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RESEARCH PAPER · Journal of Materials Chemistry · 2004

A time resolved, in-situ X-ray diffraction study of the de-intercalation of anions and lithium cations from [LiAl 2 (OH) 6 ] n X·qH 2 O (X = Cl − , Br − , NO 3 − , SO 4 2− )

Konstantin Andreevich Tarasov, Исупов Виталий Петрович, Л. Е. Чупахина, Dermot O’Hare

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A time resolved, in-situ X-ray diffraction study of the de-intercalation of anions and lithium cations from [LiAl 2 (OH) 6 ] n X·qH 2 O (X = Cl − , Br − , NO 3 − , SO 4 2− )OriginalDelamination of layered double hydroxides in water219Mechanism of the anion exchange reactions of the layered double hydroxides (LDHs) of Ca and Mg with Al164Selective anion-exchange intercalation of isomeric benzoate anions into the layered double hydroxide [LiAl2(OH)6]Cl·H2O13Mechanistic and Kinetic Studies of Guest Ion Intercalation into Layered Double Hydroxides Using Time-resolved, In-situ X-ray Powder Diffraction57Adsorption and thermal desorption of Cr(VI) on Li/Al layered double hydroxide64Isomer selective ion-exchange intercalation of nitrophenolates into the layered double hydroxide [LiAl 2 (OH) 6 ]Cl·xH 2 O30pH mediated delamination of anionic clay-like nickel–zinc hydroxysalt in water through intercalation of zwitterionic p-aminobenzoate ions16Intercalation and controlled release of 2,4-dichlorophenoxyacetic acid using rhombohedral [LiAl2(OH)6]Cl·xH2O27A Kinetic Study of the Intercalation of Lithium Salts into Al(OH)354Mechanistic and Kinetic Studies of Guest Ion Intercalation into Layered Double Hydroxides Using Time‐Resolved, in situ X‐Ray Powder Diffraction15The removal and recovery of Cr(VI) by Li/Al layered double hydroxide (LDH)76Arsenate Sorption on Lithium/Aluminum Layered Double Hydroxide Intercalated by Chloride and on Gibbsite: Sorption Isotherms, Envelopes, and Spectroscopic Studies75Deintercalation of Li/Al LDH and its application to recover adsorbed chromate from used adsorbent52Staging during anion-exchange intercalation into [LiAl2(OH)6]Cl·yH2O: structural and mechanistic insights37Solution decomposition of the layered double hydroxide (LDH) of Zn with Al59Conservation of Order, Disorder, and “Crystallinity” during Anion-Exchange Reactions among Layered Double Hydroxides (LDHs) of Zn with Al112Variable Temperature PXRD Studies of LiAl2(OH)6X·H2O (X = Cl, Br): Observation of Disorder → Order Transformation in the Interlayer17A kinetic study of the phase conversion of layered cobalt hydroxides56Insights into the electrochemistry of layered double hydroxide containing cobalt and aluminum elements in lithium hydroxide aqueous solution29A thermodynamically stable layered double hydroxide heterostructure11Chapter 5 X‐ray Diffraction38Synthesis of Li–Al-carbonate layered double hydroxide in a metal salt-free system37The intercalation of bicyclic and tricyclic carboxylates into layered double hydroxides12Hierarchically porous calcined lithium/aluminum layered double hydroxides: Facile synthesis and enhanced adsorption towards fluoride in water108An investigation of the mechanisms of goethite, hematite and magnetite-seeded Al(OH)3 precipitation from synthetic Bayer liquor20In-Situ Raman Spectroscopy Studies of Room-Temperature and Hydrothermal Reactions1Well‐Crystallized CO32–‐Type LiAl–LDH from Urea Hydrolysis of an Aqueous Chloride Solution21Layered Double Hydroxides (LDH)235Synthesis of Li/Al LDH using aluminum and LiOH70Intercalation and controlled release properties of vitamin C intercalated layered double hydroxide71Hierarchically Porous Zn/Al Layered Double Hydroxides Intercalated with Citrate and Their Adsorption toward Parachlorophenol in Water1Lithium isotope fractionation during uptake by gibbsite105Evaluation of IN SITU synthesis route of layered hydroxides in the presence of amphiphilic polymers in comparison with their corresponding physical mixtures0Physico-chemical mechanisms involved in the acceleration of the hydration of calcium sulfoaluminate cement by lithium ions99Structural and electronic analysis of Li/Al layered double hydroxides and their adsorption for CO 245Treatment of heavy metal ions in wastewater using layered double