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RESEARCH PAPER · Chemical Communications · 2016

Controllable Eu valence for photoluminescence tuning in apatite-typed phosphors by the cation cosubstitution effect

Guogang Li, Chun Che Lin, Yi Wei, Zewei Quan, Ying Tian, Yun Zhao, Ting‐Shan Chan, Jun Lin

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Controllable Eu valence for photoluminescence tuning in apatite-typed phosphors by the cation cosubstitution effectOriginalOrigin of blue emission of phosphors prepared by a solid-state reaction of Eu3+-doped LaCO3OH with Al2O3 in a hydrogen atmosphere2New insight into the structure evolution and site preferential occupancy of Na 2 Ba 6 (Si 2 O 7 )(SiO 4 ) 2 :Eu 2+ phosphor by cation substitution effect24Emitting-tunable Eu (2+/3+) -doped Ca (8−x) La (2+x) (PO 4 ) 6−x (SiO 4 ) x O 2 apatite phosphor for n-UV WLEDs with high-color-rendering27Improving photoluminescence and thermal stability of CaSi2O2N2:Eu2+ phosphors by codoping lanthanide ions (Ln = Sc, La, Gd, Yb, Lu)10Triple energy transfer and color tuning in Tb3+ and Eu3+-coactivated apatite-type gadolinium-containing phosphors18Structural properties and self-activated photoluminescence emissions in hydroxyapatite with distinct particle shapes59Achieving High Quantum Efficiency Narrow-Band β-Sialon:Eu 2+ Phosphors for High-Brightness LCD Backlights by Reducing the Eu 3+ Luminescence Killer356Electronic structure and photoluminescence properties of single component white emitting Sr 3 LuNa(PO 4 ) 3 F:Eu 2+ ,Mn 2+ phosphor for WLEDs53Neutralizing the Charge Imbalance Problem in Eu3+-Activated BaAl2O4 Nanophosphors: Theoretical Insights and Experimental Validation Considering K+ Codoping63Blue shift behavior of Eu2+ emission in eulytite-type Sr3La(PO4)3 phosphor based on the release of adjacent Eu3+-induced stress39Color tunable Ba3Lu(PO4)3:Tb3+,Mn2+ phosphor via Tb3+→Mn2+ energy transfer for white LEDs13Sr4Y6(AlO4)x(SiO4)6-xOδ:Eu2+: A novel apatite structure blue-green emitting phosphor17Energy Transfer and Multicolor Tunable Luminescence Properties of NaGd0.5Tb0.5−xEux(MoO4)2 Phosphors for UV-LED30Eu3+-doped highly thermal-stable barium yttrium aluminate as a red-emitting phosphor for UV based white LED45Tuning the luminescence of Ca 9 La(PO 4 ) 7 :Eu 2+ via artificially inducing potential luminescence centers35Controllable Eu 2+ -Doped Orthophosphate Blue-/Red-Emitting Phosphors: Charge Compensation and Lattice-Strain Control49Valent control and spectral tuning by cation site engineering strategy in Eu doped Sr1−Ba Al2Si2O8 phosphor18From Nonluminescence to Bright Blue Emission: Boron-Induced Highly Efficient Ce3+-Doped Hydroxyapatite Phosphor44Photoluminescence properties and energy transfer of apatite-type Sr3LaNa(PO4)3 F:Ce3+, Tb3+ phosphors3Controllable Eu valence based on linear structural evolution in single-phased Sr3-La1+(PO4)3-(SiO4) phosphors to realize tunable/white light emissions7Optical thermometric properties in Tb3+ and Eu3+-coactivated dual-emissive fluorophosphate phosphors54Enhanced green emission and thermal stability of