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RESEARCH PAPER · Inorganic Chemistry · 2019

Second-Sphere Polyhedron-Distortion-Induced Broadened and Red-Shifted Emission in Lu3(MgxAl2–x)(Al3–xSix)O12:Ce3+ for Warm WLED

Yunan Zhou, Weidong Zhuang, Yunsheng Hu, Ronghui Liu, Huibing Xu, Yuanhong Liu, Yanfeng Li

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Second-Sphere Polyhedron-Distortion-Induced Broadened and Red-Shifted Emission in Lu3(MgxAl2–x)(Al3–xSix)O12:Ce3+ for Warm WLEDOriginalColor tuning of β-Ca3(PO4)2-type phosphor with enhanced quantum efficiency via self-charge compensation for healthy and warm solid state lighting application55Design of a Broadband NIR Phosphor for Security-Monitoring LEDs: Tunable Photoluminescence Properties and Enhanced Thermal Stability140Enhanced quantum efficiency and thermal stability in CaWO4:Eu3+ phosphor based on structural modification induced by co-doping Al3+37Weak thermal quenching and tunable luminescence in Ce:Y3(Al,Sc)5O12 transparent ceramics for high power white LEDs/LDs83Enhanced thermal stability of CaAlSiN 3 :Eu 2+ phosphors by superficial carbon modification7Highly efficient yellow‐orange emission and superior thermal stability of Ba 2 YAl 3 Si 2 O 12 :Ce 3+ for high‐power solid lighting24Effect of Eu3+ doping on luminescence properties of a KAlSiO4:Sm3+ phosphor28Garnet phosphors for white-light-emitting diodes: modification and calculation63Improvement of thermal stability and photoluminescence in Mg 2 Y 2 Al 2 Si 2 O 12 :Ce 3+ by the cation substitution of Ca 2+ , Sr 2+ and Ba 2+ ions14Luminescence and energy transfer of warm white-emitting phosphor Mg 2 Y 2 Al 2 Si 2 O 12 :Dy 3+ ,Eu 3+ for white LEDs28Magical polyhedral twist via chemical unit co-substitution in LaAlO 3 :Mn 4+ to greatly enhance the zero phonon line for high-efficiency plant-growth LEDs49Thermal stability of nitride phosphors for light-emitting diodes66Broadband emission Gd3Sc2Al3O12:Ce3+ transparent ceramics with a high color rendering index for high-power white LEDs/LDs38Achieving an ultra-broadband infrared emission through efficient energy transfer in LiInP2O7: Cr3+, Yb3+ phosphor80Improvement of the thermal stability of bluish-cyan emitting phosphor Y 2 MgAl 4 SiO 12 :Eu 2+ using substitution cations (Zn, Ca, Sr) for white LEDs10Site-selective and cooperative doping of Gd 3 Al 5 O 12 :Ce garnets for structural stabilization and warm WLED lighting of low CCT and high CRI26The high thermal stability of white emitting phosphor Mg2Y2Al2Si2O12:Dy3+,Eu3+,La3+/Lu3+ for white light emitting diodes1Improving the luminescence thermal stability of Ca 3 Y 2 Ge 3 O 12 :Cr 3+ based on cation substitution and its application in NIR LEDs15Remarkable structure and luminescence regulation of a Gd 2 LuAl 5 O 12 :Ce garnet phosphor with a Ca 2+ /Si 4+ pair for high-quality w-WLED lighting8Multisite Cation Regulation of Broadband Cyan-Emitting (Ba1–xSrx)9Lu2Si6O24/Eu2+ Phosphors for Full-Spectrum wLEDs32Efficient and Thermally Stable Broad-Band Near-Infrared Emission in a KAlP 2 O 7 :Cr 3+ Phosphor for Nondestructive Examination191Effect of ionic couple substitution on the enhanced photoluminescence properties of (BaMg)1-x(KxAl10+x)O17:Eu2+ phosphor for white LEDs application7Elevating photoluminescence properties of Y3MgAl3SiO12:Ce3+ transparent ceramics for high-power white lighting34Design of luminescence in (Sr,Gd)Li(Al,Mg)3N4:Eu2+ deep red phosphors via crystal field engineering for full-spectrum WLEDs29Highly efficient Ce: Lu(Mg,Al)2(Si,Al)3O12 phosphor ceramics for high-power white LEDs/LDs15Biphasic Lu3MgAl3SiO12-based transparent ceramics for uniform laser-diode-driven white lighting20Auxiliaries Ce3+/Sb3+ of Sm3+ in borosilicate glass phosphors: Optimal utilization of energetic UV photons0Deep blue, cyan, orange-red, and white multicolor emissions generated by Bi3+/Eu3+ activated KBaYSi2O7 luminescent materials for white light-emitting diodes19Preparation of novel KAlSiO4: Ce3+ broadband cyan-emitting phosphors via partial cation substitution for applications in white-light LEDs20Recent Advances in Multi-Site Luminescent Materials: Design, Identification and Regulation20Excitability remodeling in Sm3+-doped aluminosilicate glass phosphors5Efficient broadband yellow-emitting Mg2.5Lu1.5Al1.5Si2.5O12:Ce3+ garnet phosphors for blue-light-pumped white light-emitting diodes21Ce3+-Doped Li2Ca5Gd(BO3)5 Phosphors with Multiple Luminescent Centers and High Pressure Sensitivity under Near UV Excitation9Design strategies of rare-earth luminescent complexes with zero thermal quenching protected by the wire-in-tube structure and the construction of a W-WLED with highly stable illumination and colour reproduction3Demystifying role of local distortion in emission colors tuning of lead-free zero-dimensional metal halide nanocrystals21Multiwavelength Excitation in Ho3+-Doped All-Inorganic Double Perovskites Achieved by Codoping Mn2+ for Warm-White LEDs and Plant Growth17A competitive trivalent-europium-activated phosphor: Achieving highly efficient red light emission in a sodium-rich garnet host17High recorded color rendering performance of single-structured Ce,Mn:Y 3 (Al,Sc) 2 Al 3 O 12 phosphor ceramics for high-power white LEDs/LDs35Strategically Developed Strong Red‐Emitting Oxyfluoride Nanophosphors for Next‐Generation Lighting Applications23Spectroscopy analysis and optical transition property of GdNbTiO6: Eu3+, Sm3+ phosphor0High-quality temperature imaging of Li2TiO3: Mn4+ thin film based on time-resolved luminescence measurement3Preparation, structure and properties of ultra-broadband yellow-emitting CaGd2Sc2Al2SiO12:Ce3+ garnet phosphors for blue-chip-pumped white LEDs18Lead-free lanthanide-based Cs 3 LnCl 6 metal halides6Enhancement of luminescence properties of broadband NIR Cr3+-activated phosphate phosphors through cationic substitution11Narrow-Band Deep-Blue Emitting Basr2(Po4)2: Eu2+ Phosphor with High Thermal Stability for Advanced Anti-Counterfeiting and Wleds0A novel deep-blue emitting BaSr2(PO4)2: Eu2+ phosphor with excellent thermostability for advanced anti-counterfeiting and white light-emitting diodes1Luminescence properties of Ce3+-activated BaLu2Al3ScSiO12 cyan-green emitting garnet phosphors for white LEDs4Broadband green-yellow emitting BaY2Al3ScSiO12:Ce3+ garnet phosphor for high-quality white LED applications5

