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RESEARCH PAPER · Chemistry of Materials · 2016

Ab Initio Structure Determination and Photoluminescent Properties of an Efficient, Thermally Stable Blue Phosphor, Ba2Y5B5O17:Ce3+

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Ab Initio Structure Determination and Photoluminescent Properties of an Efficient, Thermally Stable Blue Phosphor, Ba2Y5B5O17:Ce3+OriginalChemInform Abstract: Ab initio Structure Determination and Photoluminescent Properties of an Efficient, Thermally Stable Blue Phosphor, Ba2Y5B5O17:Ce3+.0A novel tunable green-to-red emitting phosphor Ca4LaO(BO3)3:Tb,Eu via energy transfer with high quantum yield25A novel blue-emitting Ba5(BO3)2(B2O5):Ce3+ phosphor for application in near-UV white LEDs18Site Occupancies, Luminescence, and Thermometric Properties of LiY 9 (SiO 4 ) 6 O 2 :Ce 3+ Phosphors118Synthesis and luminescence properties of a novel UV-emitting phosphor Sr3P4O13:Ce3+3Controlling the structure and morphology of zinc borate by adjusting the reaction temperature and pH value: formation mechanisms and luminescent properties17Ba 1.31 Sr 3.69 (BO 3 ) 3 Cl: A new structure type in the M 5 (BO 3 ) 3 Cl (M = bivalent cation) system12Versatile host-sensitized white light emission in a single-component K 3 ZnB 5 O 10 :Dy 3+ phosphor for ultraviolet converted light-emitting diodes47Lanthanide-Activated Phosphors Based on 4f-5d Optical Transitions: Theoretical and Experimental Aspects1025Luminescence investigations of novel orange‐red fluorapatite KL aSr 3 ( PO 4 ) 3 F: Sm 3+ phosphors with high thermal stability88Synthesis, characterization and determination of standard molar enthalpies of formation of two zinc borates with higher ratio of ZnO/B2O3 by solution calorimetry6Highly Efficient Green-Emitting Phosphors Ba2Y5B5O17 with Low Thermal Quenching Due to Fast Energy Transfer from Ce3+ to Tb3+107Tunable Optical Properties and Increased Thermal Quenching in the Blue-Emitting Phosphor Series: Ba2(Y1–xLux)5B5O17:Ce3+ (x = 0–1)1852D photonic crystal layer assisted thiosilicate ceramic plate with red‐emitting film for high quality w ‐ LED s33Geometric, electronic and optical properties of undoped and cerium-doped La5(Si2+B1−)(O13−N ) solid solutions: A theoretical investigation3Toward Bi3+ Red Luminescence with No Visible Reabsorption through Manageable Energy Interaction and Crystal Defect Modulation in Single Bi3+-Doped ZnWO4 Crystal193Syntheses, crystal structure and luminescent properties of polyborates PbLnB7O13 (Ln = Gd, Sm) with a 2D [B7O13]∞ framework13Broadband-excited and efficient blue/green/red-emitting Ba2Y5B5O17: Ce3+, Tb3+, Eu3+ phosphors using Tb3+-bridged Ce3+-Eu3+ energy transfer66An efficient green phosphor of Ce 3+ and Tb 3+ -codoped Ba 2 Lu 5 B 5 O 17 and a model for elucidating the high thermal stability of the green emission53Novel Eu 3+ -activated Ba 2 Y 5 B 5 O 17 red-emitting phosphors for white LEDs: high color purity, high quantum efficiency and excellent thermal stability33Synthesis and characterization of Ca 3 Lu(GaO) 3 (BO 3 ) 4 :Ce 3+ ,Tb 3+ phosphors: tunable-color emissions, energy transfer, and thermal stability16Dy3+-, Tb3+-, and Eu3+-activated NaCa4(BO3)3 phosphors for lighting based on near ultraviolet light emitting diodes16An efficient blue phosphor Ba 2 Lu 5 B 5 O 17 :Ce 3+ stabilized by La 2 O 3 : Photoluminescence properties and potential use in white LEDs43Ba3Y2B6O15:Ce3+—A High Symmetry, Narrow-Emitting Blue Phosphor for Wide-Gamut White Lighting188NaBaY(BO 3 ) 2 :Ce 3+ ,Tb 3+ : A novel sharp green‐emitting phosphor used for WLED and FEDs63White Light Emitting Phosphors for Solid State Lighting0Color tunable emission and energy transfer of Ce 3+ /Dy 3+ codoped Ba 3 La 2 (BO 3 ) 4 phosphor for UV white LEDs24Site-sensitive energy transfer from