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RESEARCH PAPER · Chemistry of Materials · 2024

Birefringence Disparity Induced by Synergistic Effects of Stereochemically Active Lone Pairs

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Birefringence Disparity Induced by Synergistic Effects of Stereochemically Active Lone PairsOriginalHelical ammonium halide framework constituting polar conglomerate crystals of 2-ethylanilinium chloride3Synergistic engineering of ultraviolet metal-free crystals with exceptional birefringence via pyridine-derived dimers14Violet light excitable organic halides with short ∼ns emissions for multiple optoelectronic applications0β-LaTeBO 5 and RETeBO 5 (RE = Y, Gd, Tb): explorations of new optical materials in the RE( iii )–Te( iv )–B–O system7Recent progress in structural design strategies of high-birefringence optical crystals54[K2PbI][Ga7Se12]: A New Lead-Containing Nonlinear Optical Material with Moderate Second-Harmonic Generation Response and Large Birefringence5Nonlinear Optical Series A(VO2)3(SeO3)2 (A = NH4+, K+, and H3O+) with Large Birefringence Derived from High-Anisotropic VO6 Octahedra and SeO3 Pyramids8Designing High-Performance Short-Wave UV Tellurium-Based Mixed Halides Birefringent Crystals via Halogen Substitution Engineering4NH4B5O7(OH)2 and CsRbB10O14(OH)4·H2O: Two Hydroxyborates Feature Significant Optical Anisotropy and Contain 1∞[B5O7(OH)2] Chains1Achieving the birefringence-bandgap trade-off: Hydrogen-bond engineered biuret-cyanurate14CaYIIIS 4 (III = Ga, In): Two Olivine-Type Compounds Exhibiting Exceptional Birefringence Properties1Sb 2 (SeO 3 ) 2 SeO 4 : A Selenite–Selenate Crystal with Balanced Band Gap and Birefringence3Anion-Centered Engineering for Simultaneously Enhancing Birefringence and Band Gap in Chalcogenides1V-Shaped Pseudo-Chains Coupled with Lone-Pair-Distorted [GeX 3 ] − Units Enable Large Birefringence in Ge(II) Hybrid Halides2Synergistic Enhancement of Optical Anisotropy in Nitrate Sulfamate for UV Applications: Role of Functional Group Alignment and Hydrogen Bond Network1Electronegativity Adaption Approach for Solar‐Blind UV Birefringent Crystals With Ultrawide Bandgaps2Electronegativity Adaption Approach for Solar‐Blind UV Birefringent Crystals With Ultrawide Bandgaps1Organic room-temperature phosphorescence materials6Halogen-Mediated Dimensionality Reduction in Bismuth Oxychlorides: Trade-off between Birefringence and Band Gap0

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  1. Helical ammonium halide framework constituting polar conglomerate crystals of 2-ethylanilinium chloride

    CrystEngComm · 2024-12-27

    Shohei Tashiro

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  2. Synergistic engineering of ultraviolet metal-free crystals with exceptional birefringence via pyridine-derived dimers

    Chemical Science · 2025-01-01

    Jiachen Lu, Kang Min Ok

    Read original paper ↗ ·
  3. Violet light excitable organic halides with short ∼ns emissions for multiple optoelectronic applications

    Materials Chemistry Frontiers · 2025-01-01

    Tianrui Zhou, Yunluo Wang, Zhiyu Qin, Ying Yang, Jianghua Wu, Jingshan Hou, Minghui Wang, Yongzheng Fang, Lianjun Wang, Haijie Chen, Wan Jiang

    Read original paper ↗ ·
  4. β-LaTeBO 5 and RETeBO 5 (RE = Y, Gd, Tb): explorations of new optical materials in the RE( iii )–Te( iv )–B–O system

    Inorganic Chemistry Frontiers · 2025-01-01

    Pengfei Chen, Chun‐Li Hu, Ming‐Zhi Zhang, Jiang‐Gao Mao

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  5. Recent progress in structural design strategies of high-birefringence optical crystals

    Coordination Chemistry Reviews · 2025-05-08

    A-Lan Xu, Mao‐Yin Ran, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  6. [K2PbI][Ga7Se12]: A New Lead-Containing Nonlinear Optical Material with Moderate Second-Harmonic Generation Response and Large Birefringence

    Crystal Growth & Design · 2025-05-22

    Jinlong Shi, Chunxiao Li, Pifu Gong, Jiyong Yao

    Read original paper ↗ ·
  7. Nonlinear Optical Series A(VO2)3(SeO3)2 (A = NH4+, K+, and H3O+) with Large Birefringence Derived from High-Anisotropic VO6 Octahedra and SeO3 Pyramids

    Inorganic Chemistry · 2025-06-23

    Qian Wu, Tianyu Wang, Jingfang Zhou, Pifu Gong, Haochen Li, Haotian Tian, Mingjun Xia

    Read original paper ↗ ·
  8. Designing High-Performance Short-Wave UV Tellurium-Based Mixed Halides Birefringent Crystals via Halogen Substitution Engineering

