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RESEARCH PAPER · The Journal of Physical Chemistry C · 2010

Genesis and Evolution of Surface Species during Pt Atomic Layer Deposition on Oxide Supports Characterized by in Situ XAFS Analysis and Water−Gas Shift Reaction

Worajit Setthapun, W. Damion Williams, Seung Min Kim, Hao Feng, Jeffrey W. Elam, Federico A. Rabuffetti, Kenneth Reinhard Poeppelmeier, Peter Curran Stair, Eric A. Stach, Fabio H. Ribeiro, Jeffrey T. Miller, Christopher L. Marshall

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Genesis and Evolution of Surface Species during Pt Atomic Layer Deposition on Oxide Supports Characterized by in Situ XAFS Analysis and Water−Gas Shift ReactionOriginalA Chemical Approach to Understanding Oxide Surface Structure and Reactivity4Supported Ru−Pt Bimetallic Nanoparticle Catalysts Prepared by Atomic Layer Deposition219Oriented Catalytic Platinum Nanoparticles on High Surface Area Strontium Titanate Nanocuboids121Atomic Layer Deposition of Pt on Tungsten Monocarbide (WC) for the Oxygen Reduction Reaction100Reaction mechanism studies for platinum nanoparticle growth by atomic layer deposition45Structure, Chemical Composition, And Reactivity Correlations during the In Situ Oxidation of 2-Propanol48Nucleation and growth of Pt atomic layer deposition on Al2O3 substrates using (methylcyclopentadienyl)-trimethyl platinum and O2 plasma111Subnanometer Palladium Particles Synthesized by Atomic Layer Deposition102Propane Oxidation over Pt/SrTiO3 Nanocuboids166Evolution of the Structure and Chemical State of Pd Nanoparticles during the in Situ Catalytic Reduction of NO with H 2118Nature of Ptn/TiO2(110) Interface under Water-Gas Shift Reaction Conditions: A Constrained ab Initio Thermodynamics Study52Atomic Layer Deposition for Nanotechnology20Design Strategies for the Molecular Level Synthesis of Supported Catalysts264Atomic layer deposition synthesis of platinum–tungsten carbide core–shell catalysts for the hydrogen evolution reaction123In situ coarsening study of inverse micelle-prepared Pt nanoparticles supported on γ-Al2O3: pretreatment and environmental effects70Mass Spectrometry Study of the Temperature Dependence of Pt Film Growth by Atomic Layer Deposition36Atomic Layer Deposition of Noble Metals – New Developments in Nanostructured Catalysts10Aligned carbon nanotube array functionalization for enhanced atomic layer deposition of platinum electrocatalysts60Nature of Ptn/CeO2(111) Surface under Water–Gas Shift Reaction Conditions: A Constrained ab Initio Thermodynamics Study36Catalytic Combustion and Dehydrogenation Reactions during Atomic Layer Deposition of Platinum128Scalable synthesis of palladium nanoparticle catalysts by atomic layer deposition51Synthesis of Pt–Pd Core–Shell Nanostructures by Atomic Layer Deposition: Application in Propane Oxidative Dehydrogenation to Propylene111Nanostructured materials for applications in heterogeneous catalysis662In SituStudies on Reaction Mechanisms in Atomic Layer Deposition113Crystallinity of inorganic films grown by atomic layer deposition: Overview and general trends1416Influence of Oxygen Exposure on the Nucleation of Platinum Atomic Layer Deposition: Consequences for Film Growth, Nanopatterning, and Nanoparticle Synthesis147Synthesis of supported Ni catalysts by atomic layer deposition79Resolving Precursor Deligation, Surface Species Evolution, and Nanoparticle Nucleation during Palladium Atomic Layer Deposition31Epitaxial Stabilization of Face Selective Catalysts24Atomic Layer Deposition of Noble Metals and Their Oxides361Pt@Nb-TiO2 Catalyst Membranes Fabricated by Electrospinning and Atomic Layer Deposition93Atomic Layer Deposition of Metals and Metal Oxides for Fuel Cell Applications0Atomic