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RESEARCH PAPER · Journal of Solid State Chemistry · 2005

Influence of metal ions on the structures of Keggin polyoxometalate-based solids: Hydrothermal syntheses, crystal structures and magnetic properties

Zhenyu Shi, Jun Peng, Carlos J. Gómez‐García, Samia Benmansour, Xiaojun Gu

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Influence of metal ions on the structures of Keggin polyoxometalate-based solids: Hydrothermal syntheses, crystal structures and magnetic propertiesOriginalSyntheses, structures and physical characterization of two new three-dimensional mixed-valence hexadecavanadate derivatives15A novel oxovanadate structural type – Synthesis, single crystal structure and magnetic properties of a mixed-valence polyoxovanadate formed by {V17O40(Cl)} and {V15O36(Cl)} clusters17Controlled assembly of two novel 3D hexad-supporting Keggin-polyoxometalate derivatives: {[Cu(4,4′-bipy)]3[HnXW12O40]}[4,4′-bipy]·2H2O (X=P, n=0; X=Si, n=1)8Self-assembly of two novel bisupporting Keggin-polyoxometalate derivatives: Hydrothermal synthesis and structure characterization of (X=P, m=1; X=Si, m=2)19Spin qubits with electrically gated polyoxometalate molecules429Hydrothermal synthesis and characterization of (N(C2H5)4)4[VMo12V2O44]6High-Dimensional Assembly Depending on Polyoxoanion Templates, Metal Ion Coordination Geometries, and a Flexible Bis(imidazole) Ligand168A new CuII(4,5-diazafluoren-9-one)-capped Keggin derivative: Hydrothermal synthesis and crystal characterization20Extended Architectures Constructed from Sandwich Tetra‐Metal‐Substituted Polyoxotungstates and Transition‐Metal Complexes71Supramolecular Isomerism with Polythreaded Topology Based on [Mo8O26]4- Isomers149Inorganic–organic hybrid materials with different dimensions constructed from copper–fluconazole metal–organic units and Keggin polyanion clusters54The aryl–phen and phen–phen embraces—new supramolecular motifs9New coordination polymers based on a novel polynitrile ligand: Synthesis, structure and magnetic properties of the series [M(tcnoetOH)2(4,4′-bpy)(H2O)2] (tcnoetOH−= [(NC)2CC(OCH2CH2OH)C(CN)2]−; M = Fe, Co and Ni)29Assembly of the Highest Connectivity Wells-Dawson Polyoxometalate Coordination Polymer: the Use of Organic Ligand Flexibility227Hydrothermal syntheses and crystal structures of hybrid materials based on Keggin cluster modified by iron complexes11A novel polynitrile ligand with different coordination modes: Synthesis, structure and magnetic properties of the series [M(tcnoprOH)2(H2O)2] (M=Mn, Co and Cu) (tcnoprOH−=[(NC)2CC(OCH2CH2CH2OH)C(CN)2]−)28Target Syntheses of Two New Bivanadyl Capped Keggin Polyoxometalate Derivatives9Two new supramolecular assemblies based on Keggin-type polyoxometalates through Ag...O and π...π stacking interactions19Extended Organic—Inorganic Hybrids Based on Dawson and Double-Dawson-Type Polyoxometalates56Self-Assembly of Polyoxometalate-Based Metal Organic Frameworks Based on Octamolybdates and Copper-Organic Units: from CuII, CuI,II to CuI via Changing Organic Amine219A Co-monosubstituted Keggin polyoxometalate with an antenna ligand and three cobalt(II) chains as counterion38Combination of POMs and deliberately designed macrocations: a rational approach for synthesis of POM-pillared metal–organic framework30Assembly of Multiply Chain-Modified Polyoxometalates: From One- to Three-Dimensional and from Finite to Infinite Track68Hydrothermal Syntheses, Crystal Structures, And Magnetic Properties of a Series of Complexes Constructed from Multinuclear Copper Clusters and Polyoxometalates55Two extended organic–inorganic hybrids based on sandwich tungstogermanates12Two new CuI(4,5-diazafluoren-9-one)2-modified compounds based on the Keggin anion and its bicapped bisupporting derivative3Synthesis, structural aspects and magnetic properties of an unusual 2D thiocyanato-bridged cobalt(II)–Schiff base network40Two new organic–inorganic hybrid compounds based on metal–pyrazine coordination polymers and Keggin polyoxometalates: effect of metal ions on thestructure31Isolation of four new CoII/CoIII and NiII complexes with a pentadentate Schiff base ligand: syntheses, structural descriptions and magnetic studies65Building block approach to a series of substituted Keggin-type inorganic–organic hybrids16Assembly of a New 3D Octamolybdate‐based Compound: Using the Flexible Bis(triazole) ligand with a –(CH2)6– Spacer4Rational addition