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RESEARCH PAPER · Chemical Communications · 2006

Structural diversity and chemical trends in hybrid inorganic–organic framework materials

Anthony Kevin Cheetham, C. N. R. Rao, R.K. Feller

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Structural diversity and chemical trends in hybrid inorganic–organic framework materialsOriginalThe role of temperature on the structure and dimensionality of MOFs: an illustrative study of the formation of manganese oxy-bis(benzoate) structures120Ionothermal Synthesis of Zeolites, Metal–Organic Frameworks, and Inorganic–Organic Hybrids885A “Star” Antiferromagnet: A Polymeric Iron(III) Acetate That Exhibits Both Spin Frustration and Long‐Range Magnetic Ordering202There's Room in the Middle362Assembly of a Homochiral, Body-Centered Cubic Network Composed of Vertex-Shared Mg12 Cages: Use of Electrospray Ionization Mass Spectrometry to Monitor Metal Carboxylate Nucleation127Manganese and Magnesium Homochiral Materials: Decoration of Honeycomb Channels with Homochiral Chains185Hydrothermal Synthesis, Structures, and Photoluminescent Properties of Benzenepentacarboxylate Bridged Networks Incorporating Zinc(II)−Hydroxide Clusters or Zinc(II)−Carboxylate Layers131Structural Changes and Coordinatively Unsaturated Metal Atoms on Dehydration of Honeycomb Analogous Microporous Metal–Organic Frameworks297Hybrid inorganic–organic materials: a new family in condensed matter physics327Assembly of the Highest Connectivity Wells-Dawson Polyoxometalate Coordination Polymer: the Use of Organic Ligand Flexibility227Wavelength‐Dependent Photochromic Inorganic–Organic Hybrid Based on a 3D Iodoplumbate Open‐Framework Material203Amine Grafting on Coordinatively Unsaturated Metal Centers of MOFs: Consequences for Catalysis and Metal Encapsulation1243Amine Grafting on Coordinatively Unsaturated Metal Centers of MOFs: Consequences for Catalysis and Metal Encapsulation279Preparation, Structures, and Photocatalytic Properties of Three New Uranyl−Organic Assembly Compounds218Structural transformation and high pressure methane adsorption of Co2(1,4-bdc)2dabco105Gallium−Sulfide Supertetrahedral Clusters as Building Blocks of Covalent Organic−Inorganic Networks105Directing the Structure of Metal–Organic Frameworks by Oriented Surface Growth on an Organic Monolayer208Multifunctional Microporous MOFs Exhibiting Gas/Hydrocarbon Adsorption Selectivity, Separation Capability and Three‐Dimensional Magnetic Ordering170Order−Disorder Antiferroelectric Phase Transition in a Hybrid Inorganic−Organic Framework with the Perovskite Architecture489High-Throughput Assisted Rationalization of the Formation of Metal Organic Frameworks in the Iron(III) Aminoterephthalate Solvothermal System620Self-Assembly of Polyoxometalate-Based Metal Organic Frameworks Based on Octamolybdates and Copper-Organic Units: from CuII, CuI,II to CuI via Changing Organic Amine219Tuning the Dimensionality of the Coordination Polymer Based on Polyoxometalate by Changing the Spacer Length of Ligands197Spontaneous Resolution of Chiral Polyoxometalate‐Based Compounds Consisting of 3D Chiral Inorganic Skeletons Assembled from Different Helical Units124Thermodynamics of Guest-Induced Structural Transitions in Hybrid Organic−Inorganic Frameworks337Role of Temperature and Time in the Formation of Infinite −M−O−M− Linkages and Isolated Clusters in MOFs: A Few Illustrative Examples163Microwave synthesis of hybrid inorganic–organic materials including porous Cu3(BTC)2 from Cu(II)-trimesate mixture373Synthesis, structures and properties of Mn(II) coordination frameworks based on R-isophthalate (R = –CH 3 or –C(CH 3 ) 3 ) and various dipyridyl-type co-ligands131Self-Supported Catalysts550Application of metal–organic frameworks with coordinatively unsaturated metal sites in storage and separation of methane and carbon dioxide689Design and synthesis of metal–organic frameworks using metal–organic polyhedra as supermolecular building blocks1768Magnetic metal–organic