layer deposition of platinum with enhanced nucleation and coalescence by trimethylaluminum pre-pulsing20In situ synchrotron based x-ray techniques as monitoring tools for atomic layer deposition42Scalable Production of Nanostructured Particles using Atomic Layer Deposition36Toward highly efficient photocatalysis: a flow-through Pt@TiO2@AAO membrane nanoreactor prepared by atomic layer deposition46In situ XAS and XRF study of nanoparticle nucleation during O3-based Pt deposition35Propylene Hydrogenation and Propane Dehydrogenation by a Single-Site Zn 2+ on Silica Catalyst290Atomic Layer Deposition of Platinum Nanoparticles on Titanium Oxide and Tungsten Oxide Using Platinum(II) Hexafluoroacetylacetonate and Formalin as the Reactants35Adsorbate-Induced Structural Changes in 1–3 nm Platinum Nanoparticles89Plasma‐Assisted Atomic Layer Deposition of PtOx from (MeCp)PtMe3 and O2 Plasma16Selective metal deposition at graphene line defects by atomic layer deposition306Atomic layer deposition synthesis and evaluation of core–shell Pt-WC electrocatalysts9Atomic layer deposition of ultrathin platinum films on tungsten atomic layer deposition adhesion layers: Application to high surface area substrates47Enhanced dry reforming of methane on Ni and Ni-Pt catalysts synthesized by atomic layer deposition113Fabrication and Cell Analysis of a Pt/SiO2Platinum Thin Film Electrode27Fischer-Tropsch Synthesis on ALD-synthesized Catalysts0Systematic increase of electrocatalytic turnover at nanoporous platinum surfaces prepared by atomic layer deposition24Controlling Nanoscale Properties of Supported Platinum Catalysts through Atomic Layer Deposition74Catalyst Design with Atomic Layer Deposition785Mechanistic studies for depositing highly dispersed Pt nanoparticles on carbon by use of trimethyl(methylcyclopentadienyl)platinum(IV) reactions with O2 and H238A low-temperature synthesis of electrochemical active Pt nanoparticles and thin films by atomic layer deposition on Si(111) and glassy carbon surfaces11Sodium-promoted iron catalysts prepared on different supports for high temperature Fischer–Tropsch synthesis94Recent Developments in the Synthesis of Supported Catalysts1537Identification of active sites in CO oxidation and water-gas shift over supported Pt catalysts1286Atomic layer deposition of Pd and Pt nanoparticles for catalysis: on the mechanisms of nanoparticle formation119Continuous and ultrathin platinum films on graphene using atomic layer deposition: a combined computational and experimental study50Electrocatalysts by atomic layer deposition for fuel cell applications102Atomic layer deposition—Sequential self-limiting surface reactions for advanced catalyst “bottom-up” synthesis324Virtual Special Issue on Catalysis at the U.S. Department of Energy’s National Laboratories2Highly dispersed Pt nanoparticles supported on carbon nanotubes produced by atomic layer deposition for hydrogen generation from hydrolysis of ammonia borane131Mobile setup for synchrotron based in situ characterization during thermal and plasma-enhanced atomic layer deposition25Plasma enhanced atomic layer deposited platinum thin film on Si substrate with TMA pretreatment12New Pt/Alumina model catalysts for STM and in situ XPS studies29Controllable decoration of palladium sub-nanoclusters on reduced graphene oxide with superior catalytic performance in selective oxidation of alcohols17Controllable deposition of Pt nanoparticles into a KL zeolite by atomic layer deposition for highly efficient reforming of n-heptane to aromatics61Influence of copper and potassium on the structure and carbidisation of supported iron catalysts for Fischer–Tropsch synthesis73Active Site and Electronic Structure Elucidation of Pt Nanoparticles Supported on Phase-Pure Molybdenum