of capping groups to the phosphomolybdate Keggin anion [PMo12O40]3− by mild, non-aqueous reductive aggregation30Highly dispersed platinum in metal organic framework NH2-MIL-101(Al) containing phosphotungstic acid – Characterization and catalytic performance159Cobalt Electrolyte/Dye Interactions in Dye-Sensitized Solar Cells: A Combined Computational and Experimental Study220Assembly of copper–tetrazole frameworks with role-changeable Keggin clusters: syntheses, structures, solvent-dependent luminescence and electrochemistry properties36Assembly of Cu/Ag-quinoxaline-polyoxotungstate hybrids: Influence of Keggin and Wells–Dawson polyanions on the structure10A new organopolymolybdate polymer for linking metal-organic moiety through Mo–N bonds8Five inorganic–organic hybrids based on Keggin polyanion [SiMo12O40]4−: From 0D to 2D network26Ligand mediated valence fluctuation of copper in new hybrid materials constructed from decavanadate and a Cu(1,10-phenanthroline) complex17Assembly of co-bimb-polyoxotungstate hybrids: from 1D chain to 3D framework influenced by the charge of Keggin anions25Tuning the dimension of POM-based inorganic–organic hybrids from 3D self-penetrating framework to 1D poly-pendant chain via changing POM clusters and introducing secondary spacers34Supramolecular 2D/3D Isomerism in a Compound Containing Heterometallic CuII2CoII Nodes and Dicyanamide Bridges40Two new hybrid compounds assembled from Keggin phosphotungstates, cobalt/zinc cations and V-shaped imidazole ligands11Decavanadates decorated with [Cu(en)2]2+: Convenient synthetic route, crystal structures and analysis of vibrational spectra19Modulating the polyoxometalate-based inorganic–organic hybrids from simple chains to complicated frameworks via changing POM clusters9Assembly of hybrids based on polyoxotungstates and Co-tris(imidazolyl) complexes with bifunctional electrocatalytic activities22Tuning the topology structures of polymolybdate-based hybrids from interpenetrated framework to interdigitated architecture via changing polymolybdate clusters14Syntheses and electrochemical properties of three supramolecular architectures based on Keggin silicontungstates and different metal-organic units1Assistant effect on modulating the two Mn(II) complexes1A Layered Manganese(IV)-Containing Heteropolyvanadate with a 1:14 Stoichiometry15A Spin Crossover Transition in a Mn(II) Chain Compound26Synthesis, magnetism and spectral studies of six defective dicubane tetranuclear {M 4 O 6 } (M = Ni II , Co II , Zn II ) and three trinuclear Cd II complexes with polydentate Schiff base ligands46Synthesis and characterization of a novel polyoxometalate–Cu(II) hybrid catalyst for efficient synthesis of triazols17Synthesis and characterization of a novel dicyanamide-bridged Co(II) 1-D coordination polymer with a N4-donor Schiff base ligand11Iron( ii ) and cobalt( ii ) complexes based on anionic phenanthroline-imidazolate ligands: reversible single-crystal-to-single-crystal transformations0Synthesis, structures and applications of electron-rich polyoxometalates683Preparation of inorganic–organic nanohybrid compound based on NiII, MoO3 and p-phenylenediamine by hydrothermal method and its photoluminescence property0Role of hydrogen-bonds in the crystal packing of three novel strandberg-type polyoxoanion compounds8Recent progresses on synthesis, structures and applications of reduced polyoxometalates with low-nuclearity4Field-induced single molecule magnet behavior of a dinuclear cobalt( ii ) complex: a combined experimental and theoretical study27Crystal Structure and Magnetic Properties of a New Wells-Dawson [β-P2CoW17O62]10− Polyoxoanion2Polyoxometalate-based inorganic-organic hybrids based on a half rigid N-heterocyclic carboxylate ligand: Syntheses, structures and properties6Strategies for the Photoreduction of Tc‐99 Pertechnetate to Low‐Valent Tc by Keggin Polyoxometalates5[(V IV O) 2 MII5] (M = Ni, Co) Anderson wheels4Synthesis and characterization of a novel coordination compound based on 2, 6-dimethylpiperazine1Two new 2D POMOFs based on octamolybdate/copper substituted keggin polymolybdate for enhancing electrochemical capacitor performance18Constructing Molecular Junctions with High-Spin Metal Sites in POMOFs to Trigger Heteropoly Blue States for Photocatalytic H2 Production51Magnetic ordering of mixed-valence tetranuclear coordination cobalt clusters via loss of coordinated solvent supported by powder XRD measurements0