hydroxides: A review92Mechano-hydrothermal preparation of Li-Al-OH layered double hydroxides45Anion De/Intercalation in Nickel Hydroxychloride Microspheres: A Mechanistic Study of Structural Impact on Energy Storage Performance of Multianion-Containing Layered Materials21Understanding Li-Al-CO3 layered double hydroxides. (I) Urea-supported hydrothermal synthesis45Synthesis and characterization of Zn/Al-LDH@SiO2 nanohybrid: Intercalation and release behavior of vitamin C47Kinetic, thermodynamic and isotherm investigations of Cu2+ and Zn2+ adsorption on Li Al hydrotalcite-like compound45Selective recovery of lithium from geothermal water by EGDE cross-linked spherical CTS/LMO126Lithium separation by growth of lithium aluminum layered double hydroxides on aluminum metal substrates26Synthesis and Characterization of Methanesulfonate and Ethanesulfonate Intercalated Lithium Aluminum LDHs0Elaboration and Physico-Chemical Characterization of the Gibbsite Li(OH)3 Hybrid Material3Selective Lithium Adsorption of Silicon Oxide Coated Lithium Aluminum Layered Double Hydroxide Nanocrystals and Their Regeneration20Polyacrylonitrile hybrid membrane coated with aluminum hydroxide for separating lithium13Extracting lithium from the H2SO4 leaching solution of bauxitic claystone via co-precipitation methods without addition of Al source26Lithium intercalation and deintercalation of thermally decomposed LiAl2-layered double hydroxides27Double-edged role of interlayer water on Li+ extraction from ultrahigh Mg2+/Li+ ratio brines using Li/Al-LDHs68Regulating lithium extraction based on intercalated SO42− in Li/Al-LDHs60Why is aluminum‐based lithium adsorbent ineffective in Li + extraction from sulfate‐type brines41Lithium extraction process from low grade Na+/K+ brines dependent on high layer charge layered double hydroxides40A directional growth strategy for high layer charge Li / Al‐LDHs to reinforce Li+ extraction in low‐grade salt lake brines18Desorption enhancement of aluminum-based adsorbent in lithium extraction from sulfate-type salt lakes72Effect of Anions on the Delithiation of [Li–Al] Layered Double Hydroxides: Thermodynamic Insights23Lithium Extraction from an Aqueous Medium through In Situ Synthesis of Aluminum Hydroxide: A Comprehensive Study on Adsorption and Desorption Processes, Kinetics, Isotherm Models, and Thermodynamic Parameters8Review of the state of art of Li-based inhibitors and coating technology for the corrosion protection of aluminium alloys23Spatiotemporally resolved corrosion protection of AA2024-T3 by a lithium-based conversion layer8Efficient extraction of the structural lithium from cookeite through a combined approach of roasting-leaching, co-precipitation, and elution16Steering interlayer interaction of lithium-aluminum layered double hydroxide beads for stable lithium extraction from sulfate-type brines36Hydrotalcite-derived well-dispersed and thermally stable cobalt nanoparticle catalyst for ammonia decomposition5Advanced computational strategies for lithium chemical and electrochemical adsorption: A comprehensive state-of-the-art review7Machine Learning‐Accelerated Design of High‐Efficient Lithium Adsorbents for Salt Lake Brines20Machine Learning‐Accelerated Design of High‐Efficient Lithium Adsorbents for Salt Lake Brines12Influence of the synthesis route of lithium adsorbent Li/Al LDHs on physicochemical properties and extraction properties5Dual-phase anion engineering for boosting lithium capture by Li/Al-LDHs4Effect of SO42− anions on lithium-aluminum layered double hydroxides: Implications for Li+ recovering from brines5Controllable Synthesis of Organic-Cladding Li/Al-LDH and Its High Cycling Performance for Lithium Extraction from Salt Lakes3Dritsite-like layered double hydroxides as anticorrosive material for AA2024 alloy: a preliminary study0The Current Status of Lithium Resource Extraction From Brine and Optimization Approaches for Adsorbents1A novel pulse electric field-driven electrochemical deintercalation/intercalation for efficient lithium extraction from high Na/Li ratio lepidolite leachate1Aluminium based hydrotalcite like compounds for direct lithium extraction: A critical review on crystallography and structure selectivity design0

