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RESEARCH PAPER · Dalton Transactions · 2022

Self-reduction-induced BaMgP 2 O 7 :Eu 2+/3+ : a multi-stimuli-responsive phosphor for X-ray detection, anti-counterfeiting and optical thermometry

Song Li, Zhongxian Qiu, Yahuan Mo, Hongwu Zhang, Hongzhou Lian, Jilin Zhang, Shixun Lian

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Self-reduction-induced BaMgP 2 O 7 :Eu 2+/3+ : a multi-stimuli-responsive phosphor for X-ray detection, anti-counterfeiting and optical thermometryOriginalAchieving highly thermostable red emission in singly Mn 2+ -doped BaXP 2 O 7 (X = Mg/Zn) via self-reduction36Achieving Persistent Luminescence Performance Based on the Cation-Tunable Trap Distribution3Multi-mode anti-counterfeiting guarantees from a single material CaCd 2 Ga 2 Ge 3 O 12 :Tb 3+ ,Yb 3+ – two stimuli-responsive and four-state emission6Tetrahedrally coordinated rigid crystal structure enables partial self-reduction of mixed-valence europium for optical thermometric application12Unusual magnetic behavior of TiO 2 -doped CuFeO 2 crystals (CuFe 1− x Ti x O 2 ) grown by the optical floating zone method4Precisely Manipulating the Self‐Reduction of Manganese in MgGa2O4 through Lithium Incorporation for Optical Thermometry and Anti‐Counterfeiting64Self-reduction induced CaAl12O19:Eu2+/3+: A phosphor with dynamic photoluminescence and photochromism for advanced anti-counterfeiting and encryption26Vacancy-Enhanced Self-Reduction of Eu in Pyrophosphate Phosphor39Luminescence properties of Eu2+/3+ co-activated La6Sr4(SiO4)6F2 polychromatic phosphors towards white light-emitting diodes and anti-counterfeiting8Photoluminescence and ratiometric thermo-response of Eu2+ and Eu3+ in BaAl2B2O7:Eu2+,Eu3+ phosphor materials54Isolated Coordination Polyhedron Confinement in ABP2O7:Mn2+ (A = Ba/Sr; B = Mg/Zn)5Quenching mechanism and luminescence enhancement strategy of Eu2+-activator in fluoroborate host Ba5B4O10F213Achieving color-tunable luminescence in CaF 2 :Eu phosphors for multimode anti-counterfeiting8Enhanced thermally stable performance of Pr 3+ -doped vanadate phosphor by inhibiting the intervalence charge transfer quenching channel9Structure and photoluminescence of Mn 2+/4+ -activated doubly ordered spinel Mg 4 (Ga/Al)SbO 8 : site-selective Al 3+ -to-Ga 3+ substitution enabling Mn 4+ accumulation, excellent anti-thermal quenching of Mn 2+ green emission, and optical thermometry17Achieving Multicolor Anti‐Counterfeiting via Simultaneous X‐Ray and UV/Blue Excitation in Ca2YMgScSi3O12: Mn2+16Achieving multi-wavelength excitation and multi-color tunable emission in self-reducing phosphor of Ba2MgSi2O7: Eu2+/Eu3+16Inorganic metal oxide material BaSiO3:Eu2+ for convenient 3D X-ray imaging6A highly sensitive multiple-mode optical thermometer designed in Eu 2+/3+ and Li + co-doped polymorphism compound LaSc 3 (BO 3 ) 432Developing Luminescent Ratiometric Thermometers Based on Dual-Emission of NaMgF3:Eu3+/Carbon Dot Nanocomposites12Structure Modulation and Charge Transfer in Self‐Reduction Phosphors: A Review18Novel multi-mode anti-counterfeiting encryption material of CaAl12O19:Eu, Er with multi-color down-conversion luminescence, up-conversion luminescence, dynamic luminescence, and photochromism40Non‐volatile and Secure Optical Storage Medium with Multilevel Information Encryption18Synergistic enhancement of Eu3+-doped LaAlO3 fluorescent materials by sol-gel process and aerogel structure for high power and precise transmission illumination3Tunable Optical Properties, Enhanced Photoluminescence, and Thermostability of CaO: Eu2+/3+ Phosphors by Codoping Cl– Ions5Tunable broadband visible emission achieved by phase transformation-driven self-reduction of Eu 3+ to Eu 2+ in a calcium phosphate matrix6Effects of synthesis methods on optical properties and oxidation states of europium in Eu-doped calcium fluoride6Rare-earth-free far-red-emitting Li1.5La1.5TeO6:Mn4+ phosphors for transparent phosphor film-based light projection application11Self-reduction regulation in NaZr2(PO4)3: Eu2+/Eu3+ phosphor and their potential optical thermometric applications4Effects of Sm3+ and Tm3+ substitution on the local structure and luminescence properties of Y4Al2O9:Eu3+ thermostable phosphors for solar-blind ultraviolet detection3Design and electrospinning synthesis of CaGdAl3O7:Tb3+ nanofibers with excellent green light emission0Construction of BaAl2O4:Eu2+/3+ and BaAl2O4:Eu2+/3+,Nd3+ phosphors with tunable multicolor luminescence and white-light emission via self-reduction of Eu3+ to Eu2+ in air3Environmentally Robust Sr 2‐x P 2 O 7 :xEu 3+ Red Phosphor for Multi‐Scenario Optoelectronic Applications1Self-reduction regulation in europium-doped metaphosphate phosphor1Effects of Dy3+ ion concentration on the local structure and luminescence properties of Y4Al2O9:Tb3+ phosphors1Site-selective occupancy-induced full-visible-spectrum emission in single-activator Ca10Na1-yLiy(PO4)7:Eu2 + phosphors for multifunctional applications0

