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RESEARCH PAPER · Chemistry - A European Journal · 2020

Two Rare‐Earth Molecular Ferroelectrics with High Curie Temperatures, Large Spontaneous Polarization, Switchable Second Harmonic Generation Effects, and Strong Photoluminescence

Kang Yang, Chang‐Shan Yang, Xing‐Xian Dong, Yu‐Hui Tan, Yun‐Zhi Tang, Wen‐Juan Wei

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Two Rare‐Earth Molecular Ferroelectrics with High Curie Temperatures, Large Spontaneous Polarization, Switchable Second Harmonic Generation Effects, and Strong PhotoluminescenceOriginalPhoto-induced PM 2.5 adsorption in molecular ferroelectric heterostructures6Reversible structural phase transition, dielectric switches and photoluminescence based on hexathiocyanate Thulium(III) anions14Successive Phase Transitions and Dual Dielectric Switching in an Organic–Inorganic Hybrid Perovskite37Coupling Narrow Band Gap and Switchable SHG Responses in a New Molecule Ferroelectric: Imidazolyl Propylamine Pentabromo Stibium(III)31Multifunctional rare earth molecular ferroelectrics with a piezoelectric response: (( n Bu) 4 N) 3 [Ce(NO 3 ) 4 (SCN) 2 ]((CH 3 CH 2 CH 2 CH 2 ) 4 N = tetrabutylammonium)13Para–ferroelectric phase transition induces an excellent second harmonic generation response and a prominent switchable dielectric constant change based on a metal-free ionic crystal11Crystal Structure and Ferroelectric Evidence of BaZnSi3O8, a Low‐Permittivity Microwave Dielectric Ceramic16High‐Temperature and Large‐Polarization Ferroelectric with Second Harmonic Generation Response in a Novel Crown Ether Clathrate16Elastocaloric effect in vulcanized natural rubber and natural/wastes rubber blends48Dielectric switching from a high temperature plastic phase transition in two organic salts with chiral features14A 1D chiral infinite chain organic metal halide hybrid with excellent SHG switching and moderate spontaneous polarization28Two quasi-spherical molecules [1,4-diazabicyclo(3.2.2)nonane]X (X = ClO 4 , ReO 4 ) exhibit switchable phase transition, dielectric and second-harmonic-generation properties1Unusual high-temperature host–guest inclusion compound-based ferroelectrics with nonlinear optical switching and large spontaneous polarization behaviours25Unusual symmetry breaking in high-temperature enantiomeric ferroelectrics with large spontaneous polarization20Two Manganese(II)-Based Hybrid Multifunctional Phase Transition Materials with Strong Photoluminescence, High Quantum Yield, and Switchable Dielectric Properties: (C 6 NH 16 ) 2 MnBr 4 and (C 7 NH 18 ) 2 MnBr 439H/F Substitution Induced Enhancement of Phase Transition Temperature and Quantum Yield in Rare-Earth Hybrid Perovskite11Chlorocholine Perchlorate is an Organic Ferroelectric with Two‐Step Ladder‐like Dielectric, Second Harmonic Generation Effects, and Ferroelectricity2Organic‐Inorganic Hybrid Ferroelectric and Antiferroelectric with Afterglow Emission49Organic‐Inorganic Hybrid Ferroelectric and Antiferroelectric with Afterglow Emission10Remarkable Second Harmonic Generation Response in (C 5 H 6 NO) + (CH 3 SO 3 ) − : Unraveling the Role of Hydrogen Bond in Thermal Driven Nonlinear Optical Switch50Remarkable Second Harmonic Generation Response in (C5H6NO)+(CH3SO3)−: Unraveling the Role of Hydrogen Bond in Thermal Driven Nonlinear Optical Switch10New hybrid thiocyanates: Crystal structures, optical properties and unusual dielectric switching properties5Structural distortions and phase transition behavior in a new thiocyanate-based manganese(II) hybrid: Combined experimental and theoretical investigation2Antimony Compounds as Potential Ferroelectric Materials1A Ferroelectric Zinc-Based Complex with Ultraviolet Emission3Multifunctional Lanthanide Molecular Ferroelectrics [ R / S -H 2 MPPA][Ln(btfa) 4 ] 2 Constructed by Hydrogen Bond Linking Functional Blocks3High Saturation Polarization Ferroelectricity in a Pair of α‐Phase Enantiomorphic Crystals Based on Calabash‐Shaped Molecules0High Saturation Polarization Ferroelectricity in a Pair of α‐Phase Enantiomorphic Crystals Based on Calabash‐Shaped Molecules0