frameworks2448Metallic and bimetallic nanocatalysts incorporated into highly porous coordination polymer MIL-101292Zeolitic imidazole frameworks: structural and energetics trends compared with their zeolite analogues246“Zincone” Zinc Oxide−Organic Hybrid Polymer Thin Films Formed by Molecular Layer Deposition189Synthesis and Modification of a Functionalized 3D Open-Framework Structure with MIL-53 Topology417Unprecedented Sulfone‐Functionalized Metal–Organic Frameworks and Gas‐Sorption Properties127Reversible Breaking and Forming of Metal–Ligand Coordination Bonds: Temperature‐Triggered Single‐Crystal to Single‐Crystal Transformation in a Metal–Organic Framework120Porous Chromium Terephthalate MIL‐101 with Coordinatively Unsaturated Sites: Surface Functionalization, Encapsulation, Sorption and Catalysis978Growth Mechanism of Metal–Organic Frameworks: Insights into the Nucleation by Employing a Step‐by‐Step Route399Coordination Polymers Versus Metal−Organic Frameworks276Comparative Study of Hydrogen Sulfide Adsorption in the MIL-53(Al, Cr, Fe), MIL-47(V), MIL-100(Cr), and MIL-101(Cr) Metal−Organic Frameworks at Room Temperature542Synthesis, Structure, and Luminescent Properties of Hybrid Inorganic−Organic Framework Materials Formed by Lead Aromatic Carboxylates: Inorganic Connectivity Variation from 0D to 3D220ℝPM3: A Multifunctional Microporous MOF with Recyclable Framework and High H2 Binding Energy111Chemical and Physical Solutions for Hydrogen Storage1674Chemische und physikalische Lösungen für die Speicherung von Wasserstoff179Mixed‐Linker Metal‐Organic Frameworks as Catalysts for the Synthesis of Propylene Carbonate from Propylene Oxide and CO2246Lanthanide-Based Luminescent Hybrid Materials3349Temperature-Controlled Synthesis of Metal-Organic Coordination Polymers: Crystal Structure, Supramolecular Isomerism, and Porous Property149The Effect of Pressure on ZIF‐8: Increasing Pore Size with Pressure and the Formation of a High‐Pressure Phase at 1.47 GPa530The Effect of Pressure on ZIF‐8: Increasing Pore Size with Pressure and the Formation of a High‐Pressure Phase at 1.47 GPa173Multiferroic Behavior Associated with an Order−Disorder Hydrogen Bonding Transition in Metal−Organic Frameworks (MOFs) with the Perovskite ABX3 Architecture798Zeolitic Polyoxometalate-Based Metal−Organic Frameworks (Z-POMOFs): Computational Evaluation of Hypothetical Polymorphs and the Successful Targeted Synthesis of the Redox-Active Z-POMOF1279Synthesis of metal–organic framework MIL-101 in TMAOH-Cr(NO3)3-H2BDC-H2O and its hydrogen-storage behavior157MOF-5 based mixed-linker metal–organic frameworks: Synthesis, thermal stability and catalytic application176Recent advances in crystal engineering746Amino Acid Based MOFs: Synthesis, Structure, Single Crystal to Single Crystal Transformation, Magnetic and Related Studies in a Family of Cobalt and Nickel Aminoisophthales119Copper metal–organic framework: Structure and activity in the allylic oxidation of cyclohexene with molecular oxygen133MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)1185Tuning functional sites and thermal stability of mixed-linker MOFs based on MIL-53(Al)134Silica–MOF Composites as a Stationary Phase in Liquid Chromatography142Hybrid Organic−Inorganic Polyoxometalate Compounds: From Structural Diversity to Applications1755Flexibility in a Metal–Organic Framework Material Controlled by Weak Dispersion Forces: The Bistability of MIL‐53(Al)178Synthesis and Stability of Tagged UiO-66 Zr-MOFs2031Facile synthesis of nano-sized metal-organic frameworks, chromium-benzenedicarboxylate, MIL-101181Supramolecular Structures from Polycarbene Ligands and Transition Metal Ions192Framework-structured weak ferromagnets407Mechanical properties of hybrid inorganic–organic framework materials: establishing fundamental structure–property relationships760Microporous magnets524Synthesis and Structural Characterization of Magnesium Based Coordination Networks in Different Solvents115Polyoxometalate-Based Metal Organic Frameworks (POMOFs): Structural