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RESEARCH PAPER · Angewandte Chemie International Edition · 2005

A Building‐Up Process in Open‐Framework Metal Carboxylates that Involves a Progressive Increase in Dimensionality

Meenakshi Dan-Hardi, C. N. R. Rao

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A Building‐Up Process in Open‐Framework Metal Carboxylates that Involves a Progressive Increase in DimensionalityOriginal1, 2-, 1, 3- and 1, 4-Cyclohexanedicarboxylates of Cd and Mn with chain and layered structures54Exploring conformationally flexible hydrogen-bond-functionalized ligand and counter anions in metal–organic frameworks of Cu( ii )48Hydrogen-bonded microporous network, helix and 1-D zigzag chains in MOFs of Zn(ii): studying the effects of ligating topologies, hydrogen bonding backbone and counter-anions60Structural diversity and chemical trends in hybrid inorganic–organic framework materials1082Assembling Magnetic Nanowires into Networks: A Layered CoIICarboxylate Coordination Polymer Exhibiting Single‐Chain‐Magnet Behavior246Assembling Magnetic Nanowires into Networks: A Layered CoIICarboxylate Coordination Polymer Exhibiting Single‐Chain‐Magnet Behavior245Diverse Structures and Dimensionalities in Hybrid Frameworks of Strontium and Lanthanum with Isomeric Dihydroxybenzoates49One-dimensional coordination polymer and its hydrogen bonded 2D network generated from dimeric Ag(I) building units13Structural characterization of a layered double salt Mn3(OH)2(SO4)2(H2O)2· K2SO412Synthesis, structure and luminescent property of a 2D polymer containing silver ions33Diversity of crystal structure with different lanthanide ions involving in situ oxidation–hydrolysis reaction132Inter-relationship between the structures of metal-organic frameworks: is there a role for an intermediate?0Scorpion-shaped carboxylate ligand tailored molecular square, bilayer, self-threading and (3,6)-connected nets90Supramolecular structural diversities in the metal–organic frameworks derived from pyridylamide ligands: studying the effects of ligating topologies, hydrogen bonding backbone of the ligands and counter anions30The role of temperature on the structure and dimensionality of MOFs: an illustrative study of the formation of manganese oxy-bis(benzoate) structures120Lamellar and Three‐Dimensional Hybrid Compounds Formed by Cyclohexene‐ and Cyclohexanedicarboxylates of Pb, La, and Cd92Metal–Organic Hybrids of 1,3,5‐Tris(4‐pyridylsulfanylmethyl)‐2,4,6‐trimethylbenzene with Mercuric Halides15Metal−Organic Frameworks from Copper Dimers withcis- andtrans-1,4-Cyclohexanedicarboxylate andcis,cis-1,3,5-Cyclohexanetricarboxylate60Assembly of a Homochiral, Body-Centered Cubic Network Composed of Vertex-Shared Mg12 Cages: Use of Electrospray Ionization Mass Spectrometry to Monitor Metal Carboxylate Nucleation127Coordination polymers constructed by linking metal ions with azodibenzoate anions63Hybrid compounds with chain and layered structures formed by β-alanine7Delicate Crystal Structure Changes Govern the Magnetic Properties of 1D Coordination Polymers Based on 3d Metal Carboxylates85Manipulation of molecular aggregation and supramolecular structure using self-assembled lithium mixed-anion complexes17Two zinc(II) supramolecular isomers of square grid networks formed by two flexible ligands: syntheses, structures and nonlinear optical properties60Zn(II) metal–organic frameworks (MOFs) derived from a bis-pyridyl-bis-urea ligand: effects of crystallization solvents on the structures and anion binding properties64Hierarchical Structures in Tin(II) Oxalates19Ligating topology and counter anion controlled formation of discrete metallo-macrocycle and 2D corrugated sheet in coordination compounds derived from a bis-pyridyl-bis-amide ligand and Cd (II)salts30A 3d–3d heterometallic organic framework consisting of two cross-linked coordination polymers14Novel Inorganic–Organic Hybrid Frameworks of Manganese(II): Syntheses, Crystal Structures, and Physical Properties52Nickel Catalyst Stability toward Carboxylic Acids12Transformation of mixed anionic coordination polymers of lead10New indium selenite-oxalate and indium oxalate with two- and three-dimensional structures11Hydrothermal Syntheses and Structural Diversity of Cobalt Complexes with 2,2′-Bibenzimidazole Ligand by Temperature Tuning Strategy31Metal–organic frameworks derived from bis-pyridyl-bis-amide ligands : Effect of positional isomerism of the ligands, hydrogen bonding backbone, counter anions on the supramolecular structures and selective crystallization of the sulfate anion72Porous Coordination Polymers Towards Gas Technology15Porous Coordination Polymers Towards Gas Technology0A Series of Lead(II) Complexes with π−π Stackings: Structural Diversities by Varying the Ligands149Direct synthesis of Co/Mn complex with Co-semisepulchrate entity10Structural Diversity in Coordination Polymers Composed of Divalent Transition