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RESEARCH PAPER · ACS Applied Materials & Interfaces · 2017

Composition Screening in Blue-Emitting Li4Sr1+xCa0.97–x(SiO4)2:Ce3+ Phosphors for High Quantum Efficiency and Thermally Stable Photoluminescence

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Composition Screening in Blue-Emitting Li4Sr1+xCa0.97–x(SiO4)2:Ce3+ Phosphors for High Quantum Efficiency and Thermally Stable PhotoluminescenceOriginalA strategy for realizing tunable luminescence and full-color emission in Sr 3 Gd 2 (Si 3 O 9 ) 2 :Eu phosphors by introducing dual functional Mn 2+18Achieving long-term zero-thermal-quenching with the assistance of carriers from deep traps112Analysis of the structure and abnormal photoluminescence of a red-emitting LiMgBO 3 :Mn 2+ phosphor22Control of the photoluminescence in Ba 0.97 Y 2 Si 3 O 10 :Eu 2+ phosphors via the intensification effect of the second luminescence centre14Enhancing negative thermal quenching effect via low-valence doping in two-dimensional confined core–shell upconversion nanocrystals51Improved luminescence and energy-transfer properties of Ca 14 Al 10 Zn 6 O 35 :Ti 4+ ,Mn 4+ deep-red-emitting phosphors with high brightness for light-emitting diode (LED) plant-growth lighting74Effects of the deep traps on the thermal‐stability property of CaAl 2 O 4 : Eu 2+ phosphor49On the photoluminescence of multi-sites Ce3+ in T-phase orthosilicate and energy transfer from Ce3+ to Tb3+11A zero-thermal-quenching and color-tunable phosphor LuVO4: Bi3+, Eu3+ for NUV LEDs79A novel dazzling Eu 3+ ‐doped whitlockite‐type phosphate red‐emitting phosphor for white light‐emitting diodes60Probing the luminescent properties of (Ca1-Sr )8Mg3Al2Si7O28:Ce3+/Eu2+: A combined experiment and calculation study11Thermodynamic Stabilities, Electronic Properties, and Optical Transitions of Intrinsic Defects and Lanthanide Ions (Ce3+, Eu2+, and Eu3+) in Li2SrSiO426Ca3Lu(GaO)3(BO3)4:Eu3+: A novel high-brightness and thermal-stable red-emitting phosphor for white LEDs44Crystallographic-site induced multi-color emission with high efficiency in Ca3(SiO3)3:Ce3+ phosphor19Structure, site-occpancy and luminescent properties of a novel blue phosphor Na 3 ZrMgP 3 O 12 : Eu 2+17Site-sensitive energy transfer from Ce3+ to Tb3+/Mn2+ based on an efficient phosphor Li4SrCa(SiO4)2:Ce3+18Improving Quantum Efficiency and Thermal Stability in Blue-Emitting Ba 2– x Sr x SiO 4 :Ce 3+ Phosphor via Solid Solution244Preferential Neighboring Substitution-Triggered Full Visible Spectrum Emission in Single-Phased Ca10.5–xMgx(PO4)7:Eu2+ Phosphors for High Color-Rendering White LEDs122Exploration of bluish violet‐emitting phosphor Ca 3 Al 4 ZnO 10 :Ti 4+ with enhanced emission by Ca 2+ vacancies11Ultra‐narrow band blue emission of Eu 2+ in halogenated (Alumino)borate systems based on high lattice symmetry20Highly Efficient and Thermally Stable Blue-Green (Ba0.8Eu0.2O)(Al2O3)4.575×(1+x) Phosphor through Structural Modification55Improvement the luminescent property of Y3Al5O12:Ce3+ by adding the different fluxing agents for white LEDs15Cyan-Green Phosphor (Lu2M)(Al4Si)O12:Ce3+ for High-Quality LED Lamp: Tunable Photoluminescence Properties and Enhanced Thermal Stability150Electronic structure and luminescent properties of Ce3+-doped Ba3Lu2B6O15, a high-efficient blue-emitting phosphor33Highly efficient Ce 3+ → Tb 3+ energy transfer induced bright narrowband