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RESEARCH PAPER · Inorganic Chemistry · 2014

Straightforward Reductive Routes to Air-Stable Uranium(III) and Neptunium(III) Materials

Justin N. Cross, Eric M. Villa, Victoria R. Darling, Matthew J. Polinski, Jian Hung Lin, Xiaoyan Tan, Naoki Kikugawa, Michael Shatruk, Ryan Baumbach, Thomas E. Albrecht‐Schmitt

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Straightforward Reductive Routes to Air-Stable Uranium(III) and Neptunium(III) MaterialsOriginalChemInform Abstract: Straightforward Reductive Routes to Air‐Stable Uranium(III) and Neptunium(III) Materials.0Structure–Property Correlations in the Heterobimetallic 4f/3d Materials Ln2M(TeO3)2(SO4) (Ln = Y, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, or Lu; M = Co or Zn)25Inorganic Synthesis of Actinides3One-dimensional chain structures of hexanuclear uranium( iv ) clusters bridged by formate ligands9In Situ Reduction from Uranyl Ion into a Tetravalent Uranium Trimer and Hexamer Featuring Ion-Exchange Properties and the Alexandrite Effect16Electrochemical Studies of Selected Lanthanide and Californium Cryptates24Unexpected Roles of Alkali-Metal Cations in the Assembly of Low-Valent Uranium Sulfate Molecular Complexes15Emergence of a thorium–organic framework as a radiation attenuator for selective X-ray dosimetry20Synthesis and structural characterization of an air and water stable divalent Europium squarate prepared by in situ reduction7[AnI3(THF)4] (An = Np, Pu) Preparation Bypassing An0 Metal Precursors: Access to Np3+/Pu3+ Nonaqueous and Organometallic Complexes32Two Neptunium(III) Mellitate Coordination Polymers: Completing the Series Np–Cf of Trans-Uranic An(III) Mellitates13Chemical Kinetics for the Oxidation of Californium(III) Ions with Select Radiation-Induced Inorganic Radicals (Cl2•– and SO4•–)5Actinide Sulfate Structures from Caustic Solvents1Introducing dibenzocyclooctatetraene into actinide chemistry: isolation of rare trivalent uranium sandwich complexes3Structural Regularities, Thermal Stability, and Nature of Chemical Bonding in the Series of Actinide Double Sulfates Cs[An(SO4)2(H2O)3]·H2O (An = U, Np, Pu, or Am)3

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  1. ChemInform Abstract: Straightforward Reductive Routes to Air‐Stable Uranium(III) and Neptunium(III) Materials.

    ChemInform · 2014-09-11

    Thomas E. Albrecht‐Schmitt, et al. et al.

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  2. Structure–Property Correlations in the Heterobimetallic 4f/3d Materials Ln2M(TeO3)2(SO4) (Ln = Y, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, or Lu; M = Co or Zn)

    Crystal Growth & Design · 2015-08-14

    Jian Hung Lin, Kariem Diefenbach, Mark A. Silver, Naresh S. Dalal, Thomas E. Albrecht‐Schmitt

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  3. Inorganic Synthesis of Actinides

    Elsevier eBooks · 2017-01-01

    Wei‐Qun Shi, L. Mei, Zhifang Chai

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  4. One-dimensional chain structures of hexanuclear uranium( iv ) clusters bridged by formate ligands

    RSC Advances · 2018-01-01

    Jie Ling, Huangjie Lu, Yaxing Wang, Kenndra Johnson, Shuao Wang

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  5. In Situ Reduction from Uranyl Ion into a Tetravalent Uranium Trimer and Hexamer Featuring Ion-Exchange Properties and the Alexandrite Effect

    Inorganic Chemistry · 2018-05-24

    Jian Hung Lin, Zenghui Yue, Mark A. Silver, Meiying Qie, Xiaomei Wang, Wei Liu, Xiao Lin, Hongliang Bao, Linjuan Zhang, Shuao Wang, Jian‐Qiang Wang

