lead‐Free Perovskites: From Highly Efficient Blue Afterglow to White Phosphorescence with Near‐Unity Quantum Efficiency185Dual-mode optical ratiometric thermometer based on rare earth ions doped perovskite oxides with tunable luminescence50(C16H28N)2SbCl5: A new lead-free zero-dimensional metal-halide hybrid with bright orange emission111Excitation‐Dependent Emission in All‐Inorganic Lead‐Free Cs2ScCl5·H2O Perovskite Crystals50Effects of Electron–Phonon Coupling and Spin–Spin Coupling on the Photoluminescence of Low-Dimensional Metal Halides90Methanol-induced luminescence vapochromism based on a Sb3+-doped organic indium halide hybrid55Integrated Afterglow and Self‐Trapped Exciton Emissions in Hybrid Metal Halides for Anti‐Counterfeiting Applications201Seed‐Crystal‐Induced Cold Sintering Toward Metal Halide Transparent Ceramic Scintillators313Pure White Emission with 91.9% Photoluminescence Quantum Yield of [(C3H7)4N]2Cu2I4 out of Polaronic States and Ultra-High Color Rendering Index112Zero‐Dimensional Luminescent Metal Halide Hybrids Enabling Bulk Transparent Medium as Large‐Area X‐Ray Scintillators201Highly efficient Sb3+ emitters in 0D cesium indium chloride nanocrystals with switchable photoluminescence through water-triggered structural transformation167Dopant and Compositional Modulation Triggered Broadband and Tunable Near-Infrared Emission in Cs2Ag1–xNaxInCl6:Cr3+ Nanocrystals131Self‐Trapped Exciton Emission with High Thermal Stability in Antimony‐Doped Hybrid Manganese Chloride84Multi‐Mode and Dynamic Persistent Luminescence from Metal Cytosine Halides through Balancing Excited‐State Proton Transfer103Highly Resolved X‐Ray Imaging Enabled by In(I) Doped Perovskite‐Like Cs 3 Cu 2 I 5 Single Crystal Scintillator134Efficient Near‐Infrared Luminescence in Lanthanide‐Doped Vacancy‐Ordered Double Perovskite Cs2ZrCl6 Phosphors via Te4+ Sensitization45Efficient Near‐Infrared Luminescence in Lanthanide‐Doped Vacancy‐Ordered Double Perovskite Cs2ZrCl6 Phosphors via Te4+ Sensitization149Zero‐Dimensional Organic Copper(I) Iodide Hybrid with High Anti‐Water Stability for Blue‐Light‐Excitable Solid‐State Lighting114Unraveling the triplet excited-state dynamics of Bi3+ in vacancy-ordered double perovskite Cs2SnCl6 nanocrystals76Luminescent Organic‐Inorganic Hybrid Metal Halides: An Emerging Class of Stimuli‐Responsive Materials76Highly Efficient Broadband Green Emission of (TPA)CuCl2 Single Crystals: Understanding the Formation of Self-Trapped States45Amino‐Acid‐Induced Circular Polarized Luminescence in One‐Dimensional Manganese(II) Halide Hybrid47Circularly Polarized Luminescence based on 0D Lead‐Free Antimony (III) Halide Hybrids63Bright Green Emission from Self-Trapped Excitons Triggered by Sb3+ Doping in Rb4CdCl6145Zero‐Dimensional Zn‐Based Halides with Ultra‐Long Room‐Temperature Phosphorescence for Time‐Resolved Anti‐Counterfeiting200Efficient Broadband Near‐Infrared Emission from Lead‐Free Halide Double Perovskite Single Crystal166Highly Distorted Antimony(III) Chloride [Sb 2 Cl 8 ] 2− Dimers for Near‐Infrared Luminescence up to 1070 nm160Boric Acid‐Activated Room‐Temperature Phosphorescence and Thermally Activated Delayed Fluorescence for Efficient Solid‐State Photoluminescence Materials55Supramolecular Assembly of Halide Perovskite Building Blocks73Tunable Luminescence of Sb3+ Doped 0D Cs4PbCl6 Nanocrystals from Three Distinct Emission Centers46Zero-Dimensional Hybrid Indium Halides with Efficient and Tunable White-Light Emissions47Reversible Triple-Mode Switching in Photoluminescence from 0D Hybrid Antimony Halides139Efficient Narrow-Band Green Light-Emitting Hybrid Halides for Wide Color Gamut Display46High Quantum Efficiency of Stable Sb‐Based Perovskite‐Like Halides toward White Light Emission and Flexible X‐Ray Imaging83Molecular dimensionality and photoluminescence of hybrid metal halides92Lanthanide-based ratiometric luminescence nanothermometry139Realizing High-Efficiency Yellow Emission of Organic Antimony Halides via Rational Structural Design105[PPh 3 H] 2 [SbCl 5 ]: A Zero-Dimensional Hybrid Metal Halide with a Supramolecular Framework and Stable Dual-Band Emission54Sequential and Reversible Phase Transformations in Zero‐Dimensional Organic‐Inorganic Hybrid Sb‐based Halides towards Multiple Emissions161Circularly Polarized Luminescence from Zero‐Dimensional Hybrid Lead‐Tin Bromide with Near‐Unity Photoluminescence Quantum Yield79Recent