Metals, 2,2′-Bipyridine, and Perfluorinated Dicarboxylates48Rationally designed and controlled syntheses of different series of 4d–4f heterometallic coordination frameworks based on lanthanide carboxylate and Ag(IN)2 substructures63Enhancement of H 2 uptake via fluorination but not lithiation for Zn 4 N 8 and Zn 4 N 6 O type clusters12Heterocyclic amine directed synthesis of metal(ii)-oxalates: investigating the magnetic properties of two complete series of chains with S = 5/2 to S = 1/253Template-directed synthesis of three new open-framework metal(ii) oxalates using Co(iii) complex as template65Coordination polymers derived from a bis-pyridyl-bis-amide ligand: Supramolecular structural diversities and anion binding properties23|Co(en)3|1/3[In(ox)2]·3.5H2O: A zeolitic metal-organic framework templated by Co(en)3Cl344Two 3D supramolecules with helices constructed by hydrogen bonds based on p-thioacetatebenzoic acid ligand8Syntheses and characterization of inorganic–organic hybrids with 4-(isonicotinamido)phthalate and some divalent metal centers28Thermally Triggered Reversible Transformation between Parallel Staggered Stacking and Plywood-Like Stacking of 1D Coordination Polymer Chains21One-Dimensional Coordination Polymers: Complexity and Diversity in Structures, Properties, and Applications1113Three isostructural 3D supramolecules with p-thioacetatebenzoic acid ligand: syntheses, structure characterizations, and properties1Influence of the Synthetic Conditions on the Structural Diversity of Extended Manganese−Oxalato−1,2-bis(4-pyridyl)ethylene Systems31Structural diversity of the mixed-ligand system Mn-cpdba-2,2′-bpy controlled by temperature30Syntheses and Characterizations of two Zinc(II) Metal‐organic Frameworks based on 1,4‐Naphthalenedicarboxylate and Imidazole Ligands61D−3D Metal−Organic Lattice Assemblies through Chemical Reactivity and Metal-Assisted Ligand Transformations in Ternary Pb(II)-Phenanthroline-(Hydroxy)dicarboxylic Acid Systems35Synthesis, Structure, and Physical Properties of a Barium Complex with 5‐Sulfoisophthalic Acid Sodium Salt12Synthesis and Characterization of 3d Metal Complexes Based on 1-(4-Nitrophenyl)imidazole2Supramolecular Self-Assembly of M-IDA Complexes Involving Lone-Pair···π Interactions: Crystal Structures, Hirshfeld Surface Analysis, and DFT Calculations [H2IDA = iminodiacetic acid, M = Cu(II), Ni(II)]344Synthesis, Characterization, and Luminescence of Two New Zinc(II) Coordination Polymers Constructed by 5‐(4‐Carboxybenzyloxy)Isophthalic Acid Ligand3Three New Complexes Based on a Flexible Bis(benzimidazole) Ligand and Rigid/Flexible Organic Carboxylates18Synthesis and crystal structure of mononuclear nickel(II) trifloroacetate complex0Synthesis and Molecular Structures of Carboxylic Acid Group Bearing Two Ketoimines that Exist in Enaminone Form4Anions behaviors for the dimensionalities of coordination polymers based on poly(imidazole) ligands8Solvent-free synthesis of new open-framework oxalate structures21Temperature-controlled reduction of Cu(ii) and structural transformation on the assembly of coordination network19Controlled Construction of Metal–Organic Frameworks: Hydrothermal Synthesis, X‐ray Structure, and Heterogeneous Catalytic Study91Structural diversity of terpyridine-based metal complexes with varied dicarboxylate auxiliary ligands15Structural evolution and magnetic properties of a series of coordination polymers featuring dinuclear secondary-building units and adamantane-dicarboxylato ligands16Synthesis, crystal structure, and luminescent property of [Zn2(Ox)3]H2L · 4H2O (L = 2,2′-(1,4-butanediyl-bis(1H-benzimidazole))0Temperature-controlled synthesis and luminescent properties of two novel coordination polymers modeled by hexa-carboxylate ligand derived from cyclotriphosphazene41Solid State and Solution Mediated Multistep Sequential Transformations in Metal–Organic Coordination Networks32A magnesium-based multifunctional metal–organic framework: synthesis, thermally induced structural variation, selective gas adsorption, photoluminescence and heterogeneous catalytic study51Effect of lanthanide contraction on crystal structures of Ln(iii) coordination polymers with dinuclear SBUs based on 3-(4-hydroxypyridinium-1-yl) phthalic acid and oxalic acid27Two Systems of [DabcoH2]2+/[PipH2]2+–Uranyl–Oxalate Showing Reversible Crystal-to-Crystal Transformations Controlled by the Diammonium/Uranyl/Oxalate Ratios in Aqueous Solutions ([DabcoH2]2+ = 1,4-Diazabicyclo-[2.2.2]-octaneH2 and [PipH2]2+ = PiperazineH2)23Hydrothermal Synthesis and Characterization of a Novel Lead(II) Inorganic-Organic Hybrid Framework Based on a Highly Flexible 2,2′-Thiodiacetic Acid Ligand3[Co(NH3)6]2[Cd8(C2O4)11(H2O)4]·8H2O: A 5-connected sqp topological metal–organic framework co-templated by Co(NH3)63+ cation and (H2O)4 cluster4Mimicking mineral neogenesis for the clean synthesis of metal–organic materials from mineral feedstocks: coordination polymers, MOFs and metal oxide separation59Cadmium–Furandicarboxylate Coordination Polymers Prepared with Different Types of Pyridyl Linkers: Synthesis, Divergent Dimensionalities, and Luminescence Study51From 1D chain to 2D layer and 3D network: Solvent-free syntheses of new metal oxalates3Alkaline earth metal-based metal–organic framework: hydrothermal synthesis, X-ray structure and heterogeneously catalyzed Claisen–Schmidt reaction49An unprecedented (4,8)-connected net featuring gsp2 topology and containing an exceptional coordination mode of acylamide ligand5Influence of temperature on metal-organic frameworks129Linear Coordination Polymers Assembled from Dinuclear Cu(I) Units: Interchain π–π and CH–π Interactions in Controlling Alignments of Polymeric Chains in Solid State2pH‐Tuned Modulation of 1D Chain to 3D Metal–Organic Framework: Synthesis, Structure and Their Useful Application in the Heterogeneous Claisen–Schmidt Reaction14Dinuclear Bridging Bidentate Zinc/Stearate Complex in Sulfur Cross-Linking of Rubber115Metal–Organic Frameworks Based on Alkaline Earth Metals – Hydrothermal Synthesis, X‐ray Structures, Gas Adsorption, and Heterogeneously Catalyzed Hydrogenation Reactions32Structural influence of the substituent in carboxylate anion on example of α- and β-naphthoate complexes of Co(II), Ni(II), Cu(II), and Zn(II)27Highly dense nickel hydroxide nanoparticles catalyst electrodeposited from a novel Ni(II) paddle–wheel complex12A porous framework based on tetrakis(4-pyridyloxymethyl)methane fine-tuned by metal ions: synthesis, crystal structures and adsorption properties3Characterization of an inorganic-organic hybrid polyoxomolybdate (C6H18N2)2[H2Mo7O24]•7H2O7Mechano-switchable, luminescent gels derived from salts of a long-chained, fatty-acid gelator11Heterometallic Alkaline Earth–Lanthanide Ba II –La III Microporous Metal–Organic Framework as Bifunctional Luminescent Probes of Al 3+ and MnO 4 –212Two-dimensional Cu(II)/Cd(II) complexes with double bridged [(μ-EO-N3)(μ-N-N-tetrazolate)] chains: Crystal structures, magnetic behavior and luminescence properties6Supramolecular Templating Approach for the Solvent-Free Synthesis of Open-Framework Metal Oxalates34Minerals with metal-organic framework structures59Binuclear nickel(II) complexes with 3,5-di-tert-butylbenzoate and 3,5-di-tert-butyl-4-hydroxybenzoate anions and 2,3-lutidine: the synthesis, structure, and magnetic properties22Promotion Effects of ZrO2on Mesoporous Pd Prepared by a One-Step Dealloying Method for Methanol Oxidation in an Alkaline Electrolyte8A 3d-4f Complex Constructed by the Assembly of a Cationic Template, [Cu(en)2 ]2+ , and a 3D Anionic Coordination Polymer, [Sm2 (C2 O4 )3 (C5 O5 )(H2 O)2 ]2-4Multiple functions of amines in the synthesis of anionic, cationic, and neutral indium oxalates3A paraelectric–ferroelectric phase transition of an organically templated zinc oxalate coordination polymer16In Situ, Time-Resolved, and Mechanistic Studies of Metal–Organic Framework Nucleation and Growth610Functionality in metal–organic framework minerals: proton conductivity, stability and potential for polymorphism46Solvent-assisted structural conversion involving bimetallic complexes based on the tris(oxalato)ferrate( iii ) unit with the green → blue → red crystal color sequence13Temperature tuned syntheses of two new d 10 -based Cd( ii ) cluster metal–organic frameworks: luminescence sensing and photocatalytic properties15One-dimensional copper(II) coordination polymers based on 1,3-bis(pyridin-4-yl)propane and diimine ligands2Organically templated metal sulfate-oxalates: Solvent-free synthesis, crystal structure, and proton conduction8Roles of Dinuclear Bridging Bidentate Zinc/Stearate Complexes in Sulfur Cross-Linking of Isoprene Rubber49Above-room-temperature coupling between ferroelastic domains and magnetism in an organic-inorganic hybrid: CsCu(HCOO)2Cl4Observation of Structural Diversity Based on the Cationic Influence in a Series of Zn/Cd Pyridine Carboxylate Coordination Compounds0Promoting the formation of metal–carboxylate coordination to modulate the dimensionality of ultrastable lead halide hybrids13Solvent-free synthesis and optical properties of two open-framework metal oxalates with zeolitic ABW and diamondoid topologies3Conductive MOFs: Synthesis and Applications in Supercapacitors and Batteries28Mathematical techniques for graph descriptors, entropies, spectra, and properties of oxalate-based metal organic frameworks6Easily Water‐Synthesisable Iron‐Chloranilate Frameworks as High Energy and High‐Power Cathodes for Sustainable Alkali‐Ion Batteries3Easily Water‐Synthesisable Iron‐Chloranilate Frameworks as High Energy and High‐Power Cathodes for Sustainable Alkali‐Ion Batteries0Lanthanide-Diphosphonate Frameworks Containing Dianthracene: Isolation of Metastable Intermediates and Lanthanide-Dependent UV and X-ray Light-Responsive Properties5MOFs, COFs, and HOFs19

