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RESEARCH PAPER · ACS Catalysis · 2015

Catalyst Design with Atomic Layer Deposition

Brandon J. O’Neill, David H. K. Jackson, Jechan Lee, Christian P. Canlas, Peter Curran Stair, Christopher L. Marshall, Jeffrey W. Elam, T. F. Kuech, James A. Dumesic, George W. Huber

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Catalyst Design with Atomic Layer DepositionOriginalMultiply Confined Nickel Nanocatalysts Produced by Atomic Layer Deposition for Hydrogenation Reactions118Recent Advances on the Design of Group VIII Base-Metal Catalysts with Encapsulated Structures177Stabilizing cobalt catalysts for aqueous-phase reactions by strong metal-support interaction143Improved Thermal Stability and Methane-Oxidation Activity of Pd/Al 2 O 3 Catalysts by Atomic Layer Deposition of ZrO 2145Atomic layer stack deposition-annealing synthesis of CuWO 479Molecular Chromophore–Catalyst Assemblies for Solar Fuel Applications483Ni nanoparticles supported on CNTs with excellent activity produced by atomic layer deposition for hydrogen generation from the hydrolysis of ammonia borane106ZnO modified ZSM-5 and Y zeolites fabricated by atomic layer deposition for propane conversion134Atomic layer deposition of Pd and Pt nanoparticles for catalysis: on the mechanisms of nanoparticle formation118Towards ALD thin film stabilized single-atom Pd 1 catalysts124Atomic Layer Deposited (ALD) TiO2 on Fibrous Nano-Silica (KCC-1) for Photocatalysis: Nanoparticle Formation and Size Quantization Effect180Atomic layer deposition—Sequential self-limiting surface reactions for advanced catalyst “bottom-up” synthesis322A Tandem Catalyst with Multiple Metal Oxide Interfaces Produced by Atomic Layer Deposition107Nanoengineering Energy Conversion and Storage Devices via Atomic Layer Deposition83Catalytic Reforming of Oxygenates: State of the Art and Future Prospects349Tailoring Pt–Fe2O3 Interfaces for Selective Reductive Coupling Reaction To Synthesize Imine77The effect of sulfur dioxide on the activity of hierarchical Pd-based catalysts in methane combustion102Finding the Way to Solar Fuels with Dye-Sensitized Photoelectrosynthesis Cells369Heterogeneously Catalyzed Hydrothermal Processing of C5–C6 Sugars340Atomic and molecular layer deposition: off the beaten track238Catalysis by Supported Single Metal Atoms1326Single-site zinc on silica catalysts for propylene hydrogenation and propane dehydrogenation: Synthesis and reactivity evaluation using an integrated atomic layer deposition-catalysis instrument109Porous TiO2 Nanotubes with Spatially Separated Platinum and CoOx Cocatalysts Produced by Atomic Layer Deposition for Photocatalytic Hydrogen Production354An overview of molecular layer deposition for organic and organic–inorganic hybrid materials: mechanisms, growth characteristics, and promising applications260Atomic layer deposition for nanomaterial synthesis and functionalization in energy technology170Atomic-layer-deposited ultrathin Co 9 S 8 on carbon nanotubes: an efficient bifunctional electrocatalyst for oxygen evolution/reduction reactions and rechargeable Zn–air batteries112Atomic-scale surface modifications and novel electrode designs for high-performance sodium-ion batteries via atomic layer deposition77Grand challenges for catalysis in the Science and Technology Roadmap on Catalysis for Europe: moving ahead for a sustainable future104Oxide‐Nanotrap‐Anchored Platinum Nanoparticles with High Activity and Sintering Resistance by Area‐Selective Atomic Layer Deposition97Understanding and Controlling the Aggregative Growth of Platinum Nanoparticles in Atomic Layer Deposition: An Avenue to Size Selection135Nanoengineering Heterogeneous Catalysts by Atomic Layer Deposition103Biochar as a Catalyst668Single‐Atom Electrocatalysts1345Einzelatom‐Elektrokatalysatoren105Solar