green emissions from garnet-type Ca 2 YZr 2 (AlO 4 ) 3 :Ce 3+ ,Tb 3+ phosphors for white LEDs with high color rendering index133Photoluminescence properties and energy transfer in a novel Sr 8 ZnY(PO 4 ) 7 :Tb 3+ ,Eu 3+ phosphor with high thermal stability and its great potential for application in warm white light emitting diodes128Synthesis, luminescence and application of novel europium, cerium and terbium-doped apatite phosphors32Narrow‐Band Green‐Emitting Sr2MgAl22O36:Mn2+ Phosphors with Superior Thermal Stability and Wide Color Gamut for Backlighting Display Applications195Highly efficient and thermal stable La2Si2O7:Ce3+,Tb3+,Eu3+ phosphors: Emission color tuning through terbium bridge36Blue-emitting Bi-doped double perovskite Gd2ZnTiO6 phosphor with near-ultraviolet excitation for warm white light-emitting diodes48Local Structure Modulation Induced Highly Efficient Far-Red Luminescence of La 1– x Lu x AlO 3 :Mn 4+ for Plant Cultivation89Enhancing photoluminescence properties of Mn 4+ ‐activated Sr 4− x Ba x Al 14 O 25 red phosphors for plant cultivation LEDs20Second-Sphere Polyhedron-Distortion-Induced Broadened and Red-Shifted Emission in Lu3(MgxAl2–x)(Al3–xSix)O12:Ce3+ for Warm WLED48Luminescent materials comprised of wood-based carbon quantum dots adsorbed on a Ce0.7Zr0.3O2 solid solution: synthesis, photoluminescence properties, and applications in light-emitting diode devices9Promotion of efficiency and thermal stability by restraining dynamic energy migration based on the highly symmetric rigid structure in the n-UV excitation green emission garnet phosphors62High thermal stability and blue-violet emitting phosphor CaYAlO4:Ti4+ with enhanced emission by Ca2+ vacancies12Na2Tb0.5(MoO4)(PO4):0.5Eu3+: A red-emitting phosphor with both high thermal stability and high colour purity14Modifying the Electronic Trap Distribution in Ba2Zr2Si3O12:Eu2+,Nd3+ via Regulating the Composition of Matrix Elements6From Nonluminescence to Bright Blue Emission: Boron-Induced Highly Efficient Ce3+-Doped Hydroxyapatite Phosphor44Photoluminescence Control of UCr 4 C 4 -Type Phosphors with Superior Luminous Efficiency and High Color Purity via Controlling Site Selection of Eu 2+ Activators112Tunable lanthanide/transition metal ion‐doped novel phosphors for possible application in w‐LEDs: a review77Photoluminescence control and abnormal Eu 3+ orange emission in Ln 3+ (Ln 3+ = Ce 3+ , Eu 3+ )-doped oxyapatite-type phosphors17A broadband cyan-emitting Ca 2 LuZr 2 (AlO 4 ) 3 :Ce 3+ garnet phosphor for near-ultraviolet-pumped warm-white light-emitting diodes with an improved color rendering index244Crystal structure, theoretical studies and luminescent properties of a new borate Na 3 GdB 8 O 15 with one-dimensional broad-banded anionic framework13Discovery of blue-emitting Eu2+-activated sodium aluminate phosphor with high thermal stability via phase segregation40A novel multi-center activated single-component white light-emitting phosphor for deep UV chip-based high color-rendering WLEDs190High-efficient, spherical and thermal-stable carbon dots@silica fluorescent composite as rare earth-free phosphors for white LED39Tuning the luminescence properties of Mn 4+ ‐activated CaYAlO 4 phosphor by co‐doping cations for indoor plant cultivation27Design of a Broadband NIR Phosphor for Security-Monitoring LEDs: Tunable Photoluminescence Properties and Enhanced Thermal Stability140A spatial/temporal