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RESEARCH PAPER · Advanced Optical Materials · 2020

Recent Progress in 2D Metal‐Organic Frameworks for Optical Applications

Yongshen Zheng, Fang‐Zhou Sun, Xiao Han, Jialiang Xu, Xian‐He Bu

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Recent Progress in 2D Metal‐Organic Frameworks for Optical ApplicationsOriginalMetal–organic frameworks with solvent-free lanthanide coordination environments: synthesis from aqueous ethanol solutions8A self-made portable separation device based on 2-D MOF nanosheets for the efficient separation of dyes in solutions10Hydrangea-like architectures composed of Zr-based metal–organic framework nanosheets with enhanced iodine capture6Novel synthesis of in situ CeO x nanoparticles decorated on CoP nanosheets for highly efficient electrocatalytic oxygen evolution22Structural Variation and Switchable Nonlinear Optical Behavior of Metal–Organic Frameworks50Aggregation‐induced emission materials for nonlinear optics86Strongly Coupled Systems for Nonlinear Optics57Two-Dimensional Metal-Organic Framework Materials: Synthesis, Structures, Properties and Applications927MnO2 decorated ZIF-8@GOx for synergistic chemodynamic and starvation therapy of cancer28Metal/Covalent‐Organic Framework Based Cathodes for Metal‐Ion Batteries278Enhanced photoluminescence quantum yield of terbium nano-MOFs synthesized by microwave assisted solvothermal method15Two‐Dimensional Metal–Organic Frameworks and Covalent–Organic Frameworks for Electrocatalysis: Distinct Merits by the Reduced Dimension166Crystalline Metal‐Organic Materials with Thermally Activated Delayed Fluorescence59Recent development on the alkaline earth MOFs (AEMOFs)59Energy Conversion in Single‐Crystal‐to‐Single‐Crystal Phase Transition Materials86Nonlinear Optical Properties and Applications of Fluorenone Molecular Materials161Photonic Metal‐Organic Frameworks31MOF-based multi-stimuli-responsive supramolecular nanoplatform equipped with macrocycle nanovalves for plant growth regulation62Transforming 3D CAU‐10‐H into 2D Materials with High Base Stability for Membrane Separation12Two‐dimensional MOFs: Design & Synthesis and Applications51Recent Progress in Metal‐Organic Frameworks@Cellulose Hybrids and Their Applications61Design of two-dimensional metal–organic framework nanosheets for emerging applications22Metal–Organic Framework Photonic Balls: Single Object Analysis for Local Thermal Probing56Soft Metal–Organic Frameworks Based on {Na@Ln6} as a Secondary Building Unit Featuring a Magnetocaloric Effect and Fluorescent Sensing for Cyclohexane and Fe3+10High‐Efficiency Wideband Excitable Mechanoluminescence from a Yellow MOF Phosphor as White LED and Multicolor Thin Films31Structures and electronic properties of functional molecules on metal substrates: From single molecule to self‐assemblies9Synthesis and Mechanical Properties of sub 5‐μm PolyUiO‐66 Thin Films on Gold Surfaces5Synthesis of Two New Dinuclear Lanthanide Clusters and Visual Bifunctional Sensing Devices Based on the Eu Cluster42Multi-Assembled Nanofiltration Membranes with Excellent Separation and Catalytic Performance0Multi-Assembled Nanofiltration Membranes with Excellent Separation and Catalytic Performance0Organic ultrathin nanostructure arrays: materials, methods and applications7Fabrication Technologies for the On‐Chip Integration of 2D Materials240Optical and charge transfer properties of a new cadmium based metal-organic-framework material6Metal-organic framework/conductive polymer hybrid materials for supercapacitors1022D Materials for Wearable Energy Harvesting48Metal organic frameworks as advanced extraction adsorbents for separation and analysis in proteomics and environmental research36Synthesis and structural characterization of a luminescent cadmium(II) complex with bis(4-(1H-imidazole-1-yl)phenyl)amine and 4,4′-sulfonyldibenzoate ligands0Sensing Capacity in Dysprosium Metal–Organic Frameworks Based on 5-Aminoisophthalic Acid Ligand4Metal‐Organic Framework Nanosheets as Templates to Enhance Performance in Semi‐Crystalline Organic Photovoltaic Cells18Bifunctional Fe@PCN-222 nanozyme-based cascade reaction system: Application