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RESEARCH PAPER · Solid State Sciences · 2005

Mechanism of the anion exchange reactions of the layered double hydroxides (LDHs) of Ca and Mg with Al

A.V. Radha, P. Vishnu Kamath, Chikkadasappa Shivakumara

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Mechanism of the anion exchange reactions of the layered double hydroxides (LDHs) of Ca and Mg with AlOriginalpH mediated delamination of anionic clay-like nickel–zinc hydroxysalt in water through intercalation of zwitterionic p-aminobenzoate ions16Hexamethylenetetramine Directed Synthesis and Properties of a New Family of α-Nickel Hydroxide Organic−Inorganic Hybrid Materials with High Chemical Stability99Aromatic Molecules in Restricted Geometries: Pyrene Excimer Formation in an Anchored Bilayer47One-step synthesis of spherical α-Ni(OH)2nanoarchitectures67Layered double hydroxides as potential chromate scavengers74Synthesis and characterization of layered double hydroxides (LDHs) with intercalated chromate ions64Reactions of Cu2+ and Pb2+ with Mg/Al layered double hydroxide149Formation of zinc aluminium layered double hydroxides: 4-(2,4-dichlorophenoxy) butyrate nanocomposites by direct and indirect methods4Anion substitution of nitrate-saturated layered double hydroxide of Mg and Al31Molecular modeling of layered double hydroxide intercalated with benzoate, modeling and experiment32Suppression of the Reversible Thermal Behavior of the Layered Double Hydroxide (LDH) of Mg with Al: Stabilization of Nanoparticulate Oxides16Chromate uptake characteristics of the pristine layered double hydroxides of Mg with Al83Leaching Mechanisms of Cr(VI) from Chromite Ore Processing Residue62Synthesis and characterization of arsenate-intercalated layered double hydroxides (LDHs): Prospects for arsenic mineralization53Synthèse électrochimique de films d'hydroxydes doubles lamellaires : applications aux biocapteurs0A novel conversion process for waste slag: synthesis of a hydrotalcite-like compound and zeolite from blast furnace slag and evaluation of adsorption capacities141Removal efficiency of arsenate and phosphate from aqueous solution using layered double hydroxide materials: intercalation vs. precipitation158Synthesis and characterization of [4-(2,4-dichlorophenoxybutyrate)-zinc layered hydroxide] nanohybrid35Effect of incoming and outgoing exchangeable anions on the release kinetics of phenoxyherbicides nanohybrids24Fluorescent Properties of Zn-Al Hydrotalcite and its Modified Products1New synthesis route of hydrocalumite-type materials and their application as basic catalysts for aldol condensation25Phosphate-intercalated Ca–Fe-layered double hydroxides: Crystal structure, bonding character, and release kinetics of phosphate123Synthesis of Dichlorprop-Zn/Al-hydrotalcite Nanohybrid and its Controlled Release Property (Sintesis Nanohibrid Diklorprop-Zn/Al-hidrotalsit dan Sifat Lepasan Terkawalnya)0Influence of Synthesis Temperature on Phosphate Adsorption by Zn-Al Layered Double Hydroxides in Excess Sludge Liquor22Synthesis of dichlorprop-Zn/Al-hydrotalcite nanohybrid and its controlled release property8Complete desorption of interlayer hydrogen phosphate in Mg/Al-layered double hydroxides by means of anion exchange with 1-octanesulfonate22Triphosphate removal processes over ternary CaMgAl-layered double hydroxides32Ca‐Rich Ca–Al‐Oxide, High‐Temperature‐Stable Sorbents Prepared from Hydrotalcite Precursors: Synthesis, Characterization, and CO 2 Capture Capacity83Synthesis of layered double hydroxides from eggshells25Solubility product (Ksp)-controlled removal of chromate and phosphate by hydrocalumite83Direct observation of grafting interlayer phosphate in Mg/Al layered double hydroxides38Waste‐Slag Hydrocalumite and Derivatives as Heterogeneous Base Catalysts37Chloride Binding Capacity of Cement Paste Containing Layered Double Hydroxide (LDH)21Preparation and characterization of nanocontainers of corrosion inhibitor based on layered double hydroxides103Effect of pH on the adsorption of Sunset Yellow FCF food