    Crystal Growth & Design · 2025-06-24

    Xiang Mao, Yu Yan, Yingzi Zhang, Xuehua Dong, Ling Huang, Liling Cao, Daojiang Gao, Guohong Zou

    Read original paper ↗ ·
  9. NH4B5O7(OH)2 and CsRbB10O14(OH)4·H2O: Two Hydroxyborates Feature Significant Optical Anisotropy and Contain 1∞[B5O7(OH)2] Chains

    Inorganic Chemistry · 2025-07-17

    Xueli Du, Haoran Wang, Haoran Liu, Qingyu Liu, Wenhu Wang, Jiahao Jiao, Yuchen Yan, Xueyan Wu, Min Zhang

    Read original paper ↗ ·
  10. Achieving the birefringence-bandgap trade-off: Hydrogen-bond engineered biuret-cyanurate

    Chinese Journal of Structural Chemistry · 2025-07-29

    Ziqi Chen, Miriding Mutailipu

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  11. CaYIIIS 4 (III = Ga, In): Two Olivine-Type Compounds Exhibiting Exceptional Birefringence Properties

    Inorganic Chemistry · 2025-08-21

    Chengbo Li, Haipeng Zhou, Y. Q. Chen, Jinfeng Liu, Xiu Zhu, Guisheng Xu, Jiankang Wang

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  12. Sb 2 (SeO 3 ) 2 SeO 4 : A Selenite–Selenate Crystal with Balanced Band Gap and Birefringence

    Crystal Growth & Design · 2025-12-25

    Han Bing Luo, Siyu Chen, Bailiang Li, Liling Cao, Xuehua Dong, Ling Huang, Guohong Zou

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  13. Anion-Centered Engineering for Simultaneously Enhancing Birefringence and Band Gap in Chalcogenides

    Chemistry of Materials · 2026-01-19

    Chao-Hong Xie, Lu Liu, Xiao‐Ming Jiang, Bin-Wen Liu, Guo‐Cong Guo

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  14. V-Shaped Pseudo-Chains Coupled with Lone-Pair-Distorted [GeX 3 ] − Units Enable Large Birefringence in Ge(II) Hybrid Halides

    Crystal Growth & Design · 2026-02-28

    Tiantian Wang, Lu Liu, Gangji Yi, Xiangyu Han, Xuehua Dong, Hongmei Zeng, Zhien Lin, Guohong Zou

    Read original paper ↗ ·
  15. Synergistic Enhancement of Optical Anisotropy in Nitrate Sulfamate for UV Applications: Role of Functional Group Alignment and Hydrogen Bond Network

    Small · 2026-04-09

    Xiaotian Ma, Hongyuan Sha, Qianzhen Zhang, Ruyi Niu, Xiya Wen, Xifa Long, Shilie Pan, Yun Mo Yang

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  16. Electronegativity Adaption Approach for Solar‐Blind UV Birefringent Crystals With Ultrawide Bandgaps

    Angewandte Chemie International Edition · 2026-04-23

    Xinwei Zhou, Zhiyong Bai, Ji Qi, Yuexin Zhang, Weiqi Huang, Yipeng Song, Yong Wang, Chang Liu, Sangen Zhao, Junhua Luo

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  17. Electronegativity Adaption Approach for Solar‐Blind UV Birefringent Crystals With Ultrawide Bandgaps

    Angewandte Chemie · 2026-04-23

    Xinwei Zhou, Zhiyong Bai, Ji Qi, Yuexin Zhang, Weiqi Huang, Yipeng Song, Yong Wang, Chang Liu, Sangen Zhao, Junhua Luo

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  18. Organic room-temperature phosphorescence materials

    Science China Chemistry · 2026-07-06

    Dan Liu, Zhengxu Cai, Yuping Dong, Jingyu Zhang, Runfeng Chen, Yi Chen, Zhenzhen Xu, Hongbing Fu, Zikai He, Jie Yang, Zhen Li, Xiang Ma, Qi Sun, Zhigang Shuai, Zijian Chen, Mengke Li, Shi‐Jian Su, Przemysław Data, Youhei Takeda, Jusaina Eyyathiyil, Pakkirisamy Thilagar, He‐Lou Xie, Yu Xiong, Zhenhong Qi, Dongpeng Yan, Haichao Liu, Bing Yang, Zi Wang, Chaolong Yang, Xinghuo Wang, Ying‐Wei Yang, Xiang Chen, Guangxin Yang, Wang Zhang Yuan, Shengnan Zou, Yong Zhang, Aoyuan Cheng, Guoqing Zhang, Kaka Zhang, Pengfei She, Qiang Zhao, Jingjing Guo, Y ZHAO, Hao Sun, Liangliang Zhu, Tao Wang, Eli Zysman‐Colman, Parvej Alam, Zheng Zhao, Ben Zhong Tang, Anjun Qin

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  19. Halogen-Mediated Dimensionality Reduction in Bismuth Oxychlorides: Trade-off between Birefringence and Band Gap

    Journal of Molecular Structure · 2026-08-03

    Huaiqiang Xun, Shumei Cao, Qingyue Cui, Yi Feng, Rui Wu, Chunmei Huang, Leyan Nian

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