dual-mode optical thermometry based on double-sites dependent luminescence of Li4SrCa(SiO4)2: Eu2+ phosphors with highly sensitive luminescent thermometer116Red shift properties, crystal field theory and nephelauxetic effect on Mn4+-doped SrMgAl10-yGayO17 red phosphor for plant growth LED light222Filling the cyan gap toward full-visible-spectrum LED lighting with Ca2LaHf2Al3O12:Ce3+ broadband green phosphor78Blue-emitting Sr1-Ca Lu2O4:Ce3+ phosphors for high CRI white LEDs17Achieving full-visible-spectrum LED lighting via employing an efficient Ce3+-activated cyan phosphor115Red phosphors A2GdNbO6: Mn4+ (A = Ca, Sr, Ba) for plant growth LEDs with Emerson enhancement effect39Improving thermal stability and quantum efficiency through solid solution for Ce3+-activated (Ba1-Sr )3Y2(BO3)4 phosphors16Improvement of thermal stability and photoluminescence in Mg 2 Y 2 Al 2 Si 2 O 12 :Ce 3+ by the cation substitution of Ca 2+ , Sr 2+ and Ba 2+ ions14Structural and spectroscopic investigation of an efficient and broadband NIR phosphor InBO3: Cr3+ and its application in NIR pc-LEDs106Daylight-White-Emitting and Abnormal Thermal Antiquenching Phosphors Based on a Layered Host SrIn 2 (P 2 O 7 ) 253Preparation and characterization of Gd3(ScAl)2Al3O12:Ce3+ garnet phosphors towards high-color-rendering white-light illumination15Combinations of Superior Inorganic Phosphors for Level‐Tunable Information Hiding and Encoding61Achieving high quantum efficiency independent on luminescence center through sub-lattice cage engineering10Li + Ion Induced Full Visible Emission in Single Eu 2+ ‐Doped White Emitting Phosphor: Eu 2+ Site Preference Analysis, Luminescence Properties, and WLED Applications93Finding an efficient far-red-emitting CaMg2La2W2O12:Mn4+ phosphor toward indoor plant cultivation LED lighting91Highly efficient and zero-thermal-quenching blue-emitting Eu2+-activated K-beta-alumina phosphors72Synthesis, Structure, and Photoelectric Properties of a Novel 0-Dimensional Organic–Inorganic Hybrid Perovskite (2-5-py)2MnBr424Site occupancies, photoluminescence, and temperature sensing properties of a K7ZnSc2B15O30:Ce3+, Tb3+ phosphor3Achievement of high-efficiency sunlight-like emission in Rb2CaP2O7: Ce3+, Eu2+ phosphors16Dependence of Luminous Performance on Eu3+ Site Occupation in SrIn2(P2O7)2: The Effect of the Local Environment35Ultra-wideband warm white light emission from self-trapped excitons in CsAgCl217Blue-light-excitable broadband yellow-emitting CaGd2HfSc(AlO4)3:Ce3+ garnet phosphors for white light-emitting diode devices with improved color rendering index68Tuning crystal structure and luminescence of Eu 2+ -activated LiSr 1– x Ba x PO 4 solid solution for white light-emitting diodes5Chemical unit co-substitution for a new far-red-emitting phosphor Ca3-6(NaLu)3LiSbO6:Mn4+ to achieve high quantum efficiency and superb thermal stability12A highly efficient narrow-band blue phosphor of Bi3+-activated cubic borate Ba3Lu2B6O15 towards backlight display applications85Defect-induced Ce 3+ sites preferences and multilevel concentration quenching of a high-efficiency cyan phosphor for high-quality full-visible-spectrum wLED23Improving the luminescence thermal stability of Ca 3 Y 2 Ge 3 O 12 :Cr 3+ based on cation substitution and its application in NIR LEDs15Sc dopant induced tailoring of persistent luminescence in Na 3 YSi 3 O 9 :Eu 2+ for information recording8Thermometric and Luminescence