in ratiometric fluorescence and colorimetric dual-mode sensing of glucose17Advances in 2D coordination networks for single‐crystal‐to‐single‐crystal applications beyond confined pores13Rational design and synthesis of two-dimensional conjugated metal-organic polymers for electrocatalysis applications145Metal–organic frameworks and derived materials as photocatalysts for water splitting and carbon dioxide reduction2062D MOF Nanosensor‐Integrated Digital Droplet Microfluidic Flow Cytometry for In Situ Detection of Multiple miRNAs in Single CTC Cells54Advances and challenges in two-dimensional materials for oxygen evolution90Defect Engineering in a Metal–Organic Framework System to Achieve Super-Protonic Conductivity80Lanthanoid hydrogen-bonded organic frameworks: Enhancement of luminescence by the coordination-promoted antenna effect and applications in heavy-metal ion sensing and sterilization100Integration and Applications of Nanomaterials for Ultrafast Photonics71Recent Advances on Molecule‐Based Micro/Nanocrystal Heterojunctions for Optical Applications15A new mode of luminescence in lanthanide oxalates metal–organic frameworks31Strong interfacial interactions of ZnS/Cu-TCPP hybrids contribute to excellent nonlinear optical absorption25A Doubly Interpenetrated Cu(II)‐based Metal‐Organic Framework as a Heterogeneous Catalyst for the ipso‐Hydroxylation of Arylboronic Acids9Two-dimensional nanomaterials: A critical review of recent progress, properties, applications, and future directions450Bimetallic conjugated metal–organic frameworks as bifunctional electrocatalysts for overall water splitting15Development of high refractive index UiO-66 framework derivatives via ligand halogenation13Fragment-based approach for the efficient calculation of the refractive index of metal–organic frameworks12Porous crystalline materials for memories and neuromorphic computing systems166Tunable electronic and magnetic properties of planar and corrugated phases of two-dimensional metal–organic frameworks5Tuning the optical properties of the metal–organic framework UiO-66 via ligand functionalization52Review of c(3) Optical Nonlinearities in 2D Materials for Telecommunications Applications1Nonlinear optical limiting effect and charge transfer dynamics in a Fe-porphyrin metal-organic framework15A review of telecommunications applications of X(3) optical non-linearities of 2D materials0A review of telecommunications applications of X(3) optical non-linearities of 2D materials2Third-Order Optical Nonlinearities of 2D Materials at Telecommunications Wavelengths141In Silico High-Throughput Design and Prediction of Structural and Electronic Properties of Low-Dimensional Metal–Organic Frameworks32Layer-by-layer assembly of metal-organic framework thin films: Fabrication and advanced applications64Theoretical survey on the electronic, linear and nonlinear optical properties of substituted benzenes and polycondensed π-systems. A density functional theory study11Multi‐assembled nanofiltration membranes with excellent separation and catalytic performance2Enhancing CO2 Electroreduction to Ethylene via Copper−Silver Tandem Catalyst in Boron‐Imidazolate Framework Nanosheet76Fabrication and Applications of Heterostructure Materials for Broadband Ultrafast Photonics39Cd(II)/Mn(II)/Co(II)/Ni(II)/Zn(II) Coordination Polymers Built from Dicarboxylic Acid/Tetracarboxylic Acid Ligands: Their Structural Diversity and Fluorescence Properties2Construction of a novel two-dimensional coordination polymer based on picolinic acid-containing ligand for the effective elimination of organic dyes from wastewater3Electrochemical aptasensor based on the engineered core-shell MOF nanostructures for the detection of tumor antigens50Pyrene‐Based Polyimide Covalent Organic Framework with Temperature‐Dependent Fluorescence15Electronically tunable cyanoethynylethenes and Tetracyanobuta-1, 3-dienes based Push–pull organic chromophores for enhanced nonlinear optical Activity: A DFT perspective11MXene-based heterostructures: Current trend and development in electrochemical energy storage devices142Preparation of two‐dimensional porphyrin‐based MOFs/derivatives and their potential in sensing