Ba3Si6O12N2:Eu2+ by Ce3+/P5+-doping: Unity energy transfer, charge compensation and lattice strain release6Achieving tunable emitting YAl 3 (BO 3 ) 4 :Eu phosphors by substituting cations (Sr 2+ , Ca 2+ , Ga 3+ , In 3+ ) and controlling BO 3 group polarizability11Site-selective occupation of Eu2+ activators toward full-visible-spectrum emission in well-designed borophosphate phosphors96Tuning luminescence and excellent thermal stability of Gd4.67Si3O13: Bi3+, Eu3+ with energy transfer from Bi3+ to Eu3+25Correlation among photoluminescence and the electronic and atomic structures of Sr2SiO4:xEu3+ phosphors: X-ray absorption and emission studies25Vacancies Substitution Tuning Photoluminescence and Distortion Triggered Eu Migration in NASICON-Type Phosphors11Reduction Mechanism of Eu 3+ in Ca 2+x La 8−x (SiO 4 )6O 2–0.5x : Eu 2+ Phosphors3Controlling Cr3+/Cr4+ concentration in single-phase host toward tailored super-broad near-infrared luminescence for multifunctional applications99Extension of Spectral Shift Controls from Equivalent Substitution to an Energy Migration Model Based on Eu2+/Tb3+-Activated Ba4–xSrxGd3–xLuxNa3(PO4)6F2 Phosphors11Self-reduction-induced BaMgP 2 O 7 :Eu 2+/3+ : a multi-stimuli-responsive phosphor for X-ray detection, anti-counterfeiting and optical thermometry36Effect of Al3+ on the photoluminescence and radioluminescence properties of Mn2+-Doped high silica glass11Enhanced luminescence efficiency and thermal stability via introduction of non-rare earth Bi3+ in Gd5Si2BO13:Eu3+22Effective regulation of electronic structures and luminescence properties of LiGd9(SiO4)6–(GeO4) O2:Dy3+ phosphors by tetrahedral substitution13Local structure distortion enhanced the emission intensity of KBaYSi2O7:Eu2+ phosphor for full-visible-spectrum LED lighting4Oxynitride K 2 Ba 6.72 Si 16 O 40−1.5 y N y :0.28Eu 2+ phosphor with high thermal stability realized by crystal field engineering1Enhanced red luminescence of Ca 3 Si 2− x M x O 7 :Eu 3+ (M = Al, P) phosphors via partial substitution of Si 4+ for applications in white light‐emitting diodes49Mg2+–Ca2+/Sr2+–Ca2+ bicationic sites inducing Eu2+ occupying triggering C2S emitting structure unit evolution and luminescence characteristics0Crystal Structure and Spectral Tuning of Eu2+/Eu3+ Co-Activated Na2ba1- X Sr X Ca(Po4)2 Phosphors with High Thermal Stability1Eu2+/Eu3+ Co-Activated Ba2la8(Sio4)6o2 Phosphors for Optical Thermometry1Eu2+/Eu3+ Co-Activated Ba2la8(Sio4)6o2 Phosphors for Optical Thermometry0Eu2+ doping and Mg2+-coupled Zn2+, Ca2+ and Sr2+ cations induce tunable orange-blue luminescence in cordierite3Optimizing luminescence intensity and thermal stability of Gd5Si2BO13:Tb3+ through the incorporation of non-rare earth Bi3+7Eu2+/Eu3+ co-activated Ba2La8(SiO4)6O2 phosphors for optical thermometry7High thermal stability Gd5--Si2BO13:xTb3+, yEu3+ phosphors achieve color tunable emission through Tb3+-Eu3+ energy transfer5Luminescence enhancement of CaLa3.56Ti4-M O15:0.44Eu3+ (M = Si, Zr) red-emitting phosphor via the partial substitution of Ti4+ for white light-emitting diodes and plant lighting3