dye into a layered double hydroxide (CaAl-LDH-NO3)242Thermodynamics of Carbonates69Dual Removal Process of Phosphate on Ca-Layered Double Hydroxide with Substitution of Fe for Al4A new catalytic opportunity for waste materials: Application of waste slag based catalyst in CO2 fixation reaction82New data on arsenic sorption properties of Zn–Al sulphate layered double hydroxides: Influence of competition with other anions31Fast aging treatment for the synthesis of hydrocalumites using microwaves41The role of Mg2+ ions in the corrosion behaviour of AA2024-T3 aluminium alloys immersed in chloride-containing environments25Reactivity and applications of layered silicates and layered double hydroxides116Removal of boron from oilfield wastewater via adsorption with synthetic layered double hydroxides29Intercalation and Complexation of Co(II) and Ni(II) by Chelating Ligands Incorporated in Zn-Al Layered Double Hydroxides10Structure Analysis and Fluorescence of Mg-Al-Tb Ternary Layered Double Hydroxides and Their Calcined Products3Multi-step removal mechanism of pyrophosphate using CaFe-layered double hydroxide at high pH12Effects of hydrotalcite intercalated with corrosion inhibitor on cathodic disbonding of epoxy coatings18Mechanism of boron uptake by hydrocalumite calcined at different temperatures42Enhanced removal of phosphate by hydrocalumite: synergism of AlPO4 and CaHPO4·2H2O precipitation5Surface modification and dissolution behavior of Mg–Al hydrotalcite particles37Removal behavior research of orthophosphate by CaFe-layered double hydroxides18Innovative method for hydrocalumite-like compounds' preparation and their evaluation in the transesterification reaction22Nature and reactivity of layered double hydroxides formed by coprecipitating Mg, Al and As(V): Effect of arsenic concentration, pH, and aging36Analysis of phosphate removal from aqueous solutions by hydrocalumite9Effect of interlayer anions on chromium removal using Mg–Al layered double hydroxides: Kinetic, equilibrium and thermodynamic studies58Moisture content-affected electrokinetic remediation of Cr(VI)-contaminated clay by a hydrocalumite barrier44Evaluation of Hydrocalumite-Like Compounds as Catalyst Precursors in the Photodegradation of 2,4-Dichlorophenoxyacetic Acid21Preparation of Graphene Oxide/CeO2-NiAl-Layered Double Hydroxide Composite for Cysteine Sensing0Synthesis of aminopropyltriethoxysilane grafted/tripolyphosphate intercalated ZnAl LDHs and their performance in the flame retardancy and smoke suppression of polyurethane elastomer31Simultaneous removal of Cu(II) and Cr(VI) by Mg–Al–Cl layered double hydroxide and mechanism insight107Facile synthesis of Ca/Mg/Al/Fe layered double hydroxides using steelmaking slag as raw material27Effects of Mg-Al Layered Double Hydroxide on Nitrate Leaching and Nitrogen Uptake by Maize in a Calcareous Soil19Removal mechanism of arsenate by bimetallic and trimetallic hydrocalumites depending on arsenate concentration17Kinetics, isotherms and multiple mechanisms of the removal for phosphate by Cl-hydrocalumite41Synthesis of highly effective absorbents with waste quenching blast furnace slag to remove Methyl Orange from aqueous solution58Characteristics and mechanisms of phosphate removal by calcium-iron layered double hydroxides and their hydrolysis products0Cephradine Intercalated Mg-Al Layered Double Hydroxide0Cephradine Intercalated Mg-Al Layered Double Hydroxide1Synthesis and characterization of eco-friendly Ca-Al-LDH loaded with phosphate for agricultural applications62Synthesis of some Mg/Co-Al type nano hydrotalcites and characterization55closo-Dodecaborate Intercalated Yttrium Hydroxide as a First Example of Boron Cluster Anion-Containing Layered Inorganic Substances28Characterization of the intermediate in formation of selenate-substituted ettringite28Calcination on Ca-Mg-Al Hydrotalcite from Brine Water and Its Characterization2CALCINATION ON Ca-Mg-Al HYDROTALCITE FROM BRINE WATER AND ITS CHARACTERIZATION1One-pot synthesis of CaAl-layered double hydroxide–methotrexate nanohybrid for anticancer