Carbide Nanotubes23Basics of Atomic Layer Deposition: Growth Characteristics and Conformality22Nucleation and growth process of atomic layer deposition platinum nanoparticles on strontium titanate nanocuboids18Bridging Zirconia Nodes within a Metal–Organic Framework via Catalytic Ni-Hydroxo Clusters to Form Heterobimetallic Nanowires93Controllable ALD synthesis of platinum nanoparticles by tuning different synthesis parameters16In situ conductance monitoring of Pt thin film growth by area-selective atomic layer deposition5Single atom catalyst by atomic layer deposition technique103Efficient Catalytic Microreactors with Atomic‐Layer‐Deposited Platinum Nanoparticles on Oxide Support11Mechanism of the Mn Promoter via CoMn Spinel for Morphology Control: Formation of Co2C Nanoprisms for Fischer–Tropsch to Olefins Reaction101Bottom-up precise synthesis of stable platinum dimers on graphene636Independent tuning of size and coverage of supported Pt nanoparticles using atomic layer deposition118Structure Sensitivity of Acrolein Hydrogenation by Platinum Nanoparticles on BaxSr1−xTiO3 Nanocuboids9Electron-driven and thermal chemistry during water-assisted purification of platinum nanomaterials generated by electron beam induced deposition29Morphology and CO Oxidation Activity of Pd Nanoparticles on SrTiO3 Nanopolyhedra46Replication of SMSI via ALD: TiO2 Overcoats Increase Pt-Catalyzed Acrolein Hydrogenation Selectivity20Extending the limits of Pt/C catalysts with passivation-gas-incorporated atomic layer deposition82Extended Thin-Film Electrocatalyst Structures via Pt Atomic Layer Deposition7Combining nanoparticles grown by ALD and MOFs for gas separation and catalysis applications14Mechanistic Study of Nucleation Enhancement in Atomic Layer Deposition by Pre-Treatment with Small Organometallic Molecules1Atomic Layer Deposition of Pt Thin Films Using Dimethyl (N,N-Dimethyl-3-Butene-1-Amine-N) Platinum and O2 Reactant34Surface and subsurface film growth of titanium dioxide on polydimethylsiloxane by atomic layer deposition18Single-Atom Catalysts: From Design to Application638Drying Techniques Affecting Structure‐Reactivity of Pt/Cr‐Ta : SrTiO3 Catalysts in Visible Light‐Irradiated Water Splitting Reaction5Mechanistic Study of Nucleation Enhancement in Atomic Layer Deposition by Pretreatment with Small Organometallic Molecules51Application of atomic layer deposition in fabricating high-efficiency electrocatalysts40Atomic-scale engineering of metal–oxide interfaces for advanced catalysis using atomic layer deposition48Catalysts via Atomic Layer Deposition3Creation of gallium acid and platinum metal sites in bifunctional zeolite hydroisomerization and hydrocracking catalysts by atomic layer deposition18Mechanistic studies of atomic layer deposition on oxidation catalysts – AlO x and PO x deposition14Nanostructured materials for energy conversion and storage0Reforming of methane with carbon dioxide over cerium oxide promoted nickel nanoparticles deposited on 4-channel hollow fibers by atomic layer deposition35Surface mobility and impact of precursor dosing during atomic layer deposition of platinum: in situ monitoring of nucleation and island growth29Understanding chemical and physical mechanisms in atomic layer deposition286Highly Durable and Active Pt/Sb-Doped SnO2 Oxygen Reduction Reaction Electrocatalysts Produced by Atomic Layer Deposition48Oxygen reduction reaction on nanostructured Pt-based electrocatalysts: A review197Interface Engineering for High‐Performance Photoelectrochemical Cells via Atomic Layer Deposition Technique11Controllable size and crystallinity of Ru nanoparticles on a carbon support synthesized by fluidized bed reactor-atomic layer deposition for enhanced hydrogen oxidation activity34Current