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RESEARCH PAPER · Journal of the American Chemical Society · 2019

Solar-Driven Photoelectrochemical Water Oxidation over an n-Type Lead–Titanium Oxyfluoride Anode

Naoki Hirayama, Hiroko Nakata, Haruki Wakayama, Shunta Nishioka, Tomoki Kanazawa, Ryutaro Kamata, Yosuke Ebato, Kosaku Kato, Hiromu Kumagai, Akira Yamakata, Kengo Oka, Kazuhiko Maeda

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Solar-Driven Photoelectrochemical Water Oxidation over an n-Type Lead–Titanium Oxyfluoride AnodeOriginalOxyfluoride Pb2Ti4O9F2 as a Stable Anode Material for Photoelectrochemical Water Oxidation20Activation of a Pt-loaded Pb 2 Ti 2 O 5.4 F 1.2 photocatalyst by alkaline chloride treatment for improved H 2 evolution under visible light14The effect of the photochemical environment on photoanodes for photoelectrochemical water splitting19Light Absorption Properties and Electronic Band Structures of Lead‐Vanadium Oxyhalide Apatites Pb5(VO4)3X (X=F, Cl, Br, I)12Water Oxidation through Interfacial Electron Transfer by Visible Light Using Cobalt-Modified Rutile Titania Thin-Film Photoanode16Ultra‐Narrow Depletion Layers in a Hematite Mesocrystal‐Based Photoanode for Boosting Multihole Water Oxidation86Ultra‐Narrow Depletion Layers in a Hematite Mesocrystal‐Based Photoanode for Boosting Multihole Water Oxidation8Site-Selective Deposition of a Cobalt Cocatalyst onto a Plasmonic Au/TiO2 Photoanode for Improved Water Oxidation41Recent Progress in Mixed‐Anion Materials for Solar Fuel Production58Structural Properties of NdTiO2+ x N1– x and Its Application as Photoanode15A bifunctional lead–iron oxyfluoride, PbFeO 2 F, that functions as a visible-light-responsive photoanode and an electrocatalyst for water oxidation5Photoelectrochemical H 2 evolution on WO 3 /BiVO 4 enabled by single-crystalline TiO 2 overlayer modulations28Amorphous Iron–Manganese Oxyfluorides, Promising Catalysts for Oxygen Evolution Reaction under Acidic Media48Recent Developments in the Use of Heterogeneous Semiconductor Photocatalyst Based Materials for a Visible-Light-Induced Water-Splitting System—A Brief Review65Review on the hazardous applications and photodegradation mechanisms of chlorophenols over different photocatalysts203A pressure-assisted low temperature sintering of particulate bismuth chalcohalides BiSX (X = Br, I) for fabricating efficient photoelectrodes with porous structures6Sn-Based Perovskite with a Wide Visible-Light Absorption Band Assisted by Hydride Doping16Improvement of a Pb2Ti2O5.4F1.2 Photoanode for Solar Water Splitting by Refining the Cocatalyst and Electrolyte8Durable Metal Heteroanionic Photocatalysts24Exploring novel functional properties arose from anion order in mixed anion compounds1Polypyrrole Serving as Multifunctional Surface Modifier for Photoanode Enables Efficient Photoelectrochemical Water Oxidation33Recent Progress on Mixed-Anion Materials for Energy Applications110A two-dimensional perovskite oxyfluoride Pb 3 Fe 2 O 5 F 2 as a catalyst for electrochemical oxidation of water to oxygen9Multi anion-based materials: Synthesis and catalytic applications30Fluorine-Assisted Low-Temperature Synthesis of GaN:ZnO-Related Solid Solutions with Visible-Light Photoresponse5Hydrogen-Bonded Aggregates Featuring n → π* Electronic Transition for Efficient Visible-Light-Responsive Photocatalysis40Synergy of nitrogen vacancies and Fe2P cocatalyst on graphitic carbon nitride for boosting photocatalytic CO2 conversion45Improvement of Visible‐Light H2 Evolution Activity of Pb2Ti2O5.4F1.2 Photocatalyst by Coloading of Rh and Pd Cocatalysts5Photoelectrochemical Water Oxidation Using Cobalt Phosphate‐Modified Nitrogen‐Doped Titania Nanotube Arrays7Structure, materials, and preparation of photoelectrodes5Molten Salts‐Driven Discovery of a Polar Mixed‐Anion 3D Framework at the Nanoscale: Zn4Si2O7Cl2, Charge Transport and Photoelectrocatalytic Water Splitting1Molten Salts‐Driven Discovery of a Polar Mixed‐Anion 3D Framework at the Nanoscale: Zn4Si2O7Cl2, Charge Transport and Photoelectrocatalytic Water Splitting0Aggregation‐Induced Structural Symmetry Breaking Promotes Charge Separation for Efficient Photocatalytic Hydrogen Production20Reduction of a Band Gap and Visible-Light Photocatalytic Activity Induced by the Interaction between 6s and 2p Orbitals known as Revised Lone Pair Model0Low-Temperature Microwave-Assisted Hydrothermal Synthesis of Pb2Ti2O5.4F1.2 Photocatalyst for Improved H2 Evolution under Visible Light16Photoelectrochemical Water Oxidation over Pb2Ti2O5.4F1.2 Photoanodes Prepared by the Particle Transfer Method5Gradient oxygen doping triggered a microscale built-in electric field in CdIn 2 S 4 for photoelectrochemical water splitting15Anchoring MoS2 microflowers on oxygen-doped g-C3N4 nanosheets to construct Z-Scheme hybrid compositesfor efficient photocatalytic hydrogen production1Modification of Visible‐Light‐Responsive Pb2Ti2O5.4F1.2 with Metal Oxide Cocatalysts to Improve Photocatalytic O2 Evolution toward Z‐Scheme Overall Water Splitting7Anchoring MoS2 microflowers on oxygen-doped g-C3N4 nanosheets to construct Z-scheme hybrid composites for photocatalytic hydrogen production2Energy band modulation of N‐doped rutile/anatase TiO 2 photoanode promoting charge separation toward prominent photoelectrochemical performance20Oxyfluorides for electrochemical and photoelectrochemical water oxidation: a review and basic tutorial0Emerging Mixed-Anion Semiconductors for Particulate Photocatalytic Water Splitting: Remarkable Structures and Innovative Fabrication Methods7Mesoporous Oxyhalide Aggregates Exhibiting Improved Photocatalytic Activity for Visible-Light H2 Evolution and CO2 Reduction7Photo-Driven Acceleration of Oxidation Kinetics in Aqueous Zinc–Sulfur Batteries1Enhanced visible-light-driven photocatalytic Cr( vi ) reduction over La-doped In 2 S 3 : performance and mechanistic insights0Photocorrosion in semiconductor photocatalysts: mechanisms, suppression, and use in functional material design2Reductive-defect-suppressed titanium oxynitrides via Ca 3 N 2 -assisted topochemical nitridation0In Situ X-ray Absorption Fine Structure Spectroscopy Measurement of Suspended Cobalt Oxide Nanoparticle Water Oxidation Catalyst0Construction of g-C3N4 quantum dot-decorated TiO2 heterojunction for highly efficient and stable photocatalytic CO2 reduction3Spectroelectrochemical Evolution of Fluorine-Doped Tin Oxide in Aqueous Electrolyte0