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  1. Origin of blue emission of phosphors prepared by a solid-state reaction of Eu3+-doped LaCO3OH with Al2O3 in a hydrogen atmosphere

    Ceramics International · 2016-10-19

    Min‐Ho Lee, Woo-Sik Jung

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  2. New insight into the structure evolution and site preferential occupancy of Na 2 Ba 6 (Si 2 O 7 )(SiO 4 ) 2 :Eu 2+ phosphor by cation substitution effect

    Journal of Alloys and Compounds · 2016-12-18

    Yingli Zhu, Yujun Liang, Shiqi Liu, Xingya Wu, Rui Xu, Kai Li

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  3. Emitting-tunable Eu (2+/3+) -doped Ca (8−x) La (2+x) (PO 4 ) 6−x (SiO 4 ) x O 2 apatite phosphor for n-UV WLEDs with high-color-rendering

    RSC Advances · 2017-01-01

    Yi Wei, Hui Min Jia, Hui Jin Xiao, Meng Meng Shang, Chun Che Lin, Chaochin Su, Ting‐Shan Chan, Guo Gang Li, Jun Lin

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  4. Improving photoluminescence and thermal stability of CaSi2O2N2:Eu2+ phosphors by codoping lanthanide ions (Ln = Sc, La, Gd, Yb, Lu)

    Materials Letters · 2017-09-14

    Jiarui Hao, Ling Cao, Yi Wei, Chunjie Yan, Guogang Li

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  5. Triple energy transfer and color tuning in Tb3+ and Eu3+-coactivated apatite-type gadolinium-containing phosphors

    Optical Materials · 2017-09-20

    Ning Guo, Qimeng Liang, Shuo Li, Ruizhuo Ouyang, Wei Lü

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  6. Structural properties and self-activated photoluminescence emissions in hydroxyapatite with distinct particle shapes

    Ceramics International · 2017-09-21

    Thales Rafael Machado, J.C. Sczancoski, Héctor Beltrán‐Mir, Máximo Siu Li, Juán Andrés, Eloísa Cordoncillo, Edson Roberto Leite, E. Longo

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  7. Achieving High Quantum Efficiency Narrow-Band β-Sialon:Eu 2+ Phosphors for High-Brightness LCD Backlights by Reducing the Eu 3+ Luminescence Killer

    Chemistry of Materials · 2017-12-14

    Shuxing Li, Le Wang, Dai‐Ming Tang, Yujin Cho, Xuejian Liu, Xingtai Zhou, Lu Lu, Lin Zhang, Takashi Takeda, Naoto Hirosaki, Rong‐Jun Xie

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  8. Electronic structure and photoluminescence properties of single component white emitting Sr 3 LuNa(PO 4 ) 3 F:Eu 2+ ,Mn 2+ phosphor for WLEDs

    Journal of Materials Chemistry C · 2018-01-01

    Mengmeng Jiao, Qinfeng Xu, Chuan‐Lu Yang, Mingliang Liu

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  9. Neutralizing the Charge Imbalance Problem in Eu3+-Activated BaAl2O4 Nanophosphors: Theoretical Insights and Experimental Validation Considering K+ Codoping

    ACS Omega · 2018-01-22

    Rituparna Chatterjee, Subhajit Saha, Dipayan Sen, Karamjyoti Panigrahi, Uttam Kumar Ghorai, G. C. Das, Kalyan Kumar Chattopadhyay

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  10. Blue shift behavior of Eu2+ emission in eulytite-type Sr3La(PO4)3 phosphor based on the release of adjacent Eu3+-induced stress

    Journal of Alloys and Compounds · 2018-01-31

    Yue Guo, Sung Heum Park, Byung Chun Choi, Jung Hyun Jeong, Jung Hwan Kim

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  11. Color tunable Ba3Lu(PO4)3:Tb3+,Mn2+ phosphor via Tb3+→Mn2+ energy transfer for white LEDs

    Ceramics International · 2018-05-21

    Mengmeng Jiao, Qinfeng Xu, Yimei Xu, Yalin Li, Chuan‐Lu Yang, Mingliang Liu

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  12. Sr4Y6(AlO4)x(SiO4)6-xOδ:Eu2+: A novel apatite structure blue-green emitting phosphor

    Ceramics International · 2018-07-29

    Shan Yan, Ye Jin, Dai Pan, Guotao Xiang, Xu Luo, Yuanqing Yang

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  13. Energy Transfer and Multicolor Tunable Luminescence Properties of NaGd0.5Tb0.5−xEux(MoO4)2 Phosphors for UV-LED

    Journal of Electronic Materials · 2018-08-06

    Heng Wang, Ting Yang, Feng Li, Zhanglei Ning, Mengjiao Liu, Xin Lai, Daojiang Gao, Jian Bi

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  14. Eu3+-doped highly thermal-stable barium yttrium aluminate as a red-emitting phosphor for UV based white LED