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  1. Syntheses, structures and physical characterization of two new three-dimensional mixed-valence hexadecavanadate derivatives

    Journal of Molecular Structure · 2006-06-20

    Bao‐Xia Dong, Carlos J. Gómez‐García, Jun Peng, Samia Benmansour, Yumei Kong

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  2. A novel oxovanadate structural type – Synthesis, single crystal structure and magnetic properties of a mixed-valence polyoxovanadate formed by {V17O40(Cl)} and {V15O36(Cl)} clusters

    Polyhedron · 2006-11-14

    Bao‐Xia Dong, Carlos J. Gómez‐García, Jun Peng, Samia Benmansour, Jian‐Fang Ma

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  3. Controlled assembly of two novel 3D hexad-supporting Keggin-polyoxometalate derivatives: {[Cu(4,4′-bipy)]3[HnXW12O40]}[4,4′-bipy]·2H2O (X=P, n=0; X=Si, n=1)

    Journal of Molecular Structure · 2007-02-07

    Jing‐Quan Sha, Jun Peng, Hongsheng Liu, Bo Xue, Jing Chen, Aixiang Tian, Bao‐Xia Dong, Pengpeng Zhang

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  4. Self-assembly of two novel bisupporting Keggin-polyoxometalate derivatives: Hydrothermal synthesis and structure characterization of (X=P, m=1; X=Si, m=2)

    Journal of Molecular Structure · 2007-02-07

    Jing Chen, Jing‐Quan Sha, Jun Peng, Zhenyu Shi, Bao‐Xia Dong, Aixiang Tian

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  5. Spin qubits with electrically gated polyoxometalate molecules

    Nature Nanotechnology · 2007-05-01

    J. Lehmann, Alejandro Gaita‐Ariño, Eugenio Coronado, Daniel Loss

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  6. Hydrothermal synthesis and characterization of (N(C2H5)4)4[VMo12V2O44]

    Crystal Research and Technology · 2007-06-14

    Sabri Çevik, Z. Alkan, M. Poyraz, Musa Sarı, Orhan Büyükgüngör

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  7. High-Dimensional Assembly Depending on Polyoxoanion Templates, Metal Ion Coordination Geometries, and a Flexible Bis(imidazole) Ligand

    Inorganic Chemistry · 2007-06-26

    Bao‐Xia Dong, Jun Peng, Carlos J. Gómez‐García, Samia Benmansour, Heng‐Qing Jia, Ninghai Hu

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  8. A new CuII(4,5-diazafluoren-9-one)-capped Keggin derivative: Hydrothermal synthesis and crystal characterization

    Inorganica Chimica Acta · 2007-09-07

    Aixiang Tian, Zhangang Han, Jun Peng, Jun Ying, Jingquan Sha, Bao‐Xia Dong, Jiangli Zhai, Hongsheng Liu