Trends, Energetics, and High Electrocatalytic Efficiency for Hydrogen Evolution Reaction545Synthesis of isostructural metal–organic frameworks, CPO-27s, with ultrasound, microwave, and conventional heating: Effect of synthesis methods and metal ions116Recent Advances in s-Block Metal Carboxylate Networks222Hybrid Nanosheets of an Inorganic–Organic Framework Material: Facile Synthesis, Structure, and Elastic Properties183A Multifunctional Organic–Inorganic Hybrid Structure Based on MnIII–Porphyrin and Polyoxometalate as a Highly Effective Dye Scavenger and Heterogenous Catalyst420Nanoarchitectonics for Mesoporous Materials727Conductive metal–organic frameworks and networks: fact or fantasy?290Luminescence tuning of MOFs via ligand to metal and metal to metal energy transfer by co-doping of 2∞[Gd2Cl6(bipy)3]·2bipy with europium and terbium110The impact of ligands upon topology and functionality of octacyanidometallate-based assemblies176An Ionothermal Synthetic Approach to Porous Polyoxometalate‐Based Metal–Organic Frameworks179Negative Linear Compressibility of a Metal–Organic Framework280Trypsin‐Immobilized Metal–Organic Framework as a Biocatalyst In Proteomics Analysis176Three‐Dimensional Visualization of Defects Formed during the Synthesis of Metal–Organic Frameworks: A Fluorescence Microscopy Study139Dynamic magnetic MOFs618Design and construction of coordination polymers with mixed-ligand synthetic strategy774Solvent-free allylic oxidation of alkenes with O2 mediated by Fe- and Cr-MIL-101247Hierarchical bicontinuous porosity in metal–organic frameworks templated from functional block co-oligomer micelles139Design and Preparation of Materials for Advanced Electrochemical Storage435Ionic Conductivity in the Metal–Organic Framework UiO‐66 by Dehydration and Insertion of Lithium tert‐Butoxide222A Continuous π-Stacked Starfish Array of Two-Dimensional Luminescent MOF for Detection of Nitro Explosives167Integration of Intrinsic Proton Conduction and Guest-Accessible Nanospace into a Coordination Polymer134A symbol approach for classification of molecule-based magnetic materials exemplified by coordination polymers of metal carboxylates209A Palladium‐Nanoparticle and Silicon‐Nanowire‐Array Hybrid: A Platform for Catalytic Heterogeneous Reactions126Crystalline metal-organic frameworks (MOFs): synthesis, structure and function361Solid-state principles applied to organic–inorganic perovskites: new tricks for an old dog1030Water adsorption in MOFs: fundamentals and applications1444Zeolitic imidazolate framework materials: recent progress in synthesis and applications1009Hydrocarbon oxidation over Fe- and Cr-containing metal-organic frameworks MIL-100 and MIL-101–a comparative study121Organic Thermoelectric Materials: Emerging Green Energy Materials Converting Heat to Electricity Directly and Efficiently999Entangled structures in polyoxometalate-based coordination polymers112A 3D Aluminoborate Open Framework Interpenetrated by 2D Zinc–Amine Coordination‐Polymer Networks in Its 11‐Ring Channels129Cascade Reactions Catalyzed by Metal Organic Frameworks191Molecular Interactions Driving the Layer-by-Layer Assembly of Multilayers882Synthesis of metal-organic frameworks (MOFs) with microwave or ultrasound: Rapid reaction, phase-selectivity, and size reduction594Alkaline Earth Metal (Mg, Sr, Ba)–Organic Frameworks Based on 2,2′,6,6′-Tetracarboxybiphenyl for Proton Conduction110Metal-organic framework nanosheets as building blocks for molecular sieving membranes1731Reversible Solid-to-Liquid Phase Transition of Coordination Polymer Crystals247Multifunctional metal–organic frameworks: from academia to industrial applications1003Perovskite Solar Cells: Beyond Methylammonium Lead Iodide324Tandem MOF-Based Photonic Crystals for Enhanced Analyte-Specific Optical Detection107Multifunctional Radical-Doped Polyoxometalate-Based Host–Guest Material: Photochromism and Photocatalytic Activity145Insulator-to-Proton-Conductor Transition in a Dense Metal–Organic Framework106Synthesis and