Status on the Manufacturing of Nanomaterials for Proton Exchange Membrane Energy Systems by Vapor-Based Processes18Metal–Support Interactions and C1 Chemistry: Transforming Pt-CeO 2 into a Highly Active and Stable Catalyst for the Conversion of Carbon Dioxide and Methane94Resolving the Evolution of Atomic Layer-Deposited Thin-Film Growth by Continuous In Situ X-Ray Absorption Spectroscopy17Thermal Interface Enhancement via Inclusion of an Adhesive Layer Using Plasma-Enhanced Atomic Layer Deposition10Molecular approaches to heterogeneous catalysis59Ambient pressure x-ray photoelectron spectroscopy setup for synchrotron-based in situ and operando atomic layer deposition research23Single-electron transport in focused electron beam induced deposition (FEBID)-based nanostructures0Reversible dehydrogenation and rehydrogenation of cyclohexane and methylcyclohexane by single-site platinum catalyst182Designing Sites in Heterogeneous Catalysis: Are We Reaching Selectivities Competitive With Those of Homogeneous Catalysts?431Fabrication of DNA-Templated Pt Nanostructures by Area-Selective Atomic Layer Deposition8Subnanometric Pt‐Sn Monolayers Over a Rod‐Shaped Al2O3 for Propane Dehydrogenation15Effect of Nitrogen Doping and Oxidation of Graphene on the Deposition of Platinum from Trimethyl(methylcyclopentadienyl)platinum(IV)1Conformal Three-Dimensional Platinum Coating Using Rotary-Type Atomic Layer Deposition for a Diesel Oxidation Catalyst Application5Synthesis of platinum nanoparticles on strontium titanate nanocuboids via surface organometallic grafting for the catalytic hydrogenolysis of plastic waste46Dimension Control of Platinum Nanostructures by Atomic Layer Deposition: From Surface Chemical Reactions to Applications18Atomic layer deposition of thin films: from a chemistry perspective85Treasuring trash: Pt/SrTiO3 catalysts process plastic waste into high-value materials25Atomic layer deposition of piezoelectric materials: a timely review17In vacuo studies on reaction mechanisms in ALD processes of ruthenium and platinum films14Atomic layer deposition of Pt nanoparticles using dimethyl (N, N–dimethyl-3-butene-1-amine−N) platinum and H2 reactant and its application to 2D WS2 photodetectors3Organic Synthesis Catalyzed by Metal Nanoparticles0Role of the Oxidizing Co-Reactant in Pt Growth by Atomic Layer Deposition Using MeCpPtMe3 and O2/O3/O2-Plasma8Recent Advances in Carbon Nitride Supported Single‐Atom Catalysts: Synthesis, Characterization, and Applications for CO2 Photoreduction13Ultrasmall and Highly Dispersed Pt Entities Deposited on Mesoporous N‐doped Carbon Nanospheres by Pulsed CVD for Improved HER37In Vacuo XPS Study on Pt Growth by Atomic Layer Deposition Using MeCpPtMe3 and N2/NH3 Plasma2Ambient pressure x-ray photoelectron spectroscopy study on the initial atomic layer deposition process of platinum3Substance migration in the synthesis of single-atom catalysts14Spontaneous Reactions by Atomic Hydrogen – An Extraordinary Reactant for Atomic Layer Deposition of Platinum2Atomic Layer Deposition on Spray-Dried Supraparticles to Rationally Design Catalysts with Ultralow Noble Metal Loadings2Enhancing Direct Solar Water Splitting via ALD of Multifunctional TiO 2 /Pt Nanoparticle Coatings With Engineered Interfaces to GaAs/GaInP Tandem Cells8Highly Reactive Atomic Hydrogen as an Alternative Reactant for Atomic Layer Deposition of Platinum Using MeCpPtMe30Precise construction of multicomponent catalysts by atomic layer deposition0Atomic Layer Deposition on Particulate Materials from 1988 through 2023: A Quantitative Review of Technologies, Materials, and Applications19Surface engineering and functionalization of powder-based materials by fluidized-bed atomic layer deposition for emerging applications7