Ce3+ to Tb3+/Mn2+ based on an efficient phosphor Li4SrCa(SiO4)2:Ce3+18Single-phased white-emitting Ca3Y(GaO)3(BO3)4:Ce3+,Tb3+,Sm3+ phosphors with high-efficiency: Photoluminescence, energy transfer and application in near-UV-pumped white LEDs63Ultra‐narrow band blue emission of Eu 2+ in halogenated (Alumino)borate systems based on high lattice symmetry20Structure, site occupancies, and luminescence properties of Ca10M(PO4)7: Ce3+ (M = Li, Na, K) phosphors14Identifying an efficient, thermally robust inorganic phosphor host via machine learning362Electronic structure and luminescent properties of Ce3+-doped Ba3Lu2B6O15, a high-efficient blue-emitting phosphor33Density-functional theory calculations, luminescence properties and fluorescence ratiometric thermo-sensitivity for a novel borate based red phosphor: NaBaSc(BO 3 ) 2 :Ce 3+ ,Mn 2+58Design of a novel scandium silicate based blue-emitting phosphor with high efficiency and robust thermal stability for warm WLEDs and field emission displays36Luminescence properties in relation to controllable morphologies of Ba 3 [Ge 2 B 7 O 16 (OH) 2 ](OH)(H 2 O):Eu 3+ and its thermal conversion product Ba 3 Ge 2 B 6 O 16 :Eu 3+6Non-concentration quenching, good thermal stability and high quantum efficiency of K 5 Y(P 2 O 7 ) 2 :Eu 3+ /Tb 3+ phosphors with a novel two-dimensional layer structure78Novel bismuth activated blue-emitting phosphor Ba 2 Y 5 B 5 O 17 :Bi 3+ with strong NUV excitation for WLEDs82Site Occupancy Studies and Luminescence Properties of Emission Tunable Phosphors Ca 9 La(PO 4 ) 7 :Re (Re = Ce 3+ , Eu 2+ )69Investigation of site occupancy and photoluminescence of Ce3+ in cubic borate Ba3Y2(B2O5)3 and Ce3+ → Tb3+ energy transfer behavior16One‐Step Synthesis of Silica‐Coated Carbon Dots with Controllable Solid‐State Fluorescence for White Light‐Emitting Diodes126Sr2LiScB4O10:Ce3+/Tb3+: A Green-Emitting Phosphor with High Energy Transfer Efficiency and Stability for LEDs and FEDs107Synthesis of Ba1−Sr YSi2O5N and discussion based on structure analysis and DFT calculation5Structural origin of blue luminescence in Ce-doped Ba2Y5B5O17 and Ba3Y2B6O15 with multiple cation sites and occupational disorder9Eu3+-based efficient red phosphors Y1-xEuxGa3(BO3)4 (0 < x ≤ 1): A potential candidate for near ultraviolet LEDs with high thermal stability21Facile synthesis of high-pressure polymorph β-YB3O6 by co-doping Bi3+ and RE3+ (RE = Tb, Eu) with color-tunable emissions via energy transfer9Site occupation and 4f → 5d transitions of Ce3+ ions at mixed Ca2+/Y3+ sites in CaYAlO4: Insights from first-principles calculations13From Nonluminescence to Bright Blue Emission: Boron-Induced Highly Efficient Ce3+-Doped Hydroxyapatite Phosphor44Dopant and excitation wavelength dependent color tunability in Dy3+ and Eu3+ doped CaBi2B2O7 phosphors for NUV warm white LEDs33Site occupancy and tunable photoluminescence properties of Eu2+-Activated Ba3Sc(BO3)3 phosphors for white light emitting diodes33Color-tunable emissions via energy transfer in Bi3+ and Eu3+ doped β-LaB5O9: Sol-gel synthesis and photoluminescence15A broadband cyan-emitting Ca 2 LuZr 2 (AlO 4 ) 3 :Ce 3+ garnet phosphor for near-ultraviolet-pumped warm-white light-emitting diodes with an improved color rendering index245Multisite-Occupancy-Driven Intense Narrow-Band Blue Emission from Sr 5 SiO 4 Cl 6 :Eu 2+ Phosphor with Excellent Stability and Color Performance69Synthesis of Ba2CaZn2Si6O17:Eu2+ Phosphors: Synthesis, Microstructure and Luminescence Characteristics9Temperature-Dependent Luminescence of Red-Emitting Ba2Y5B5O17: Eu3+ Phosphors with Efficiencies Close to Unity for Near-UV LEDs20Bright tunable white-light emissions from Bi3+/Eu3+ co-doped Ba2Y5B5O17 phosphors via energy transfer for UV-excited white light-emitting diodes56Predicting Thermal Quenching in