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RESEARCH PAPER · Angewandte Chemie International Edition · 2012

Materials Discovery by Flux Crystal Growth: Quaternary and Higher Order Oxides

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Materials Discovery by Flux Crystal Growth: Quaternary and Higher Order OxidesOriginalSoluble human leukocyte antigen-G (SHLA-G) in Tunisian kidney transplantation.2Wolf Prize: A. P. Alivisatos and C. M. Lieber / F. A. Cotton Medal: R. G. Cooks / Southern Chemist Award: H.‐C. zur Loye1Wolf‐Preis: A. P. Alivisatos und C. M. Lieber / F. A. Cotton Medal: R. G. Cooks / Southern Chemist Award: H.‐C. zur Loye0Li3Al(MoO4)3, a lyonsite molybdate12ChemInform Abstract: Materials Discovery by Flux Crystal Growth: Quaternary and Higher Order Oxides1On the synthesis, characterization, and magnetization of Ln-M-X (Ln = lanthanide; M = Ti-Cr, Cu, Mo, Pd; X = Al, Ga) intermetallics1Preparation of Inorganic Photocatalytic Materials for Overall Water Splitting102Aerosol‐Assisted Molten Salt Synthesis of NaInS2 Nanoplates for Use as a New Photoanode Material38Single crystal growth and structural characterization of four complex uranium oxides: CaUO4, β-Ca3UO6, K4CaU3O12, and K4SrU3O1220Flux growth of Sr2Ta2O7 crystals and subsequent nitridation to form SrTaO2N crystals36Flux Growth and Magnetoresistance Behavior of Rare Earth Zintl Phase EuMgSn21Hydroflux Crystal Growth of Platinum Group Metal Hydroxides: Sr 6 NaPd 2 (OH) 17 , Li 2 Pt(OH) 6 , Na 2 Pt(OH) 6 , Sr 2 Pt(OH) 8 , and Ba 2 Pt(OH) 858Synthesis and Crystal Structure of the New Samarium Oxyhydroxide, SmO(OH)1Spatial and Temporal Confinement of Salt Fluxes for the Shape-Controlled Synthesis of Fe2O3 Nanocrystals41Coupled Nd and B′ spin ordering in the double perovskites Nd 2 Na B′ O 6 ( B′=Ru , Os)19Salt melt synthesis of ceramics, semiconductors and carbon nanostructures688Synthesis and Crystal Structure of a New Complex Uranium Oxide, Na4.5Nd0.5UO65Crystal Growth of New Hexahydroxometallates Using a Hydroflux60Synthesis and Crystal Structure of Dibarium Tungstate Hydrate, Ba2WO5·H2O7Low-temperature growth of spinel-type Li 1+x Mn 2−x O 4 crystals using a LiCl–KCl flux and their performance as a positive active material in lithium-ion rechargeable batteries14Synthesis, structure, and optical properties of a series of quaternary oxides, K2Ba(MO4)2 (M = Cr, Mo, W)21Crystal growth, structural characterization, cation–cation interaction classification, and optical properties of uranium( vi ) containing oxychlorides, A 4 U 5 O 16 Cl 2 (A = K, Rb), Cs 5 U 7 O 22 Cl 3 , and AUO 3 Cl (A = Rb, Cs)27Platinum group metal oxides for heterogeneous catalysis: Novel synthesis and advanced characterization0Rapid Microwave Preparation and ab Initio Studies of the Stability of the Complex Noble Metal Oxides La 2 BaPdO 5 and La 2 BaPtO 511Single-Crystal Growth and Size Control of Three Novel Polar Intermetallics: Eu2.94(2)Ca6.06In8Ge8, Eu3.13(2)Ca5.87In8Ge8, and Sr3.23(3)Ca5.77In8Ge8 with Crystal Structure, Chemical Bonding, and Magnetism Studies8Ca54In13B4–xH23+x: A Complex Metal Subhydride Featuring Ionic and Metallic Regions11Crystal Growth and Structure Determination of the New Neodymium Germanate, Na2NdGeO4(OH)5Crystal growth, structures, magnetic and photoluminescent properties of NaLnGeO4 (Ln = Sm, Eu, Gd, Tb)27Crystal Growth and Structure Determination of the New Neodymium Germanate, Na5Nd4Ge4O16(OH)5Growth, structural and magnetic characterization of Al-substituted barium hexaferrite single crystals99Single crystal growth and structural characterization of ternary transition-metal uranium oxides: MnUO4, FeUO4, and NiU2O617Ti-Substituted BaFe12O19 Single Crystal Growth and Characterization54Single Crystal Growth and Structural Characterization of a Novel Mixed-Valent Ternary Uranium Oxide, K8U7O2410Simple correction for the sample shape and radial offset effects on SQUID magnetometers: Magnetic measurements on Ln2O3 (Ln=Gd, Dy, Er) standards113Photoluminescent and Magnetic Properties of Lanthanide Containing Apatites: NaxLn10–x(SiO4)6O2–yFy, CaxLn10–x(SiO4)6O2–yFy (Ln = Eu, Gd, and Sm), Gd9.34(SiO4)6O2, and K1.32Pr8.68(SiO4)6O1.36F0.6452Synthesis and Crystal Structure of Sodium Arsenate Oxyhydroxide: Na4(AsO4)OH12Flux-mediated crystal growth of metal oxides: synthetic tunability of particle morphologies, sizes, and surface features for photocatalysis research154A 5 RE 4 X[TO 4 ] 4 crystal growth and photoluminescence. Fluoride flux synthesis of sodium and potassium rare earth silicate oxyfluorides29A 5 RE 4 X[TO 4 ] 4 crystal growth and photoluminescence. Hydroflux synthesis of sodium rare earth silicate hydroxides20A novel flux coating method for the fabrication of layers of visible-light-responsive Ta 3 N 5 crystals on tantalum substrates21Carbides of group IVA, VA and VIA transition metals as alternative HER and ORR catalysts and support materials184Flux crystal growth and structural analysis of two cesium uranium oxides, Cs 2.2 U 5 O 16 and Cs 2 U 4 O 13 , containing multiple cation–cation interactions9Flux growth of hexagonal cylindrical LiCoO 2 crystals surrounded by Li-ion conducting preferential facets and their electrochemical properties studied by single-particle measurements25Flux growth of patterned LiCoO 2 crystal arrays directly on a Pt substrate in molten LiNO 39Novel La 3 Fe(MoO 4 ) 6 phase: magnetic properties and ethanol reactivity5One-pot in situ molten salt synthesis of octahedral Fe 3 O 4 for efficient microwave absorption application47Growth, structural and magnetic characterization of Co- and Ni-substituted barium hexaferrite single crystals75Crystallographic and Spectroscopic Investigations on Nine Metal–Rare‐Earth Silicates with the Apatite Structure Type23Tungsten substituted BaFe12O19 single crystal growth and characterization30Aerosol-Assisted Synthesis of Shape-Controlled CoFe2O4: Topotactic versus Direct Melt Crystallization33Hydroflux synthesis and crystal structure of new lanthanide tungstate oxyhydroxides10Fabrication of La2Ti2O7 Crystals Using an Alkali-Metal Molybdate Flux Growth Method and Their Nitridability To Form LaTiO2N Crystals under a High-Temperature NH3 Atmosphere47Flux Crystal Growth and Structure Determination of K5Y2FSi4O136Cu-substituted barium hexaferrite crystal growth and characterization40Flux Crystal Growth and Optical Properties of Two Uranium-Containing Silicates: A2USiO6 (A = Cs, Rb)19Two Structure Types Based on Si6O15 Rings: Synthesis and Structural and Spectroscopic Characterisation of Cs1.86K1.14DySi6O15 and Cs1.6K1.4SmSi6O1512Conceptual Inorganic Materials Discovery – A Road Map46Towards Shape Control of Metal Oxide Nanocrystals in Confined Molten Media22Synthesis of the Layered Quaternary Uranium-Containing Oxide Cs2Mn3U6O22 and Characterization of its Magnetic Properties7Synthesis, characterization, and properties of reduced europium molybdates and tungstates21NH3-Assisted Flux-Mediated Direct Growth of LaTiO2N Crystallites for Visible-Light-Induced Water Splitting73Structural and electronic investigations of PbTa4O11 and BiTa7O19 constructed from α-U3O8 types of layers15Fluoride Flux Crystal Growth and Structure Determination of K5Sc2FSi4O136Single crystal growth and characterization of the reduced barium sodium siliconiobate, Ba3Na0.32Nb6O12(Si2O7)28Structural and millimeter-wave characterization of flux grown Al substituted barium hexaferrite single crystals43Growth of Individual, Highly Oriented LiFePO4 Crystals on a SUS Substrate Using NaCl–KCl Flux Coating21A2MnU3O11 (A = K, Rb) and Li3.2Mn1.8U6O22: Three New Alkali-Metal Manganese Uranium(VI) Oxides Related to Natrotantite11Single crystal growth and characterization of the first reduced lanthanum molybdenum oxychloride, La20Mo12O63Cl4, with an unusual trigonal prismatic MoO6 unit14Growth, structural and magnetic characterization of Zn-substituted barium hexaferrite single crystals56Unique Growth Manner of Li5La3Ta2O12 Crystals from Lithium Hydroxide Flux at Low Temperature10Structural and photoluminescence properties of doped and REE-endmember mixed-framework rare-earth sorosilicates7Synthesis of anhydrous K2TiOF4 via a mild hydrothermal method8Hydrothermal synthesis, structure, and property