    Optics & Laser Technology · 2018-10-01

    Zhiwen Gao, Pengfei Sun, Yifan Zhong, Ruijin Yu, Bin Deng

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  15. Tuning the luminescence of Ca 9 La(PO 4 ) 7 :Eu 2+ via artificially inducing potential luminescence centers

    Journal of Materials Chemistry C · 2019-01-01

    Xiaotong Li, Panlai Li, Chunjiao Liu, Li Zhang, Danjie Dai, Zhenhua Xing, Zhiping Yang, Zhijun Wang

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  16. Controllable Eu 2+ -Doped Orthophosphate Blue-/Red-Emitting Phosphors: Charge Compensation and Lattice-Strain Control

    Inorganic Chemistry · 2019-04-23

    Yi Wei, Junsong Gao, Gongcheng Xing, Guogang Li, Peipei Dang, Sisi Liang, Yu Shu Huang, Chun Che Lin, Ting‐Shan Chan, Jun Lin

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  17. Valent control and spectral tuning by cation site engineering strategy in Eu doped Sr1−Ba Al2Si2O8 phosphor

    Journal of Alloys and Compounds · 2019-07-19

    Baochen Wang, Ziyao Wang, Yangai Liu, Shiling Duan, Zhaohui Huang, Minghao Fang

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  18. From Nonluminescence to Bright Blue Emission: Boron-Induced Highly Efficient Ce3+-Doped Hydroxyapatite Phosphor

    Inorganic Chemistry · 2019-09-24

    Xujian Zhang, Jilin Zhang, Wentao Ma, Shuzhen Liao, Xinguo Zhang, Zhengliang Wang, Liping Yu, Shixun Lian

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  19. Photoluminescence properties and energy transfer of apatite-type Sr3LaNa(PO4)3 F:Ce3+, Tb3+ phosphors

    Materials Research Express · 2019-10-02

    Wen-Hui Du, Na Zhang, Ningze Zhuo, Linyan Xie, Teng Jiang, Yue-Hua Zhu, Shao-Wen Cheng, Haibo Wang

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  20. Controllable Eu valence based on linear structural evolution in single-phased Sr3-La1+(PO4)3-(SiO4) phosphors to realize tunable/white light emissions

    Journal of Alloys and Compounds · 2019-10-21

    Yue Guo, Yeqing Chen, Qingguang Zeng, Sung Heum Park, Byung Chun Choi, Jung Hyun Jeong

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  21. Optical thermometric properties in Tb3+ and Eu3+-coactivated dual-emissive fluorophosphate phosphors

    Optics & Laser Technology · 2019-11-14

    Ning Guo, Ying H. Pan, Wenzhen Lv, Ruizhuo Ouyang, Baiqi Shao

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  22. Enhanced green emission and thermal stability of Ba3Si6O12N2:Eu2+ by Ce3+/P5+-doping: Unity energy transfer, charge compensation and lattice strain release

    Journal of Luminescence · 2019-12-24

    Jiarui Hao, Mengxuan Tao, Zhiyu Gao, Shuoting Chen, Yixin Liu, Hongquan Wang, Yi Wei, Мaxim S. Моlokeev, Guogang Li

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  23. Achieving tunable emitting YAl 3 (BO 3 ) 4 :Eu phosphors by substituting cations (Sr 2+ , Ca 2+ , Ga 3+ , In 3+ ) and controlling BO 3 group polarizability

    CrystEngComm · 2020-01-01

    Jinjin Liu, Zhijun Wang, Xue Li, Xiangyu Meng, Keliang Qiu, Dawei Wang, Jinxin Zhao, Weidong Lai, Zhiping Yang, Panlai Li

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  24. Site-selective occupation of Eu2+ activators toward full-visible-spectrum emission in well-designed borophosphate phosphors

    Chemical Engineering Journal · 2020-04-20

    xingxing sheng, Pengpeng Dai, Zhiyi Sun, Dawei Wen

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  25. Tuning luminescence and excellent thermal stability of Gd4.67Si3O13: Bi3+, Eu3+ with energy transfer from Bi3+ to Eu3+