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  1. Photo-induced PM 2.5 adsorption in molecular ferroelectric heterostructures

    Journal of Materials Chemistry C · 2020-01-01

    Kaige Gao, Chunlin Liu, Binbin Zhang

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  2. Reversible structural phase transition, dielectric switches and photoluminescence based on hexathiocyanate Thulium(III) anions

    Inorganica Chimica Acta · 2020-10-01

    Xing‐Xian Dong, Ning Song, Bin Huang, Yu‐Hui Tan, Yun‐Zhi Tang, Wen‐Juan Wei, Yu-Kong Li, Qing Shu

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  3. Successive Phase Transitions and Dual Dielectric Switching in an Organic–Inorganic Hybrid Perovskite

    Inorganic Chemistry · 2020-12-09

    Lin Zhou, Ruixia Li, Ping‐Ping Shi, Qiong Ye, Da‐Wei Fu

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  4. Coupling Narrow Band Gap and Switchable SHG Responses in a New Molecule Ferroelectric: Imidazolyl Propylamine Pentabromo Stibium(III)

    Inorganic Chemistry · 2020-12-24

    Ning Song, Xing‐Xian Dong, Jiachang Zhuang, Yukong Li, Ding‐Chong Han, Yu‐Hui Tan, Wen‐Juan Wei, Yun‐Zhi Tang

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  5. Multifunctional rare earth molecular ferroelectrics with a piezoelectric response: (( n Bu) 4 N) 3 [Ce(NO 3 ) 4 (SCN) 2 ]((CH 3 CH 2 CH 2 CH 2 ) 4 N = tetrabutylammonium)

    CrystEngComm · 2021-01-01

    Ting‐Ting Ying, Yu‐Hui Tan, Yun‐Zhi Tang, Xiao Jiang Long, Ning Song, Yukong Li, Zhen Yu Sun

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  6. Para–ferroelectric phase transition induces an excellent second harmonic generation response and a prominent switchable dielectric constant change based on a metal-free ionic crystal

    CrystEngComm · 2021-01-01

    Ding‐Chong Han, Yu-Kong Li, Yao Liu, Yu‐Hui Tan, Yun‐Zhi Tang, Wen‐Juan Wei, Peng-kang Du, Hao Zhang

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  7. Crystal Structure and Ferroelectric Evidence of BaZnSi3O8, a Low‐Permittivity Microwave Dielectric Ceramic

    Chemistry - A European Journal · 2021-01-18

    Zheng‐Yu Zou, Xiaoqiang Song, Lei Jiang, Changlai Yuan, Wenzhong Lü, Yongming Hu, Wen Lei

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  8. High‐Temperature and Large‐Polarization Ferroelectric with Second Harmonic Generation Response in a Novel Crown Ether Clathrate

    Chemistry - A European Journal · 2021-07-28

    Ding Chong Han, Yu Tan, Yu Kong Li, Jia Hui Wen, Yun‐Zhi Tang, Wen Juan Wei, Peng-kang Du, Hao Zhang

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  9. Elastocaloric effect in vulcanized natural rubber and natural/wastes rubber blends