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  6. Electrochemical Studies of Selected Lanthanide and Californium Cryptates

    Inorganic Chemistry · 2019-07-10

    Matthew L. Marsh, Frankie D. White, David S. Meeker, Carla D. McKinley, David Dan, Cayla E. Van Alstine, Todd N. Poe, Danielle L. Gray, David E. Hobart, Thomas E. Albrecht‐Schmitt

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  7. Unexpected Roles of Alkali-Metal Cations in the Assembly of Low-Valent Uranium Sulfate Molecular Complexes

    Inorganic Chemistry · 2020-02-04

    Zenghui Yue, Xiaofeng Guo, Mei‐Ling Feng, Yue‐Jian Lin, Yu Ju, Xiao Lin, Zhi‐Hui Zhang, Xiao-Jing Guo, Jian Hung Lin, Yuying Huang, Jian‐Qiang Wang

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  8. Emergence of a thorium–organic framework as a radiation attenuator for selective X-ray dosimetry

    Chemical Communications · 2021-01-01

    Zhaofa Zheng, Huangjie Lu, Xiaofeng Guo, Zhengyang Zhou, Yumin Wang, Zi‐Jian Li, Guoping Xiao, Yuan Qian, Jian Hung Lin, Jian‐Qiang Wang

    Read original paper ↗ ·

  9. Synthesis and structural characterization of an air and water stable divalent Europium squarate prepared by in situ reduction

    Journal of Solid State Chemistry · 2021-02-09

    Jason P. Stone, Elizabeth A. Decoteau, Matthew J. Polinski

    Read original paper ↗ ·

  10. [AnI3(THF)4] (An = Np, Pu) Preparation Bypassing An0 Metal Precursors: Access to Np3+/Pu3+ Nonaqueous and Organometallic Complexes

    Journal of the American Chemical Society · 2021-12-02

    Conrad A. P. Goodwin, Michael T. Janicke, Brian L. Scott, Andrew J. Gaunt

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  11. Two Neptunium(III) Mellitate Coordination Polymers: Completing the Series Np–Cf of Trans-Uranic An(III) Mellitates

    Inorganic Chemistry · 2022-10-25

    Nicholas Beck, Zhuanling Bai, Jacob P. Brannon, Daniela Gomez Martinez, Dennis Grödler, Brian N. Long, Todd N. Poe, Brian M. Rotermund, Thomas E. Albrecht-Schönzart, Joseph M. Sperling

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  12. Chemical Kinetics for the Oxidation of Californium(III) Ions with Select Radiation-Induced Inorganic Radicals (Cl2•– and SO4•–)

    The Journal of Physical Chemistry A · 2024-01-12

    Brian M. Rotermund, Stephen P. Mezyk, Joseph M. Sperling, Nicholas Beck, Hannah B. Wineinger, Andrew R. Cook, Thomas E. Albrecht-Schönzart, Gregory P. Horne

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  13. Actinide Sulfate Structures from Caustic Solvents

    Inorganic Chemistry · 2024-07-04

    Teagan F. M. Sweet, A. Kirstin Sockwell, Amy E. Hixon, Peter Carman Burns

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  14. Introducing dibenzocyclooctatetraene into actinide chemistry: isolation of rare trivalent uranium sandwich complexes

    Inorganic Chemistry Frontiers · 2024-10-15

    Ernesto Castellanos, Wei Su, Selvan Demir

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  15. Structural Regularities, Thermal Stability, and Nature of Chemical Bonding in the Series of Actinide Double Sulfates Cs[An(SO4)2(H2O)3]·H2O (An = U, Np, Pu, or Am)

    Inorganic Chemistry · 2025-02-18

    Tatiana R. Poliakova, Iurii M. Nevolin, Andrei A. Shiryaev, Alexander Fedoseev, Mikhail S. Grigoriev, А. А. Аверин, Vladislava Zubkova, Daniil Andreevich Novichkov, Alexander L. Trigub, Anna Krot, M. I. Volgin, Petr Igorevich Matveev

    Read original paper ↗ ·
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