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RESEARCH PAPER · The Journal of Physical Chemistry B · 2007

Conservation of Order, Disorder, and “Crystallinity” during Anion-Exchange Reactions among Layered Double Hydroxides (LDHs) of Zn with Al

A.V. Radha, P. Vishnu Kamath, Chikkadasappa Shivakumara

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Conservation of Order, Disorder, and “Crystallinity” during Anion-Exchange Reactions among Layered Double Hydroxides (LDHs) of Zn with AlOriginalHydrogen Storage on Platinum Nanoparticles Doped on Superactivated Carbon179Chromate uptake characteristics of the pristine layered double hydroxides of Mg with Al83Gas Adsorption and Storage in Metal−Organic Framework MOF-177636The application of focused microwave irradiation coupled with freeze drying to investigate the reaction of MgO and Al2O3 slurries in the formation of layered double hydroxides9Comment on “Kinetics and Mechanistic Model for Hydrogen Spillover on Bridged Metal-Organic Frameworks”18Reply to “Comment on ‘Kinetics and Mechanistic Model for Hydrogen Spillover on Bridged Metal-Organic Frameworks'”10Electrochemical Synthesis of Zn−Al Layered Double Hydroxide (LDH) Films122Intercalation of l -Dopa into Layered Double Hydroxides: Enhancement of Both Chemical and Stereochemical Stabilities of a Drug through Host−Guest Interactions120A novel glucose sensor based on monodispersed Ni/Al layered double hydroxide and chitosan122Hydrotalcite docked Rh-TPPTS complexes as efficient catalysts for the arylation of 2-cyclohexen-1-one in neat water20Synthesis and characterization of arsenate-intercalated layered double hydroxides (LDHs): Prospects for arsenic mineralization53Intracrystalline Oxidation of Thiosulfate-Intercalated Layered Double Hydroxides34Bromide-ion distribution in the interlayer of the layered double hydroxides of Zn and Al: Observation of positional disorder9Polytype Selection and Structural Disorder Mediated by Intercalated Sulfate Ions Among the Layered Double Hydroxides of Zn with Al and Cr18One-Step Synthesis of Organic LDH and Its Comparison with Regeneration and Anion Exchange Method140Influence of textural properties and trace water on the reactivity and deactivation of reconstructed layered hydroxide catalysts for transesterification of tributyrin with methanol45Structure of Bayerite-Based Lithium−Aluminum Layered Double Hydroxides (LDHs): Observation of Monoclinic Symmetry56Intercalation of [M(ox)3]3− (M=Cr, Rh) complexes into NiIIFeIII-LDH41Kilogram-scale synthesis of Mg–Al–CO3 LDHs nanosheets using a new two-stage reactor8Structural and microstructural changes during anion exchange of CoAl layered double hydroxides: anin situX-ray powder diffraction study25Thermal decomposition of Co-Al layered double hydroxide: Identification of precursor to oxide with spinel structure10Evaluation of ionic conductivity for Mg–Al layered double hydroxide intercalated with inorganic anions86Structural Model Proposition and Thermodynamic and Vibrational Analysis of Hydrotalcite-Like Compounds by DFT Calculations98Polytype Transformations in the SO42– Containing Layered Double Hydroxides of Zinc with Aluminum and Chromium: The Metal Hydroxide Layer as a Structural Synthon17A New Strategy for Immobilization of Electroactive Species on the Surface of Solid Electrode11Assembly Chemistry of Anion-intercalated Layered Materials29Dissolution of nano-size Mg–Al–Cl hydrotalcite in aqueous media127The urea method for the direct synthesis of ZnAl layered double hydroxides with nitrate as the interlayer anion125Controlled release of nitrate from hydrotalcite modified formulations52Chemical composition and interlayer arrangement of polytype 3R2 Mg–Al layered double hydroxides9Polytypism in the Lithium–Aluminum Layered Double Hydroxides: The [LiAl 2 (OH) 6 ] + Layer as a Structural Synthon59Anion Exchange Reaction Potentials as Approximate Estimates of the Relative Thermodynamic Stabilities of Mg/Al Layered Double Hydroxides Containing Different Anions24Comparative Structural, thermodynamic and electronic analyses of ZnAlAn− hydrotalcite-like compounds (An−Cl−, F−, Br−, OH−, CO32− or NO3−): An ab initio study183Synthesis of 3R1and 1H Polytypes of Sulfate-Intercalated Layered Double Hydroxides (LDHs) by Postintracrystalline Oxidation and Simultaneous Intercalation-Oxidation of Thiosulfate5Comparative X-ray diffraction and infrared spectroscopy study of Zn–Al layered double hydroxides: Vanadate vs nitrate64Correlation among Structure, Microstructure, and Electrochemical Properties of NiAl–CO3Layered