Progress of Bismuth Effect on All‐Inorganic Lead‐Free Metal Halide Derivatives: Crystals Structure, Luminescence Properties, and Applications70Mn 2+ -doped Cs 2 ZnBr 4 scintillator for X-ray imaging65Recent Advances on Mn2+‐Doping in Diverse Metal Halide Perovskites66Multiple Light Source-Excited Organic Manganese Halides for Water-Jet Rewritable Luminescent Paper and Anti-Counterfeiting68A Melt‐Quenched Luminescent Glass of an Organic–Inorganic Manganese Halide as a Large‐Area Scintillator for Radiation Detection50A Melt‐Quenched Luminescent Glass of an Organic–Inorganic Manganese Halide as a Large‐Area Scintillator for Radiation Detection201Near-unity quantum yield in zero-dimensional lead-free manganese-based halides for flexible X-ray imaging with high spatial resolution116In situ recrystallization of zero-dimensional hybrid metal halide glass-ceramics toward improved scintillation performance81Photophysical studies for Cu( i )-based halides: broad excitation bands and highly efficient single-component warm white-light-emitting diodes96Regulation and application of organic luminescence from low-dimensional organic–inorganic hybrid metal halides53Stepwise Crystalline Structural Transformation in 0D Hybrid Antimony Halides with Triplet Turn-on and Color-Adjustable Luminescence Switching58Variable halide perovskites: diversification of anti-counterfeiting applications49Highly Efficient, Flexible, and Eco-Friendly Manganese(II) Halide Nanocrystal Membrane with Low Light Scattering for High-Resolution X-ray Imaging87Temperature-Dependent Reversible Optical Properties of Mn-Based Organic–Inorganic Hybrid (C 8 H 20 N) 2 MnCl 4 Metal Halides94Chemical doping of lead-free metal-halide-perovskite related materials for efficient white-light photoluminescence61Single‐Component 0D Metal–Organic Halides with Color‐Variable Long‐Afterglow toward Multi‐Level Information Security and White‐Light LED123Highly Emissive Chiral Mn(II) Bromide Hybrids for UV‐Pumped Circularly Polarized LEDs and Scintillator Image Applications73Multi‐Responsive 0D Organic–Inorganic Hybrid Cuprous Bromides Constructed via Ultra‐Facile Approaches for Multimodal Luminescent Anti‐Counterfeiting54Ultrabright Light Emission Properties of All-Inorganic and Hybrid Organic–Inorganic Copper(I) Halides121Improving X-ray Scintillating Merits of Zero-Dimensional Organic–Manganese(II) Halide Hybrids via Enhancing the Ligand Polarizability for High-Resolution Imaging85Crystal-Liquid-Glass Transition and Near-Unity Photoluminescence Quantum Yield in Low Melting Point Hybrid Metal Halides116Intense Hydrochromic Photon Upconversion from Lead‐Free 0D Metal Halides For Water Detection and Information Encryption67Transparent glassy composites incorporating lead-free anti-perovskite halide nanocrystals enable tunable emission and ultrastable X-ray imaging51Anomalous Charge Transfer from Organic Ligands to Metal Halides in Zero‐Dimensional [(C6H5)4P]2SbCl5 Enabled by Pressure‐Induced Lone Pair‐π Interaction64Integrating Achiral and Chiral Organic Ligands in Zero‐Dimensional Hybrid Metal Halides to Boost Circularly Polarized Luminescence81Synthesis of Layered Lead-Free Perovskite Nanocrystals with Precise Size and Shape Control and Their Photocatalytic Activity74Theoretical and Experimental Advances in High-Pressure Behaviors of Nanoparticles46Achieving Highly Efficient Warm‐White Light Emission in All‐Inorganic Copper‐Silver Halides via Structural Regulation47Machine learning in analytical chemistry: From synthesis of nanostructures to their applications in luminescence sensing75Ultralow‐loss Optical Waveguides through Balancing Deep‐Blue TADF and Orange Room Temperature Phosphorescence in Hybrid Antimony Halide Microstructures144Reversible Triple-Mode Photo- and Radioluminescence and Nonlinear Optical Switching in Highly Efficient 0D Hybrid Cuprous Halides1090D Hybrid Cuprous Halide as an Efficient Light Emitter and X‐Ray Scintillator60Tailored ZnO nanostructures for efficient sensing of toxic metallic ions of drainage systems45Perovskite white light emitting diodes: A review58A novel thermally-stable single-phase phosphor Ca2InTaO6:Dy3+ for NUV-excited white LEDs60Water-Molecule-Induced Reversible Fluorescence in a One-Dimensional Mn-Based Hybrid Halide for Anticounterfeiting and Digital Encryption–Decryption75Manipulating Lone‐Pair‐Driven Luminescence in 0D Tin Halides by Pressure‐Tuned Stereochemical