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RESEARCH PAPER · The Journal of Physical Chemistry Letters · 2017

Bandgap Narrowing of Lead-Free Perovskite-Type Hybrids for Visible-Light-Absorbing Ferroelectric Semiconductors

Chengmin Ji, Zhihua Sun, Aurang Zeb, Sijie Liu, Jing Zhang, Maochun Hong, Junhua Luo

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Bandgap Narrowing of Lead-Free Perovskite-Type Hybrids for Visible-Light-Absorbing Ferroelectric SemiconductorsOriginalLaryngeal Cancer In Children And Adolescents34(2-Methylpiperidine)PbI 3 : an ABX 3 -type organic–inorganic hybrid chain compound and its semiconducting nanowires with photoconductive properties25[C 5 H 12 N]CdCl 3 : an ABX 3 perovskite-type semiconducting switchable dielectric phase transition material55First-principles study on the electric structure and ferroelectricity in epitaxial CsSnI 3 films32Mixed Bromine–Chlorine Induced Great Dielectric and Second-Order Nonlinear Optical Properties Changes in Phase Transitions Compounds [H2mdap][BiBr5(1-x)Cl5x] (x = 0.00–1.00)17Structural phase transition-associated dielectric transition and ferroelectricity in coordination compounds166Lead-Free Hybrid Material with an Exceptional Dielectric Phase Transition Induced by a Chair-to-Boat Conformation Change of the Organic Cation43Effect of ferroelectricity on charge conduction in a PCBM/perovskite device structure7The First Molecule‐Based Blue‐Light Optical‐Dielectric Switching Material in Both Hybrid Bulk Crystal and Flexible Thin Film Forms17Broadband white-light emission with a high color rendering index in a two-dimensional organic–inorganic hybrid perovskite94[C 6 H 14 N]PbI 3 : a one-dimensional perovskite-like order–disorder phase transition material with semiconducting and switchable dielectric attributes55Rational design of a triiodide-intercalated dielectric-switching hybrid for visible-light absorption20Alloying n‐Butylamine into CsPbBr3 To Give a Two‐Dimensional Bilayered Perovskite Ferroelectric Material189Alloying n‐Butylamine into CsPbBr3 To Give a Two‐Dimensional Bilayered Perovskite Ferroelectric Material31A novel bismuth-based hybrid material with highly activity for fast removal of rhodamine B under dark conditions27Ferroelectricity and Ferroelasticity in Organic Inorganic Hybrid (Pyrrolidinium)3[Sb2Cl9]85All inorganic based Nd0.9Mn0.1FeO3 perovskite for Li-ion battery application: Synthesis, structural and morphological investigation21Lead-free hybrid perovskites for photovoltaics33Ferroelectric Property, Switchable Dielectric, and Excellent Second Harmonic Generation Response in a Homochiral Organic Salt: l -Prolinammonium 1-Adamantane Carboxylate13Structural Phase Transition and Switchable Dielectric Properties of a Unique Two-Dimensional Organic–Inorganic Hybrid Perovskite Compound [C6H11NH2CH3]4Pb3I1043Rational chemical doping of metal halide perovskites290[C5H12N]SnCl3: A Tin Halide Organic–Inorganic Hybrid as an Above‐Room‐Temperature Solid‐State Nonlinear Optical Switch56H/F substituted perovskite compounds with above-room-temperature ferroelasticity: [(CH 3 ) 4 P][Cd(SCN) 3 ] and [(CH 3 ) 3 PCH 2 F][Cd(SCN) 3 ]56Lead-free hybrid ferroelectric material based on formamidine: [NH 2 CHNH 2 ] 3 Bi 2 I 960Symmetry breaking structural phase transitions, dielectric properties and molecular motions of formamidinium cations in 1D and 2D hybrid compounds: (NH 2 CHNH 2 ) 3 [Bi 2 Cl 9 ] and (NH 2 CHNH 2 ) 3 [Bi 2 Br 9 ]41Two-Dimensional Hybrid Perovskite-Type Ferroelectric for Highly Polarization-Sensitive Shortwave Photodetection335Halide Perovskites for Nonlinear Optics355Structural and Functional Diversity in Lead‐Free Halide Perovskite Materials348Indirect but Efficient: Laser-Excited Electrons Can Drive Ultrafast Polarization Switching in Ferroelectric Materials61Strategies Toward Extending the