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RESEARCH PAPER · Nature Communications · 2025

Upcycling polyolefins to methane-free liquid fuel by a Ru1-ZrO2 catalyst

Jicong Yan, Guanna Li, Zhanwu Lei, Xiaolu Yuan, Junting Li, Xiaoru Wang, Bo Wang, Bo Wang, Fuping Tian, Tao Hu, Lei Huang, Yujia Ding, Xiaoke Xi, Feng Zhu, Shuo Zhang, Jiong Li, Yu Chen, Ruiguo Cao, Xiang Wang, Xiang Wang

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Upcycling polyolefins to methane-free liquid fuel by a Ru1-ZrO2 catalystOriginalSynergistic effect of acidic sites and mesoporous confinement in Ce-doped Ru/SBA-15 catalysts for efficient hydrogenolysis of low-density polyethylene to liquid fuels7Upcycling of poly(ethylene terephthalate) waste plastics to terephthalonitrile6Synergistic Catalysis for Recycling and Upcycling of Plastics35The silent partner in catalysis: How support architectures dictate efficiency in polyolefin hydrogenolysis1Plasma catalytic hydrogenolysis of polyethylene to gasoline-range fuels over Sm/USY catalysts10ZrO2/Bi19S27Br3 Heterojunction with a Strong Coupled Interface for Efficient CO2 Photoreduction to Yield CH48Toward Sustainable Plastic Waste Valorization: Green Synergistic Catalytic Strategies for Plastic Upcycling12Plasma Catalysis for Plastic Waste Conversion into Value‐Added Products: Advancements and Perspectives11Single-atom Ru coupled with AlCl3 to promote asymmetric C-C coupling between CH4 and CO29Chemical recycling of polycarbonate waste into advanced aviation fuel candidates via nickel–oxygen vacancy dual sites4A review of recent advances in thermal-catalytic cracking of plastic waste8Recent developments in recycling technologies for polymeric plastics8Acidified montmorillonite (MMT)-supported ultrafine Ru nanoparticles for polyethylene plastic upcycling0Dual advantages of rapid zeolite channel diffusion and Ni sites: 1Ni/L-DAl zeolite enables efficient polyolefin hydrocracking to liquid fuel1Efficient oxidative upcycling of waste polyolefins into functional carboxylic acid additives over non-noble-metal catalysts1Enhancing aromatic yield by zeolites in polypropylene hydrocracking to jet fuel over Ru 1 -ZrO 2 without forming CH 40Highly selective hydrocracking of polypropylene to gasoline-range fuels over the Pt/MCM-22 catalyst0Highly selective production of gasoline-range hydrocarbons via hydroconversion of polyolefins over Ru/CeO 2 and BEA hybrid catalysts0Solvent-free recycling of polystyrene waste into valuable mono-aromatics over a Ni/NbO x catalyst0Synergistic pore-acidity engineering of hierarchical ZSM-5 for hydrogen-free upcycling of Polyethylene to C8–C12 Methylated Aromatics1Efficient depolymerization of polystyrene waste into styrene monomers over the microwave-assisted Zn/b-ZnO catalyst system1Acid sites in hydrogen-involved polyolefin upcycling: mechanistic insights and design principles0Hydrocracking Polyolefins to Jet Fuel over a NiW/WO x Catalyst2Acid Site Engineering of Ni/BEA Zeolites Enables Efficient Upcycling of Polyolefin Plastics to Liquid Fuels1Enhanced Fluorine Resistance and Catalytic Performance of the Zirconia-Supported Ru Single-Atom and WO x Cluster Catalysts for Elimination of the Typical Hydrofluorocarbon (HFC-134a)1Thermo-chemical upgrading of waste polyethylene and polypropylene plastics0Hydrogenolysis Versus Hydrocracking for Polyolefin Upcycling0Preparing methane‐resistant Ru catalysts via moderate metal‐support interactions for polyethylene hydrogenolysis0Catalytic Upcycling of Polyolefins and Polystyrene: Integrating Active Site Design With Mass Transfer Considerations4Mapping the influence of plastic feedstock characteristics on product selectivity from the co-pyrolysis with waste cooking oil for sustainable aviation fuel -range aromatic hydrocarbons2Selective Hydrocracking of Polystyrene without Solvent to Alkylbenzenes over a Single-Atom Catalyst Co1-Al2O33Oligomerization and co-oligomerization of waste polypropylene cracking products to sustainable aviation fuel components0Synergistic catalytic co-liquefaction of lignin and polyethylene in a water–pentane biphasic system: An efficient route to sustainable liquid fuels0Atomically precise catalysts design toward efficient waste plastic hydrogenolysis2Catalytic synergy between NiCl2 and NiSx in hydrodechlorination for plastic chemical recycling0Selective hydrogenolysis of waste polyolefins to aviation fuel over a Co‑modified Ni/SiO2 catalyst1Stepwise Hydrodeoxygenation of Mixed Oxygenated Plastics Enables Sequential Production of Jet- and Gasoline-Range Fuels0Unveiling the Cu-Ov-Ce sites for selective C–C bond cleavage in lignin β-O-4 and β-1 ketone models over CuOx/CeO2 catalysts0Quantitative Polyethylene Upcycling to Liquid Olefins over Ru-Containing Layered Zeolites0Visible-Light HAT Photocatalysis for Switchable Polyethylene Degradation and C–H Functionalization0Bridging barriers: Integrated process intensification and catalytic strategies for valorizing waste polyolefin plastics to hydrocarbon products0Mechanochemical AlCl3-Catalyzed Cracking of Waste Polyolefins and Synthetic Rubbers into Liquid Fuel0Role of molybdenum promotion in Ni/SiO2 catalysts for Polyolefins Hydrogenolysis0Highly active and selective heterogeneous Ru/La2O3-CeO2 catalyst for hydrogenolysis of LDPE to valuable chemicals0Efficient and Selective Low-Temperature Polypropylene Hydrogenolysis Using Zr-Doped Mixed Metal Oxides Catalysts0Selective Consecutive Decarboxylation Enables Skeletal Contraction of Waste PET0

