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RESEARCH PAPER · Chemical Society Reviews · 2017

An updated roadmap for the integration of metal–organic frameworks with electronic devices and chemical sensors

Ivo Stassen, Nicholas C. Burtch, Alec A. Talin, Paolo Falcaro, Mark D. Allendorf, Rob Ameloot

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An updated roadmap for the integration of metal–organic frameworks with electronic devices and chemical sensorsOriginalSurface-supported metal–organic framework thin films: fabrication methods, applications, and challenges698RETRACTED: Metallic Conductivity in a Two-Dimensional Cobalt Dithiolene Metal–Organic Framework359Mixed-Ligand LMOF Fluorosensors for Detection of Cr(VI) Oxyanions and Fe3+/Pd2+ Cations in Aqueous Media176A Microporous and Naturally Nanostructured Thermoelectric Metal-Organic Framework with Ultralow Thermal Conductivity246Signature of Metallic Behavior in the Metal–Organic Frameworks M 3 (hexaiminobenzene) 2 (M = Ni, Cu)449Construction of heterostructured ZnIn2S4@NH2-MIL-125(Ti) nanocomposites for visible-light-driven H2 production579Electrocatalytic Metal–Organic Frameworks for Energy Applications226The Applications of Metal−Organic Frameworks in Electrochemical Sensors409Self-Organized Frameworks on Textiles (SOFT): Conductive Fabrics for Simultaneous Sensing, Capture, and Filtration of Gases342Mechanical Properties in Metal–Organic Frameworks: Emerging Opportunities and Challenges for Device Functionality and Technological Applications262Conductive two-dimensional metal–organic frameworks as multifunctional materials530Electronic metal–organic framework sensors147Highly sensitive and selective SO 2 MOF sensor: the integration of MFM-300 MOF as a sensitive layer on a capacitive interdigitated electrode175Luminescent metal–organic frameworks as chemical sensors: common pitfalls and proposed best practices158Metal–organic framework nanosheets (MONs): a new dimension in materials chemistry161New synthetic strategies to prepare metal–organic frameworks306Stable dye-encapsulated indium–organic framework as dual-emitting sensor for the detection of Hg 2+ /Cr 2 O 7 2− and a wide range of nitro-compounds149The role of redox hopping in metal–organic framework electrocatalysis189The simultaneous detection and removal of organophosphorus pesticides by a novel Zr-MOF based smart adsorbent286Metal–Organic Framework Thin Film Coated Optical Fiber Sensors: A Novel Waveguide-Based Chemical Sensing Platform207Multifunctional Sensor Based on Porous Carbon Derived from Metal–Organic Frameworks for Real Time Health Monitoring160Shape engineering of metal–organic frameworks240Titanium-based metal–organic frameworks for photocatalytic applications347Bottom‐Up Fabrication of Semiconductive Metal–Organic Framework Ultrathin Films228Defective Metal‐Organic Frameworks728Construction of a Hierarchical Architecture of Covalent Organic Frameworks via a Postsynthetic Approach168Functionalization of Metal–Organic Frameworks for Photoactive Materials188Development of a UiO-Type Thin Film Electrocatalysis Platform with Redox-Active Linkers170Metal–Organic Frameworks for High Charge–Discharge Rates in Lithium–Sulfur Batteries399Metal–Organic Frameworks as Platform Materials for Solar Fuels Catalysis168Through-Space Intervalence Charge Transfer as a Mechanism for Charge Delocalization in Metal–Organic Frameworks166Lower Activation Energy for Catalytic Reactions through Host–Guest Cooperation within Metal–Organic Frameworks211Interface-Assisted Synthesis of 2D Materials: Trend and Challenges710A coronene-based semiconducting two-dimensional metal-organic framework with ferromagnetic behavior344Facile Synthesis of Vanadium Metal‐Organic Frameworks for High‐Performance Supercapacitors220Single-Phase White-Light-Emitting and Photoluminescent Color-Tuning Coordination Assemblies567Polyoxometalate-Based Metal–Organic Frameworks with Conductive Polypyrrole for Supercapacitors211Ultrathin two-dimensional metal-organic framework nanosheets for functional electronic devices222Large‐Area Preparation of Crack‐Free Crystalline Microporous Conductive Membrane to Upgrade High Energy Lithium–Sulfur Batteries243High-mobility band-like charge transport in a semiconducting two-dimensional metal–organic framework526Covalent-Organic Frameworks Composed of Rhenium Bipyridine and Metal Porphyrins: Designing Heterobimetallic Frameworks with Two Distinct Metal Sites139Flexible Films of Covalent Organic Frameworks with Ultralow Dielectric Constants under High Humidity188Conductance Photoswitching of Metal–Organic Frameworks with Embedded Spiropyran1582D Metal–Organic Framework Nanosheets with Time‐Dependent and Multilevel Memristive Switching155Antibodies@MOFs: An In Vitro Protective Coating for Preparation and Storage of Biopharmaceuticals176Reversible Optical