Near‐Infrared Photovoltaic Response of Perovskite Solar Cells18TiO2/Bi5O7I Composite Films for Dye-Sensitized Solar Cells6Ferroelectricity in Ethylammonium Bismuth-Based Organic–Inorganic Hybrid: (C2H5NH3)2[BiBr5]57[NH 2 CHNH 2 ] 3 Sb 2 I 9 : a lead-free and low-toxicity organic–inorganic hybrid ferroelectric based on antimony( iii ) as a potential semiconducting absorber33Correlation between crystal structures and polar (ferroelectric) properties of hybrids of haloantimonates( iii ) and halobismuthates( iii )62Ferroelectricity in a lead free organic–inorganic 0D hybrid: formamidinium bromoantimonate( iii )18Halogen substitution regulates the phase transition temperature and band gap of semiconductor compounds29Two Rare‐Earth Molecular Ferroelectrics with High Curie Temperatures, Large Spontaneous Polarization, Switchable Second Harmonic Generation Effects, and Strong Photoluminescence28(1-C5H14N2Br)2MnBr4: A Lead-Free Zero-Dimensional Organic-Metal Halide With Intense Green Photoluminescence30Pb‐Based Halide Perovskites: Recent Advances in Photo(electro)catalytic Applications and Looking Beyond163Lead-free molecular ferroelectric [N,N-dimethylimidazole]3Bi2I9 with narrow bandgap16Photo-degradation organic dyes by Sb-based organic-inorganic hybrid ferroelectrics15Lead-free antimony-based halides bis(thiomorpholine) pentachloroantimonate(III) monohydrate8Coupling Narrow Band Gap and Switchable SHG Responses in a New Molecule Ferroelectric: Imidazolyl Propylamine Pentabromo Stibium(III)31Exploring a layered iodide perovskite crystal with centimetered dimension for extended spectral polarization-sensitive photodetection19How to apply metal halide perovskites to photocatalysis: challenges and development87Towards ferroelectricity-inducing chains of halogenoantimonates( iii ) and halogenobismuthates( iii )23Compatible Ferroelectricity, Antiferroelectricity and Broadband Emission for a Multi-Functional 2D Organic-Inorganic Hybrid Perovskite0Compatible Ferroelectricity, Antiferroelectricity and Broadband Emission for a Multi-Functional 2D Organic-Inorganic Hybrid Perovskite0Using a Porphyrin Diacid Cation to Stabilize a Square-Pyramidal BiX5 (X = Br, Cl/Br) Unit4Hybrid organic–inorganic perovskite ferroelectrics bring light to semiconducting applications: Bandgap engineering as a starting point42Advances in Theoretical Calculation of Halide Perovskites for Photocatalysis210D Perovskites: Unique Properties, Synthesis, and Their Applications388A zero-dimensional lead-free bismuth-based metal halide: [C 6 H 5 (CH 2 ) 2 CH(NH 3 )CH 3 ] 2 BiCl 51Ferroelectric properties in metal-coordinated complex tris(2-hydroxyethyl) ammonium trichloro cadmium( ii )5Tunable hybrid perovskites with a narrow bandgap and multistage phase transition properties: 2,2-difluoroethylamine·antimony hexabromide4Hybrid Organic Lead Iodides: Role of Organic Cation Structure in Obtaining 1D Chains of Face-Sharing Octahedra vs 2D Perovskites29Two-Dimensional Organic–Inorganic Hybrid Materials with Dielectric Switching and Photoluminescence Properties29Self‐Assembly of 2D Hybrid Double Perovskites on 3D Cs2AgBiBr6 Crystals towards Ultrasensitive Detection of Weak Polarized Light20Self‐Assembly of 2D Hybrid Double Perovskites on 3D Cs2AgBiBr6 Crystals towards Ultrasensitive Detection of Weak Polarized Light3Diffusion in weakly coordinating solvents8Highly Distorted Antimony(III) Chloride [Sb 2 Cl 8 ] 2− Dimers for Near‐Infrared Luminescence up to 1070 nm160Highly Distorted Antimony(III) Chloride [Sb2Cl8]2− Dimers for Near‐Infrared Luminescence up to 1070 nm25Zero-Dimensional Molecular Ferroelectrics with Significant Nonlinear Effect and Giant Entropy33Perovskite‐Type Hybrid Ferroelectric Semiconductors: A Potential Photosensitive Candidate Family for New Optoelectronic Applications6Emerging Halide Perovskite Ferroelectrics161The first 