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  9. Extended Architectures Constructed from Sandwich Tetra‐Metal‐Substituted Polyoxotungstates and Transition‐Metal Complexes

    Chemistry - An Asian Journal · 2007-09-18

    Shou‐Tian Zheng, Ming‐Hui Wang, Guo‐Yu Yang

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  10. Supramolecular Isomerism with Polythreaded Topology Based on [Mo8O26]4- Isomers

    Inorganic Chemistry · 2007-12-15

    Ya‐Qian Lan, Li, Xinlong Wang, Kui‐Zhan Shao, Zhong‐Min Su, Enbo Wang

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  11. Inorganic–organic hybrid materials with different dimensions constructed from copper–fluconazole metal–organic units and Keggin polyanion clusters

    Dalton Transactions · 2008-01-01

    Shun‐Li Li, Ya‐Qian Lan, Jian‐Fang Ma, Jin Zhong Yang, Jie Liu, Yao-Mei Fu, Zhong‐Min Su

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  12. The aryl–phen and phen–phen embraces—new supramolecular motifs

    CrystEngComm · 2008-01-01

    Edwin C. Constable, Valérie Chaurin, Catherine E. Housecroft, Markus A. Neuburger, Silvia Schaffner

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  13. New coordination polymers based on a novel polynitrile ligand: Synthesis, structure and magnetic properties of the series [M(tcnoetOH)2(4,4′-bpy)(H2O)2] (tcnoetOH−= [(NC)2CC(OCH2CH2OH)C(CN)2]−; M = Fe, Co and Ni)

    Inorganica Chimica Acta · 2008-03-05

    Samia Benmansour, Fatima Setifi, Carlos J. Gómez‐García, Smaı̈l Triki, Eugenio Coronado

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  14. Assembly of the Highest Connectivity Wells-Dawson Polyoxometalate Coordination Polymer: the Use of Organic Ligand Flexibility

    Inorganic Chemistry · 2008-03-11

    Aixiang Tian, Jun Ying, Jun Peng, Jing‐Quan Sha, Zhangang Han, Jian‐Fang Ma, Zhong‐Min Su, Ninghai Hu, Heng‐Qing Jia

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  15. Hydrothermal syntheses and crystal structures of hybrid materials based on Keggin cluster modified by iron complexes

    Journal of Coordination Chemistry · 2008-04-20

    Jingquan Sha, Jun Peng, Hongsheng Liu, Jing Chen, Aixiang Tian, Bao‐Xia Dong, Pengpeng Zhang

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  16. A novel polynitrile ligand with different coordination modes: Synthesis, structure and magnetic properties of the series [M(tcnoprOH)2(H2O)2] (M=Mn, Co and Cu) (tcnoprOH−=[(NC)2CC(OCH2CH2CH2OH)C(CN)2]−)

    Journal of Molecular Structure · 2008-05-04

    Samia Benmansour, Fatima Setifi, Carlos J. Gómez‐García, Smaı̈l Triki, Eugenio Coronado, J.-Y. Salaun

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  17. Target Syntheses of Two New Bivanadyl Capped Keggin Polyoxometalate Derivatives

    Journal of Cluster Science · 2008-06-19

    Jingquan Sha, Jun Peng, Shujing Zhou, Min Zhu, Ling Li Han, Dan Chen

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  18. Two new supramolecular assemblies based on Keggin-type polyoxometalates through Ag...O and π...π stacking interactions

    Journal of Molecular Structure · 2008-06-29

    Jing Chen, Jingquan Sha, Jun Peng, Zhenyu Shi, Aixiang Tian, Pengpeng Zhang

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  19. Extended Organic—Inorganic Hybrids Based on Dawson and Double-Dawson-Type Polyoxometalates

    Inorganic Chemistry · 2008-08-05

    Zhiming Zhang, Yangguang Li, Yonghui Wang, Yanfei Qi, Enbo Wang

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  20. Self-Assembly of Polyoxometalate-Based Metal Organic Frameworks Based on Octamolybdates and Copper-Organic Units: from CuII, CuI,II to CuI via Changing Organic Amine