Activity from Static to Dynamic45A review of the relationship between the structure and nonlinear optical properties of organic-inorganic hybrid materials149Breaking the Inherent Interarrangement of [B3O6] Clusters for Nonlinear Optics with Orbital Hybridization Enhancement142Pressure-Regulated Excitonic Transitions in Emergent Metal Halides45Recent advances in lead-free Cs2ZrCl6 metal halide perovskites and their derivatives: From fundamentals to advanced applications52Highly Efficient and Flexible Scintillation Screen Based on Organic Mn(II) Halide Hybrids toward Planar and Nonplanar X‐Ray Imaging72Zero-Dimensional Hybrid Antimony Chloride with Near-Unity Broad-Band Orange-Red Emission toward Solid-State Lighting45A 0D hybrid lead-free halide with near-unity photoluminescence quantum yield toward multifunctional optoelectronic applications76Heterovalent Doping in CsCdCl3 Enabled Tunable Multimode Luminescence and Photochromism Toward Multilevel Anti‐Counterfeiting54Constructing Efficient and Thermostable Red‐NIR Emitter via Cross Relaxation and Crystal‐Field Engineering of Holmium‐Based Perovskite‐Type Half Metal68Multi-stimuli-responsive luminescence enabled by crown ether anchored chiral antimony halide phosphors54Supramolecular assembly of blue and green halide perovskites with near-unity photoluminescence166Capillary Manganese Halide Needle‐Like Array Scintillator with Isolated Light Crosstalk for Micro‐X‐Ray Imaging85Multisite Fine‐Tuning in Hybrid Cadmium Halides Enables Wide Range Emissions for Anti‐Counterfeiting92Blue‐Light‐Excitable Red‐to‐Near Infrared Photoluminescence in 0D Antimony(III) Bromide Hybrids for Supplemental Lighting55Integrating Full‐Color 2D Optical Waveguide and Heterojunction Engineering in Halide Microsheets for Multichannel Photonic Logical Gates61Solid‐State Photochemical Cascade Process Boosting Smart Ultralong Room‐Temperature Phosphorescence in Bismuth Halides95Efficient Circularly Polarized Luminescence and Bright White Emission from Hybrid Indium‐Based Perovskites via Achiral Building Blocks62Surfactant-Assisted Synthesis of Hybrid Copper(I) Halide Nanocrystals for X-ray Scintillation Imaging51Multiphase Transformation in Hybrid Copper(I)-Based Halides Enable Improved X-ray Scintillation and Real-Time Imaging95Achieving Strong Circularly Polarized Luminescence through Cascade Cationic Insertion in Lead‐free Hybrid Metal Halides63Near‐infrared emitting metal halide materials: Luminescence design and applications78Achieving Near‐Unity Red Light Photoluminescence in Antimony Halide Crystals via Polyhedron Regulation90Low‐Dimensional Metal Halide for High Performance Scintillators103Broad Dual Emission from Cs2Zr1–xMoxCl6: Enhancing the NIR Emission in Lead-free Vacancy Ordered Double Perovskites57A Luminescent Hybrid Bimetallic Halide Family with Solvent‐Coordinated Rare Earth and Alkaline Earth Metals54Rigid Phase Formation and Sb 3+ Doping of Tin (IV) Halide Hybrids toward Photoluminescence Enhancement and Tuning for Anti‐Counterfeiting and Information Encryption73Multimode Luminescence Tailoring in PMA 4 Na(In,Sb)Cl 8 Organic–inorganic Hybrid Metal Halide via Rigid Benzene Ring Induced Local Lattice Distortion58High‐Resolution X‐Ray Circular Polarization Imaging Enabled by Luminescent Photopolymerized Chiral Metal‐Organic Polymers51Hybrid Eu(II)-bromide scintillators with efficient 5d-4f bandgap transition for X-ray imaging97Advanced Organic–Inorganic Hybrid Materials for Optoelectronic Applications221Dynamic Phosphorescence/Fluorescence Switching in Hybrid Metal Halides Toward Time‐Resolved Multi‐Level Anti‐Counterfeiting59Naphthalenediimide and perylenediimide based donor-acceptor crystalline hybrid materials: Structures and applications90Excitation-mode-selective emission through multiexcitonic states in a double perovskite single crystal82Emerging 0D Hybrid Metal Halide Luminescent Glasses112Dynamic Ultralong Phosphorescence and Optical Waveguiding Switches in Silver‐Organic Complex via Reversible Single‐Crystal‐to‐Single‐Crystal Conversion58Crown Ether‐Assisted Alkali‐Metal Copper(I) Iodide Supramolecular Scintillators with Near‐Unity Emission for Ultrahigh‐Resolution X‐Ray Imaging57Mn(II)‐Based Hybrid Halide Ionogel Scintillator Film for Large‐Area and High‐Resolution X‐ray Imaging61A universal strategy toward two-component organic-inorganic metal halide luminescent glasses and glass-crystal composites51