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  1. Delamination of layered double hydroxides in water

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  2. Mechanism of the anion exchange reactions of the layered double hydroxides (LDHs) of Ca and Mg with Al

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    A.V. Radha, P. Vishnu Kamath, Chikkadasappa Shivakumara

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  3. Selective anion-exchange intercalation of isomeric benzoate anions into the layered double hydroxide [LiAl2(OH)6]Cl·H2O

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  4. Mechanistic and Kinetic Studies of Guest Ion Intercalation into Layered Double Hydroxides Using Time-resolved, In-situ X-ray Powder Diffraction

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  5. Adsorption and thermal desorption of Cr(VI) on Li/Al layered double hydroxide

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  6. Isomer selective ion-exchange intercalation of nitrophenolates into the layered double hydroxide [LiAl 2 (OH) 6 ]Cl·xH 2 O

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  7. pH mediated delamination of anionic clay-like nickel–zinc hydroxysalt in water through intercalation of zwitterionic p-aminobenzoate ions

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    Sylvia Britto, Jacqueline T. Rajamathi, Narayanan Ravishankar, Chikkadasappa Shivakumara, Michael Rajamathi

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  8. Intercalation and controlled release of 2,4-dichlorophenoxyacetic acid using rhombohedral [LiAl2(OH)6]Cl·xH2O

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  9. A Kinetic Study of the Intercalation of Lithium Salts into Al(OH)3

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  10. Mechanistic and Kinetic Studies of Guest Ion Intercalation into Layered Double Hydroxides Using Time‐Resolved, in situ X‐Ray Powder Diffraction

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  11. The removal and recovery of Cr(VI) by Li/Al layered double hydroxide (LDH)

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  12. Arsenate Sorption on Lithium/Aluminum Layered Double Hydroxide Intercalated by Chloride and on Gibbsite: Sorption Isotherms, Envelopes, and Spectroscopic Studies

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  13. Deintercalation of Li/Al LDH and its application to recover adsorbed chromate from used adsorbent

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  14. Staging during anion-exchange intercalation into [LiAl2(OH)6]Cl·yH2O: structural and mechanistic insights

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  15. Solution decomposition of the layered double hydroxide (LDH) of Zn with Al

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  16. Conservation of Order, Disorder, and “Crystallinity” during Anion-Exchange Reactions among Layered Double Hydroxides (LDHs) of Zn with Al

    The Journal of Physical Chemistry B · 2007-03-09

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  17. Variable Temperature PXRD Studies of LiAl2(OH)6X·H2O (X = Cl, Br): Observation of Disorder → Order Transformation in the Interlayer

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  18. A kinetic study of the phase conversion of layered cobalt hydroxides

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  19. Insights into the electrochemistry of layered double hydroxide containing cobalt and aluminum elements in lithium hydroxide aqueous solution

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  20. A thermodynamically stable layered double hydroxide heterostructure

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  21. Chapter 5 X‐ray Diffraction

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  22. Synthesis of Li–Al-carbonate layered double hydroxide in a metal salt-free system

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  23. The intercalation of bicyclic and tricyclic carboxylates into layered double hydroxides

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  24. Hierarchically porous calcined lithium/aluminum layered double hydroxides: Facile synthesis and enhanced adsorption towards fluoride in water

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  25. An investigation of the mechanisms of goethite, hematite and magnetite-seeded Al(OH)3 precipitation from synthetic Bayer liquor

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  34. Physico-chemical mechanisms involved in the acceleration of the hydration of calcium sulfoaluminate cement by lithium ions

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  40. Synthesis and characterization of Zn/Al-LDH@SiO2 nanohybrid: Intercalation and release behavior of vitamin C

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  41. Kinetic, thermodynamic and isotherm investigations of Cu2+ and Zn2+ adsorption on Li Al hydrotalcite-like compound

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  44. Synthesis and Characterization of Methanesulfonate and Ethanesulfonate Intercalated Lithium Aluminum LDHs

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  48. Extracting lithium from the H2SO4 leaching solution of bauxitic claystone via co-precipitation methods without addition of Al source

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  49. Lithium intercalation and deintercalation of thermally decomposed LiAl2-layered double hydroxides

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  50. Double-edged role of interlayer water on Li+ extraction from ultrahigh Mg2+/Li+ ratio brines using Li/Al-LDHs

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