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  1. Oxyfluoride Pb2Ti4O9F2 as a Stable Anode Material for Photoelectrochemical Water Oxidation

    The Journal of Physical Chemistry C · 2019-12-31

    Kazuhiko Maeda, Naoki Hirayama, Hiroko Nakata, Haruki Wakayama, Kengo Oka

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  2. Activation of a Pt-loaded Pb 2 Ti 2 O 5.4 F 1.2 photocatalyst by alkaline chloride treatment for improved H 2 evolution under visible light

    Journal of Materials Chemistry A · 2020-01-01

    Haruki Wakayama, Kosaku Kato, Kodai Kashihara, Tomoki Uchiyama, Akinobu Miyoshi, Hiroko Nakata, Daling Lu, Kengo Oka, Akira Yamakata, Yoshiharu Uchimoto, Kazuhiko Maeda

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  3. The effect of the photochemical environment on photoanodes for photoelectrochemical water splitting

    Dalton Transactions · 2020-01-01

    Xiaoqian Huang, Yanfei Li, Xiaoru Gao, Qihui Xue, Ruikang Zhang, Yuanzhe Gao, Zhangang Han, Mingfei Shao

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  4. Light Absorption Properties and Electronic Band Structures of Lead‐Vanadium Oxyhalide Apatites Pb5(VO4)3X (X=F, Cl, Br, I)