Studies of Eu3+ Activated Casr2(Po4)2 Phosphor for Temperature Sensing and Solid-State Lighting Applications2Tunable emission of Li 4 SrCaSi 2 O 4− y N 2 y / 3 :Eu 2+ phosphors based on anion substitution induction for WLEDs and optical thermometry12Ni2+-Doped Garnet Solid-Solution Phosphor-Converted Broadband Shortwave Infrared Light-Emitting Diodes toward Spectroscopy Application186How to Obtain Anti‐Thermal‐Quenching Inorganic Luminescent Materials for Light‐Emitting Diode Applications252Single-component white emitting phosphor Mg2Y2Al2Si2O12:Tb3+, Eu3+, Tm3+ for white LEDs40K0.5La0.5SrMgWO6: Mn4+: A high-efficiency perovskite structure phosphor for plant cultivation LEDs16Recent development of aluminate materials for solid state lighting37Pressure-driven Eu2+-doped K3Sc(PO4)2: A broad cyan-green emitting phosphor for closing the cyan cavity in solid-state lighting and applying in optical pressure sensor18Spectral design in Cr3+-doped NIR phosphors via crystal field modulation20Bright blue emissions on UV-excitation of LaBO3 (B=In, Ga, Al) perovskite structured phosphors for commercial solid-state lighting applications2Stable zero-thermal quenching cover wide temperature range achieves in cerium doped KY3F10 ultraviolet luminescent single crystal8Highly Efficient Broad-Band Green-Emitting Cerium(III)-Activated Garnet Phosphor Allows the Fabrication of Blue-Chip-Based Warm-White LED Device with a Superior Color Rendering Index69Thermometric and luminescence studies of Eu3+ activated CaSr2(PO4)2 phosphor for non-contact optical thermometry and solid state lighting applications33Color-tunable blue-emitting Na2MgSiO4:Ce3+ phosphors for white light-emitting diodes33Tuning emission color of Eu2+-activated phosphor through phase segregation22Strategies for Enhancement Luminance of Sub‐Micrometer Phosphor: A Sub‐Micrometer Narrow‐Band Red Phosphor with Ultrahigh Thermal Stability50Preparation and characterization of a new orange-red phosphor Ba2LaTaO6:Eu3+ with abnormal thermal quenching14A novel extra-broadband visible-NIR phosphor doped with Ce3+ and Cr3+ towards multifunctional advanced applications20A new blueish phosphor K2Ca3Si3O10:Ce3+ with excellent thermal stability4Local Structure and Self‐Defect Evolution under Nonstoichiometric Effect Unlock Zero‐Thermal‐Quenching15Optimization of deliquescence-proof perovskite-like Cs3ErF6 phosphor and dual-mode luminescent intensity ratio thermometry5Eu 2+ -Doped Ca 4 Y 3 Si 7 O 15 N 5 Phosphor with High Thermal Stability and Pressure Sensitivity for Dual-Functional Applications in W-LEDs and Pressure Sensors32Highly bright broadband cyan-emitting CaLu2HfGaAl3O12:Ce3+ garnet phosphors for high-color-quality white light-emitting diodes15Multi‐Mode Optical Manometry Based on Li 4 SrCa(SiO 4 ) 2 :Eu 2+ Phosphors61High-Efficiency Ce3+ Activated Orthorhombic Lanthanide Silicate Blue Phosphors for Plant Growth Lighting25Structurally stable Mn4+-doped oxide phosphor with improved thermal stability for agricultural lighting22Highly crystalline Y3Al5O12:Ce3+ phosphor-in-silica glass ceramics for high-power solid-state lighting43Regulation of Anti‐Thermal Quenching and Emission Color in Eu 2+ ‐Activated Na‐Beta‐Alumina Phosphors for Full‐Spectrum Illumination11Three-mode optical thermometry based on multiresponsive Ba1-xSrxLaLiWO6:Er3+, Yb3+ phosphors29Ce3+-Doped Li2Ca5Gd(BO3)5 Phosphors with Multiple Luminescent Centers and High Pressure