Writing and Data Storage in an Anthracene‐Loaded Metal–Organic Framework153A new post-synthetic polymerization strategy makes metal–organic frameworks more stable170Diverse π–π stacking motifs modulate electrical conductivity in tetrathiafulvalene-based metal–organic frameworks181Emerging porous materials in confined spaces: from chromatographic applications to flow chemistry157Photofunctional MOF-based hybrid materials for the chemical sensing of biomarkers135Electrically-Transduced Chemical Sensors Based on Two-Dimensional Nanomaterials773Cyclodextrin-metal–organic framework (CD-MOF): From synthesis to applications241Stable Hierarchical Bimetal–Organic Nanostructures as HighPerformance Electrocatalysts for the Oxygen Evolution Reaction506Synthesis of MOF-derived nanostructures and their applications as anodes in lithium and sodium ion batteries269MOF‐on‐MOF: Oriented Growth of Multiple Layered Thin Films of Metal–Organic Frameworks222Integration of a (–Cu–S–)n plane in a metal–organic framework affords high electrical conductivity199Metal–Organic Framework-Templated Biomaterials: Recent Progress in Synthesis, Functionalization, and Applications163Alternatives to Cryogenic Distillation: Advanced Porous Materials in Adsorptive Light Olefin/Paraffin Separations342Metal-Organic Frameworks for Chemiresistive Sensors680Rising Up: Hierarchical Metal–Organic Frameworks in Experiments and Simulations146Recent advances of molecularly imprinted polymer-based sensors in the detection of food safety hazard factors178Engineering Donor–Acceptor Heterostructure Metal–Organic Framework Crystals for Photonic Logic Computation155Van der Waals Heterostructured MOF‐on‐MOF Thin Films: Cascading Functionality to Realize Advanced Chemiresistive Sensing305Metal–Organic Frameworks for Food Safety533Renal-Clearable Porphyrinic Metal–Organic Framework Nanodots for Enhanced Photodynamic Therapy160Linker functionalized metal-organic frameworks341Photostimulus‐Responsive Large‐Area Two‐Dimensional Covalent Organic Framework Films195Nanohybrid photocatalysts with ZnIn2S4 nanosheets encapsulated UiO-66 octahedral nanoparticles for visible-light-driven hydrogen generation242Electrocatalytic Hydrogen Evolution from a Cobaloxime-Based Metal–Organic Framework Thin Film223MOFs and COFs for Batteries and Supercapacitors189Advanced Photoresponsive Materials Using the Metal–Organic Framework Approach297Efficient and tunable one-dimensional charge transport in layered lanthanide metal–organic frameworks341Single Crystals of Electrically Conductive Two-Dimensional Metal–Organic Frameworks: Structural and Electrical Transport Properties403Electrospinning of Metal–Organic Frameworks for Energy and Environmental Applications370Recent developments in luminescent coordination polymers: Designing strategies, sensing application and theoretical evidences508Controlling the morphology of metal–organic frameworks and porous carbon materials: metal oxides as primary architecture-directing agents333Electrical conductivity and magnetic bistability in metal–organic frameworks and coordination polymers: charge transport and spin crossover at the nanoscale204Functional metal–organic frameworks as effective sensors of gases and volatile compounds1241Recent advances in the shaping of metal–organic frameworks157Sensing organic analytes by metal–organic frameworks: a new way of considering the topic295Hydrophobic Metal–Organic Frameworks: Assessment, Construction, and Diverse Applications284Fluorinated metal-organic framework as bifunctional filler toward highly improving output performance of triboelectric nanogenerators166Demonstration of a Broadband Photodetector Based on a Two‐Dimensional Metal–Organic Framework183Halogenated Metal–Organic Framework Glasses and Liquids159The Chemistry of Reticular Framework Nanoparticles: MOF, ZIF, and COF Materials350Imaging Beam‐Sensitive Materials by Electron Microscopy219Conductive MOFs373Gas Sensors Based on Chemi-Resistive Hybrid Functional Nanomaterials429Electrically Conductive Metal–Organic Frameworks1999Metal ion detection using luminescent-MOFs: Principles, strategies and roadmap262Area-Selective Deposition: Fundamentals, Applications, and Future Outlook360Metal-organic frameworks-based sensitive electrochemiluminescence biosensing169Four-dimensional metal-organic frameworks153Pseudocapacitance: From Fundamental Understanding to High Power Energy Storage Materials1942Electroactive Covalent Organic Frameworks: Design, Synthesis, and Applications217Electronic Structure Modeling of Metal–Organic Frameworks329Electronic Devices Using Open Framework Materials315A Porphyrinic Zirconium Metal–Organic Framework for Oxygen Reduction Reaction: Tailoring the Spacing between Active-Sites through Chain-Based Inorganic Building Units247Metal–organic frameworks and their derivatives for electrically-transduced