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  1. Achieving highly thermostable red emission in singly Mn 2+ -doped BaXP 2 O 7 (X = Mg/Zn) via self-reduction

    Inorganic Chemistry Frontiers · 2022-01-01

    Song Li, Wei Hu, M.G. Brik, Shixun Lian, Zhongxian Qiu

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  2. Achieving Persistent Luminescence Performance Based on the Cation-Tunable Trap Distribution

    Materials · 2022-12-19

    Tao Wang, Rui Li, Mengya Zhang, Panlai Li, Zhijun Wang

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  3. Multi-mode anti-counterfeiting guarantees from a single material CaCd 2 Ga 2 Ge 3 O 12 :Tb 3+ ,Yb 3+ – two stimuli-responsive and four-state emission

    Dalton Transactions · 2022-12-31

    Zhuobing Wang, Zhuobing Wang, Liwei Yang, Zhenbin Wang, Zhenbin Wang, Jiajia Cao, Cunhua Ma, Mingjin Zhang, Weisheng Liu

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  4. Tetrahedrally coordinated rigid crystal structure enables partial self-reduction of mixed-valence europium for optical thermometric application

    Dalton Transactions · 2023-01-01

    Zhichao Meng, Yan Na Gao, Jian Zheng Song, Zelong Jiang, Wei Zhong Lv, Qingguang Zeng, Dawei Wen, Tao Hu

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  5. Unusual magnetic behavior of TiO 2 -doped CuFeO 2 crystals (CuFe 1− x Ti x O 2 ) grown by the optical floating zone method

    CrystEngComm · 2023-01-01

    Jingwen Hou, Bernard Albert Goodman, Yuchen Lu, Qunyue Zhang, Bin Huang, Long Chen, Shoulei Xu, Wen Deng, Dingkang Xiong

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  6. Precisely Manipulating the Self‐Reduction of Manganese in MgGa2O4 through Lithium Incorporation for Optical Thermometry and Anti‐Counterfeiting

    Advanced Optical Materials · 2023-06-09

    Junpeng Xue, ling yun li, Marcin Runowski, Yue Guo, Bo Ram Lee, Jung Hyun Jeong, Peng Du, Sung Heum Park

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  7. Self-reduction induced CaAl12O19:Eu2+/3+: A phosphor with dynamic photoluminescence and photochromism for advanced anti-counterfeiting and encryption

    Ceramics International · 2023-06-16

    Xiaoping Jiang, Yue Guo, Lixi Wang, Qitu Zhang

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  8. Vacancy-Enhanced Self-Reduction of Eu in Pyrophosphate Phosphor

    Inorganic Chemistry · 2023-07-25

    Hongling Wang, Ke Su, Lefu Mei, Qingfeng Guo, Libing Liao

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  9. Luminescence properties of Eu2+/3+ co-activated La6Sr4(SiO4)6F2 polychromatic phosphors towards white light-emitting diodes and anti-counterfeiting

    Journal of Luminescence · 2023-07-29

    Guojian Chen, Laihui Luo, Weiping Li, Peng Du

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  10. Photoluminescence and ratiometric thermo-response of Eu2+ and Eu3+ in BaAl2B2O7:Eu2+,Eu3+ phosphor materials

    Journal of Rare Earths · 2023-08-19

    Ziyao Wang, Haitao Fu, Xiufeng Zhan, Bo Tong, Guofeng Ma, Hubertus T. Hintzen

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  11. Isolated Coordination Polyhedron Confinement in ABP2O7:Mn2+ (A = Ba/Sr; B = Mg/Zn)