conversion of CO2 to CO using Earth-abundant electrocatalysts prepared by atomic layer modification of CuO542Highly Stable Porous-Carbon-Coated Ni Catalysts for the Reductive Amination of Levulinic Acid via an Unconventional Pathway106Rh-MnO Interface Sites Formed by Atomic Layer Deposition Promote Syngas Conversion to Higher Oxygenates91Design and Properties of Confined Nanocatalysts by Atomic Layer Deposition169Porous TiO2/Pt/TiO2 Sandwich Catalyst for Highly Selective Semihydrogenation of Alkyne to Olefin98Multishelled CaO Microspheres Stabilized by Atomic Layer Deposition of Al2O3 for Enhanced CO2 Capture Performance221Single atom catalyst by atomic layer deposition technique104Mechanistic Understanding and the Rational Design of Sinter-Resistant Heterogeneous Catalysts318Bottom-up precise synthesis of stable platinum dimers on graphene633Independent tuning of size and coverage of supported Pt nanoparticles using atomic layer deposition117Recent advances and future prospect in catalysts for oxidative coupling of methane to ethylene: A review247Review Article: Catalysts design and synthesis via selective atomic layer deposition129Area-Selective Atomic Layer Deposition of Metal Oxides on Noble Metals through Catalytic Oxygen Activation118Atomic layer deposition of nickel carbide for supercapacitors and electrocatalytic hydrogen evolution110Single-atom catalysts and their applications in organic chemistry224Atomic layer deposition of Pt nanoparticles on low surface area zirconium oxide for the efficient base-free oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid72Atomic Layer Deposition on Porous Materials: Problems with Conventional Approaches to Catalyst and Fuel Cell Electrode Preparation111Catalytic Oxidation of Methane: Pd and Beyond149Nano‐Sized Inorganic Energy‐Materials by the Low‐Temperature Molecular Precursor Approach82From Single Atoms to Nanoparticles: Autocatalysis and Metal Aggregation in Atomic Layer Deposition of Pt on TiO2 Nanopowder75Recent advances in the precise control of isolated single-site catalysts by chemical methods325Bridging homogeneous and heterogeneous catalysis by heterogeneous single-metal-site catalysts1118Catalyst design using an inverse strategy: From mechanistic studies on inverted model catalysts to applications of oxide-coated metal nanoparticles101Advanced Chemical Looping Materials for CO2 Utilization: A Review146Extending the limits of Pt/C catalysts with passivation-gas-incorporated atomic layer deposition81Subnanometer Substructures in Nanoassemblies Formed from Clusters under a Reactive Atmosphere Revealed Using Machine Learning92Atomic layer deposition for biosensing applications119Interface Tailoring of Heterogeneous Catalysts by Atomic Layer Deposition172Atomic Layer Deposition for Membranes: Basics, Challenges, and Opportunities203Titanate-based perovskites for photochemical and photoelectrochemical water splitting applications: A review114Recently developed methods to enhance stability of heterogeneous catalysts for conversion of biomass-derived feedstocks115Synthesis of Doped, Ternary, and Quaternary Materials by Atomic Layer Deposition: A Review280Fundamental catalytic challenges to design improved biomass conversion technologies100From the Bottom-Up: Toward Area-Selective Atomic Layer Deposition with High Selectivity424Atomically dispersed iron hydroxide anchored on Pt for preferential oxidation of CO in H2641Highly efficient hydrogen sensors based on Pd nanoparticles supported on boron nitride coated ZnO nanowires139Particle atomic layer deposition125Recent advances in hydrodeoxygenation of biomass-derived oxygenates over heterogeneous catalysts535Review—On Atomic Layer Deposition: Current Progress and Future Challenges78Bio-Based Chemicals from Renewable Biomass for Integrated Biorefineries357Single