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  38. Antimony‐Doped Lead‐Free Zero‐Dimensional Tin(IV)‐Based Organic–Inorganic Metal Halide Hybrids with High Photoluminescence Quantum Yield and Remarkable Stability

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  39. Two SbX5-based isostructural polar 1D hybrid antimony halides with tunable broadband emission, nonlinear optics, and semiconductor properties

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  40. 0D Perovskites: Unique Properties, Synthesis, and Their Applications

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  42. Selective Luminescence Response of a Zero-Dimensional Hybrid Antimony(III) Halide to Solvent Molecules: Size-Effect and Supramolecular Interactions

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  43. Guest-Induced Reversible Phase Transformation of Organic–Inorganic Phenylpiperazinium Antimony (III) Chlorides with Solvatochromic Photoluminescence

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  44. Blue light-emitting diodes based on halide perovskites: Recent advances and strategies

    Materials Today · 2021-11-10

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  45. Simultaneous Synthesis, Modification, and DFT Calculation of Three‐Color Lead Halide Perovskite Phosphors for Improving Stability and Luminous Efficiency of WLEDs

    Advanced Optical Materials · 2021-11-18

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  46. Pressure‐Treated Engineering to Harvest Enhanced Green Emission in Mn‐Based Organic–Inorganic Metal Halides at Ambient Conditions

    Advanced Functional Materials · 2021-11-23

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  47. Recent Advances in All‐Inorganic Zero‐Dimensional Metal Halides

    ChemPlusChem · 2021-11-25

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  48. Synergistic electronic coupling/cross-talk between the isolated metal halide units of zero dimensional heterometallic (Sb, Mn) halide hybrid with enhanced emission

    Journal of Materials Chemistry C · 2021-11-29

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  49. Exploring the Ruddlesden–Popper layered organic–inorganic hybrid semiconducting perovskite for visible-blind ultraviolet photodetection

    CrystEngComm · 2021-12-01

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