    Ceramics International · 2020-06-08

    Ye Jin, Ying Wang, Yiping Wang, Yiping Wang, Yiping Wang

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  26. Correlation among photoluminescence and the electronic and atomic structures of Sr2SiO4:xEu3+ phosphors: X-ray absorption and emission studies

    Scientific Reports · 2020-07-29

    Shiyan Zheng, J. W. Chiou, Yueh-Han Li, Cheng‐Fu Yang, Sekhar C. Ray, Kuan‐Hung Chen, Chun-Yu Chang, A.R. Shelke, Hsiao‐Tsu Wang, Ping‐Hung Yeh, Chun-Yen Lai, Shang‐Hsien Hsieh, Chih‐Wen Pao, Jeng‐Lung Chen, Jyh‐Fu Lee, Huang-Ming Tsai, Huang‐Wen Fu, Chih-Yu Hua, Hong‐Ji Lin, Chien‐Te Chen, W. F. Pong

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  27. Vacancies Substitution Tuning Photoluminescence and Distortion Triggered Eu Migration in NASICON-Type Phosphors

    ACS Sustainable Chemistry & Engineering · 2021-01-07

    Hongzhi Zhang, Yuchang Su, Zhongbao Luo, Jing Zhang, Jinyu Yang

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  28. Reduction Mechanism of Eu 3+ in Ca 2+x La 8−x (SiO 4 )6O 2–0.5x : Eu 2+ Phosphors

    ECS Journal of Solid State Science and Technology · 2021-04-22

    ChaoFei Luo, Ke Liu, Weiwei Ji, Zhan Li, Liangjun Yin, Luyuan Hao, Xin Fang Xu, Simeon Agathopoulos

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  29. Controlling Cr3+/Cr4+ concentration in single-phase host toward tailored super-broad near-infrared luminescence for multifunctional applications

    Materials Today Chemistry · 2021-09-11

    Hao-Bin Cai, H. Chen, Hao Zhou, Jing Wei Zhao, Zhen Song, Quanlin Liu

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  30. Extension of Spectral Shift Controls from Equivalent Substitution to an Energy Migration Model Based on Eu2+/Tb3+-Activated Ba4–xSrxGd3–xLuxNa3(PO4)6F2 Phosphors

    Inorganic Chemistry · 2021-10-14

    Zhibin Mei, Quwei Ni, Mengqing Li, Jieying Li, Jiansheng Huo, Wanqiang Liu, Qianming Wang

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  31. Self-reduction-induced BaMgP 2 O 7 :Eu 2+/3+ : a multi-stimuli-responsive phosphor for X-ray detection, anti-counterfeiting and optical thermometry

    Dalton Transactions · 2022-01-01

    Song Li, Zhongxian Qiu, Yahuan Mo, Hongwu Zhang, Hongzhou Lian, Jilin Zhang, Shixun Lian

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  32. Effect of Al3+ on the photoluminescence and radioluminescence properties of Mn2+-Doped high silica glass

    Ceramics International · 2022-03-30

    Yiting Tao, Xiben Ma, Jingang Wang, Ying Du, Panting Wang, Danping Chen

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  33. Enhanced luminescence efficiency and thermal stability via introduction of non-rare earth Bi3+ in Gd5Si2BO13:Eu3+

    Journal of Rare Earths · 2022-05-05

    Yukun Liu, Yangai Liu, Haojun Yu, Chenguang Yang, Ci’an Xie, Jian Chen

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  34. Effective regulation of electronic structures and luminescence properties of LiGd9(SiO4)6–(GeO4) O2:Dy3+ phosphors by tetrahedral substitution

    Journal of Rare Earths · 2022-05-23

    Yuanyuan Zhang, Lefu Mei, Haikun Liu, Sergey M. Aksenov, Dina V. Deyneko, Deliang Chen

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  35. Local structure distortion enhanced the emission intensity of KBaYSi2O7:Eu2+ phosphor for full-visible-spectrum LED lighting

    Journal of Luminescence · 2022-06-08

    Fu Du, Shengnan Wang, Lei Chen, Yanfei Xiao, Fengli Yang, Jiaqin Peng, Xinyu Ye

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  36. Oxynitride K 2 Ba 6.72 Si 16 O 40−1.5 y N y :0.28Eu 2+ phosphor with high thermal stability realized by crystal field engineering