characterization of rare earth silicate compounds: NaBa3Ln3Si6O20 (Ln = Y, Nd, Sm, Eu, Gd)14Flux-mediated syntheses, structural characterization and low-temperature polymorphism of the p-type semiconductor Cu2Ta4O1118Single crystal growth, structural characteristics and magnetic properties of chromium substituted M-type ferrites33Crystal growth of incommensurate members of 2H-hexagonal perovskite related oxides: Ba4M Pt3−O9 (M=Co, Ni, Cu, Zn, Mg, Pt)7Influence of rare earth cation size on the crystal structure in rare earth silicates, Na2RESiO4(OH) (RE = Sc, Yb) and NaRESiO4 (RE = La, Yb)22High-Temperature Salt Flux Crystal Growth of New Lanthanide Molybdenum Oxides, Ln5Mo2O12 Ln = Eu, Tb, Dy, Ho, and Er: Magnetic Coupling within Mixed Valent Mo(IV/V) Rutile-Like Chains22Synthesis, structure, and polymorphism of A3LnSi2O7 (A=Na, K; Ln=Sm, Ho, Yb)12La3Cu4P4O2 and La5Cu4P4O4Cl2: synthesis, structure and 31P solid state NMR spectroscopy12A series of inorganic–organic hybrid cadmium borates with novel Cd-centred [Cd@B 14 O 20 (OH) 6 ] 2− clusters27Ba 4 Ru 3 O 10.2 (OH) 1.8 : a new member of the layered hexagonal perovskite family crystallised from water14BaFe10.5Mn1.5O19 single crystal growth5Frequency-Doubling Oxide Fluorides, Borate Fluorides, and Fluorooxoborates9Growth of hollow-structured LiMn 2 O 4 crystals starting from Mn metal in molten KCl through the microscale Kirkendall effect10Intrinsic blue-white luminescence, luminescence color tunability, synthesis, structure, and polymorphism of K 3 YSi 2 O 734Palladium pnictide oxides Nd 10 Pd 3 As 8 O 10 and Sm 10 Pd 3 As 8 O 10 – low temperature structural phase transition and physical properties3Production of barium lead hexaferrite single crystals from the flux2Flux Growth of [NaK6F][(UO2)3(Si2O7)2] and [KK6Cl][(UO2)3(Si2O7)2]: The Effect of Surface Area to Volume Ratios on Reaction Products38New Lanthanide Mixed-Valent Vanadium(III/IV) Oxosilicates, Ln4V5–xZnxSi4O22 (Ln = La, Ce, Pr, and Nd), Crystallizing in a Quasi Two-Dimensional Rutile-Based Structure15On the Use of Dynamical Diffraction Theory To Refine Crystal Structure from Electron Diffraction Data: Application to KLa5O5(VO4)2, a Material with Promising Luminescent Properties21Going with the Flow: Continuous Flow Routes to Colloidal Nanoparticles33Growth Manner of Octahedral-Shaped Li(Ni1/3Co1/3Mn1/3)O2 Single Crystals in Molten Na2SO4100Design and Crystal Growth of Magnetic Double Perovskite Iridates: Ln2MIrO6 (Ln = La, Pr, Nd, Sm-Gd; M = Mg, Ni)62A5RE4X[TO4]4 crystal growth: Fluoride flux synthesis of Na5Ln4F[GeO4]4 (Ln=Pr, Nd), the first quaternary germanate oxyfluorides11Single crystal growth and characterization of NaxLn1−xMoO4, Ln=La, Ce, Pr, Nd, Sm, and Eu (x=0.397–0.499)9Understanding the Formation of Salt-Inclusion Phases: An Enhanced Flux Growth Method for the Targeted Synthesis of Salt-Inclusion Cesium Halide Uranyl Silicates61Oxygen Anion Solubility as a Factor in Molten Flux Crystal Growth, Synthesis, and Characterization of Four New Reduced Lanthanide Molybdenum Oxides: Ce4.918(3)Mo3O16, Pr4.880(3)Mo3O16, Nd4.910(3)Mo3O16, and Sm4.952(3)Mo3O1615Salt flux synthesis of single and bimetallic carbide nanowires6Cold Sintering: A Paradigm Shift for Processing and Integration of Ceramics514Cold Sintering: A Paradigm Shift for Processing and Integration of Ceramics132Progress in discovery and structural design of color conversion phosphors for LEDs1095Synthesis of a Ferrolite: A Zeolitic All‐Iron Framework10Synthesis of a Ferrolite: A Zeolitic All‐Iron Framework1The quaternary arsenide oxides Ce9Au5–x As8O6 and Pr9Au5–x As8O62Millimetre-wave isolator based on Al substituted Ba ferrite4High-Temperature Flux Growth as a Tool for the Preparation of Mixed-Framework Metal-Y Silicates: A Systematic Evaluation of the Influence of Experimental Parameters3Growth of idiomorphic LiMnPO 4 crystals in molten NaCl–KCl and LiF–NaCl–KCl fluxes12In situ identification of kinetic factors that expedite inorganic crystal formation and discovery38Choosing a Flux1Growth of well-developed LaOCl microplates by chloride salt-assisted method27Intrinsic Electrochemical