Sensitivity under Near UV Excitation9Overcoming the cyan gap for full‐spectrum lighting using cation‐substitution‐induced rigid Ca 2 YZr 2 Al 3 O 12 :Ce 3+9New green garnet-type phosphor LuMgAl5SiO12:Ce3+ for filling cyan gap to achieve full-spectrum and high colour-rendering-index white light-emitting diodes19A post-reduction strategy to enhance near-infrared-II emission from Li 4 SrCa(SiO 4 ) 2 :Cr 4+ phosphors11Less is more: An oxyfluoride garnet broadband cyan-green phosphor towards highly efficient full-spectrum WLEDs22Solid solution structural engineering enhances the luminescence of SrMgAl10O17:Cr3+ for agricultural lighting12Super thermally stable Rb-β-Al2O3:Eu blue phosphor for full-spectra lighting4Enhanced Thermally Stability and Broadened Emission for Gd 3 Ga 5 O 12 :Cr 3+ Phosphors via Si 3 N 4 Substitution17An efficient violet-excited and cyan-green/near-infrared dual emitting phosphor for full-spectrum lighting14Synthesis and luminescent properties of a novel long-afterglow phosphor BaGd2Al2Ga2SiO12: Ce3+8Enhanced Quantum Efficiency via Co‐Substitution in Red‐Emitting Phosphor Sr2[MgAl5N7] : Eu2+ for Advanced Spectroscopic Applications Including Laser Displays with Ultra‐High Luminescence Saturation Threshold11Enhanced Quantum Efficiency via Co‐Substitution in Red‐Emitting Phosphor Sr2[MgAl5N7] : Eu2+ for Advanced Spectroscopic Applications Including Laser Displays with Ultra‐High Luminescence Saturation Threshold10Structure–Photoluminescence Relationship in Ce3+-Doped K5Y(P2O7)2 and Its Sensitization to Dy3+ with Enhanced White Light Emission7Thermal stable and bright yellow-emitting phosphor Na3+xK1-x(AlSiO4)4:Eu2+ for solid-state lighting2Broadband near-infrared emission of Cr3+ doped Zn7Sb2O12 phosphors for night vision imaging system sources5Research progress on the design and regulation of Eu 2+ /Ce 3+ -activated anti-/zero thermal quenching phosphors9High-performance (Y1–Ce )3Al5O12 ceramics synthesized by spark plasma sintering for high-power laser-driven lighting1A review of recent advances in Ce3+-activated garnet phosphors for blue-chip-pumped pc-WLEDs81The great potential of inorganic phosphors in the growing field of plant cultivation: A review9Interstitial Solid Solution Design Breaks the Property Ceiling: Cr 3+ Doped Near‐Infrared Phosphors with EQE Exceeding 50% and Zero‐Thermal‐Quenching Characteristics19A Blue Light–Excited Broadband Chartreuse‐Emitting LuMg 2 Al 3 Si 2 O 12 :Ce 3+ Garnet Phosphor With High Thermal Stability for High‐Performance White LEDs0Neutron scintillation properties improvement of LYBO:Ce crystal grown from remelting and intermediate reduction0Stepwise cation substitution for enhanced luminescence in Bi 3+ -activated Sr 2 LaAlO 5 phosphors: rigidity modulation and crystal-field engineering via Lu 3+ and Ba 2+ co-doping0Heavy-element substitution simultaneously boosts comprehensive photoluminescence performance of Ce3+-activated garnets toward multifunctional optical applications0Preparation of high quantum efficiency broadband blue phosphors Ca0.87-xSrxAl2Si2O8:0.13Eu2+ for high color rendering white LEDs via a cation substitution strategy0Halide‐Composition Tunable CsPbX 3 @Porous Silica Phosphors With Tunable Emission Wavelength and High Water Stability0Boosting nUV/blue emission of Ba3Sc(BO3)3:Ce3+ via Mg2+ induced charge compensation and site redistribution0

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