    Dalton Transactions · 2023-01-01

    Aijun Mao, Xinwei Wang, Yali Guo, Xuejie Zhai, Pai Lv

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  37. Enhanced red luminescence of Ca 3 Si 2− x M x O 7 :Eu 3+ (M = Al, P) phosphors via partial substitution of Si 4+ for applications in white light‐emitting diodes

    Rare Metals · 2023-09-12

    Yu-Hao Ma, Xi Gao, Wentao Zhang, Zhen-Rui Yang, Zhou Zhao, Chen Qu

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  38. Mg2+–Ca2+/Sr2+–Ca2+ bicationic sites inducing Eu2+ occupying triggering C2S emitting structure unit evolution and luminescence characteristics

    Journal of Materials Science Materials in Electronics · 2023-11-01

    Jian Liu, Jingwen Zhang, Weihua Zhu, Fabin Cao, Xingmei Shen, Weiming Liu, Xingrong Wu

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  39. Crystal Structure and Spectral Tuning of Eu2+/Eu3+ Co-Activated Na2ba1- X Sr X Ca(Po4)2 Phosphors with High Thermal Stability

    SSRN Electronic Journal · 2024-01-01

    Junwei Tang, Jiayong Si, Di Wu, Tianliang Zhou, Gemei Cai

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  40. Eu2+/Eu3+ Co-Activated Ba2la8(Sio4)6o2 Phosphors for Optical Thermometry

    SSRN Electronic Journal · 2024-01-01

    Ju Cheng, Ju Cheng, Sheng Zhang, Jinlong Cheng, Jinlong Cheng, Peng‐Cheng Ma, Hualing Yu, Zhangyin Zhai

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  41. Eu2+/Eu3+ Co-Activated Ba2la8(Sio4)6o2 Phosphors for Optical Thermometry

    SSRN Electronic Journal · 2024-01-01

    Cheng Ju, Ju Cheng, Sheng Zhang, Jinlong Cheng, Jinlong Cheng, Peng‐Cheng Ma, Hualing Yu, Zhangyin Zhai

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  42. Eu2+ doping and Mg2+-coupled Zn2+, Ca2+ and Sr2+ cations induce tunable orange-blue luminescence in cordierite

    Journal of Luminescence · 2024-03-28

    Jingwen Zhang, Jian Liu, Zhifeng Zhang, Weihua Zhu, Weihua Zhu, Ying Xiong, Fabin Cao, Xudong Zhu, Jiangcheng Pan, Xingmei Shen, Weiming Liu, Xingrong Wu

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  43. Optimizing luminescence intensity and thermal stability of Gd5Si2BO13:Tb3+ through the incorporation of non-rare earth Bi3+

    Optical Materials · 2024-05-19

    Xiaoyu Xing, Yangai Liu, Yangai Liu, Yukun Liu, Yukun Liu, Ci’an Xie, Tonglu Sun, Chenguang Yang, Juyu Yang, Linlin Wang, Lefu Mei, Ruiyu Mi

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  44. Eu2+/Eu3+ co-activated Ba2La8(SiO4)6O2 phosphors for optical thermometry

    Journal of Luminescence · 2024-06-21

    Cheng Ju, Ju Cheng, Sheng Zhang, Jinlong Cheng, Jinlong Cheng, Peng‐Cheng Ma, Hualing Yu, Zhangyin Zhai

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  45. High thermal stability Gd5--Si2BO13:xTb3+, yEu3+ phosphors achieve color tunable emission through Tb3+-Eu3+ energy transfer

    Journal of Luminescence · 2025-07-05

    Xiaoyu Xing, YuKun Liu, YuKun Liu, Ruiyu Mi, Lefu Mei

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  46. Luminescence enhancement of CaLa3.56Ti4-M O15:0.44Eu3+ (M = Si, Zr) red-emitting phosphor via the partial substitution of Ti4+ for white light-emitting diodes and plant lighting

    Ceramics International · 2026-02-16

    Enze You, Xianzhu Zhou, Wentao Zhang, Xue Song Huang

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