Metal Atom Photocatalysis190Opportunities for Atomic Layer Deposition in Emerging Energy Technologies111Conformality in atomic layer deposition: Current status overview of analysis and modelling508Sandwiched SiO2@Ni@ZrO2 as a coke resistant nanocatalyst for dry reforming of methane148New development of atomic layer deposition: processes, methods and applications536Remarkable improvement in low temperature performance of model three-way catalysts through solution atomic layer deposition97Supported Noble‐Metal Single Atoms for Heterogeneous Catalysis371New Strategies for the Preparation of Sinter‐Resistant Metal‐Nanoparticle‐Based Catalysts384Review Article: Atomic layer deposition of doped ZnO films89Single-Atom Catalysts: From Design to Application633Origin of synergistic effects in bicomponent cobalt oxide-platinum catalysts for selective hydrogenation reaction211Surface and Interface Control in Nanoparticle Catalysis864Atomic layer deposition on particulate materials70Propane Dehydrogenation over Pt Clusters Localized at the Sn Single-Site in Zeolite Framework239Advances in design strategies for preparation of biochar based catalytic system for production of high value chemicals84Applications of atomic layer deposition and chemical vapor deposition for perovskite solar cells198Single-Atom Catalysts for Electrochemical Hydrogen Evolution Reaction: Recent Advances and Future Perspectives289Single‐Atom Catalysts in Catalytic Biomedicine368Understanding chemical and physical mechanisms in atomic layer deposition283Heterogeneous Single Atom Electrocatalysis, Where “Singles” Are “Married”158Inherently Selective Atomic Layer Deposition and Applications121Photocatalytic degradation of organic dye via atomic layer deposited TiO2 on ceramic membranes in single-pass flow-through operation105Single‐Atom Catalytic Materials for Advanced Battery Systems223Energy performance of Power-to-Liquid applications integrating biogas upgrading, reverse water gas shift, solid oxide electrolysis and Fischer-Tropsch technologies98Area-Selective Atomic Layer Deposition of Two-Dimensional WS2 Nanolayers86Atomic layer deposition of solid-state electrolytes for next-generation lithium-ion batteries and beyond: Opportunities and challenges85Encapsulation Methods for Control of Catalyst Deactivation: A Review202Synthesis of highly dispersed Pt nanoparticles into carbon supports by fluidized bed reactor atomic layer deposition to boost PEMFC performance136Recent Progress in Single‐Atom Catalysts for Photocatalytic Water Splitting84Intrinsically Active Surface in a Pt/γ-Mo 2 N Catalyst for the Water–Gas Shift Reaction: Molybdenum Nitride or Molybdenum Oxide?110Strategic Atomic Layer Deposition and Electrospinning of Cobalt Sulfide/Nitride Composite as Efficient Bifunctional Electrocatalysts for Overall Water Splitting76Distance Effect of Ni-Pt Dual Sites for Active Hydrogen Transfer in Tandem Reaction74Enhanced visible light photocatalytic activity of Fe2O3 modified TiO2 prepared by atomic layer deposition128Single-metal-atom catalysts: An emerging platform for electrocatalytic oxygen reduction92Recent Advances in Graphitic Carbon Nitride Supported Single‐Atom Catalysts for Energy Conversion79Advanced Electrocatalysts with Single-Metal-Atom Active Sites1004Design of PtZn nanoalloy catalysts for propane dehydrogenation through interface tailoring via atomic layer deposition71Surface modification and functionalization of powder materials by atomic layer deposition: a review73Electrochemical Activation of Atomic Layer-Deposited Cobalt Phosphate Electrocatalysts for Water Oxidation98A CoN‐based OER Electrocatalyst Capable in Neutral Medium: Atomic Layer Deposition as Rational Strategy for Fabrication92Deciphering Metal–Oxide and Metal–Metal Interplay via Surface Organometallic Chemistry: A Case Study