Characteristics in the Individual Needle-like LiCoO2 Crystals Synthesized by Flux Growth13Introduction0Where Do New Materials Come From? Neither the Stork nor the Birds and the Bees! In Search of the Next “First Material”1Effects of Alkali Cations and Sulfate/Chloride Anions on the Flux Growth of {001}-Faceted β-Li2TiO3 Crystals17Flux versus Hydrothermal Growth: Polymorphism of A2(UO2)Si2O6 (A = Rb, Cs)19Discovery-Synthesis, Design, and Prediction of Chalcogenide Phases208BaFe4O7 and K0.22Ba0.89Fe4O7: Canted Antiferromagnetic Diferrites with Exceptionally High Magnetic Ordering Temperatures18A fresnoite-structure-related mixed valent titanium(III/IV) chlorosilicate, Ba3Ti2Si4O14Cl: A flux crystal growth route to Ti(III) containing oxides11Crystal structures and photoluminescence properties of two novel sorosilicates with an unprecedented ratio of di- and trisilicate groups: Ba 2 Ho 10 (Si 2 O 7 ) 3 (Si 3 O 10 ) 2 and isotypic Ba 2 Er 10 (Si 2 O 7 ) 3 (Si 3 O 10 ) 23Copper Vacancies and Heavy Holes in the Two-Dimensional Semiconductor KCu3–xSe214Flux growth in a horizontal configuration: An analog to vapor transport growth52High‐Temperature Methods1Reactive Fluxes0Investigation of Ba-Fe-O System near the BaFe12O195Observation of Intense X-ray Scintillation in a Family of Mixed Anion Silicates, Cs3RESi4O10F2 (RE = Y, Eu–Lu), Obtained via an Enhanced Flux Crystal Growth Technique59Prospective crystal-chemistry : relaxors, ferroics and low temperature SPS0Polarized R aman scattering on single crystals of rare earth orthochromite RCrO3 ( R = La , Pr , Nd , and Sm )24Synthesis and visible-light-induced sacrificial photocatalytic water oxidation of quinary oxynitride BaNb0.5Ta0.5O2N crystals19[M(1,2-dap)3][B10O13(OH)6] (M = Co, Ni): Two New Borates Containing [B10O13(OH)6]2− Cluster Units14Engaging the flux-grown La1−Sr Fe1−Ti O3 crystals in visible-light-driven photocatalytic hydrogen generation16Raman and Density Functional Theory Studies of Li2Mo4O13 Structures in Crystalline and Molten States10Complex tunnel structure of new La 6 (Mo 2 O 7 )(MoO 4 ) 8 : crystal growth from flux and high structural complexity5Prospect and Reality of Ni‐Rich Cathode for Commercialization920Growth of {100}-faceted NaFeTiO 4 crystals with a tunable aspect ratio from a NaCl–Na 2 SO 4 binary flux7Understanding the role of oxygen ion (O 2− ) activity in 1-D crystal growth of rutile TiO 2 in molten salts16Crystal growth and optimization of Pr:CaGdAlO 4 by the flux-Czochralski method14Binary flux-promoted formation of trigonal ZnIn 2 S 4 layered crystals using ZnS-containing industrial waste and their photocatalytic performance for H 2 production56Electric–elastic properties of a novel high-quality CdTeMoO 6 piezoelectric crystal12Research progress of single crystal growth for topological semimetals0The Electrochemistry of Metal Carbides: From Salt Melt Synthesis to Voltammetry of Microparticles0[Co(H2O)6]3[U2O4F7]2: A Model System for Understanding the Formation of Dimensionally Reduced Materials11In Situ Neutron Diffraction Studies of the Flux Crystal Growth of the Reduced Molybdates La 4 Mo 2 O 11 and Ce 4 Mo 2 O 11 : Revealing Unexpected Mixed-Valent Transient Intermediates and Determining the Sequence of Events during Crystal Growth19Undulated oxo-centered layers in PbLn3O4(VO4) (Ln= La and Nd) and relationship with Nd4O4(GeO4)1Observation of an Unusual Uranyl Cation–Cation Interaction in the Strongly Fluorescent Layered Uranyl Phosphates Rb6[(UO2)7O4(PO4)4] and Cs6[(UO2)7O4(PO4)4]26A Family of Layered Phosphates Crystallizing in a Rare Geometrical Isomer of the Phosphuranylite Topology: Synthesis, Characterization, and Computational Modeling of A4[(UO2)3O2(PO4)2] (A = Alkali Metal) Exhibiting Intralayer Ion Exchange21Na2(UO2)(BO3): An All-Uranium(V) Borate Synthesized under Mild Hydrothermal Conditions18Synergies and competition between current approaches to materials discovery4Toward Shape-Controlled Metal Oxynitride and Nitride Particles for Solar Energy Applications50Comparison of Uranium(VI) and Thorium(IV) Silicates Synthesized via Mixed Fluxes Techniques14