2D organic-inorganic hybrid relaxor-ferroelectric single crystal19Inorganic Solid‐State Nonlinear Optical Switch with a Linearly Tunable Tc Spanning a Wide Temperature Range22Inorganic Solid‐State Nonlinear Optical Switch with a Linearly Tunable Tc Spanning a Wide Temperature Range2Density Functional Theory Computation of the Electronic, Elastic, Phonon, X-ray Spectroscopy, and the Optoelectronic Properties of CsXI3(X: Si, Ge, Sn) Halide Perovskite Materials6Metal halide perovskites quantum dots: Synthesis and modification strategies for solar CO2 conversion20First-principles calculations to investigate structural, elastic, thermodynamic, electronic, and optical properties of AgXCl3 (X = Fe, Co & Mn)15Family of Chiral Ferroelectric Compounds with Widely Tunable Band Gaps15Halide Anions Tuning of Lead‐Free Perovskite‐Type Ferroelectric Semiconductors with Inverse High‐Temperature Symmetry Breaking11Centrosymmetry-Breaking Morphotropic Phase Boundary: A Pathway to Highly Sensitive and Strong Pressure-Responsive Nonlinear Optical Switches4Reversible Phase Transition and Dielectric Response of Hybrid Lead-Free Antimony-Based Crystals10Ferroic Characteristics of Metal‐Halide Perovskites0A new organic–inorganic chloride (H3N–(CH2)6–NH3)[SnCl6]: Crystal structure, thermal analysis, vibrational study, and electrical properties1Halogen Substitution Strategy for Exploiting High‐Performance Molecular Ferroelectrics1Phosphonium Cation-Based Ferroelectric 1D Halide Perovskite-Like Semiconductor for Mechanical Energy Harvesting9Ferroelectric, Switchable Dielectric and Nonlinear Optical Properties in Inorganic–Organic Lead-Free 1D Hybrids Based on Bi(III) and Azetidine: (C3NH8)2[BiCl5], (C3NH8)2[BiBr5]9Highly resistive lead-free perovskite ferroelectric enables self-driven X-ray detection with ultralow dose7Ferroelectricity and piezoelectric energy harvesting of an A 3 M 2 X 9 -type 0D bromobismuthate hybrid with a bulky organic quaternary amine9Secret agent in the secret service: Utilization of Sb( iii )-based complexes’ emission properties for the study of forgery and document authenticity2Three antimony-based organic–inorganic hybrid perovskites (1,4-3.2.2-H 2 dabcn)SbX 5 (X = Cl, Br, I) show progressively decreasing phase transition temperatures and bandgaps7Emerging low-dimensional perovskite photoferroelectrics: From crystallographic microstructure to applications8Photogalvanic effects in non-centrosymmetric halide perovskites17Structural Phase Transition‐Associated Ferroelectricity and Piezoelectric Energy Harvesting in 0D Halogenozincate Hybrid via Cation's Terminal Group Lengthening4Band Gap Engineering Based on X-Site Ion Tuning in Copper Organic–Inorganic Hybrid Perovskite5Zero-Dimensional Antimony Oxychloride Scintillators with High Photoluminescent Efficiency7Rotational Flexibility in Dication Drives Ambient Temperature Ferroelectricity in an Organic–Inorganic Hybrid Halide2Rotational Flexibility in Dication Drives Ambient Temperature Ferroelectricity in an Organic–Inorganic Hybrid Halide5Fundamental Properties of Low-Dimensional Perovskite-Related Light Absorbers: [(CH 2 ) 3 NH 2 ] 3 Sb 2 X 9 (X = I, Br, Cl), Azetidinium Antimony Halides2Multifunctional Lanthanide Molecular Ferroelectrics [ R / S -H 2 MPPA][Ln(btfa) 4 ] 2 Constructed by Hydrogen Bond Linking Functional Blocks3Polarity‐Gated Anti‐Thermal Luminescence in a Reentrant Luminescent Ferroelectric: (3,3‐difluoropyrrolidinium) 2 SbCl 5 with Dual Curie Points0Probing Ferroelectricity in Hybrid Halide Perovskites through Tunneling Spectroscopy0Dimensionality Engineering: A Pathway to Ferroelectric Halide Perovskites3(C6H16N)3Sb2I9: thermally switchable dielectric and semiconducting hybrid with structural phase transition0ZnO-induced nonlinear optical enhancement in lead-free Cs3BiI6/ZnO nanocomposites: Experimental and DFT insights0