    Chemistry - An Asian Journal · 2020-01-08

    Masashi Nakamura, Kenji Oqmhula, Keishu Utimula, Miharu Eguchi, Kengo Oka, Kenta Hongo, Ryo Maezono, Kazuhiko Maeda

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  5. Water Oxidation through Interfacial Electron Transfer by Visible Light Using Cobalt-Modified Rutile Titania Thin-Film Photoanode

    ACS Applied Materials & Interfaces · 2020-01-31

    Hideyuki Tanaka, Tomoki Uchiyama, Nozomi Kawakami, Megumi Okazaki, Yoshiharu Uchimoto, Kazuhiko Maeda

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  6. Ultra‐Narrow Depletion Layers in a Hematite Mesocrystal‐Based Photoanode for Boosting Multihole Water Oxidation

    Angewandte Chemie International Edition · 2020-03-16

    Zhujun Zhang, Hiroki Nagashima, Takashi Tachikawa

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  7. Ultra‐Narrow Depletion Layers in a Hematite Mesocrystal‐Based Photoanode for Boosting Multihole Water Oxidation

    Angewandte Chemie · 2020-03-16

    Zhujun Zhang, Hiroki Nagashima, Takashi Tachikawa

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  8. Site-Selective Deposition of a Cobalt Cocatalyst onto a Plasmonic Au/TiO2 Photoanode for Improved Water Oxidation

    ACS Applied Energy Materials · 2020-05-27

    Megumi Okazaki, Yoshiki Suganami, Naoki Hirayama, Hiroko Nakata, Tomoya Oshikiri, Toshiyuki Yokoi, Hiroaki Misawa, Kazuhiko Maeda

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  9. Recent Progress in Mixed‐Anion Materials for Solar Fuel Production

    Solar RRL · 2020-10-24

    Akinobu Miyoshi, Kazuhiko Maeda

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  10. Structural Properties of NdTiO2+ x N1– x and Its Application as Photoanode

    Inorganic Chemistry · 2020-12-29

    Zili Ma, Kaixuan Chen, Aleksander Jaworski, Jianhong Chen, Anna Rokicińska, Piotr Kuśtrowski, Richard Dronskowski, Adam Slabon

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  11. A bifunctional lead–iron oxyfluoride, PbFeO 2 F, that functions as a visible-light-responsive photoanode and an electrocatalyst for water oxidation

    RSC Advances · 2021-01-01

    Ryusuke Mizuochi, Kazunari Izumi, Yoshiyuki Inaguma, Kazuhiko Maeda

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  12. Photoelectrochemical H 2 evolution on WO 3 /BiVO 4 enabled by single-crystalline TiO 2 overlayer modulations

    Nanoscale · 2021-01-01

    Eunoak Park, Santosh S. Patil, Hyeonkwon Lee, Vijay S. Kumbhar, Kiyoung Lee

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  13. Amorphous Iron–Manganese Oxyfluorides, Promising Catalysts for Oxygen Evolution Reaction under Acidic Media

    ACS Applied Energy Materials · 2021-01-18

    Kévin Lemoine, Zahra Goharibajestani, Romain Moury, Alexandre Terry, Amandine Guiet, Jean−Marc Grenèche, Annie Hémon‐Ribaud, Nina Heidary, V. Maisonneuve, Nikolay Kornienko, Jérôme Lhoste

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  14. Recent Developments in the Use of Heterogeneous Semiconductor Photocatalyst Based Materials for a Visible-Light-Induced Water-Splitting System—A Brief Review

    Catalysts · 2021-01-25

    Prabhakarn Arunachalam, Keiji Nagai, Mabrook S. Amer, Mohamed A. Ghanem, Rajabathar Jothi Ramalingam, Abdullah Mohammed Al-Mayouf

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  15. Review on the hazardous applications and photodegradation mechanisms of chlorophenols over different photocatalysts

    Environmental Research · 2021-01-27

    Amir Zada, Muhammad Khan, Muhammad Asim Khan, Qasim Khan, Aziz Habibi‐Yangjeh, Alei Dang, Muhammad Maqbool

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  16. A pressure-assisted low temperature sintering of particulate bismuth chalcohalides BiSX (X = Br, I) for fabricating efficient photoelectrodes with porous structures