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  1. Soluble human leukocyte antigen-G (SHLA-G) in Tunisian kidney transplantation.

    PubMed · 2011-01-01

    R. Bardi, Imen Sfar, Hajer Aounallah Skhiri, C Kallala, E. Abderrahim, Taieb Ben Abdallah, Yosr Gorgi

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  2. Wolf Prize: A. P. Alivisatos and C. M. Lieber / F. A. Cotton Medal: R. G. Cooks / Southern Chemist Award: H.‐C. zur Loye

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  3. Wolf‐Preis: A. P. Alivisatos und C. M. Lieber / F. A. Cotton Medal: R. G. Cooks / Southern Chemist Award: H.‐C. zur Loye

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  4. Li3Al(MoO4)3, a lyonsite molybdate

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  5. ChemInform Abstract: Materials Discovery by Flux Crystal Growth: Quaternary and Higher Order Oxides

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  6. On the synthesis, characterization, and magnetization of Ln-M-X (Ln = lanthanide; M = Ti-Cr, Cu, Mo, Pd; X = Al, Ga) intermetallics

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  7. Preparation of Inorganic Photocatalytic Materials for Overall Water Splitting

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  8. Aerosol‐Assisted Molten Salt Synthesis of NaInS2 Nanoplates for Use as a New Photoanode Material

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  9. Single crystal growth and structural characterization of four complex uranium oxides: CaUO4, β-Ca3UO6, K4CaU3O12, and K4SrU3O12

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  10. Flux growth of Sr2Ta2O7 crystals and subsequent nitridation to form SrTaO2N crystals