and biomedical applications20Cu-Based Tris(chloropropyl) Phosphate MOF Nanosheets for Surface Plasmon Resonance-Based Fiber-Optic Biosensing11Ozonolysis–oxidation-driven top-down strategy for the target preparation of ultrathin 2D metal–organic framework monolayers14Crystal Sponge Behavior in a Two-Dimensional Rare-Earth Hybrid Coordinate Polymer13Interfacial Engineering of Two-Dimensional Metal–Organic Framework Thin Films for Biomimetic Photoadaptative Sensors12Achieving High Intrinsic Proton Conductivity via Functionalization of MOF-808 by Ionic Liquid60Third-order nonlinear optical response of 2D materials in the telecom band0Third-order nonlinear optical response of 2D materials in the telecom band0Enhancing Gas Adsorption/Desorption Performance of Optical Fiber Pressure Sensor Using MOF Composite6Optical nonlinearity of 2D materials0Scalable and sustainable manufacturing of ultrathin metal–organic framework nanosheets (MONs) for solar cell applications12Single-crystal metal-organic frameworks for electronic and opto-electronic devices33Amyloid detection in neurodegenerative diseases using MOFs16Bioinspired 2D nanofluidic membranes for energy applications100Perspective into ion storage of pristine metal-organic frameworks in capacitive deionization26Recent advances of 2D metal-organic frameworks for electrochemical carbon dioxide reduction6Fabrication and sensing properties of a molecularly imprinted polymer on a photonic PDMS substrate for the optical detection of C-reactive protein23In Situ Exfoliation Growth Strategy Realizing Controlled Synthesis of 3D to 2D MOF Materials as High-Performance Electrochemical Biosensors11Recent and emerging trends of metal-organic frameworks (MOFs)-based sensors for detecting food contaminants: A critical and comprehensive review266Laser Processing of Emerging Nanomaterials for Optoelectronics and Photocatalysis27UiO-66 uniformly assembled foldable polyimide films with high transmittance and excellent ultraviolet resistance4Emerging trends and future challenges of advanced 2D nanomaterials for combating bacterial resistance50C-doped MoSeTe for SO2, H2S, Cl2 gas sensing study based on first-principles4Utilizing excited-state proton transfer fluorescence quenching mechanism, layered rare earth hydroxides enable ultra-sensitive detection of nitroaromatic14Central Metal-Triggered Structural Transformation of a 2D Layered MOF: Mechanistic Studies and Applications4Photocatalytic degradation of perfluorooctanoic acid (PFOA) by metal organic framework MIL-177-HT: New insights into the role of specific surface area, charge separation and dimensionality38Two-dimensional nano-biomaterials in regulating the tumor microenvironment for immunotherapy40Defect engineering strategies in monolayer VSe2 for enhanced hydrogen evolution reaction: a computational study5Revealing the structural and optical constant of the UiO-66 coated with MoS2 QDs1Modeling of graphene like structure by utilizing phenanthrocarbazole for tailoring the second-order nonlinear optical properties2Microstructural Regulation of Co TCPP by Acetylene Black: Enhanced Electrochemical Performance for Wearable Supercapacitors1“Delocalized π-bond” guided pyramidal nanocrystal superstructures for excellent light trapping in SERS9Nanomaterials for Flexible Neuromorphics105Synthesis of Homochiral N‐Heterocyclic Carbene‐Based Nanosheets for Enhanced Asymmetric Catalysis14Recent Advancement in 2D Metal–Organic Framework for Environmental Remediation: A Review48Tuning the morphology and energy levels in organic solar cells with metal–organic framework nanosheets6Advancements in framework materials for enhanced energy harvesting26A ferroelectric proton conductor with colossal polarization induced by in-plane symmetry breaking in a two-dimensional coordination polymer9Enhancements of the first and second hyperpolarizability of a GMP coordination polymer: crystal structure and computational studies19Metal-organic-frameworks (MOFs) advanced synthetic strategies and applications, including light emitting diodes, solar cells and photodetectors9A universal three-dimensional metal-organic frameworks assisted strategy facilitates non-covalent interaction