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RESEARCH ARTICLE · Journal of the American Chemical Society · 2025

One-Step Radical-Induced Synthesis of Graft Copolymers for Effective Compatibilization of Polyethylene and Polypropylene

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One-Step Radical-Induced Synthesis of Graft Copolymers for Effective Compatibilization of Polyethylene and PolypropyleneOriginalMechanical Recycling of Mixed Plastics by Supramolecular Dynamic Cross-Linking Strategy40Tandem Polymerization of Comb-like iPP-g-PE Copolymers: Synthesis, Characterization, and Compatibilization of Isotactic Polypropylene and Polyethylene Blends3On-Demand Nonalternating Copolymerization Enables Upcycling of Mixed Polyethylene and Nylon Plastics14Sulfur Treatment of Coordinative Chain Transfer Polymerization Products for Extending Polyolefin Chains with Polysulfide Linkages3Efficient Compatibilization and Toughening of Polyethylene and Polypropylene Blends through Dynamic Cross-Linking: A Sustainable Approach to Polyolefin Recycling8Compatibilization of Polyethylene and Polypropylene via Dynamic Cross-Linking16One-Step Compatibilization and Upcycling of Mixed Polyolefins Using a Dynamic Disulfide-Linked Bismaleimide Cross-Linker7Dual‐Fluorophore Labeling for Polymer Blending Differentiation and Visualization0Recent developments in recycling technologies for polymeric plastics8A synergistic compatibilization strategy for NBR/PA6 blends with ethylene–butadiene–fluorostyrene multiblock terpolymers0Robust Grafting of Glycidyl Methacrylate on Polyethylene Powder via Surface-Initiated ATRP: A Facile Approach to Functional Polyolefins0Single-atom catalysts boost radical-mediated organic synthesis0Synergistic Compatibilization of LDPE/PS/PA6 Ternary Blends by Combining Reactive and Non‐Reactive Compatibilizers2Compatibilization of Polyolefin Blends through Acid–Base Interactions4Designing Resource-Efficient Polypropylene-Based Elastomers via Moderately Selective Catalyst for Toughening and Compatibilization0Hydrolyzable Graft Copolymers with In-Chain Esters from Polyethylene via Oxidative Chlorination1Unexpected Ductility Enhancement in Crystalline–Crystalline Polyolefin Diblock Copolymers without Introducing Soft Segments0In Situ Compatibilization of Polyethylene/Polypropylene Blends Enabled by Supramolecular Dynamic Cross-Linking for Efficient Upcycling4CO 2 -Based Polyalkenamer- g -Polycarbonate Graft Copolymers: One-Step Synthesis and Application as Highly Effective Polyolefin/Polycarbonate Compatibilizers0Direct Polymer-on-Polymer Grafting of Polyolefins under Visible Light2Polyolefin blends with co-continuous architectures enabled by dynamic covalent crosslinking2Synergistic Enhancement of Environmental Stress Crack Resistance and Mechanical Properties of HDPE via Reactive Blending‐Induced Disulfide‐Linked Covalent Networks1Additive-Free Compatibilization of Commodity Polypropylene/Polyethylene via Partial Melting and Recrystallization1One-Step Radical-Based Compatibilization of PE/PP Blends via Dynamic Covalent Crosslinking: Creating Interfacial Reversible Crosslinks and Utilizing Their Block- or Graft-like Structures as Compatibilizers2Covalent adaptable networks act as macromolecular compatibilizers: Insights from polypropylene/polyethylene blends0Visible-Light HAT Photocatalysis for Switchable Polyethylene Degradation and C–H Functionalization0Decoupling Mechanical Performance and Macrophase Morphology in Compatibilized Polymer Blends0Harnessing Composition and Sequence in Carbonylative Polymerization of Olefin for Tailored Material Properties0

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  2. Tandem Polymerization of Comb-like iPP-g-PE Copolymers: Synthesis, Characterization, and Compatibilization of Isotactic Polypropylene and Polyethylene Blends