    Polymer · 2021-10-29

    Nicolas Candau, Eduard Vives, Ana Inés Fernández, Maria Lluïsa Maspoch

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  10. Dielectric switching from a high temperature plastic phase transition in two organic salts with chiral features

    Materials Advances · 2021-12-20

    Ting‐Ting Ying, Yan‐Le Huang, Ning Song, Yu‐Hui Tan, Yun‐Zhi Tang, Zhen Yu Sun, Jiachang Zhuang, Xing‐Xian Dong

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  11. A 1D chiral infinite chain organic metal halide hybrid with excellent SHG switching and moderate spontaneous polarization

    New Journal of Chemistry · 2022-01-01

    Jiachang Zhuang, Yu‐Hui Tan, Xiao‐Wei Fan, Yun‐Zhi Tang, Ning Song, Yihua Zhang, Hao Zhang, Shaopeng Chen

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  12. Two quasi-spherical molecules [1,4-diazabicyclo(3.2.2)nonane]X (X = ClO 4 , ReO 4 ) exhibit switchable phase transition, dielectric and second-harmonic-generation properties

    New Journal of Chemistry · 2022-01-01

    Xiuli You, Wenjun Rao, Keke Han, Lingyu Wang, Mengxia Zhang, Zhenhong Wei

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  13. Unusual high-temperature host–guest inclusion compound-based ferroelectrics with nonlinear optical switching and large spontaneous polarization behaviours

    Inorganic Chemistry Frontiers · 2022-01-01

    Yu-Kong Li, Yu‐Hui Tan, Yun‐Zhi Tang, Xiao‐Wei Fan, Su-Fen Wang, Ting‐Ting Ying, Hao Zhang

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  14. Unusual symmetry breaking in high-temperature enantiomeric ferroelectrics with large spontaneous polarization

    Dalton Transactions · 2022-01-01

    Yu-Kong Li, Ting‐Ting Ying, Hao Zhang, Yu‐Hui Tan, Yun‐Zhi Tang, Fang‐Xin Wang, Ming‐Yang Wan

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  15. Two Manganese(II)-Based Hybrid Multifunctional Phase Transition Materials with Strong Photoluminescence, High Quantum Yield, and Switchable Dielectric Properties: (C 6 NH 16 ) 2 MnBr 4 and (C 7 NH 18 ) 2 MnBr 4

    Inorganic Chemistry · 2022-06-28

    Hao Zhang, Yu‐Hui Tan, Yun‐Zhi Tang, Xiao‐Wei Fan, Xin‐Lin Peng, Rui‐Rui Han, Yu-Kong Li, Fang‐Xin Wang

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  16. H/F Substitution Induced Enhancement of Phase Transition Temperature and Quantum Yield in Rare-Earth Hybrid Perovskite

    Crystal Growth & Design · 2022-12-12

    Wang Luo, Zhi‐Yuan Yue, Na Wang, Hua‐Kai Li, Ze‐Jiang Xu, Heng‐Yun Ye, Lang Liu, Chao Yi Shi, Le‐Ping Miao

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  17. Chlorocholine Perchlorate is an Organic Ferroelectric with Two‐Step Ladder‐like Dielectric, Second Harmonic Generation Effects, and Ferroelectricity

    ChemPhysChem · 2023-04-24

    Duo‐Fu Li, Yao‐Zhen Wu, Xiaoli He, Xiang‐Hong Deng, Jing Chen, Jia Fu, Yan Sui

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  18. Organic‐Inorganic Hybrid Ferroelectric and Antiferroelectric with Afterglow Emission

    Angewandte Chemie International Edition · 2024-01-26

    Zhi‐Xu Zhang, He Wang, Hao‐Fei Ni, Na Wang, Changfeng Wang, Pei‐Zhi Huang, Qiang‐Qiang Jia, Gele Teri, Da‐Wei Fu, Yujian Zhang, Zhongfu An, Yi Zhang

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  19. Organic‐Inorganic Hybrid Ferroelectric and Antiferroelectric with Afterglow Emission