Double Hydroxide Thin Films71Uniform nanoparticles of hydrotalcite-like materials and their textural properties at optimized conditions of urea hydrothermal treatment26Coupling physical chemical techniques with hydrotalcite-like compounds to exploit their structural features and new multifunctional hybrids with luminescent properties24Layered Double Hydroxides (LDH)235Observation of cation ordering and anion-mediated structure selection among the layered double hydroxides of Cu(ii) and Cr(iii)23Thermodynamics of Carbonates69The importance of proper crystal-chemical and geometrical reasoning demonstrated using layered single and double hydroxides87The importance of proper crystal-chemical and geometrical reasoning demonstrated using layered single and double hydroxides5Experimental and theoretical investigation into the elimination of organic pollutants from solution by layered double hydroxides60Hybrid Magnetic Superconductors Formed by TaS2 Layers and Spin Crossover Complexes17Zn- and Co-based layered double hydroxides: prediction of theaparameter from the fraction of trivalent cations andvice versa15A novel nonenzymatic electrochemical glucose sensor modified with Ni/Al layered double hydroxide56Structure evolution of layered double hydroxides activated by ultrasound induced reconstruction42MgZnAl hydrotalcite-like compounds preparation by a green method: effect of zinc content10Perchlorate uptake and molecular mechanisms by magnesium/aluminum carbonate layered double hydroxides and the calcined layered double hydroxides75A short-range ordered–disordered transition of a NiOOH/Ni(OH) 2 pair induces switchable wettability56Sorption of strontium and yttrium radionuclides from aqueous solutions onto layered double hydroxides of various compositions11Carbon cloth supported NiAl-layered double hydroxides for flexible application and highly sensitive electrochemical sensors76Dehydration and Dehydroxylation of Layered Double Hydroxides: New Insights from Solid-State NMR and FT-IR Studies of Deuterated Samples53Tuning and Investigating the Structure of MII-FeIII Layered Double Hydroxides (MII = NiII, CoII and MgII) in Relation to their Composition: From Synthesis to Anionic Exchange Properties17Stepwise anodic electrodeposition of nanoporous NiOOH/Ni(OH)2 with controllable wettability and its applications4How the Method of Synthesis Governs the Local and Global Structure of Zinc Aluminum Layered Double Hydroxides104Optimization of ammonia nitrogen removal by SO 4 2− intercalated hydrotalcite using response surface methodology10Control of crystallite and particle size in the synthesis of layered double hydroxides: Macromolecular insights and a complementary modeling tool87Theoretical studies of structure and racemization mechanism of aspartate-intercalated hydrotalcite13D Transition Metal Ordering and Rietveld Stacking Fault Quantification in the New Oxychalcogenides La2O2Cu2–4xCd2xSe228A solid state NMR study of layered double hydroxides intercalated with para-amino salicylate, a tuberculosis drug24Layered hydroxide anion exchanger and their applications related to pesticides: a brief review20Antimony Removal from Aqueous Solutions by the Use of Zn-Al Sulphate Layered Double Hydroxide14Synthesis and Characterization of Layered Double Hydroxides Containing Optically Active Transition Metal Ion10Functional Host–Guest Materials8Synthesis of a highly dispersed CuO catalyst on CoAl-HT for the epoxidation of styrene48Prospects use of hybrid layered double hydroxides‐polyacrylamide as controlled release media for antibiotic molecules13Bi-substituted Mg3Al–CO3 layered double hydroxides22A bionanohybrid ZnAl-NADS ecological pesticide as a treatment for soft rot disease in potato (Solanum tuberosum L.)9Contribuições químicas à astrobiologia: estudo da interação entre biomoléculas e minerais por espectroscopia raman0Mg-Zn-Al LDH: Influence of intercalated anions on CO 2 removal from natural gas52Effects of preparation methods on the property and hydrodesulfurization activity of NiAlZrW catalysts derived from tungstate intercalated NiAlZr layered double hydroxides20Layered clay minerals, synthetic layered double hydroxides and hydroxide salts applied as pickering emulsifiers78Impact of cation redox chemistry on continuous hydrothermal synthesis of 2D-Ni(Co/Fe) hydroxides5The Periodic Table as a Guide to the Construction and Properties of Layered Double Hydroxides25[SnS4]4- clusters modified MgAl-LDH composites for mercury ions removal from acid wastewater35Intercalation of $\hbox {LDH NO}_{{3}}$ LDH NO 3 