Inorganic Phosphors149Energy transfer induced color-tunable emissions from Ba2Gd5B5O17:Ce3+/Tb3+ borate phosphors for white LEDs32La1-Eu B4O6(OH)2Cl (0 ≤ x ≤ 0.54): Strong 4f-4f excitations due to the noncentrosymmetric and oxychloride coordination of Eu3+3Energy transfer from Tb3+ to Eu3+ in ZnLaB5O10: A candidate for near ultraviolet LED pumped phosphor11Discovery of a new phosphor via aliovalent cation substitution: DFT predictions, phase transition and luminescence properties for lighting and anti-counterfeiting applications22Efficient Bi 3+ to Eu 3+ energy transfer and color tunable emissions in K 7 CaY 2 (B 5 O 10 ) 3 -based phosphors22Vacancies Substitution Tuning Photoluminescence and Distortion Triggered Eu Migration in NASICON-Type Phosphors11Intense NUV excitation of Eu3+ in LiSrY2(BO3)3 by utilizing the local symmetry-broken characteristic: A candidate for NUV LED pumped red phosphor10Realization of non-rare earth doped blue-emitting phosphor Ba2Y5B5O17: Sb by selective site excitation, and its application in n-UV excited wLEDs3Ce3+ sensitized Tb3+ and Dy3+ photoluminescence in β-LaB5O9 prepared by sol–gel method7Preparation of M2B5O9Cl:Eu2+ (M=Sr, Ca) blue phosphors by a facile low-temperature self-reduction method and their enhanced luminescent properties25A novel blue emitting phosphor LaScO3:Bi3+ for white LEDs: high quantum efficiency, high color purity and excellent thermal stability34Luminescence in the solid state7Lanthanide-based luminescent materials0BaCa13Mg2(SiO4)8: Ce3+ — A blue phosphor with high brightness, high internal quantum efficiency and excellent thermal stability for w-LEDs32Highly bright broadband cyan-emitting CaLu2HfGaAl3O12:Ce3+ garnet phosphors for high-color-quality white light-emitting diodes15Synthesis and photoluminescence properties of Ce3+ and Tb3+ doped Na3Gd(PO4)2 phosphors for white LEDs5Colossal Chromatic Shift in the Ba 2 Ca 2 B 4 O 10 :Ce 3+ Phosphor45High-Efficiency Ce3+ Activated Orthorhombic Lanthanide Silicate Blue Phosphors for Plant Growth Lighting25High-Quantum-Efficiency Blue Phosphors with Superior Thermal Stability Derived from Eu3+-Doped Faujasite Y Zeolite11Blue Ca4MgAl2Si3O14:Ce3+, Li+ phosphor with excellent performance for human-centered green plant growth lighting12A novel borate phosphor Lu 5 Ba 6 B 9 O 27 :Ce 3+ codoped with Sr 2+ /Tb 3+ for NUV-white light emitting diode application10Efficient Ultraviolet Circularly Polarized Luminescence in Zero‐Dimensional Hybrid Cerium Bromides32Efficient Ultraviolet Circularly Polarized Luminescence in Zero‐Dimensional Hybrid Cerium Bromides5Tailoring optical temperature sensing performance of K7MgSc2B15O30:Mn2+ via structure modulation3Crystal structure refinement and thermal properties of Ba2Lu5O2(BO3)5, a first example of barium rare-earth borate containing oxo-centered [OM4]+ tetrahedra1High-brightness Bi3+ activated Gd2GeO5 blue phosphor for white light-emitting diodes: Synthesis, characterization, and thermal stability2Double Borates of the BaO–Lu2O3–B2O3 System: Crystal Chemistry, Thermal and Optical Properties0An Efficient Broadband Cyan Phosphor for Full‐Spectrum pc‐WLEDs24Europium(II) Activated Blue–Cyan Aluminosilicate Phosphors with Zero Thermal Quenching3Borate-based luminescent materials: A comprehensive review of structural influences on thermal stability and luminescence characteristics13Ba2Y[BO3][Si2O6]:Ce3+ phosphor with high-efficiency blue emission and excellent quantum yield enabled by mixed-dimensional anionic framework engineering7Holistic Insight into the Zero Thermal Quenching Novel β-BaB2O4:Ce3+ Phosphor for Optoelectronic Applications1An efficient blue Ca3(Gd,Y)2B4O12:Ce3+ phosphor for near ultraviolet-excited white LEDs5An Efficient Blue (Na, Li) 2 Ba 6 Si 4 O 15 :Ce 3+ Phosphor for Near‐Ultraviolet‐Excited White LEDs0