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  2. Design of a Broadband NIR Phosphor for Security-Monitoring LEDs: Tunable Photoluminescence Properties and Enhanced Thermal Stability

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  3. Enhanced quantum efficiency and thermal stability in CaWO4:Eu3+ phosphor based on structural modification induced by co-doping Al3+

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  4. Weak thermal quenching and tunable luminescence in Ce:Y3(Al,Sc)5O12 transparent ceramics for high power white LEDs/LDs

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  5. Enhanced thermal stability of CaAlSiN 3 :Eu 2+ phosphors by superficial carbon modification

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  6. Highly efficient yellow‐orange emission and superior thermal stability of Ba 2 YAl 3 Si 2 O 12 :Ce 3+ for high‐power solid lighting

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  7. Effect of Eu3+ doping on luminescence properties of a KAlSiO4:Sm3+ phosphor

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  8. Garnet phosphors for white-light-emitting diodes: modification and calculation

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  10. Luminescence and energy transfer of warm white-emitting phosphor Mg 2 Y 2 Al 2 Si 2 O 12 :Dy 3+ ,Eu 3+ for white LEDs

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  11. Magical polyhedral twist via chemical unit co-substitution in LaAlO 3 :Mn 4+ to greatly enhance the zero phonon line for high-efficiency plant-growth LEDs

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  12. Thermal stability of nitride phosphors for light-emitting diodes

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  13. Broadband emission Gd3Sc2Al3O12:Ce3+ transparent ceramics with a high color rendering index for high-power white LEDs/LDs

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  14. Achieving an ultra-broadband infrared emission through efficient energy transfer in LiInP2O7: Cr3+, Yb3+ phosphor

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  15. Improvement of the thermal stability of bluish-cyan emitting phosphor Y 2 MgAl 4 SiO 12 :Eu 2+ using substitution cations (Zn, Ca, Sr) for white LEDs

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  16. Site-selective and cooperative doping of Gd 3 Al 5 O 12 :Ce garnets for structural stabilization and warm WLED lighting of low CCT and high CRI

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  17. The high thermal stability of white emitting phosphor Mg2Y2Al2Si2O12:Dy3+,Eu3+,La3+/Lu3+ for white light emitting diodes

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  18. Improving the luminescence thermal stability of Ca 3 Y 2 Ge 3 O 12 :Cr 3+ based on cation substitution and its application in NIR LEDs

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  19. Remarkable structure and luminescence regulation of a Gd 2 LuAl 5 O 12 :Ce garnet phosphor with a Ca 2+ /Si 4+ pair for high-quality w-WLED lighting

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  20. Multisite Cation Regulation of Broadband Cyan-Emitting (Ba1–xSrx)9Lu2Si6O24/Eu2+ Phosphors for Full-Spectrum wLEDs

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  21. Efficient and Thermally Stable Broad-Band Near-Infrared Emission in a KAlP 2 O 7 :Cr 3+ Phosphor for Nondestructive Examination

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  22. Effect of ionic couple substitution on the enhanced photoluminescence properties of (BaMg)1-x(KxAl10+x)O17:Eu2+ phosphor for white LEDs application

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  23. Elevating photoluminescence properties of Y3MgAl3SiO12:Ce3+ transparent ceramics for high-power white lighting

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