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  1. 1, 2-, 1, 3- and 1, 4-Cyclohexanedicarboxylates of Cd and Mn with chain and layered structures

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  2. Exploring conformationally flexible hydrogen-bond-functionalized ligand and counter anions in metal–organic frameworks of Cu( ii )

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  4. Structural diversity and chemical trends in hybrid inorganic–organic framework materials

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  5. Assembling Magnetic Nanowires into Networks: A Layered CoIICarboxylate Coordination Polymer Exhibiting Single‐Chain‐Magnet Behavior

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  7. Diverse Structures and Dimensionalities in Hybrid Frameworks of Strontium and Lanthanum with Isomeric Dihydroxybenzoates

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  8. One-dimensional coordination polymer and its hydrogen bonded 2D network generated from dimeric Ag(I) building units

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  9. Structural characterization of a layered double salt Mn3(OH)2(SO4)2(H2O)2· K2SO4

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  10. Synthesis, structure and luminescent property of a 2D polymer containing silver ions

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  11. Diversity of crystal structure with different lanthanide ions involving in situ oxidation–hydrolysis reaction

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  12. Inter-relationship between the structures of metal-organic frameworks: is there a role for an intermediate?

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  13. Scorpion-shaped carboxylate ligand tailored molecular square, bilayer, self-threading and (3,6)-connected nets

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  14. Supramolecular structural diversities in the metal–organic frameworks derived from pyridylamide ligands: studying the effects of ligating topologies, hydrogen bonding backbone of the ligands and counter anions

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  15. The role of temperature on the structure and dimensionality of MOFs: an illustrative study of the formation of manganese oxy-bis(benzoate) structures

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  16. Lamellar and Three‐Dimensional Hybrid Compounds Formed by Cyclohexene‐ and Cyclohexanedicarboxylates of Pb, La, and Cd

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  17. Metal–Organic Hybrids of 1,3,5‐Tris(4‐pyridylsulfanylmethyl)‐2,4,6‐trimethylbenzene with Mercuric Halides

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  18. Metal−Organic Frameworks from Copper Dimers withcis- andtrans-1,4-Cyclohexanedicarboxylate andcis,cis-1,3,5-Cyclohexanetricarboxylate

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  19. Assembly of a Homochiral, Body-Centered Cubic Network Composed of Vertex-Shared Mg12 Cages: Use of Electrospray Ionization Mass Spectrometry to Monitor Metal Carboxylate Nucleation