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  2. A novel tunable green-to-red emitting phosphor Ca4LaO(BO3)3:Tb,Eu via energy transfer with high quantum yield

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  3. A novel blue-emitting Ba5(BO3)2(B2O5):Ce3+ phosphor for application in near-UV white LEDs

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  4. Site Occupancies, Luminescence, and Thermometric Properties of LiY 9 (SiO 4 ) 6 O 2 :Ce 3+ Phosphors

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  5. Synthesis and luminescence properties of a novel UV-emitting phosphor Sr3P4O13:Ce3+

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  6. Controlling the structure and morphology of zinc borate by adjusting the reaction temperature and pH value: formation mechanisms and luminescent properties

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  7. Ba 1.31 Sr 3.69 (BO 3 ) 3 Cl: A new structure type in the M 5 (BO 3 ) 3 Cl (M = bivalent cation) system

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  8. Versatile host-sensitized white light emission in a single-component K 3 ZnB 5 O 10 :Dy 3+ phosphor for ultraviolet converted light-emitting diodes

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  9. Lanthanide-Activated Phosphors Based on 4f-5d Optical Transitions: Theoretical and Experimental Aspects

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  10. Luminescence investigations of novel orange‐red fluorapatite KL aSr 3 ( PO 4 ) 3 F: Sm 3+ phosphors with high thermal stability

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  11. Synthesis, characterization and determination of standard molar enthalpies of formation of two zinc borates with higher ratio of ZnO/B2O3 by solution calorimetry

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  12. Highly Efficient Green-Emitting Phosphors Ba2Y5B5O17 with Low Thermal Quenching Due to Fast Energy Transfer from Ce3+ to Tb3+

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  13. Tunable Optical Properties and Increased Thermal Quenching in the Blue-Emitting Phosphor Series: Ba2(Y1–xLux)5B5O17:Ce3+ (x = 0–1)

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  14. 2D photonic crystal layer assisted thiosilicate ceramic plate with red‐emitting film for high quality w ‐ LED s

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  16. Toward Bi3+ Red Luminescence with No Visible Reabsorption through Manageable Energy Interaction and Crystal Defect Modulation in Single Bi3+-Doped ZnWO4 Crystal

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  17. Syntheses, crystal structure and luminescent properties of polyborates PbLnB7O13 (Ln = Gd, Sm) with a 2D [B7O13]∞ framework

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  18. Broadband-excited and efficient blue/green/red-emitting Ba2Y5B5O17: Ce3+, Tb3+, Eu3+ phosphors using Tb3+-bridged Ce3+-Eu3+ energy transfer

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  20. Novel Eu 3+ -activated Ba 2 Y 5 B 5 O 17 red-emitting phosphors for white LEDs: high color purity, high quantum efficiency and excellent thermal stability

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  23. An efficient blue phosphor Ba 2 Lu 5 B 5 O 17 :Ce 3+ stabilized by La 2 O 3 : Photoluminescence properties and potential use in white LEDs