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  1. Synergistic effect of acidic sites and mesoporous confinement in Ce-doped Ru/SBA-15 catalysts for efficient hydrogenolysis of low-density polyethylene to liquid fuels

    Catalysis Science & Technology · 2025-01-01

    Zhibin Ren, Zhicheng Luo, Huiyan Zhang

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  2. Upcycling of poly(ethylene terephthalate) waste plastics to terephthalonitrile

    Green Chemistry · 2025-01-01

    Phuc T.T. Nguyen, Jiong Cheng, Junyu Mi, Ning Yan

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  3. Synergistic Catalysis for Recycling and Upcycling of Plastics

    ACS Catalysis · 2025-05-07

    Hongshun Ran, Xinyang Sun, Mengying Zheng, Yaxuan Jing

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  4. The silent partner in catalysis: How support architectures dictate efficiency in polyolefin hydrogenolysis

    Nano Research · 2025-08-22

    Xueping Zhang, Wenli Wang, Mei Hong, Yamei Lin, Guoping Lu

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  5. Plasma catalytic hydrogenolysis of polyethylene to gasoline-range fuels over Sm/USY catalysts

    Applied Catalysis B: Environmental · 2025-09-08

    Chengxin Hou, Yanan Diao, Tianqi Yun, Jianhui Han, Tianhao Shi, Bingbing Chen, Chuan Shi

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  6. ZrO2/Bi19S27Br3 Heterojunction with a Strong Coupled Interface for Efficient CO2 Photoreduction to Yield CH4

    Transactions of Tianjin University · 2025-10-01

    Wei Ouyang, Junze Zhao, Junjiang Chen, Yuqing Wang, Min Xue, Yunwu Zhang, Zijie Gong, Jun Di, Sheng Yin, Jiexiang Xia

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  7. Toward Sustainable Plastic Waste Valorization: Green Synergistic Catalytic Strategies for Plastic Upcycling

    Advanced Sustainable Systems · 2025-10-10

    Luyao Zhang, Junliang Chen, Jinzhou Li, Jing Wu, Pin Gao, Jianping Yang

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  8. Plasma Catalysis for Plastic Waste Conversion into Value‐Added Products: Advancements and Perspectives

    Advanced Functional Materials · 2025-11-10

    Yanan Diao, Xuetao Qin, Chengxin Hou, Bingbing Chen, Tianqi Yun, Xinwen Guo, Ding Ma, Chuan Shi

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  9. Single-atom Ru coupled with AlCl3 to promote asymmetric C-C coupling between CH4 and CO2