    Journal of Photochemistry and Photobiology A Chemistry · 2021-03-23

    Naoyuki Nishimura, Hajime Suzuki, Masanobu Higashi, Ryu Abe

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  17. Sn-Based Perovskite with a Wide Visible-Light Absorption Band Assisted by Hydride Doping

    Chemistry of Materials · 2021-05-04

    Masashi Nakamura, Hiroshi K. WATANABE, Hirofumi Akamatsu, Kotaro Fujii, Masatomo Yashima, George Hasegawa, Miki Inada, Katsuro Hayashi, Kazuhiko Maeda

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  18. Improvement of a Pb2Ti2O5.4F1.2 Photoanode for Solar Water Splitting by Refining the Cocatalyst and Electrolyte

    Bulletin of the Chemical Society of Japan · 2021-05-14

    Kazuhiko Maeda, Naoki Hirayama, Hiroko Nakata, Kengo Oka

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  19. Durable Metal Heteroanionic Photocatalysts

    ACS Applied Materials & Interfaces · 2021-07-28

    Kaustav Chatterjee, Sara E. Skrabalak

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  20. Exploring novel functional properties arose from anion order in mixed anion compounds

    Journal of the Ceramic Society of Japan · 2021-08-31

    Kengo Oka

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  21. Polypyrrole Serving as Multifunctional Surface Modifier for Photoanode Enables Efficient Photoelectrochemical Water Oxidation

    Small · 2021-11-05

    Weiwei Xu, Linxing Meng, Wei Tian, Shengnan Li, Fengren Cao, Liang Li

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  22. Recent Progress on Mixed-Anion Materials for Energy Applications

    Bulletin of the Chemical Society of Japan · 2021-11-15

    Kazuhiko Maeda, Fumitaka Takeiri, Genki Kobayashi, Satoru Matsuishi, Hiraku Ogino, Shintaro Ida, Takao Mori, Yoshiharu Uchimoto, Setsuhisa Tanabe, Tetsuya Hasegawa, Nobuhito Imanaka, Hiroshi Kageyama

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  23. A two-dimensional perovskite oxyfluoride Pb 3 Fe 2 O 5 F 2 as a catalyst for electrochemical oxidation of water to oxygen

    Sustainable Energy & Fuels · 2022-01-01

    Ryusuke Mizuochi, Kengo Oka, Yoshiyuki Inaguma, Kazuhiko Maeda

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  24. Multi anion-based materials: Synthesis and catalytic applications

    Materials Research Bulletin · 2022-03-27

    Gaurav Yadav, Md. Ahmaruzzaman

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  25. Fluorine-Assisted Low-Temperature Synthesis of GaN:ZnO-Related Solid Solutions with Visible-Light Photoresponse

    ACS Applied Materials & Interfaces · 2022-04-22

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  26. Hydrogen-Bonded Aggregates Featuring n → π* Electronic Transition for Efficient Visible-Light-Responsive Photocatalysis

    ACS Catalysis · 2022-05-12

    Pengju Yang, Ya Zhang, Hongxia Zhang, Jianghong Zhao, Zhihong Wei, Hu Shi, Zhanfeng Zheng, Yamin Huang, Hengquan Yang

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  27. Synergy of nitrogen vacancies and Fe2P cocatalyst on graphitic carbon nitride for boosting photocatalytic CO2 conversion

    Chemical Engineering Journal · 2022-05-21

    Xiangli Shi, Pengfei An, Qiong Zhang, Qi Song, Deli Jiang, Dan Bi Tian, Di Li

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  28. Improvement of Visible‐Light H2 Evolution Activity of Pb2Ti2O5.4F1.2 Photocatalyst by Coloading of Rh and Pd Cocatalysts

    Chemistry - A European Journal · 2022-05-27

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  29. Photoelectrochemical Water Oxidation Using Cobalt Phosphate‐Modified Nitrogen‐Doped Titania Nanotube Arrays

    Small Structures · 2022-11-29

    Unseock Kang, Ryusuke Mizuochi, Hyunwoong Park, Kazuhiko Maeda

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  30. Structure, materials, and preparation of photoelectrodes

    Elsevier eBooks · 2023-01-01

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  31. Molten Salts‐Driven Discovery of a Polar Mixed‐Anion 3D Framework at the Nanoscale: Zn4Si2O7Cl2, Charge Transport and Photoelectrocatalytic Water Splitting