application31Crystal Chemistry of Pyroaurite from the Kovdor Pluton, Kola Peninsula, Russia, and the Långban Fe–Mn deposit, Värmland, Sweden10One step preparation of ZnFe2O4/Zn5(OH)6(CO3)2 nanocomposite with improved As(V) removal capacity1Acid Mine Drainage Treatment Options Using Recycled Bayer Liquor1Layered gadolinium hydroxides for simultaneous drug delivery and imaging44Relationship between the particle size and dosage of LDHs and concrete resistance against chloride ingress169The isotopic exchangeability of phosphate in Mg-Al layered double hydroxides27[Mg-Al]-LDH and [Zn-Al]-LDH as Matrices for Removal of High Loadings of Phosphate42Synthesis of layered organic–inorganic nanohybrid zinc–aluminium-2-(4-chlorophenoxy)-2-methyl propionic acid with controlled release properties6Superplasticizer to layered calcium aluminate hydrate interface characterized using model organic molecules7Synthesis and application of layered double hydroxide-hosted 2-aminoterephthalate for the Knoevenagel condensation reaction6Advances in Flame Retardant Poly(Lactic Acid)119Phosphorus recovery through adsorption by layered double hydroxide nano-composites and transfer into a struvite-like fertilizer130Eu-Doped layered yttrium hydroxides sensitized by a series of benzenedicarboxylate and sulphobenzoate anions22Use of calcium aluminum–layered double hydroxide to control chloride ion penetration of cement-based materials15Layered double hydroxides for phosphorus recovery from acidified and non-acidified dewatered sludge72Interaction of Pristine Hydrocalumite-Like Layered Double Hydroxides with Carbon Dioxide14Development of a Zeolite A/LDH Composite for Simultaneous Cation and Anion Removal19Double-Edged Effect of Humic Acid on Multiple Sorption Modes of Calcined Layered Double Hydroxides: Inhibition and Promotion17Acid-salt treated CoAl layered double hydroxide nanosheets with enhanced adsorption capacity of methyl orange dye124Sequestration of orthophosphate by Ca2Al-NO3 layered double hydroxide – Insight into reactivity and mechanism45Degradation of bisphenol A by Fe-Al layered double hydroxides: A new synergy of homo- and heterogeneous Fenton systems61Roles of Mg-Al layered double hydroxides and solution chemistry on P transport in soil23Low Carbonate Contaminative and Ultrasmall NiAl LDH Prepared by Acid Salt Treatment with High Adsorption Capacity of Methyl Orange63Transport and retention of phosphorus in soil with addition of Mg-Al layered double hydroxides: Effects of material dosage, flow velocity and pH27Layered Double Hydroxides: A Toolbox for Chemistry and Biology156Atomic Level Understanding of Orthophosphate Adsorption by Magnesium Aluminum-Layered Double Hydroxides—A Multitechnique Study45Corrosion protection of steel by Mg-Al layered double hydroxides in simulated concrete pore solution: Effect of SO42-79In-situ synthesis of calcium aluminum layered double hydroxides for advanced treatment of leachate biochemical tail water9Layered rare-earth hydroxides: a new family of anion-exchangeable layered inorganic materials57Layered double hydroxide nanocomposites for agricultural applications17Development of nanocomposite films with special optical properties from hybrid double layered hydroxides0Electrospun poly(lactic acid) nanofibers loaded with silver sulfadiazine/[Mg–Al]‐layered double hydroxide as an antimicrobial wound dressing52Layered Double Hydroxide Protective Films Developed on Aluminum and Aluminum Alloys: Synthetic Methods and Anti-Corrosion Mechanisms68Mechanism of phosphate adsorption on superparamagnetic microparticles modified with transitional elements: Experimental observation and computational modelling18Porous Materials for Environmental Applications0Synthesis and topotactic exchange reactions of new layered double hydroxides intercalated with ammonium/sulfate10Layered Double Hydroxides in Bioinspired Nanotechnology41Superior extreme pressure properties of different layer LDH nanoplatelets used as boundary lubricants37Syntheses of Layered Double Hydroxides from de-K Bittern and Their Anion Exchange