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  20. Coordination polymers constructed by linking metal ions with azodibenzoate anions

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  21. Hybrid compounds with chain and layered structures formed by β-alanine

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  22. Delicate Crystal Structure Changes Govern the Magnetic Properties of 1D Coordination Polymers Based on 3d Metal Carboxylates

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  23. Manipulation of molecular aggregation and supramolecular structure using self-assembled lithium mixed-anion complexes

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  25. Zn(II) metal–organic frameworks (MOFs) derived from a bis-pyridyl-bis-urea ligand: effects of crystallization solvents on the structures and anion binding properties

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  26. Hierarchical Structures in Tin(II) Oxalates

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  27. Ligating topology and counter anion controlled formation of discrete metallo-macrocycle and 2D corrugated sheet in coordination compounds derived from a bis-pyridyl-bis-amide ligand and Cd (II)salts

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  28. A 3d–3d heterometallic organic framework consisting of two cross-linked coordination polymers

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  29. Novel Inorganic–Organic Hybrid Frameworks of Manganese(II): Syntheses, Crystal Structures, and Physical Properties

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  30. Nickel Catalyst Stability toward Carboxylic Acids

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  31. Transformation of mixed anionic coordination polymers of lead

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  32. New indium selenite-oxalate and indium oxalate with two- and three-dimensional structures

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  33. Hydrothermal Syntheses and Structural Diversity of Cobalt Complexes with 2,2′-Bibenzimidazole Ligand by Temperature Tuning Strategy

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  34. Metal–organic frameworks derived from bis-pyridyl-bis-amide ligands : Effect of positional isomerism of the ligands, hydrogen bonding backbone, counter anions on the supramolecular structures and selective crystallization of the sulfate anion

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  35. Porous Coordination Polymers Towards Gas Technology

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  36. Porous Coordination Polymers Towards Gas Technology

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  37. A Series of Lead(II) Complexes with π−π Stackings: Structural Diversities by Varying the Ligands

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  38. Direct synthesis of Co/Mn complex with Co-semisepulchrate entity

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  39. Structural Diversity in Coordination Polymers Composed of Divalent Transition Metals, 2,2′-Bipyridine, and Perfluorinated Dicarboxylates

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  40. Rationally designed and controlled syntheses of different series of 4d–4f heterometallic coordination frameworks based on lanthanide carboxylate and Ag(IN)2 substructures

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    Yongcai Qiu, Zhihui Liu, Jixia Mou, Hong Deng, Mat­thias Zeller

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  41. Enhancement of H 2 uptake via fluorination but not lithiation for Zn 4 N 8 and Zn 4 N 6 O type clusters

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    Carl Redshaw, Surajit Jana, Congxiao Shang, M.R.J. Elsegood, Xuesong Lu, Zhengxiao Guo

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  42. Heterocyclic amine directed synthesis of metal(ii)-oxalates: investigating the magnetic properties of two complete series of chains with S = 5/2 to S = 1/2

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  43. Template-directed synthesis of three new open-framework metal(ii) oxalates using Co(iii) complex as template

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  44. Coordination polymers derived from a bis-pyridyl-bis-amide ligand: Supramolecular structural diversities and anion binding properties

    Inorganica Chimica Acta · 2010-02-05

    N.N. Adarsh, D. Krishna Kumar, Eringathodi Suresh, Parthasarathi Dastidar

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  45. |Co(en)3|1/3[In(ox)2]·3.5H2O: A zeolitic metal-organic framework templated by Co(en)3Cl3

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    Qinhe Pan, Jiyang Li, Qiang Chen, Yide Han, Ze Chang, Wei‐Chao Song, Xian‐He Bu

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  46. Two 3D supramolecules with helices constructed by hydrogen bonds based on p-thioacetatebenzoic acid ligand

    Structural Chemistry · 2010-05-26

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  47. Syntheses and characterization of inorganic–organic hybrids with 4-(isonicotinamido)phthalate and some divalent metal centers

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    Man Chen, Qin Hua, Zheng‐Shuai Bai, Taka‐aki Okamura, Zhi Guo Su, Wei‐Yin Sun, Norikazu Ueyama

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  48. Thermally Triggered Reversible Transformation between Parallel Staggered Stacking and Plywood-Like Stacking of 1D Coordination Polymer Chains

    Inorganic Chemistry · 2010-07-07

    Jian‐Ke Sun, Xu‐Hui Jin, Chao Chen, Jie Zhang

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  49. One-Dimensional Coordination Polymers: Complexity and Diversity in Structures, Properties, and Applications

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