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RESEARCH PAPER · Chemical Reviews · 2024

Advances in Nonreactive Polymer Compatibilizers for Commodity Polyolefin Blends

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Advances in Nonreactive Polymer Compatibilizers for Commodity Polyolefin BlendsOriginalCombining the Incompatible: Melt State Grafting between High-Density Polyethylene and Isotactic Polypropylene without a Coupling Agent14Integrated Ziegler–Natta/Brookhart‐Ni Catalysts for the Synthesis of Sutured Polar High‐Impact Polypropylenes3Integrated Ziegler–Natta/Brookhart‐Ni Catalysts for the Synthesis of Sutured Polar High‐Impact Polypropylenes9Polyolefin containing multi-block polymers and upcycling of mixed plastics10Sustainable, antifouling poly (ethylene furanoate)/ poly (lactic acid) (PEF/PLA) blend electrospun nanofibrous membranes for switchable premix emulsification/demulsification18Correlating chlorinated polyethylene molecular structure to compatibilization efficiency for mixed polymer waste1Plastic Polymer Blends and Alloys0Pyrolysis-based methods to upcycle plastic wastes to value-added carbons13Recent developments in recycling of post-consumer polyethylene waste33Recent research progress and applications of thermoplastic elastomers grafted compatibilizers in polymer blends and composites19Strategies to Improve the Compatibility of PET and PE Blends0Synthesis of butadiene-derived polyolefin graft copolymers and their crystallization behaviors4Upcycling of mixed polyolefin wastes to 3D structured carbon Joule heaters for decarbonized hydrogen production12Compatibilization of isotactic polypropylene (iPP) and polyethylene (PE) with PP-based olefin block copolymers11Robust, Reprocessable and Scalable Ethylene Acrylic Acid Copolymer (EAA) Derived Vitrimer Based on Dual Cross-linked Networks2Integrating Community Service into Student Learning: A Model Event of a Plastic Waste Cleanup2Super-Ductile, Ultra-Tough and High-Impact Polyolefin Alloys1Synthesis of highly effective polyester/polyacrylate compatibilizers using switchable polymerization15Single Catalyst with Dynamic Ligands Enabled Synthesis of Olefin Block Copolymers13Synthesis of Graft‐Modified Polyolefin Compatibilizers for Compatibilizing Mixed Plastics8Influence of Partial Disentanglement of Macromolecules on the Rheological, Thermal, and Mechanical Properties of Polypropylene–Polyethylene Blends4One-Step Radical-Induced Synthesis of Graft Copolymers for Effective Compatibilization of Polyethylene and Polypropylene29Synthesis of HDPE ‐ b ‐ i PP Diblock Copolymers via Subsequent Coordintive Chain‐Transfer Polymerization and Their Use as Compatibilizers for HDPE / i PP Blends2Skeletal Editing of Alkenes and Alkynes via Single‐Carbon‐Atom Insertion5Phase Behavior of Reversibly Bonding Polymer Blends9Identification of phase-separated structures and polymer crystals inside polyolefin blends4Polyolefin‐based Multiblock Copolymers from Cascade ROMP‐RAFT Polymerization0Polyolefin‐based Multiblock Copolymers from Cascade ROMP‐RAFT Polymerization12Enhancing interfacial compatibility and performance of polylactic Acid/ poly(butylene adipate-co-terephthalate) blends via innovative reactive compatibilization4Mechanical Recycling of Mixed Plastics by Supramolecular Dynamic Cross-Linking Strategy40Ethylene-propylene block copolymers featuring dual crystalline networks: high-performance elastomers and sustainable high-density polyethylene/isotactic polypropylene blends upcycling10Block copolymer molecular design to address practical limitations to recycling polyolefin blends12On-Demand Nonalternating Copolymerization Enables Upcycling of Mixed Polyethylene and Nylon Plastics14Autonomous discovery of functional random heteropolymer blends through evolutionary formulation optimization12An Approach Toward Achieving Greener Composites by Valorization of Waste and Other Underutilized Polymeric Materials1Compatibilization of iPP/PS Blends with Diblock and Triblock Copolymers4Incorporation of Oxime Functionality into Polyolefins via Iron-Catalyzed C–H Imidoylation4Molecularly engineered Janus nanosheets dual-anchored interfaces for multifunctional polylactic acid blends in intelligent packaging6Polymer Blend Spiking Method for Quantifying Polypropylene Variants in 100% Polypropylene Blends1Crystal structure, thermal, rheological and mechanical properties of self-reinforced melt-spun high- and low-density polyethylene blends3Efficient Compatibilization and Toughening of Polyethylene and Polypropylene Blends through Dynamic Cross-Linking: A Sustainable Approach to Polyolefin Recycling8Precision Oligomeric Building Blocks toward Chemically Recyclable Polyolefin-like Materials4One-Step Compatibilization and Upcycling of Mixed Polyolefins Using a Dynamic Disulfide-Linked Bismaleimide Cross-Linker7Research progress on compatibilizers for physical blending recycling of polyolefins0Dual‐Fluorophore Labeling for Polymer Blending Differentiation and Visualization0Segmented multiblock polyolefin compatibilizers from non-living metathesis chain-shuffling3From inert carbon chains to closed-loop recycling: emerging polyolefin chemistry enabled by telechelic (macro)monomers0Topological universal dynamic compatibilization enhances recycling of mixed plastics17Block Copolymers: Emerging Building Blocks for Additive Manufacturing3A synergistic compatibilization strategy for NBR/PA6 blends with ethylene–butadiene–fluorostyrene multiblock terpolymers0Machine learning approaches to predicting metal catalyst performance in