Property6Anion exchange in green rust : the chloride, sulphate and carbonate binary and ternary systems0Selenium oxyanion exchange with Mg(II)-Fe(III) and Fe(II)-Fe(III) layered double hydroxides12Layered terbium hydroxides for simultaneous drug delivery and imaging18Preparation of a novel hafnium-loaded Fe3O4@SiO2 superparamagnetic nanoparticles and its adsorption performance for phosphate in water4Kinetic, thermodynamic and equilibrium studies on chloride adsorption from simulated concrete pore solution by core@shell zeolite-LTA@Mg-Al layered double hydroxides34Optimization of hydrocalumite preparation under microwave irradiation for recovering aluminium from a saline slag31Reconstruction and intercalating anion exchange of ZnAl-layered double hydroxide30Divalent metal release and antimicrobial effects of layered double hydroxides44Study of the action of nano-alumina particles in hydrated lime pastes13Inorganic Materials in Drug Delivery1Adsorption performance and mechanism of Ca–Al-LDHs prepared by oyster shell and pop can for phosphate from aqueous solutions60Mg–Al-Layered Double Hydroxide Doped with Phosphate Radical for Preparation of Slow-Release Phosphate Fertilizers0Layered double hydroxides for removing and recovering phosphate: Recent advances and future directions140Permanganate loaded Ca-Al-LDH coating for active corrosion protection of 2024-T3 alloy37Removal of amoxicillin from water by concrete-based hydrotalcites: Efficiency and mechanism19Corrosion protection of Zn–Al–Mg‐coated steel by a layered double hydroxide conversion layer14Single/synchronous adsorption of Cu(II), Cd(II) and Cr(VI) in water by layered double hydroxides doped with different divalent metals8Preparation of Ca2Al1–mFem(OH)6Cl·2H2O-Doped Hydrocalumites and Application of Their Derived Mixed Oxides in the Photodegradation of Ibuprofen10LDH has been grown: What is next? Overview on methods of post-treatment of LDH conversion coatings56Indulgent of the physiochemical features of MgCr-LDH nanosheets towards photodegradation process of methylene blue75The Structure, Preparation, Characterization, and Intercalation Mechanism of Layered Hydroxides Intercalated with Guest Anions43Enhanced recovery of phosphate from wastewater using hollow hierarchical hydrotalcite/hydroxide composite microspheres adsorbent23Ultrasound-assisted synthesis of magnetic layer CaAl hydrotalcite composite for removal of fuchsin acid in simulated solution6Intercalated Organic Redox-active Anions for Enhanced Capacity of Layered Double Hydroxides8Layered Double Hydroxides for Regulating Phosphate in Water to Achieve Long-Term Nutritional Management33Methodology for development of smart epoxy coatings incorporated with Ethylenediamine-N, N'-disuccinic ac-id (EDDS) layered double hydroxides (LDHs) for corrosion protection of XC38 carbon steel0Analytical study on elimination of lead by anionic clays: Characterization, adsorption kinetics, isotherm, thermodynamic, mechanism and adsorption3Anti-corrosion applications of 2D transition metal based layered materials28Enhanced phosphorus recovery from waste streams via crystallization and its integration with other techniques0Sebacate intercalated Ca Al layered double hydroxide pigments for corrosion protection of low carbon steel: Anion exchange and electrochemical properties15Hydrocalumite–TiO2 hybrid systems synthesized from aluminum salt cake for photodegradation of ibuprofen9Growth mechanism and corrosion resistance of layered double hydroxide film on magnesium alloy without external addition of magnesium and aluminum salts21Enhancement of corrosion, biocompatibility and drug delivery properties of nitinol implants surface by Al-Zn-LDH nanohybrids12Design of dual-functional Mg/Al layered double hydroxide for smart protective coatings7Understanding and Enhancing the Cycling Stability of Layered Double Hydroxides with Intercalated Ferrocene Anions for Energy Storage Application1What controls the labile cations content in ultramafic minerals and tailings for carbon capture and storage: An experimental approach5