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    Ya‐Qian Lan, Shun‐Li Li, Xinlong Wang, Kui‐Zhan Shao, Dong‐Ying Du, Hong‐Ying Zang, Zhong‐Min Su

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  21. A Co-monosubstituted Keggin polyoxometalate with an antenna ligand and three cobalt(II) chains as counterion

    Inorganica Chimica Acta · 2008-09-19

    Hongsheng Liu, Carlos J. Gómez‐García, Jun Peng, Jingquan Sha, Lixia Wang, Yechao Yan

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  22. Combination of POMs and deliberately designed macrocations: a rational approach for synthesis of POM-pillared metal–organic framework

    Dalton Transactions · 2008-12-16

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  23. Assembly of Multiply Chain-Modified Polyoxometalates: From One- to Three-Dimensional and from Finite to Infinite Track

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  24. Hydrothermal Syntheses, Crystal Structures, And Magnetic Properties of a Series of Complexes Constructed from Multinuclear Copper Clusters and Polyoxometalates

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  25. Two extended organic–inorganic hybrids based on sandwich tungstogermanates

    Journal of Coordination Chemistry · 2009-07-28

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  26. Two new CuI(4,5-diazafluoren-9-one)2-modified compounds based on the Keggin anion and its bicapped bisupporting derivative

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  27. Synthesis, structural aspects and magnetic properties of an unusual 2D thiocyanato-bridged cobalt(II)–Schiff base network

    Inorganica Chimica Acta · 2010-08-03

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  28. Two new organic–inorganic hybrid compounds based on metal–pyrazine coordination polymers and Keggin polyoxometalates: effect of metal ions on thestructure

    Journal of Solid State Chemistry · 2010-10-02

    Feng‐Yun Cui, Xiaoyu Ma, Cong Li, Tao Dong, Yuanzhe Gao, Zhangang Han, Yingnan Chi, Changwen Hu

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  29. Isolation of four new CoII/CoIII and NiII complexes with a pentadentate Schiff base ligand: syntheses, structural descriptions and magnetic studies

    Dalton Transactions · 2011-01-01

    Sambuddha Banerjee, Madhusudan Nandy, Soma Sen, S. K. Mandal, Georgina M. Rosair, Alexandra M. Z. Slawin, Carlos J. Gómez‐García, J.M. Clemente-Juan, Ennio Zangrando, N. Guidolin, Samiran Mitra

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  30. Building block approach to a series of substituted Keggin-type inorganic–organic hybrids

    Solid State Sciences · 2011-01-20

    Dong‐Ying Du, Jun‐Sheng Qin, Gang Yuan, Ya‐Qian Lan, Xinlong Wang, Kui‐Zhan Shao, Zhong‐Min Su

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  31. Assembly of a New 3D Octamolybdate‐based Compound: Using the Flexible Bis(triazole) ligand with a –(CH2)6– Spacer

    Zeitschrift für anorganische und allgemeine Chemie · 2011-10-27

    Ai‐Xiang Tian, Xiaojing Liu, Guiying Liu, Jun Ying, Xiuli Wang

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  32. Rational addition of capping groups to the phosphomolybdate Keggin anion [PMo12O40]3− by mild, non-aqueous reductive aggregation

    Chemical Communications · 2012-01-01

    Ridla Bakri, Andrew Booth, Gavin Harle, Paul S. Middleton, Corinne Wills, W. Clegg, Ross W. Harrington, R. John Errington

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  33. Highly dispersed platinum in metal organic framework NH2-MIL-101(Al) containing phosphotungstic acid – Characterization and catalytic performance

    Journal of Catalysis · 2012-02-21

    Enrique V. Ramos–Fernández, Cyriel Pieters, Bart van der Linden, Jana Juan‐Alcañiz, Pablo Serra‐Crespo, Martinus W. G. M. Verhoeven, J. W. Niemantsverdriet, Jorge Gascón, Freek Kapteijn

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  34. Cobalt Electrolyte/Dye Interactions in Dye-Sensitized Solar Cells: A Combined Computational and Experimental Study