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  1. A Chemical Approach to Understanding Oxide Surface Structure and Reactivity

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  2. Supported Ru−Pt Bimetallic Nanoparticle Catalysts Prepared by Atomic Layer Deposition

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  3. Oriented Catalytic Platinum Nanoparticles on High Surface Area Strontium Titanate Nanocuboids

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  4. Atomic Layer Deposition of Pt on Tungsten Monocarbide (WC) for the Oxygen Reduction Reaction

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  5. Reaction mechanism studies for platinum nanoparticle growth by atomic layer deposition

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  6. Structure, Chemical Composition, And Reactivity Correlations during the In Situ Oxidation of 2-Propanol

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  7. Nucleation and growth of Pt atomic layer deposition on Al2O3 substrates using (methylcyclopentadienyl)-trimethyl platinum and O2 plasma

    Journal of Applied Physics · 2011-04-15

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  8. Subnanometer Palladium Particles Synthesized by Atomic Layer Deposition

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  9. Propane Oxidation over Pt/SrTiO3 Nanocuboids

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  10. Evolution of the Structure and Chemical State of Pd Nanoparticles during the in Situ Catalytic Reduction of NO with H 2

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  11. Nature of Ptn/TiO2(110) Interface under Water-Gas Shift Reaction Conditions: A Constrained ab Initio Thermodynamics Study

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  12. Atomic Layer Deposition for Nanotechnology

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  13. Design Strategies for the Molecular Level Synthesis of Supported Catalysts

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  14. Atomic layer deposition synthesis of platinum–tungsten carbide core–shell catalysts for the hydrogen evolution reaction

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  15. In situ coarsening study of inverse micelle-prepared Pt nanoparticles supported on γ-Al2O3: pretreatment and environmental effects

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  16. Mass Spectrometry Study of the Temperature Dependence of Pt Film Growth by Atomic Layer Deposition

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  17. Atomic Layer Deposition of Noble Metals – New Developments in Nanostructured Catalysts

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  18. Aligned carbon nanotube array functionalization for enhanced atomic layer deposition of platinum electrocatalysts

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  19. Nature of Ptn/CeO2(111) Surface under Water–Gas Shift Reaction Conditions: A Constrained ab Initio Thermodynamics Study

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  20. Catalytic Combustion and Dehydrogenation Reactions during Atomic Layer Deposition of Platinum

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  22. Synthesis of Pt–Pd Core–Shell Nanostructures by Atomic Layer Deposition: Application in Propane Oxidative Dehydrogenation to Propylene

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  24. In SituStudies on Reaction Mechanisms in Atomic Layer Deposition

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  26. Influence of Oxygen Exposure on the Nucleation of Platinum Atomic Layer Deposition: Consequences for Film Growth, Nanopatterning, and Nanoparticle Synthesis

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  35. Scalable Production of Nanostructured Particles using Atomic Layer Deposition

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  36. Toward highly efficient photocatalysis: a flow-through Pt@TiO2@AAO membrane nanoreactor prepared by atomic layer deposition

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  37. In situ XAS and XRF study of nanoparticle nucleation during O3-based Pt deposition

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  38. Propylene Hydrogenation and Propane Dehydrogenation by a Single-Site Zn 2+ on Silica Catalyst

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  39. Atomic Layer Deposition of Platinum Nanoparticles on Titanium Oxide and Tungsten Oxide Using Platinum(II) Hexafluoroacetylacetonate and Formalin as the Reactants

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  40. Adsorbate-Induced Structural Changes in 1–3 nm Platinum Nanoparticles

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  41. Plasma‐Assisted Atomic Layer Deposition of PtOx from (MeCp)PtMe3 and O2 Plasma

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  42. Selective metal deposition at graphene line defects by atomic layer deposition

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  43. Atomic layer deposition synthesis and evaluation of core–shell Pt-WC electrocatalysts

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  44. Atomic layer deposition of ultrathin platinum films on tungsten atomic layer deposition adhesion layers: Application to high surface area substrates

    Journal of Vacuum Science & Technology A Vacuum Surfaces and Films · 2014-12-01

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  45. Enhanced dry reforming of methane on Ni and Ni-Pt catalysts synthesized by atomic layer deposition

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  46. Fabrication and Cell Analysis of a Pt/SiO2Platinum Thin Film Electrode

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  47. Fischer-Tropsch Synthesis on ALD-synthesized Catalysts

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  48. Systematic increase of electrocatalytic turnover at nanoporous platinum surfaces prepared by atomic layer deposition

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  49. Controlling Nanoscale Properties of Supported Platinum Catalysts through Atomic Layer Deposition

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  50. Catalyst Design with Atomic Layer Deposition

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    Brandon J. O’Neill, David H. K. Jackson, Jechan Lee, Christian P. Canlas, Peter Curran Stair, Christopher L. Marshall, Jeffrey W. Elam, T. F. Kuech, James A. Dumesic, George W. Huber

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