of active/interfacial layers for over 19 % efficiency organic photovoltaics1Recent Progresses in Two‐Dimensional Carbon‐Metal Composites for Catalysis Applications4Postsynthetic Modification of Metal–Organic Layers15On the Importance of Squaramide and Squarate Derivatives as Metal–Organic Framework Building Blocks02D/2D MOF/MXene Schottky Junction: Prolonged Carrier Lifetime and Enhanced Hydrogen Evolution Efficiency12D/2D MOF/MXene Schottky Junction: Prolonged Carrier Lifetime and Enhanced Hydrogen Evolution Efficiency73Recent developments in the incorporation of 1D/2D nanofillers in polymer derived ceramics—a review21Optimizing the Structure and Performances of Cu-MOF@Ti3C2TX Hybrid Electrodes by Introducing Modulated Ligand7Turning Defects Into Advantages: Structures, Synthesis, and Applications of 2D Amorphous Carbon12Synthesis and Structure of Metal–Organic Coordination Polymer Based on Lanthanum(III) and Brominated Terphenyldicarboxylic Acid0Calculation of the Refractive Index of Metal-Organic Frameworks Using Empirical Electronic Polarizabilities2Controlled surface chiral modification of 2D layered MOFs matrices for full-color circularly polarized luminescence1Fundamentals of charge transport in two-dimensional framework materials23Prospects of two-dimensional nanoscale functional materials with relevance in sensing and actuation0Water-stable metal-organic frameworks-based materials as optical sensors0Faradaic and Nonfaradaic Electrode Innovations on Brackish Water Reduction by Capacitive Deionization: A Critical Review9Computational study on optoelectronic properties of perylene diimide derivatives and their supramolecular complexes with guanosine monophosphate2Impact of 2D nanomaterials on adsorption performances0Integrating intrinsic charge-trapping sites in an insulated MOF nanoparticle-based dielectric layer for effective photo/synaptic transistors0Layered sql-type cobalt triazine-carboxylate MOF for enhanced pseudocapacitance and visible-light hydrogen evolution5Synergistic NiCo-MOF–rGO scalable hybrid composite for advanced energy storage0Recent Advances in Metal‐Organic Framework‐Integrated Nanocomposite Hydrogels for Sensors and Sensing Systems14Functional pyromellitic diimides: the revolutionizing building blocks for supramolecular organic and metal organic frameworks2The Metal Coordination Effects on the Optoelectronic Properties of Perylene Diimide and Nucleotide Supramolecular Complex (GMP:PDI: Ag(I)/Co(II)/Zn(II)): Computational and Experimental Studies3Enhanced Light-Responsive Proton Conduction in MOF-808 via Cooperative Azobenzene and Ionic Liquid Functionalization3Intercalation-engineered MOF for ultrasensitive ratiometric fluorescent sensing of enoxacin0Two‐Dimensional Frameworks From Metal Oxo Clusters at Liquid Interfaces1Spin Meets the Light: Emergence of Paramagnetic Metal‐organic Frameworks (PMOFs) for Optical and Electrochemical Sensing Over the Last Five Years2Advancing metal ions detection with porphyrinic coordination organic framework optical sensors0Confining a Keggin-Type Polyoxometalate in AIE-Active Co-MOF for Productive Photocatalytic Water Oxidation0Tunable third-order nonlinear optical response of MIL-88B-derived Fe3O4: Solvent and magnetic-field effects02D organic framework membranes: extending functions in natural ion channels to scalable nanofluidic applications0Giant Negative Linear Compression along the Stacking Direction of a Highly Compressive Two-Dimensional Coordination Polymer0

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  47. Lanthanoid hydrogen-bonded organic frameworks: Enhancement of luminescence by the coordination-promoted antenna effect and applications in heavy-metal ion sensing and sterilization

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  48. Integration and Applications of Nanomaterials for Ultrafast Photonics

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  49. Recent Advances on Molecule‐Based Micro/Nanocrystal Heterojunctions for Optical Applications

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  50. A new mode of luminescence in lanthanide oxalates metal–organic frameworks

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