    Nature Communications · 2025-11-18

    Ning Cao, Bing Qiang Huang, Ke Wang, Zhenglong Li, Mi Yan, Pengfei Xie

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  10. Chemical recycling of polycarbonate waste into advanced aviation fuel candidates via nickel–oxygen vacancy dual sites

    Green Chemistry · 2025-11-19

    Yushuang Huang, Jiawei Xie, Yisong Zhou, Qianqian Song, Yuan Lei, Changan Zhou, Chao Wang, Kui Ma, Lei Song, Hairong Yue, Ji‐Jun Zou

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  11. A review of recent advances in thermal-catalytic cracking of plastic waste

    Catalysis Science & Technology · 2025-11-27

    Zhongxu Wang, Jiahui Zhang, Qihao Wu, Quanhua Wang, Yi Liu, Jiajun Zheng, Yan Wang, Weijiong Dai, Ruifeng Li

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  12. Recent developments in recycling technologies for polymeric plastics

    Polymer Chemistry · 2025-12-29

    Zhihao Wang, En Fang, Liangyu Chen, Zhiqiang Fan, Shaofei Song

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  13. Acidified montmorillonite (MMT)-supported ultrafine Ru nanoparticles for polyethylene plastic upcycling

    Green Chemistry · 2026-01-01

    Ruoyan Bai, Roudan Lian, Jian Zhang, Maolin Zhang

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  14. Dual advantages of rapid zeolite channel diffusion and Ni sites: 1Ni/L-DAl zeolite enables efficient polyolefin hydrocracking to liquid fuel

    Green Chemistry · 2026-01-01

    Hongyu Fu, Huibin Liu, Abulikemu Abulizi, Kenji Okitsu, Yasuaki Maeda, Tiezhen Ren, Aisha Nulahong, Changhai Liang

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  15. Efficient oxidative upcycling of waste polyolefins into functional carboxylic acid additives over non-noble-metal catalysts

    Green Chemistry · 2026-01-01

    Yi Hao, Kaili Wang, Rongrong Jia, Ping Cheng, Xin Feng, Li Li, Guanna Li, Liyi Shi, Lei Huang

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  16. Enhancing aromatic yield by zeolites in polypropylene hydrocracking to jet fuel over Ru 1 -ZrO 2 without forming CH 4

    Catalysis Science & Technology · 2026-01-01

    Bo Wang, Huiwen Zhao, Jicong Yan, Li Han, Lihua Shi, HaiTao LIU, Tao Hu, Fuping Tian, Xiang Wang

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  17. Highly selective hydrocracking of polypropylene to gasoline-range fuels over the Pt/MCM-22 catalyst

    Catalysis Science & Technology · 2026-01-01

    Jiawei Xu, Huijuan Han, Y ZHAO, Qi Li, Rongyu Yang, Yuhan Yang, Hao Xu, Shichao Han, Xiaomin Tang, Longfeng Zhu, Qinming Wu, Jiusheng Li

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  18. Highly selective production of gasoline-range hydrocarbons via hydroconversion of polyolefins over Ru/CeO 2 and BEA hybrid catalysts

    Green Chemistry · 2026-01-01

    Junho Suh, Hyeongdong Jung, Junho Yoon, Jae‐Soon Choi, Jungup Bang, Do Heui Kim

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  19. Solvent-free recycling of polystyrene waste into valuable mono-aromatics over a Ni/NbO x catalyst

    Catalysis Science & Technology · 2026-01-01

    Zhen Yan, Leyang Qi, Jicong Yan, Qi Zhang, Fuping Tian, Xiang Wang

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  20. Synergistic pore-acidity engineering of hierarchical ZSM-5 for hydrogen-free upcycling of Polyethylene to C8–C12 Methylated Aromatics

    The Innovation Energy · 2026-01-01

    Bingyan Sun, Bo Li, Marc Mate, Linjia Yin, Qihui Song, Xiaopeng Shi, Dingran Wang, Fawei Lin, Kaige Wang

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  21. Efficient depolymerization of polystyrene waste into styrene monomers over the microwave-assisted Zn/b-ZnO catalyst system

    Journal of environmental chemical engineering · 2026-01-18

    Zijian Zhang, Bonan Liu, Li Yang, Jingwen Wang, Yuqing Dong, Chao Tang, Ping Wang, Haijiao Xie, Lei Zhang, Lu Zhang, Jun Zhao, Yu Fan, Wangjing Ma