gas sensors264Advanced technologies for the fabrication of MOF thin films157Construction of NH2-MIL-125(Ti)/CdS Z-scheme heterojunction for efficient photocatalytic H2 evolution148Fabrication of ultra-thin 2D covalent organic framework nanosheets and their application in functional electronic devices136Luminescence response mode and chemical sensing mechanism for lanthanide-functionalized metal–organic framework hybrids278Direct X-ray and electron-beam lithography of halogenated zeolitic imidazolate frameworks199Pristine Hollow Metal–Organic Frameworks: Design, Synthesis and Application242Rare earth metal–organic frameworks (RE-MOFs): Synthesis, properties, and biomedical applications257Biosensors based on fluorescence carbon nanomaterials for detection of pesticides216Atomically precise single-crystal structures of electrically conducting 2D metal–organic frameworks457Construction of hierarchical ZnIn2S4@PCN-224 heterojunction for boosting photocatalytic performance in hydrogen production and degradation of tetracycline hydrochloride3391 + 1 > 2: A critical review of MOF/bismuth-based semiconductor composites for boosted photocatalysis139Copper( i )–iodide cluster structures as functional and processable platform materials266Metal–organic frameworks for chemical sensing devices327Nanoconfinement and mass transport in metal–organic frameworks188Recent progress on pristine metal/covalent-organic frameworks and their composites for lithium–sulfur batteries263Recent progress on pristine two-dimensional metal–organic frameworks as active components in supercapacitors170Two-dimensional conjugated metal–organic frameworks (2D c -MOFs): chemistry and function for MOFtronics563Ferrocene-contained metal organic frameworks: From synthesis to applications139Two-dimensional MOF and COF nanosheets for next-generation optoelectronic applications190Asymmetric catalysis using metal-organic frameworks142Recent advances in the development of electronically and ionically conductive metal-organic frameworks232Functional supramolecular systems: design and applications143Metal organic framework (MOF) in aqueous energy devices136The Current Status of MOF and COF Applications1194Porphyrinic MOF Film for Multifaceted Electrochemical Sensing213Metal–Organic Framework Nanosheets: Programmable 2D Materials for Catalysis, Sensing, Electronics, and Separation Applications191Enhanced catalytic sulfamethoxazole degradation via peroxymonosulfate activation over amorphous CoSx@SiO2 nanocages derived from ZIF-67231Glucose Detection Devices and Methods Based on Metal–Organic Frameworks and Related Materials180Layer‐by‐Layer Growth of Preferred‐Oriented MOF Thin Film on Nanowire Array for High‐Performance Chemiresistive Sensing185Metal-organic frameworks (MOFs) and their derivatives as emerging catalysts for electro-Fenton process in water purification179Metal-organic framework-based materials for flexible supercapacitor application209Carbon Nanotube Based Metal–Organic Framework Hybrids From Fundamentals Toward Applications155Metal‐Organic Framework Based Gas Sensors491A Zr-MOF nanoflower sensor and its mixed-matrix membrane for the highly sensitive detection of nitroaromatics184Recent advances in metal–organic frameworks for gas adsorption/separation262Recent progress on MOF-based optical sensors for VOC sensing256Metal–Organic Network-Forming Glasses313Bromo- and iodo-bridged building units in metal-organic frameworks for enhanced carrier transport and CO2 photoreduction by water vapor135Metal‐Organic Frameworks and Electrospinning: A Happy Marriage for Wastewater Treatment223Porous crystalline materials for memories and neuromorphic computing systems166Tackling orientation of metal-organic frameworks (MOFs): The quest to enhance MOF performance396Post‐Synthetic Surface Modification of Metal–Organic Frameworks and Their Potential Applications190A label-free multicolor colorimetric and fluorescence dual mode biosensing of HIV-1 DNA based on the bifunctional NiFe2O4@UiO-66 nanozyme151Advances in flexible sensors for intelligent perception system enhanced by artificial intelligence165Molecular Catalysis of Energy Relevance in Metal–Organic Frameworks: From Higher Coordination Sphere to System Effects141A comprehensive review on thermal management of electronic devices207Biomedical Metal–Organic Framework Materials: Perspectives and Challenges188Application of metal-organic frameworks for sensing of VOCs and other volatile biomarkers137Defect-enabling zirconium-based metal–organic frameworks for energy and environmental remediation applications217Strategies to Improve Electrical Conductivity in Metal–Organic Frameworks: A Comparative Study198Metal-organic frameworks: A comprehensive review on common approaches to enhance the energy storage capacity in supercapacitor157

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