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  24. Ba3Y2B6O15:Ce3+—A High Symmetry, Narrow-Emitting Blue Phosphor for Wide-Gamut White Lighting

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  25. NaBaY(BO 3 ) 2 :Ce 3+ ,Tb 3+ : A novel sharp green‐emitting phosphor used for WLED and FEDs

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  26. White Light Emitting Phosphors for Solid State Lighting

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  28. Site-sensitive energy transfer from Ce3+ to Tb3+/Mn2+ based on an efficient phosphor Li4SrCa(SiO4)2:Ce3+

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  29. Single-phased white-emitting Ca3Y(GaO)3(BO3)4:Ce3+,Tb3+,Sm3+ phosphors with high-efficiency: Photoluminescence, energy transfer and application in near-UV-pumped white LEDs

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  30. Ultra‐narrow band blue emission of Eu 2+ in halogenated (Alumino)borate systems based on high lattice symmetry

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  31. Structure, site occupancies, and luminescence properties of Ca10M(PO4)7: Ce3+ (M = Li, Na, K) phosphors

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  32. Identifying an efficient, thermally robust inorganic phosphor host via machine learning

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  33. Electronic structure and luminescent properties of Ce3+-doped Ba3Lu2B6O15, a high-efficient blue-emitting phosphor

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  34. Density-functional theory calculations, luminescence properties and fluorescence ratiometric thermo-sensitivity for a novel borate based red phosphor: NaBaSc(BO 3 ) 2 :Ce 3+ ,Mn 2+

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  36. Luminescence properties in relation to controllable morphologies of Ba 3 [Ge 2 B 7 O 16 (OH) 2 ](OH)(H 2 O):Eu 3+ and its thermal conversion product Ba 3 Ge 2 B 6 O 16 :Eu 3+

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  37. Non-concentration quenching, good thermal stability and high quantum efficiency of K 5 Y(P 2 O 7 ) 2 :Eu 3+ /Tb 3+ phosphors with a novel two-dimensional layer structure

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  39. Site Occupancy Studies and Luminescence Properties of Emission Tunable Phosphors Ca 9 La(PO 4 ) 7 :Re (Re = Ce 3+ , Eu 2+ )

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  40. Investigation of site occupancy and photoluminescence of Ce3+ in cubic borate Ba3Y2(B2O5)3 and Ce3+ → Tb3+ energy transfer behavior

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  42. Sr2LiScB4O10:Ce3+/Tb3+: A Green-Emitting Phosphor with High Energy Transfer Efficiency and Stability for LEDs and FEDs

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  43. Synthesis of Ba1−Sr YSi2O5N and discussion based on structure analysis and DFT calculation

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  44. Structural origin of blue luminescence in Ce-doped Ba2Y5B5O17 and Ba3Y2B6O15 with multiple cation sites and occupational disorder

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  45. Eu3+-based efficient red phosphors Y1-xEuxGa3(BO3)4 (0 < x ≤ 1): A potential candidate for near ultraviolet LEDs with high thermal stability

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  46. Facile synthesis of high-pressure polymorph β-YB3O6 by co-doping Bi3+ and RE3+ (RE = Tb, Eu) with color-tunable emissions via energy transfer

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  47. Site occupation and 4f → 5d transitions of Ce3+ ions at mixed Ca2+/Y3+ sites in CaYAlO4: Insights from first-principles calculations

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  48. From Nonluminescence to Bright Blue Emission: Boron-Induced Highly Efficient Ce3+-Doped Hydroxyapatite Phosphor

    Inorganic Chemistry · 2019-09-24

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  49. Dopant and excitation wavelength dependent color tunability in Dy3+ and Eu3+ doped CaBi2B2O7 phosphors for NUV warm white LEDs

    Materials Research Bulletin · 2019-09-29

    Yan Gao, Yinhe Li, Xiaorui Sun, Pengfei Jiang, Rihong Cong, Tao Yang

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  50. Site occupancy and tunable photoluminescence properties of Eu2+-Activated Ba3Sc(BO3)3 phosphors for white light emitting diodes

    Journal of Alloys and Compounds · 2019-10-12

    Dan Zhang, Guangshe Li, Zhihua Leng, Liping Li

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