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  1. pH mediated delamination of anionic clay-like nickel–zinc hydroxysalt in water through intercalation of zwitterionic p-aminobenzoate ions

    Solid State Sciences · 2006-01-24

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  2. Hexamethylenetetramine Directed Synthesis and Properties of a New Family of α-Nickel Hydroxide Organic−Inorganic Hybrid Materials with High Chemical Stability

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  3. Aromatic Molecules in Restricted Geometries: Pyrene Excimer Formation in an Anchored Bilayer

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  4. One-step synthesis of spherical α-Ni(OH)2nanoarchitectures

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  5. Layered double hydroxides as potential chromate scavengers

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  6. Synthesis and characterization of layered double hydroxides (LDHs) with intercalated chromate ions

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  7. Reactions of Cu2+ and Pb2+ with Mg/Al layered double hydroxide

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  8. Formation of zinc aluminium layered double hydroxides: 4-(2,4-dichlorophenoxy) butyrate nanocomposites by direct and indirect methods

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    Norhayati Hashim, Mohd Zobir Hussein, Asmah Hj Yahaya, Zulkarnain Zainal

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  9. Anion substitution of nitrate-saturated layered double hydroxide of Mg and Al

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  10. Molecular modeling of layered double hydroxide intercalated with benzoate, modeling and experiment

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  11. Suppression of the Reversible Thermal Behavior of the Layered Double Hydroxide (LDH) of Mg with Al: Stabilization of Nanoparticulate Oxides

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  12. Chromate uptake characteristics of the pristine layered double hydroxides of Mg with Al

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  13. Leaching Mechanisms of Cr(VI) from Chromite Ore Processing Residue

    Journal of Environmental Quality · 2008-10-23

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  14. Synthesis and characterization of arsenate-intercalated layered double hydroxides (LDHs): Prospects for arsenic mineralization

    Journal of Colloid and Interface Science · 2009-01-10

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  15. Synthèse électrochimique de films d'hydroxydes doubles lamellaires : applications aux biocapteurs

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  16. A novel conversion process for waste slag: synthesis of a hydrotalcite-like compound and zeolite from blast furnace slag and evaluation of adsorption capacities

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  17. Removal efficiency of arsenate and phosphate from aqueous solution using layered double hydroxide materials: intercalation vs. precipitation

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  18. Synthesis and characterization of [4-(2,4-dichlorophenoxybutyrate)-zinc layered hydroxide] nanohybrid

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  19. Effect of incoming and outgoing exchangeable anions on the release kinetics of phenoxyherbicides nanohybrids

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  20. Fluorescent Properties of Zn-Al Hydrotalcite and its Modified Products

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  21. New synthesis route of hydrocalumite-type materials and their application as basic catalysts for aldol condensation

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  22. Phosphate-intercalated Ca–Fe-layered double hydroxides: Crystal structure, bonding character, and release kinetics of phosphate