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    Fei Yang, Chunjing Qv, Li Pan, Zhe Ma, Yue‐Sheng Li

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  3. On-Demand Nonalternating Copolymerization Enables Upcycling of Mixed Polyethylene and Nylon Plastics

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    Wenli Zhang, Shi‐Yu Chen, Xiao‐Bing Lu, Ye Liu

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  4. Sulfur Treatment of Coordinative Chain Transfer Polymerization Products for Extending Polyolefin Chains with Polysulfide Linkages

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  5. Efficient Compatibilization and Toughening of Polyethylene and Polypropylene Blends through Dynamic Cross-Linking: A Sustainable Approach to Polyolefin Recycling

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  6. Compatibilization of Polyethylene and Polypropylene via Dynamic Cross-Linking

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  7. One-Step Compatibilization and Upcycling of Mixed Polyolefins Using a Dynamic Disulfide-Linked Bismaleimide Cross-Linker

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  10. A synergistic compatibilization strategy for NBR/PA6 blends with ethylene–butadiene–fluorostyrene multiblock terpolymers

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  13. Synergistic Compatibilization of LDPE/PS/PA6 Ternary Blends by Combining Reactive and Non‐Reactive Compatibilizers

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    Guohua Wu, Ning Luo, Tianqi Jin, Hengti Wang, Yongjin Li, Lijun Ye

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  14. Compatibilization of Polyolefin Blends through Acid–Base Interactions

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    Yucheng Yuan, Jiawei He, Tuhin Ganguly, Yuhan Zhang, Brayan Rondon, Jiangwei Liu, Hashini Ranathunga, Ming-Chi Wang, John Santoro, J. Wang, Jeffery A. Byers, Jia Niu, Mingjiang Zhong, Dunwei Wang

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  15. Designing Resource-Efficient Polypropylene-Based Elastomers via Moderately Selective Catalyst for Toughening and Compatibilization

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    Hao Cai, Huixin Gao, Zhe Ma, Li Pan, Yue‐Sheng Li

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  16. Hydrolyzable Graft Copolymers with In-Chain Esters from Polyethylene via Oxidative Chlorination

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    Jaime J. M. Pang, Albert Ong, Wei Wei Loh, J H S Teo, Debbie Hwee Leng Seng, Lewis Queh, Li Zibiao, Jason Y. C. Lim

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  17. Unexpected Ductility Enhancement in Crystalline–Crystalline Polyolefin Diblock Copolymers without Introducing Soft Segments

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  18. In Situ Compatibilization of Polyethylene/Polypropylene Blends Enabled by Supramolecular Dynamic Cross-Linking for Efficient Upcycling

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  19. CO 2 -Based Polyalkenamer- g -Polycarbonate Graft Copolymers: One-Step Synthesis and Application as Highly Effective Polyolefin/Polycarbonate Compatibilizers

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  20. Direct Polymer-on-Polymer Grafting of Polyolefins under Visible Light

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  21. Polyolefin blends with co-continuous architectures enabled by dynamic covalent crosslinking

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  22. Synergistic Enhancement of Environmental Stress Crack Resistance and Mechanical Properties of HDPE via Reactive Blending‐Induced Disulfide‐Linked Covalent Networks

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    Yu Chen, Wei Tian, Yongjun Zhu, Qiang Xu, T M Li, Shibo Wang, J Q Huang, Weifu Dong

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  23. Additive-Free Compatibilization of Commodity Polypropylene/Polyethylene via Partial Melting and Recrystallization

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  24. One-Step Radical-Based Compatibilization of PE/PP Blends via Dynamic Covalent Crosslinking: Creating Interfacial Reversible Crosslinks and Utilizing Their Block- or Graft-like Structures as Compatibilizers

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  25. Covalent adaptable networks act as macromolecular compatibilizers: Insights from polypropylene/polyethylene blends

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  26. Visible-Light HAT Photocatalysis for Switchable Polyethylene Degradation and C–H Functionalization

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