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  1. Laryngeal Cancer In Children And Adolescents

    Otolaryngologic Clinics of North America · 1997-04-01

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  3. [C 5 H 12 N]CdCl 3 : an ABX 3 perovskite-type semiconducting switchable dielectric phase transition material

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  4. First-principles study on the electric structure and ferroelectricity in epitaxial CsSnI 3 films

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  5. Mixed Bromine–Chlorine Induced Great Dielectric and Second-Order Nonlinear Optical Properties Changes in Phase Transitions Compounds [H2mdap][BiBr5(1-x)Cl5x] (x = 0.00–1.00)

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  6. Structural phase transition-associated dielectric transition and ferroelectricity in coordination compounds

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  7. Lead-Free Hybrid Material with an Exceptional Dielectric Phase Transition Induced by a Chair-to-Boat Conformation Change of the Organic Cation

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  8. Effect of ferroelectricity on charge conduction in a PCBM/perovskite device structure

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  9. The First Molecule‐Based Blue‐Light Optical‐Dielectric Switching Material in Both Hybrid Bulk Crystal and Flexible Thin Film Forms

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  10. Broadband white-light emission with a high color rendering index in a two-dimensional organic–inorganic hybrid perovskite

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  11. [C 6 H 14 N]PbI 3 : a one-dimensional perovskite-like order–disorder phase transition material with semiconducting and switchable dielectric attributes

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  12. Rational design of a triiodide-intercalated dielectric-switching hybrid for visible-light absorption

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  13. Alloying n‐Butylamine into CsPbBr3 To Give a Two‐Dimensional Bilayered Perovskite Ferroelectric Material

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  14. Alloying n‐Butylamine into CsPbBr3 To Give a Two‐Dimensional Bilayered Perovskite Ferroelectric Material

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  15. A novel bismuth-based hybrid material with highly activity for fast removal of rhodamine B under dark conditions

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  16. Ferroelectricity and Ferroelasticity in Organic Inorganic Hybrid (Pyrrolidinium)3[Sb2Cl9]

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  18. Lead-free hybrid perovskites for photovoltaics

    Beilstein Journal of Nanotechnology · 2018-08-21

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  19. Ferroelectric Property, Switchable Dielectric, and Excellent Second Harmonic Generation Response in a Homochiral Organic Salt: l -Prolinammonium 1-Adamantane Carboxylate

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  21. Rational chemical doping of metal halide perovskites

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  22. [C5H12N]SnCl3: A Tin Halide Organic–Inorganic Hybrid as an Above‐Room‐Temperature Solid‐State Nonlinear Optical Switch

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  23. H/F substituted perovskite compounds with above-room-temperature ferroelasticity: [(CH 3 ) 4 P][Cd(SCN) 3 ] and [(CH 3 ) 3 PCH 2 F][Cd(SCN) 3 ]

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  25. Symmetry breaking structural phase transitions, dielectric properties and molecular motions of formamidinium cations in 1D and 2D hybrid compounds: (NH 2 CHNH 2 ) 3 [Bi 2 Cl 9 ] and (NH 2 CHNH 2 ) 3 [Bi 2 Br 9 ]

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  33. [NH 2 CHNH 2 ] 3 Sb 2 I 9 : a lead-free and low-toxicity organic–inorganic hybrid ferroelectric based on antimony( iii ) as a potential semiconducting absorber

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  34. Correlation between crystal structures and polar (ferroelectric) properties of hybrids of haloantimonates( iii ) and halobismuthates( iii )

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  35. Ferroelectricity in a lead free organic–inorganic 0D hybrid: formamidinium bromoantimonate( iii )

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  36. Halogen substitution regulates the phase transition temperature and band gap of semiconductor compounds

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  37. Two Rare‐Earth Molecular Ferroelectrics with High Curie Temperatures, Large Spontaneous Polarization, Switchable Second Harmonic Generation Effects, and Strong Photoluminescence

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  38. (1-C5H14N2Br)2MnBr4: A Lead-Free Zero-Dimensional Organic-Metal Halide With Intense Green Photoluminescence

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  39. Pb‐Based Halide Perovskites: Recent Advances in Photo(electro)catalytic Applications and Looking Beyond

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  40. Lead-free molecular ferroelectric [N,N-dimethylimidazole]3Bi2I9 with narrow bandgap

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  41. Photo-degradation organic dyes by Sb-based organic-inorganic hybrid ferroelectrics

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  42. Lead-free antimony-based halides bis(thiomorpholine) pentachloroantimonate(III) monohydrate

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  43. Coupling Narrow Band Gap and Switchable SHG Responses in a New Molecule Ferroelectric: Imidazolyl Propylamine Pentabromo Stibium(III)

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  44. Exploring a layered iodide perovskite crystal with centimetered dimension for extended spectral polarization-sensitive photodetection

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  45. How to apply metal halide perovskites to photocatalysis: challenges and development

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  46. Towards ferroelectricity-inducing chains of halogenoantimonates( iii ) and halogenobismuthates( iii )

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  47. Compatible Ferroelectricity, Antiferroelectricity and Broadband Emission for a Multi-Functional 2D Organic-Inorganic Hybrid Perovskite

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  48. Compatible Ferroelectricity, Antiferroelectricity and Broadband Emission for a Multi-Functional 2D Organic-Inorganic Hybrid Perovskite

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  49. Using a Porphyrin Diacid Cation to Stabilize a Square-Pyramidal BiX5 (X = Br, Cl/Br) Unit

    Inorganic Chemistry · 2021-03-25

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  50. Hybrid organic–inorganic perovskite ferroelectrics bring light to semiconducting applications: Bandgap engineering as a starting point

    APL Materials · 2021-04-01

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