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  23. Synthesis of Dichlorprop-Zn/Al-hydrotalcite Nanohybrid and its Controlled Release Property (Sintesis Nanohibrid Diklorprop-Zn/Al-hidrotalsit dan Sifat Lepasan Terkawalnya)

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  24. Influence of Synthesis Temperature on Phosphate Adsorption by Zn-Al Layered Double Hydroxides in Excess Sludge Liquor

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  25. Synthesis of dichlorprop-Zn/Al-hydrotalcite nanohybrid and its controlled release property

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  26. Complete desorption of interlayer hydrogen phosphate in Mg/Al-layered double hydroxides by means of anion exchange with 1-octanesulfonate

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  27. Triphosphate removal processes over ternary CaMgAl-layered double hydroxides

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  28. Ca‐Rich Ca–Al‐Oxide, High‐Temperature‐Stable Sorbents Prepared from Hydrotalcite Precursors: Synthesis, Characterization, and CO 2 Capture Capacity

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  29. Synthesis of layered double hydroxides from eggshells

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  30. Solubility product (Ksp)-controlled removal of chromate and phosphate by hydrocalumite

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  31. Direct observation of grafting interlayer phosphate in Mg/Al layered double hydroxides

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  32. Waste‐Slag Hydrocalumite and Derivatives as Heterogeneous Base Catalysts

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  33. Chloride Binding Capacity of Cement Paste Containing Layered Double Hydroxide (LDH)

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  34. Preparation and characterization of nanocontainers of corrosion inhibitor based on layered double hydroxides

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  35. Effect of pH on the adsorption of Sunset Yellow FCF food dye into a layered double hydroxide (CaAl-LDH-NO3)

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  36. Thermodynamics of Carbonates

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  37. Dual Removal Process of Phosphate on Ca-Layered Double Hydroxide with Substitution of Fe for Al

    Journal of Hazardous Toxic and Radioactive Waste · 2013-02-28

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  38. A new catalytic opportunity for waste materials: Application of waste slag based catalyst in CO2 fixation reaction

    Journal of CO2 Utilization · 2013-04-06

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  39. New data on arsenic sorption properties of Zn–Al sulphate layered double hydroxides: Influence of competition with other anions

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  40. Fast aging treatment for the synthesis of hydrocalumites using microwaves

    Applied Clay Science · 2013-06-28

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  41. The role of Mg2+ ions in the corrosion behaviour of AA2024-T3 aluminium alloys immersed in chloride-containing environments

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  42. Reactivity and applications of layered silicates and layered double hydroxides

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  43. Removal of boron from oilfield wastewater via adsorption with synthetic layered double hydroxides

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  44. Intercalation and Complexation of Co(II) and Ni(II) by Chelating Ligands Incorporated in Zn-Al Layered Double Hydroxides

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  45. Structure Analysis and Fluorescence of Mg-Al-Tb Ternary Layered Double Hydroxides and Their Calcined Products

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  46. Multi-step removal mechanism of pyrophosphate using CaFe-layered double hydroxide at high pH

    Applied Clay Science · 2014-12-27

    Jizhi Zhou, Xiaoman Li, Wentao Li, Wei Jie Feng, Yongwen Su, Jia Zhang, Zhi Ping Xu, Guangren Qian

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  47. Effects of hydrotalcite intercalated with corrosion inhibitor on cathodic disbonding of epoxy coatings

    Journal of Coatings Technology and Research · 2015-01-13

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  48. Mechanism of boron uptake by hydrocalumite calcined at different temperatures

    Journal of Hazardous Materials · 2015-01-30

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  49. Enhanced removal of phosphate by hydrocalumite: synergism of AlPO4 and CaHPO4·2H2O precipitation

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  50. Surface modification and dissolution behavior of Mg–Al hydrotalcite particles

    Journal of the Taiwan Institute of Chemical Engineers · 2015-04-27

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