with short-chain intercalants1Sonication accelerated formation of Mg-Al-phosphate layered double hydroxide via sol-gel prepared mixed metal oxides66Application of Layered Double Magnesium–Aluminum Oxides for the Purification of Aqueous Solutions from Dyes1Use of Layered Double Oxides and Hydroxides of Mg and Al for Removing Dyes from Aqueous Solutions Containing 137Cs, 90Sr, 90Y, and U(VI)2Zn-Al LDH growth on AA2024 and zinc and their intercalation with chloride: Comparison of crystal structure and kinetics73Order and Disorder in Layered Double Hydroxides: Lessons Learned from the Green Rust Sulphate - Nikischerite Series.0Sensitive determination of kojic acid in tomato sauces using Ni–Fe layered double hydroxide synthesized through Fe-MIL-88 metal-organic framework templated route9Superior extreme pressure properties of different layer LDH nanoplatelets used as boundary lubricants37Computational investigation of two-dimensional LDHs and the modification of their electronic structure induced by defects17Effect of Drying on the Fabrication of MgAl Layered Double Hydroxides79Single-Step Topochemical Synthesis of NiFe Layered Double Hydroxides for Superior Anion Removal from Aquatic Systems34Order and Disorder in Layered Double Hydroxides: Lessons Learned from the Green Rust Sulfate─Nikischerite Series10Long-Range and Short-Range Structures of Multimetallic Layered Double Hydroxides28Synergy of Various Defects in CoAl-Layered Double Hydroxides Photocatalyzed CO2 Reduction: A First-Principles Study12Influence of Structural Disorders on the Tribological Behavior of Phosphate-Intercalated Layered Double Hydroxide Additives in Polyalphaolefin16Formation of crystalline multimetallic layered double hydroxide precipitates during uptake of Co, Ni, and Zn onto γ-alumina: Evidence from EXAFS, XRD, and TEM13Development of an innovative and eco-compatible composite material for the reversible trapping of pollutants : application to the depollution of industrial effluents0Anion Exchange Reactions of 3R2-MgAl-Carbonate-LDH: Comparison with the 3R1 Analogue and Formation of 3R2 Polytype of MgAl-LDH with Other Interlayer Anions10Design and Evaluation of Natural Degradation Behavior of Poly (lactic acid)/Organo-Modified-Ni-Zn-Al-Layered Double Hydroxides Nanocomposites Film7In-depth characterization of phosphate intercalated Mg Al Layered double hydroxides and study of the PO 4 release properties12A NiFeSn oxyhydroxide electrocatalyst wet gel for highly efficient water electrolysis in alkaline media47Production of MgAl/layered double hydroxide microspheres and investigation of the volumetric heat transfer coefficient in spray drying7Fabrication of new in‐situ ternary nano/microcomposite LDH/Ag2O/Bayerite in trimetallic NiAg/Al layered double hydroxides for CO2 capture material5Tunable Growth of Layered Double Hydroxide Nanosheets through Hydrothermal Conversion of Atomic Layer Deposition Seed Layers7Photothermal effect enhanced antibacterial activity of CuAl-layered double hydroxides11Aqueous phase synthesis and electronic spectroscopy of nanostructured layered double hydroxides2CO2 capture by new ternary nanocomposite LDH /bayerite/ Ag2O in tetrametallic NiZnAgAl layered double hydroxides fabricated via in situ growth2Ag single-atom modification of MgAl-LDH to enhance the CH 4 product selectivity in CO 2 reduction: a DFT study7Engineering ZnAl-LDHs: The Impact of Synthesis Parameters on Material Properties for Adsorption Applications4Efficient removal of triarylmethane biocide from aqueous solutions using ZnAl/LDH: Adsorption kinetics, isotherms, and thermodynamic insights9New pentametallic MnNiCoCu / X ( X = Al, Fe) layered double hydroxides and their hybrids with Keggin‐type polyoxometalates for CO 2 capture0Benzoate-mediated generation of front–back reversible photoluminescence in transparent polymer/LDH:Tb,Eu nanocomposite films0New quaternary composite LDH /bayerite/nitratine/carbon in the hybrid matrix bimetallic NiAl LDH /carbon for CO 2 capture0Controlled release of pyrithione from ZnAl layered double hydroxides to inhibit biocolonization on porous building-material surfaces0

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  2. Chromate uptake characteristics of the pristine layered double hydroxides of Mg with Al

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  4. The application of focused microwave irradiation coupled with freeze drying to investigate the reaction of MgO and Al2O3 slurries in the formation of layered double hydroxides

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