    Journal of the American Chemical Society · 2012-10-31

    Edoardo Mosconi, Jun‐Ho Yum, Florian Keßler, Carlos J. Gómez‐García, Cristiano Zuccaccia, Antonio Cinti, Mohammad Khaja Nazeeruddin, Michaël Grätzel, Filippo De Angelis

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  35. Assembly of copper–tetrazole frameworks with role-changeable Keggin clusters: syntheses, structures, solvent-dependent luminescence and electrochemistry properties

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  36. Assembly of Cu/Ag-quinoxaline-polyoxotungstate hybrids: Influence of Keggin and Wells–Dawson polyanions on the structure

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  37. A new organopolymolybdate polymer for linking metal-organic moiety through Mo–N bonds

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  38. Five inorganic–organic hybrids based on Keggin polyanion [SiMo12O40]4−: From 0D to 2D network

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  39. Ligand mediated valence fluctuation of copper in new hybrid materials constructed from decavanadate and a Cu(1,10-phenanthroline) complex

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  40. Assembly of co-bimb-polyoxotungstate hybrids: from 1D chain to 3D framework influenced by the charge of Keggin anions

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  41. Tuning the dimension of POM-based inorganic–organic hybrids from 3D self-penetrating framework to 1D poly-pendant chain via changing POM clusters and introducing secondary spacers

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  42. Supramolecular 2D/3D Isomerism in a Compound Containing Heterometallic CuII2CoII Nodes and Dicyanamide Bridges

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  43. Two new hybrid compounds assembled from Keggin phosphotungstates, cobalt/zinc cations and V-shaped imidazole ligands

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    Di Wu, Kun Wang, Huiyuan Ma, Haijun Pang, Tingting Yu, Zhuanfang Zhang, Shaobin Li, Heng Liu

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  44. Decavanadates decorated with [Cu(en)2]2+: Convenient synthetic route, crystal structures and analysis of vibrational spectra

    Polyhedron · 2014-07-07

    Mariia V. Pavliuk, Valeriya G. Makhankova, Oleksiy V. Khavryuchenko, Vladimir N. Kokozay, Irina V. Omelchenko, Олег В. Шишкин, Julia Jezierska

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  45. Modulating the polyoxometalate-based inorganic–organic hybrids from simple chains to complicated frameworks via changing POM clusters

    RSC Advances · 2014-09-30

    Yan Ping Yu, Huiyuan Ma, Haijun Pang, Li Zhang, Shaobin Li, Chunyan Zhao, Zhuanfang Zhang

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  46. Assembly of hybrids based on polyoxotungstates and Co-tris(imidazolyl) complexes with bifunctional electrocatalytic activities

    RSC Advances · 2015-01-01

    Wanli Zhou, Jun Peng, Zheyu Zhang, Zhenyu Shi, Aftab Ahmad Khan, Hongsheng Liu

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  47. Tuning the topology structures of polymolybdate-based hybrids from interpenetrated framework to interdigitated architecture via changing polymolybdate clusters

    New Journal of Chemistry · 2015-01-01

    Shaobin Li, Li Zhang, Huiyuan Ma, Haijun Pang, Chunyan Zhao

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  48. Syntheses and electrochemical properties of three supramolecular architectures based on Keggin silicontungstates and different metal-organic units

    Structural Chemistry · 2015-02-25

    Chunjing Zhang, Zhuanfang Zhang, Ying Guo, Heng Liu, Huiyuan Ma, Bo Liu, Haijun Pang, Shaobin Li

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  49. Assistant effect on modulating the two Mn(II) complexes

    Russian Journal of Coordination Chemistry · 2015-09-01

    J. Wang, Lijun Lu, A. Q. Ma, Wei-Ping Wu, Bin Xie, Yu Wu

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  50. A Layered Manganese(IV)-Containing Heteropolyvanadate with a 1:14 Stoichiometry

    Inorganic Chemistry · 2015-10-23

    Weiwei Guo, John Bacsa, Jan van Leusen, Kevin P. Sullivan, Hongjin Lv, Paul Kögerler, Craig L. Hill

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