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  22. Acid sites in hydrogen-involved polyolefin upcycling: mechanistic insights and design principles

    Science China Chemistry · 2026-01-27

    Qi Zhang, Xiang Wang

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  23. Hydrocracking Polyolefins to Jet Fuel over a NiW/WO x Catalyst

    ACS Catalysis · 2026-02-04

    Xiaoru Wang, Xiaoru Wang, Zhanwu Lei, Jicong Yan, Penglong Wang, Ruifeng Chong, Fuping Tian, Tao Hu, Ruiguo Cao, Xiang Wang, Xiang Wang

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  24. Acid Site Engineering of Ni/BEA Zeolites Enables Efficient Upcycling of Polyolefin Plastics to Liquid Fuels

    ChemSusChem · 2026-02-16

    张春华, Xinru Zhou, Xinlei Han, X.S. Lu, Zhengyan Qu, Jiuxuan Zhang, Feng Zeng, Hong Li Jiang, Zhenchen Tang, Rui Chen

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  25. Enhanced Fluorine Resistance and Catalytic Performance of the Zirconia-Supported Ru Single-Atom and WO x Cluster Catalysts for Elimination of the Typical Hydrofluorocarbon (HFC-134a)

    Environmental Science & Technology · 2026-02-16

    Qinpei Sun, Yuxi Liu, Xiaohui Yu, Linke Wu, Yiwen Jia, Zhuo Wang, Keying Shang, Zhiquan Hou, Jiguang Deng, Hongxing Dai

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  26. Thermo-chemical upgrading of waste polyethylene and polypropylene plastics

    Scientia Sinica Chimica · 2026-02-26

    Wanying Han, Longfei Lin, Buxing Han

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  27. Hydrogenolysis Versus Hydrocracking for Polyolefin Upcycling

    Engineering · 2026-03-01

    Ruoxi Zhang, Aaron David Sadow, Wenyu Huang

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  28. Preparing methane‐resistant Ru catalysts via moderate metal‐support interactions for polyethylene hydrogenolysis

    AIChE Journal · 2026-03-16

    Yiwei Fang, Yundao Jing, Jinquan Ming, Wenjie Wang, Weixiao Sun, Xiaohu Ge, Wenyao Chen, Gang Qian, Yueqiang Cao, Xuezhi Duan, Xinggui Zhou, Jing Zhang

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  29. Catalytic Upcycling of Polyolefins and Polystyrene: Integrating Active Site Design With Mass Transfer Considerations

    ChemSusChem · 2026-03-29

    Xinlei Han, Jie Sun, Jiuxuan Zhang, Zhengyan Qu, Hong Jiang, Zhenchen Tang, Rui Chen

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  30. Mapping the influence of plastic feedstock characteristics on product selectivity from the co-pyrolysis with waste cooking oil for sustainable aviation fuel -range aromatic hydrocarbons

    Journal of Cleaner Production · 2026-04-01

    L.J. Zhang, Qiuhao Wu, Haiping Yang, H G Chen, Roger R. Ruan, Jingai Shao, Yunpu Wang

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  31. Selective Hydrocracking of Polystyrene without Solvent to Alkylbenzenes over a Single-Atom Catalyst Co1-Al2O3

    ACS Catalysis · 2026-04-14

    Leyang Qi, Yujia Ding, Hongbo Xie, Jicong Yan, Chunsheng Bai, Fuping Tian, Qinge Fan, Ruifeng Chong, Tao Hu, H T Ma, Xiang Wang

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  32. Oligomerization and co-oligomerization of waste polypropylene cracking products to sustainable aviation fuel components

    Fuel · 2026-04-16

    Rita Skoda‐Földes, Dávid Ispán, Júlia Fütyű, Ágnes Szegedi, Anna Vikár, Hanna E. Solt, József Valyon, Ferenc Lónyi, Dominik Horváth, Ferenc Hőke, Jenő Hancsók

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  33. Synergistic catalytic co-liquefaction of lignin and polyethylene in a water–pentane biphasic system: An efficient route to sustainable liquid fuels

    Waste Management · 2026-05-22

    Shitong Yu, Zhitong Ge, Samudrala Shanthi Priya, Kuen Kee Hyun, Saidakmalov Saidalo, Khusenov Arslonnazar, Samir Ibrahim Gadow, Jun Xiao, Rui Xiao, Zhicheng Luo

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  34. Atomically precise catalysts design toward efficient waste plastic hydrogenolysis