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  11. Flux Growth and Magnetoresistance Behavior of Rare Earth Zintl Phase EuMgSn

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    Xiaowei Ma, Jun Lü, Jeffrey B. Whalen, Susan E. Latturner

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  12. Hydroflux Crystal Growth of Platinum Group Metal Hydroxides: Sr 6 NaPd 2 (OH) 17 , Li 2 Pt(OH) 6 , Na 2 Pt(OH) 6 , Sr 2 Pt(OH) 8 , and Ba 2 Pt(OH) 8

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  13. Synthesis and Crystal Structure of the New Samarium Oxyhydroxide, SmO(OH)

    Journal of Chemical Crystallography · 2013-04-17

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  14. Spatial and Temporal Confinement of Salt Fluxes for the Shape-Controlled Synthesis of Fe2O3 Nanocrystals

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  15. Coupled Nd and B′ spin ordering in the double perovskites Nd 2 Na B′ O 6 ( B′=Ru , Os)

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  16. Salt melt synthesis of ceramics, semiconductors and carbon nanostructures

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  17. Synthesis and Crystal Structure of a New Complex Uranium Oxide, Na4.5Nd0.5UO6

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  18. Crystal Growth of New Hexahydroxometallates Using a Hydroflux

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  19. Synthesis and Crystal Structure of Dibarium Tungstate Hydrate, Ba2WO5·H2O

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  20. Low-temperature growth of spinel-type Li 1+x Mn 2−x O 4 crystals using a LiCl–KCl flux and their performance as a positive active material in lithium-ion rechargeable batteries

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  21. Synthesis, structure, and optical properties of a series of quaternary oxides, K2Ba(MO4)2 (M = Cr, Mo, W)

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  22. Crystal growth, structural characterization, cation–cation interaction classification, and optical properties of uranium( vi ) containing oxychlorides, A 4 U 5 O 16 Cl 2 (A = K, Rb), Cs 5 U 7 O 22 Cl 3 , and AUO 3 Cl (A = Rb, Cs)

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  23. Platinum group metal oxides for heterogeneous catalysis: Novel synthesis and advanced characterization

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  24. Rapid Microwave Preparation and ab Initio Studies of the Stability of the Complex Noble Metal Oxides La 2 BaPdO 5 and La 2 BaPtO 5

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  25. Single-Crystal Growth and Size Control of Three Novel Polar Intermetallics: Eu2.94(2)Ca6.06In8Ge8, Eu3.13(2)Ca5.87In8Ge8, and Sr3.23(3)Ca5.77In8Ge8 with Crystal Structure, Chemical Bonding, and Magnetism Studies

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  26. Ca54In13B4–xH23+x: A Complex Metal Subhydride Featuring Ionic and Metallic Regions

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  27. Crystal Growth and Structure Determination of the New Neodymium Germanate, Na2NdGeO4(OH)

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  28. Crystal growth, structures, magnetic and photoluminescent properties of NaLnGeO4 (Ln = Sm, Eu, Gd, Tb)

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  29. Crystal Growth and Structure Determination of the New Neodymium Germanate, Na5Nd4Ge4O16(OH)

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  30. Growth, structural and magnetic characterization of Al-substituted barium hexaferrite single crystals

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  31. Single crystal growth and structural characterization of ternary transition-metal uranium oxides: MnUO4, FeUO4, and NiU2O6

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  32. Ti-Substituted BaFe12O19 Single Crystal Growth and Characterization

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  33. Single Crystal Growth and Structural Characterization of a Novel Mixed-Valent Ternary Uranium Oxide, K8U7O24

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    Cory Michael Read, Mark D. Smith, Hans‐Conrad zur Loye

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  34. Simple correction for the sample shape and radial offset effects on SQUID magnetometers: Magnetic measurements on Ln2O3 (Ln=Gd, Dy, Er) standards

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  35. Photoluminescent and Magnetic Properties of Lanthanide Containing Apatites: NaxLn10–x(SiO4)6O2–yFy, CaxLn10–x(SiO4)6O2–yFy (Ln = Eu, Gd, and Sm), Gd9.34(SiO4)6O2, and K1.32Pr8.68(SiO4)6O1.36F0.64

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  36. Synthesis and Crystal Structure of Sodium Arsenate Oxyhydroxide: Na4(AsO4)OH

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