    Inorganic Chemistry · 2023-11-02

    Li Song, Zhenzhen Zhang, Jilin Zhang, Jiayu Wu, Zhongxian Qiu, M.G. Brik, Shixun Lian

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  12. Quenching mechanism and luminescence enhancement strategy of Eu2+-activator in fluoroborate host Ba5B4O10F2

    Ceramics International · 2023-12-16

    Donglei Wei, Joo Hyun Kim, Sung Heum Park, Bo Ram Lee

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  13. Achieving color-tunable luminescence in CaF 2 :Eu phosphors for multimode anti-counterfeiting

    Journal of Materials Chemistry C · 2024-01-01

    Linglu Kuang, Feng Zhang, Jian Zhang, Xiaodie Zhu, Tian Xu, Jianxiong Shao, Yichun Liu, Xuhui Xu, Zhichao Liu

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  14. Enhanced thermally stable performance of Pr 3+ -doped vanadate phosphor by inhibiting the intervalence charge transfer quenching channel

    Dalton Transactions · 2024-01-01

    Jianxia Liu, Chunwei Yang, Hong Chai, Yanmei Xin, Song Qu, Ning Guo

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  15. Structure and photoluminescence of Mn 2+/4+ -activated doubly ordered spinel Mg 4 (Ga/Al)SbO 8 : site-selective Al 3+ -to-Ga 3+ substitution enabling Mn 4+ accumulation, excellent anti-thermal quenching of Mn 2+ green emission, and optical thermometry

    Inorganic Chemistry Frontiers · 2024-01-01

    Zien Cheng, Guangxiang Lu, Yuxuan Qi, Jinmei Huang, Gonggui Yan, Leiming Fang, Maxim Avdeev, Tao Yang, Pengfei Jiang

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  16. Achieving Multicolor Anti‐Counterfeiting via Simultaneous X‐Ray and UV/Blue Excitation in Ca2YMgScSi3O12: Mn2+

    Advanced Optical Materials · 2024-01-22

    Xinran Wang, Heng Dai, Baozhu Li, Xuhui Xu, Jian Zhang, Daiyuan Liu, Yichun Liu, Zhichao Liu

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  17. Achieving multi-wavelength excitation and multi-color tunable emission in self-reducing phosphor of Ba2MgSi2O7: Eu2+/Eu3+

    Journal of Luminescence · 2024-02-29

    Wenying Teng, Houhe Dong, Chen Hu, Xiaowei Yang, Jiaqi Wang, Xukun Liang, Bowen Yang, Jinrui Ru, Bing Teng, Degao Zhong

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  18. Inorganic metal oxide material BaSiO3:Eu2+ for convenient 3D X-ray imaging

    Journal of Luminescence · 2024-03-03

    Kuo Shen, Ruiting Zhang, Yahong Jin, Yanmei Li, Yihua Hu

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  19. A highly sensitive multiple-mode optical thermometer designed in Eu 2+/3+ and Li + co-doped polymorphism compound LaSc 3 (BO 3 ) 4

    Journal of Advanced Ceramics · 2024-04-24

    Nan Yang, Zhuo Li, Tingxia Zhou, Ziwang Zhang, Wenzhong Shi, Yexiang Tong, Jianxin Shi

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  20. Developing Luminescent Ratiometric Thermometers Based on Dual-Emission of NaMgF3:Eu3+/Carbon Dot Nanocomposites

    ACS Applied Nano Materials · 2024-06-25

    Rui Li, Xiaoyi Wu, Yeqing Chen, Qingguang Zeng, Tingting Deng, Ting Yu

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  21. Structure Modulation and Charge Transfer in Self‐Reduction Phosphors: A Review

    Laser & Photonics Review · 2024-08-09

    Hongling Wang, Lefu Mei, Ke Su, Jingyi Liu, Qi Wang, Zhaojie Wu, Qingfeng Guo, Libing Liao

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  22. Novel multi-mode anti-counterfeiting encryption material of CaAl12O19:Eu, Er with multi-color down-conversion luminescence, up-conversion luminescence, dynamic luminescence, and photochromism

    Journal of Colloid and Interface Science · 2024-08-26

    Xiaoping Jiang, Yue Guo, Lixi Wang, Qitu Zhang

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  23. Non‐volatile and Secure Optical Storage Medium with Multilevel Information Encryption