    Angewandte Chemie International Edition · 2023-04-12

    Ram Kumar, Yang Song, Anissa Ghoridi, Philippe Boullay, Gwenaëlle Rousse, Christel Gervais, Cristina Coelho, Houria Kabbour, Capucine Sassoye, Patricia Beaunier, Victor Castaing, Bruno Viana, M. Luisa Ruiz‐González, José María González-Calbet, Christel Laberty‐Robert, David Portehault

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  32. Molten Salts‐Driven Discovery of a Polar Mixed‐Anion 3D Framework at the Nanoscale: Zn4Si2O7Cl2, Charge Transport and Photoelectrocatalytic Water Splitting

    Angewandte Chemie · 2023-04-12

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  33. Aggregation‐Induced Structural Symmetry Breaking Promotes Charge Separation for Efficient Photocatalytic Hydrogen Production

    ChemSusChem · 2023-04-20

    Tian He, Ya Zhang, Hongxia Zhang, Jianghong Zhao, Hu Shi, Hengquan Yang, Pengju Yang

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  34. Reduction of a Band Gap and Visible-Light Photocatalytic Activity Induced by the Interaction between 6s and 2p Orbitals known as Revised Lone Pair Model

    Journal of the Japan Society of Colour Material · 2023-05-20

    Kengo Oka, Naoki Noma, Mitsunobu Iwasaki

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  35. Low-Temperature Microwave-Assisted Hydrothermal Synthesis of Pb2Ti2O5.4F1.2 Photocatalyst for Improved H2 Evolution under Visible Light

    ACS Materials Letters · 2023-08-02

    Kenta Aihara, Ryusuke Mizuochi, Megumi Okazaki, Shunta Nishioka, Shuhei Yasuda, Toshiyuki Yokoi, Fumitaka Ishiwari, Akinori Saeki, Miki Inada, Kazuhiko Maeda

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  36. Photoelectrochemical Water Oxidation over Pb2Ti2O5.4F1.2 Photoanodes Prepared by the Particle Transfer Method

    The Journal of Physical Chemistry C · 2023-10-31

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  37. Gradient oxygen doping triggered a microscale built-in electric field in CdIn 2 S 4 for photoelectrochemical water splitting

    Nanoscale · 2024-01-01

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  38. Anchoring MoS2 microflowers on oxygen-doped g-C3N4 nanosheets to construct Z-Scheme hybrid compositesfor efficient photocatalytic hydrogen production

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  39. Modification of Visible‐Light‐Responsive Pb2Ti2O5.4F1.2 with Metal Oxide Cocatalysts to Improve Photocatalytic O2 Evolution toward Z‐Scheme Overall Water Splitting

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  40. Anchoring MoS2 microflowers on oxygen-doped g-C3N4 nanosheets to construct Z-scheme hybrid composites for photocatalytic hydrogen production

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  41. Energy band modulation of N‐doped rutile/anatase TiO 2 photoanode promoting charge separation toward prominent photoelectrochemical performance

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  42. Oxyfluorides for electrochemical and photoelectrochemical water oxidation: a review and basic tutorial

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  43. Emerging Mixed-Anion Semiconductors for Particulate Photocatalytic Water Splitting: Remarkable Structures and Innovative Fabrication Methods

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  44. Mesoporous Oxyhalide Aggregates Exhibiting Improved Photocatalytic Activity for Visible-Light H2 Evolution and CO2 Reduction

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  45. Photo-Driven Acceleration of Oxidation Kinetics in Aqueous Zinc–Sulfur Batteries

    ACS Applied Materials & Interfaces · 2025-12-08

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  46. Enhanced visible-light-driven photocatalytic Cr( vi ) reduction over La-doped In 2 S 3 : performance and mechanistic insights

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  47. Photocorrosion in semiconductor photocatalysts: mechanisms, suppression, and use in functional material design

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  48. Reductive-defect-suppressed titanium oxynitrides via Ca 3 N 2 -assisted topochemical nitridation

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  49. In Situ X-ray Absorption Fine Structure Spectroscopy Measurement of Suspended Cobalt Oxide Nanoparticle Water Oxidation Catalyst

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  50. Construction of g-C3N4 quantum dot-decorated TiO2 heterojunction for highly efficient and stable photocatalytic CO2 reduction

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