olefin polymerization0Modifying Mechanical Performance of an LLDPE / PP Waste Blend During a Single Recycling Cycle Using Organometallic Complexes0Synergistic Compatibilization of LDPE/PS/PA6 Ternary Blends by Combining Reactive and Non‐Reactive Compatibilizers2Synthesis of topologically controlled functional polyethylenes: combining C–H activation with copolymerization of ethylene and polar monomers using a scandium catalyst0Synthesis of well-defined polyolefin graft copolymers based on single-site transition metal-mediated olefin polymerization0Unlocking intrinsically chiral bipyrenyl-based aggregation-induced emission luminogens: circularly polarized luminescence and dynamic chirality amplification12Compatibilization of Low Molecular Weight Polypropylene in High Molecular Weight Matrix Via Solvent Swelling4Circularity in polyethylene waste management through multidimensional integration3Compatibilization of Polyolefin Blends through Acid–Base Interactions4Aqueous chemi-mechanical recycling for blending, decolorizing, and purifying mixed polyolefins0C–H Insertion Functionalization of Polyolefins for Versatile Polyolefin-Polyester Compatibilization10Dynamic Covalent Chemistry Enables Self‐Healing and Compatibilization in Polypropylene Composites3Designing Resource-Efficient Polypropylene-Based Elastomers via Moderately Selective Catalyst for Toughening and Compatibilization0Fast-Dissociative and Slow-Associative Dual Dynamic Bonds Enable Self-Healing and Recyclable Polyethylene Networks for Sustainable High-Voltage Cable Insulation1Mechanical Property Evolution and Mechanisms of Polyolefins Under Thermo-Oxidative Aging2Polymer-Functionalized Nanocatalysts: Engineering Interfaces and Microenvironments for Enhanced Catalysis5Upcycling and Redesigning of Polyolefins3Cleavage Alkylation Coupling with Versatile Amide-Based Eutectic Catalytic Systems0In Situ Compatibilization of Polyethylene/Polypropylene Blends Enabled by Supramolecular Dynamic Cross-Linking for Efficient Upcycling4Interfacial engineering of biodegradable poly(lactic acid)/poly(ε-caprolactone) blends via reactive compatibilization for multifunctional performance0Chemically Recyclable Polyester Miscible with HDPE Transforms Contamination into Functional Enhancement0CO 2 -Based Polyalkenamer- g -Polycarbonate Graft Copolymers: One-Step Synthesis and Application as Highly Effective Polyolefin/Polycarbonate Compatibilizers0Molecular weight-directed interfacial localization of polystyrene-grafted silica nanoparticles for compatibilizing polyamide 6/polycarbonate blends0Salt-induced phase separation in a miscible polymethylmethacrylate/polyvinylidene fluoride blend0Diverse Functionalization of Nonpolar Polyolefins through Late-Stage Incorporation of Alkyl Bromides0Steric-bulk directed polymerization of ethylene to disentangled ultra-high molecular weight polyethylene1Tunable Hydrazination of sp 2 and sp 3 C–H Bonds of Polystyrenes with Fe( III )0Identifying the roots of property variability in post-consumer recycled polypropylene feedstocks2Additive-Free Compatibilization of Commodity Polypropylene/Polyethylene via Partial Melting and Recrystallization1C(sp2)–H functionalization with carbene intermediate0Impact of Commercial Polyolefin Architecture and Composition on Its Ability to Compatibilize High‐Density Polyethylene/Isotactic Polypropylene Blends0Strategies to Improve the Compatibility of Polyethylene Terephthalate and Polyethylene Blends0Covalent adaptable networks act as macromolecular compatibilizers: Insights from polypropylene/polyethylene blends0Switching the Crystallization Priority Component upon Fast-Cooling PE/PP Recycled Blend and Its CaCO 3 Composite0Ultrastrong Polyketone Hot-Melt Adhesives Enabled by Ni-Catalyzed Carbonylative Polymerization2Thermoplastic Post-Consumer Recyclates for Buried Infrastructure: Barriers, Classification Gaps, and a Path Toward Quality-Assured Use0Reprocessable Vitrimers From Post‐Consumer Polyolefin Blends: Elucidating Phase‐Selective Dynamic Networks0Accelerated Crystallization and Morphology Change by Surface‐Induced Nucleation in Polypropylene/Poly(butylene terephthalate) Blends1From polyolefins to functionally integrated materials: A review of lithium-ion battery separator innovations0Interface Engineering of PE/PP/ABS Ternary Blends: A Comparative Study on the Compatibilization Effects of Janus Nanosheets and POE- g -MAH0Strong adhesion of high-density polyethylene (HDPE) and isotactic polypropylene (iPP) with ethylene-styrene-butadiene (ESB) copolymers0Adhesion to untreated polypropylene by enhancing interfacial polymer chain entanglement0Too Much of a Good Thing? Thermodynamic Limits of Supramolecular Polymer Compatibilizers0The role of reactive extrusion in mechanical recycling of plastics in geographically isolated economies0A Miktoarm Star Copolymer as a “Chameleon” Compatibilizer for Polymer Blends0High-Temperature Tensile and Creep Behavior of Polypropylene/Poly(butylene terephthalate) Blends: Matrix Fibrillation and Interfacial Debonding0Decoupling Mechanical Performance and Macrophase Morphology in Compatibilized Polymer Blends0Synthesis of Ethylene–Styrene Copolymers by N ‑Heterocycle‑Fused Scandium Catalysts: Tuning Mechanical Properties and Enhancing LDPE/PS Compatibility0Recent Advances in Addition Copolymerization of Cyclobutenes0One-Step Reactive Branching for Compatibilization of PA6/PA66 Blends: Achieving Concurrent Improvements in Mechanical Properties, Foamability, and Creep Resistance0

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