    Nature Communications · 2026-06-06

    Zedong Zhang, Shijie Shen, Wenwu Zhong, Wen‐Gang Cui, Yaxiong Yang, Jia Wang, Shule Wang, Hongge Pan, Dingsheng S. Wang

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  35. Catalytic synergy between NiCl2 and NiSx in hydrodechlorination for plastic chemical recycling

    Chemical Engineering Journal · 2026-06-06

    Guangzheng Sun, Fengyu Tian, Xianfu Zeng, Zifan Wu, Shupeng Gao, Yidi Wang, Bin Dong, Bin Liu (5899), Yongming Chai

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  36. Selective hydrogenolysis of waste polyolefins to aviation fuel over a Co‑modified Ni/SiO2 catalyst

    Applied Catalysis B: Environmental · 2026-06-15

    Jiahui Zhan, Ruihong Dai, Baohuan Wei, Ting Sun, Hu Luo, Shumin Li, Xuan Huang, Haozhi Zhou, Lin Xia, Xiaofang Liu, Shunan Zhang, Shicheng Zhang, H J Wang, Shurong Wang, Yuhan Sun

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  37. Stepwise Hydrodeoxygenation of Mixed Oxygenated Plastics Enables Sequential Production of Jet- and Gasoline-Range Fuels

    Environmental Science & Technology · 2026-06-16

    Yue Zhu, Zhouying Mao, Pengfei An, Buxing Han, Qingqing Mei

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  38. Unveiling the Cu-Ov-Ce sites for selective C–C bond cleavage in lignin β-O-4 and β-1 ketone models over CuOx/CeO2 catalysts

    Journal of Catalysis · 2026-06-22

    Xin Qu, Qunfeng Chen, Peng Zheng, Yuzhen Hu, Lungang Chen, Longlong Ma, Qi Zhang

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  39. Quantitative Polyethylene Upcycling to Liquid Olefins over Ru-Containing Layered Zeolites

    Journal of the American Chemical Society · 2026-07-03

    Malin Eqi, Yi Yang, Jiashuo Zheng, Guangjun Wu, Yuchao Chai, Landong Li

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  40. Visible-Light HAT Photocatalysis for Switchable Polyethylene Degradation and C–H Functionalization

    ACS Macro Letters · 2026-07-10

    Manish Kumar, Zhisheng Lin, Stephen Don Sarkar, Eva M. Harth, Cyrille Andre Boyer

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  41. Bridging barriers: Integrated process intensification and catalytic strategies for valorizing waste polyolefin plastics to hydrocarbon products

    Green Energy & Environment · 2026-09-01

    Ruizhe Chen, Leilei Cheng, Wenbo Zhang, Jiajun Li, Jing Gu, Haoran Yuan, Yong Chen

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  42. Mechanochemical AlCl3-Catalyzed Cracking of Waste Polyolefins and Synthetic Rubbers into Liquid Fuel

    ACS Sustainable Chemistry & Engineering · 2026-09-07

    Xiaojuan Zhao, Lizheng Chen, Wenjuan Zhang, Gang Liu, Dayang Wang

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  43. Role of molybdenum promotion in Ni/SiO2 catalysts for Polyolefins Hydrogenolysis

    Chemical Engineering Journal · 2026-09-14

    Xiyan Huang, Muhammad Waseem, Weiyang Xue, Antonija Grubišić Čabo, Songbo He, Jessi E. S. van der Hoeven, Hero Jan Heeres, Jingxiu Xie

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  44. Highly active and selective heterogeneous Ru/La2O3-CeO2 catalyst for hydrogenolysis of LDPE to valuable chemicals

    Chemical Engineering Journal · 2026-09-18

    Zichen Peng, S. M. A. Hakim Siddiki, Yusuke Kita, Pengru Chen, Masazumi Tamura

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  45. Efficient and Selective Low-Temperature Polypropylene Hydrogenolysis Using Zr-Doped Mixed Metal Oxides Catalysts

    ACS Catalysis · 2026-09-21

    Frederick Z.T. Yang, Haokun Wang, Roland C. Turnell‐Ritson, Dermot O’Hare

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  46. Selective Consecutive Decarboxylation Enables Skeletal Contraction of Waste PET

    Journal of the American Chemical Society · 2026-10-10

    Yue Zhu, Zhouying Mao, Buxing Han, Qingqing Mei

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