    Advanced Science · 2024-10-16

    Jie Shao, Xiyang Li, Meng Liu, Haiqin Sun, Dengfeng Peng, Fuchi Liu, Qiwei Zhang

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  24. Synergistic enhancement of Eu3+-doped LaAlO3 fluorescent materials by sol-gel process and aerogel structure for high power and precise transmission illumination

    Journal of Alloys and Compounds · 2024-11-12

    Qinxin Wang, Limin Che, Lei Su, Wenqi Liu, Zhun Fan, Man Yuan, Zhao Yang, Guangxi Liu, Haibo Wang, Sheng Cui

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  25. Tunable Optical Properties, Enhanced Photoluminescence, and Thermostability of CaO: Eu2+/3+ Phosphors by Codoping Cl– Ions

    Inorganic Chemistry · 2024-12-12

    Yi‐Hong Liu, Xiankai Wang, Jingyi Jing, Haifeng Zou, Xiaolu Yang, Yanhua Song, Ye Sheng

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  26. Tunable broadband visible emission achieved by phase transformation-driven self-reduction of Eu 3+ to Eu 2+ in a calcium phosphate matrix

    Dalton Transactions · 2025-01-01

    Sapargali Pazylbek, Jonas Stadulis, Guna Doke, Andris Antuzevičš, Vladimir A. Pankratov, Greta Merkininkaitė, Artūras Katelnikovas, Aleksej Žarkov

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  27. Effects of synthesis methods on optical properties and oxidation states of europium in Eu-doped calcium fluoride

    Journal of Luminescence · 2025-03-12

    Kirill K. Volik, Elizaveta A. Mukhanova, Ilia A. Pankin, P.D. Kuznetsova, Oleg Evgenevich Polozhentsev, Andrei A. Tereshchenko, Alexander V. Soldatov

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  28. Rare-earth-free far-red-emitting Li1.5La1.5TeO6:Mn4+ phosphors for transparent phosphor film-based light projection application

    Journal of Alloys and Compounds · 2025-04-01

    Jun Kyu Lee, Weiwei Xiang, Jae Su Yu

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  29. Self-reduction regulation in NaZr2(PO4)3: Eu2+/Eu3+ phosphor and their potential optical thermometric applications

    Journal of Alloys and Compounds · 2025-07-15

    Xiaokun Li, Jiejun Ren, Lina Chen, Peng Meng, Zhanhui Zhang

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  30. Effects of Sm3+ and Tm3+ substitution on the local structure and luminescence properties of Y4Al2O9:Eu3+ thermostable phosphors for solar-blind ultraviolet detection

    Journal of Alloys and Compounds · 2025-12-14

    Si Wu, Zhengce An, Liping Lu, Chang Sun, Haiying Sun, Xiaoyun Mi, Zhaohui Bai

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  31. Design and electrospinning synthesis of CaGdAl3O7:Tb3+ nanofibers with excellent green light emission

    SSRN Electronic Journal · 2026-01-01

    Jinzhan Li, Beibei Yang, Zhendong Jiang, Jiajia He

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  32. Construction of BaAl2O4:Eu2+/3+ and BaAl2O4:Eu2+/3+,Nd3+ phosphors with tunable multicolor luminescence and white-light emission via self-reduction of Eu3+ to Eu2+ in air

    Journal of Alloys and Compounds · 2026-01-26

    Xiaohan Liu, Hong Shao, Dan Li, Xiangting Dong, Ming Zhang

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  33. Environmentally Robust Sr 2‐x P 2 O 7 :xEu 3+ Red Phosphor for Multi‐Scenario Optoelectronic Applications

    Advanced Optical Materials · 2026-02-11

    Jingyi Liu, Hongling Wang, Wanting Fang, Nuoyi Jia, Ke Su, Xin Pan, Libing Liao, Lefu Mei

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  34. Self-reduction regulation in europium-doped metaphosphate phosphor

    Ceramics International · 2026-03-24

    Shanli Qin, Linawa Shen, Xiaohua Lan, Qi Pang, Liya Zhou, Peican Chen

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  35. Effects of Dy3+ ion concentration on the local structure and luminescence properties of Y4Al2O9:Tb3+ phosphors

    Ceramics International · 2026-05-04

    Si Wu, Zhengce An, Liping Lü, Chang Sun, Haiying Sun, Xiaoyun Mi, Zhaohui Bai

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  36. Site-selective occupancy-induced full-visible-spectrum emission in single-activator Ca10Na1-yLiy(PO4)7:Eu2 + phosphors for multifunctional applications

    Journal of Alloys and Compounds · 2026-07-26

    L Y Xu, H X Xu, Duanduan He, Zhi Dong, Xin Chen, Fei Long, Xu Wang, Chaoyong Deng, Xucheng Li

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