    Angewandte Chemie · 2024-01-26

    Zhi‐Xu Zhang, He Wang, Hao‐Fei Ni, Na Wang, Changfeng Wang, Pei‐Zhi Huang, Qiang‐Qiang Jia, Gele Teri, Da‐Wei Fu, Yujian Zhang, Zhongfu An, Yi Zhang

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  20. Remarkable Second Harmonic Generation Response in (C 5 H 6 NO) + (CH 3 SO 3 ) − : Unraveling the Role of Hydrogen Bond in Thermal Driven Nonlinear Optical Switch

    Angewandte Chemie International Edition · 2024-06-10

    Zi‐Peng Zhang, Xin Liu, Rui‐Xi Wang, Shuang Zhao, Wen‐Jie He, Hong‐Yu Chen, Xue‐Bin Deng, Li‐Ming Wu, Zhengyang Zhou, Ling Chen

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  21. Remarkable Second Harmonic Generation Response in (C5H6NO)+(CH3SO3)−: Unraveling the Role of Hydrogen Bond in Thermal Driven Nonlinear Optical Switch

    Angewandte Chemie · 2024-06-11

    Zi‐Peng Zhang, Xin Liu, Rui‐Xi Wang, Shuang Zhao, Wen‐Jie He, Hong‐Yu Chen, Xue‐Bin Deng, Li‐Ming Wu, Zhengyang Zhou, Ling Chen

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  22. New hybrid thiocyanates: Crystal structures, optical properties and unusual dielectric switching properties

    Inorganic Chemistry Communications · 2025-03-18

    Soulayma Mtar, Mirosław Mączka, Szymon Smółka, Maciej Ptak, Michał Winkel, Anna Gągor, Adam Sieradzki, Mohamed Boujelbene

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  23. Structural distortions and phase transition behavior in a new thiocyanate-based manganese(II) hybrid: Combined experimental and theoretical investigation

    Inorganic Chemistry Communications · 2025-11-20

    Soulayma Mtar, Emna Bouaziz, Mirosław Mączka, Paulina Peksa, Sergiu G. Shova, Adam Sieradzki, Mohamed Boujelbene

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  24. Antimony Compounds as Potential Ferroelectric Materials

    Inorganic Materials Applied Research · 2025-12-01

    Alexey Milinskii, Irina V. Egorova, I. N. Nesina

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  25. A Ferroelectric Zinc-Based Complex with Ultraviolet Emission

    Inorganic Chemistry · 2026-02-02

    Gen-Feng Li, Zhe‐Kun Xu, Huan Xu, Xiao‐Gang Chen, Yan Qin, Peng‐Fei Li

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  26. Multifunctional Lanthanide Molecular Ferroelectrics [ R / S -H 2 MPPA][Ln(btfa) 4 ] 2 Constructed by Hydrogen Bond Linking Functional Blocks

    Inorganic Chemistry · 2026-02-24

    Chun-Pu Chen, Xiaolu Guo, Ya Gao, Ping Lu, Dongcheng Liu, Fu-Pei Liang

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  27. High Saturation Polarization Ferroelectricity in a Pair of α‐Phase Enantiomorphic Crystals Based on Calabash‐Shaped Molecules

    Angewandte Chemie International Edition · 2026-08-25

    Mengxiang Luo, Xiao Sun, Yanlin LAI, Si Yang, Lin Zhou, Xiuli You, Wenjing Guo, Zhenhong Wei, Hu Cai

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  28. High Saturation Polarization Ferroelectricity in a Pair of α‐Phase Enantiomorphic Crystals Based on Calabash‐Shaped Molecules

    Angewandte Chemie · 2026-08-25

    Mengxiang Luo, Xiao Sun, Yanlin LAI, Si Yang, Lin Zhou, Xiuli You, Wenjing Guo, Zhenhong Wei, Hu Cai

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