applications of metal-organic framework–quantum dot (QD@MOF) composites350Supramolecular interactions in the solid state130Chiral chemistry of metal–camphorate frameworks268Discovering connections between terahertz vibrations and elasticity underpinning the collective dynamics of the HKUST-1 metal–organic framework115Layer-by-layer assembly of versatile nanoarchitectures with diverse dimensionality: a new perspective for rational construction of multilayer assemblies368On the application of the tolerance factor to inorganic and hybrid halide perovskites: a revised system1172Unprecedented Topological Complexity in a Metal–Organic Framework Constructed from Simple Building Units232Heterometallic Alkaline Earth–Lanthanide Ba II –La III Microporous Metal–Organic Framework as Bifunctional Luminescent Probes of Al 3+ and MnO 4 –212Recent advances in enzyme immobilization techniques: Metal-organic frameworks as novel substrates446Two‐Dimensional‐Material Membranes: A New Family of High‐Performance Separation Membranes841A Robust Sulfonate-Based Metal–Organic Framework with Permanent Porosity for Efficient CO2 Capture and Conversion217Porphyrin-based metal-organic frameworks for solar fuel synthesis photocatalysis: band gap tuning via iron substitutions123A Two-Dimensional Polymer Synthesized through Topochemical [2 + 2]-Cycloaddition on the Multigram Scale173Melt‐Quenched Hybrid Glasses from Metal–Organic Frameworks111Geometric Principles for Designing Highly Symmetric Self-Assembling Protein Nanomaterials112Two‐Dimensional Metal–Organic Framework Nanosheets for Membrane‐Based Gas Separation470Two‐Dimensional Metal–Organic Framework Nanosheets for Membrane‐Based Gas Separation313Metal–organic framework nanosheets (MONs): a new dimension in materials chemistry161Tolerance factors of hybrid organic–inorganic perovskites: recent improvements and current state of research108Unusual Missing Linkers in an Organosulfonate-Based Primitive–Cubic (pcu)-Type Metal–Organic Framework for CO2 Capture and Conversion under Ambient Conditions170Thermodynamic and Kinetic Effects in the Crystallization of Metal–Organic Frameworks173In Situ, Time-Resolved, and Mechanistic Studies of Metal–Organic Framework Nucleation and Growth610Towards Macroscopic Crystalline 2D Polymers153MIL‐53 and its Isoreticular Analogues: a Review of the Chemistry and Structure of a Prototypical Flexible Metal‐Organic Framework135Progress and challenges of graphene oxide/metal-organic composites145Recent progress in fundamental understanding of halide perovskite semiconductors139Advances in the green chemistry of coordination polymer materials129Octacyanidometallates for multifunctional molecule-based materials164Metal–Organic Framework Magnets634Zeolitic imidazolate framework-8 (ZIF-8) for drug delivery: A critical review197Overall photocatalytic water splitting by an organolead iodide crystalline material210Investigation of the MOF adsorbents and the gas adsorptive separation mechanisms142A review on g-C 3 N 4 incorporated with organics for enhanced photocatalytic water splitting123An extensive review on three dimension architectural Metal-Organic Frameworks towards supercapacitor application212The structural appeal of metal–organic frameworks in antimicrobial applications113Metal–organic frameworks for active food packaging. A review134Inorganic–Organic Hybrid Dielectrics for Energy Conversion: Mechanism, Strategy, and Applications107A review on MOFs synthesis and effect of their structural characteristics for hydrogen adsorption108Analysis of metal–organic framework-based photosynthetic CO2 reduction152

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    Sebastian Bauer, Thomas Bein, Norbert Stock

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  50. Eight coordination with bis(bidentate) bridging ligands: zeolitic topology versus square grid networks

    Chemical Communications · 2007-12-17

    Jianyong Zhang, Ai-Ling Cheng, Qi Yue, Weiwei Sun, En‐Qing Gao

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