with CO 2 Hydrogenation to Methanol99Gas sensing materials roadmap85Single-Atom Catalysts Designed and Prepared by the Atomic Layer Deposition Technique344Stable Palladium Oxide Clusters Encapsulated in Silicalite-1 for Complete Methane Oxidation81CO2-mediated oxidative dehydrogenation of light alkanes to olefins: Advances and perspectives in catalyst design and process improvement107Theoretical Inspection of M1/PMA Single-Atom Electrocatalyst: Ultra-High Performance for Water Splitting (HER/OER) and Oxygen Reduction Reactions (OER)209Chemical recycling of plastic waste via thermocatalytic routes157Water treatment based on atomically engineered materials: Atomic layer deposition and beyond104Toward low-cost biological and hybrid biological/catalytic conversion of cellulosic biomass to fuels265Unravelling the synergy in platinum-nickel bimetal catalysts designed by atomic layer deposition for efficient hydrolytic dehydrogenation of ammonia borane106Atomic Lego Catalysts Synthesized by Atomic Layer Deposition72Designing Sites in Heterogeneous Catalysis: Are We Reaching Selectivities Competitive With Those of Homogeneous Catalysts?424In Situ Spectroscopic Characterization and Theoretical Calculations Identify Partially Reduced ZnO 1− x /Cu Interfaces for Methanol Synthesis from CO 2127Heterolytic Dissociation of H 2 in Heterogeneous Catalysis326Atomic/Molecular Layer Deposition for Designer's Functional Metal–Organic Materials84Atomic layer deposition for membrane modification, functionalization and preparation: A review95An Ultrahigh Rate and Stable Zinc Anode by Facet‐Matching‐Induced Dendrite Regulation162Advanced Strategies for Stabilizing Single-Atom Catalysts for Energy Storage and Conversion191Surface and Interface Coordination Chemistry Learned from Model Heterogeneous Metal Nanocatalysts: From Atomically Dispersed Catalysts to Atomically Precise Clusters278Recent advances in interface engineering of Fe/Co/Ni-based heterostructure electrocatalysts for water splitting110Single‐atom catalysts for electrochemical N 2 reduction to NH 397Mechanism of the application of single-atom catalyst-activated PMS/PDS to the degradation of organic pollutants in water environment: A review224Atomic-level reactive sites for electrocatalytic nitrogen reduction to ammonia under ambient conditions80Transition Metal Single‐Atom Catalysts for the Electrocatalytic Nitrate Reduction: Mechanism, Synthesis, Characterization, Application, and Prospects92Emerging Atomic Layer Deposition for the Development of High-Performance Lithium-Ion Batteries147Atomic Layer Deposition—A Versatile Toolbox for Designing/Engineering Electrodes for Advanced Supercapacitors82A Comprehensive Review on Modification of Titanium Dioxide‐Based Catalysts in Advanced Oxidation Processes for Water Treatment86Artificial CO 2 photoreduction: a review of photocatalyst design and product selectivity regulation85Structured Catalysts and Catalytic Processes: Transport and Reaction Perspectives140Well-defined diatomic catalysis for photosynthesis of C2H4 from CO2144Atom-by-atom design of Cu/ZrOx clusters on MgO for CO2 hydrogenation using liquid-phase atomic layer deposition72Safety Landscape of Therapeutic Nanozymes and Future Research Directions96Recent Advances in Single‐Atom Catalyst for Solar Energy Conversion: A Comprehensive Review and Future Outlook99Exploring the properties, types, and performance of atomic site catalysts in electrochemical hydrogen evolution reactions166Machine learning-driven design of single-atom catalysts for carbon dioxide valorization to high-value chemicals: a review of photocatalysis, electrocatalysis, and thermocatalysis71Unlocking catalytic longevity: a critical review of catalyst deactivation pathways and regeneration technologies131

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