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RESEARCH PAPER · Science Advances · 2024

Low-temperature dechlorination of polyvinyl chloride (PVC) for production of H 2 and carbon materials using liquid metal catalysts

Felipe Polo‐Garzon, Zili Wu, Yuanyuan Li, Junyan Zhang, Xinbin Yu, Elena Toups, Eddie Lopez Honorato, Joshua T. Damron, Jeffrey C. Foster, Yongqiang Q. Cheng, Luke L. Daemen, Anibal Javier Ramirez-Cuesta, Harry M. Meyer

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Low-temperature dechlorination of polyvinyl chloride (PVC) for production of H 2 and carbon materials using liquid metal catalystsOriginalUpcycling Polyethylene to High‐Purity Hydrogen under Ambient Conditions via Mechanocatalysis2Upcycling Polyethylene to High‐Purity Hydrogen under Ambient Conditions via Mechanocatalysis15Dynamic interface catalysis and carbon dioxide reduction of liquid metals4Upgrading polyolefin plastics: experiences from petroleum refining and distinct characteristics19Synergistic co-pyrolysis of polyvinyl chloride and corn stalk for improved products and dechlorination behavior9Graphene Derivative-Based Particulate Photocatalysts for Energy Conversion Applications: Current Achievements, Bottlenecks, and Future Outlook53Synergistic Catalysis for Recycling and Upcycling of Plastics35Three-stage thermochemical conversion of waste polyvinyl chloride4Poly(vinyl chloride) degradation: identification of acidic degradation products, their emission rates, and implications for heritage collections8Research and Application of Ga-Based Liquid Metals in Catalysis8Production of Polymer Monomers through Integrated Catalytic Approaches3Multifunctional Liquid Metal for Biomimicry Application0Degradation and utilization of polyvinyl chloride (PVC): Challenges and opportunities toward a circular economy24High‐Performance Electrochemical Chloride Ion Storage with Hierarchical Ternary Metal Hydroxides for Sustainable Water Purification4Chlorine release induced by contact electrification between polyvinyl chloride microplastics and moist air0A review of recent advances in thermal-catalytic cracking of plastic waste8Dechlorination of poly(vinyl chloride): thermal benchmarks and complementary non-thermal pathways toward sustainable recycling1Integrating chemical and biological conversion for waste plastics recycling and upcycling toward a circular bioeconomy0Microscopic Mechanism of Hydrogen Generation During Pyrolysis of the High-Voltage Cable PVC Outer Sheath0Study on electrical contact of a solid–liquid interface between a copper-based electrode and liquid metal1Hydrothermal Fenton-like process for dehydrochlorination and recovering of PVC pipe microplastics in aquatic systems4Recent advancements in catalytic processes for plastic upcycling into fuels: a major step in sustainable waste management and energy production3Elucidating the role of overlooked environmentally persistent free radicals and reactive chlorine species on photoaged chlorine-containing microplastics: New insights into formation mechanisms and health risks2Aggregation‐Induced Synergy in Photocatalysis: Enhanced Light Harvesting and Efficient Charge Separation3Electrocatalytic degradation strategies for plastic fibers with sustainable resource recovery potential4Interfacial configurational entropy tuning strategy enabling liquid alloys for efficient depolymerization of polyolefin waste2Structuring PVC circularity in the built environment: A systems-based ISM-MICMAC analysis0A Resilient In Situ Raman-Based Framework for Identifying Thermally Aged Microplastics: Validation in Waste-to-Energy Incineration0Phase separation in heritage objects made of plasticised PVC—the case of Joseph Beuys’ multiples0Upcycling waste thermoplastics into sulfur-doped hard carbon via sulfonation-assisted crosslinking for sodium/potassium-ion storage0Recent advances in catalytic technologies for plastic conversion: a review0Enhanced Catalytic Dechlorination of Polyvinyl Chloride (PVC) and H2 Production Enabled by Synergistic Gaδ+/Ga0 Active Sites in Liquid Metal Particles0Emerging Approaches for Dechlorination of Plastic Waste Prior to Thermochemical Recycling: A Comprehensive Review0Detoxification of Chlorinated Dioxins and Furans in Soils via One-Step, Self-Sustaining Smoldering0Challenges in polyolefin re/upcycling catalysis specific to polymer feedstock0

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  1. Upcycling Polyethylene to High‐Purity Hydrogen under Ambient Conditions via Mechanocatalysis

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  2. Upcycling Polyethylene to High‐Purity Hydrogen under Ambient Conditions via Mechanocatalysis

    Angewandte Chemie International Edition · 2024-11-11

    Rui Gu, Tonghui Wang, Yue Ma, Tong‐Xing Wang, Rui‐Qi Yao, Yingnan Zhao, Zi Wen, Gao‐Feng Han, Xingyou Lang, Qing Jiang

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  3. Dynamic interface catalysis and carbon dioxide reduction of liquid metals

    Dalton Transactions · 2025-01-01

    Jiajun Gu, Yanyang Zhang, Yinjun Zhang, Lianwei Shan, Haitao Wu, Huanyan Xu, Dan Li, Xiulan He, Limin Dong

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  4. Upgrading polyolefin plastics: experiences from petroleum refining and distinct characteristics

    Science China Chemistry · 2025-03-19

    Rongxin Zhang, Guangchao Deng, Zhuoyang Jiang, Yiyi Fan, Yanqi Guo, Zhongwen Dong, Wenjun Chen, Bo Peng, Fan Zhang

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  5. Synergistic co-pyrolysis of polyvinyl chloride and corn stalk for improved products and dechlorination behavior

    Journal of Cleaner Production · 2025-04-14

    Yongfu Zeng, Enzheng Hu, Guangwen Xu, Zuohua Liu, Guocan Zheng, Dean Pan, Jianglong Yu, Xin Jia, Moshan Li, Youcai Ma

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  6. Graphene Derivative-Based Particulate Photocatalysts for Energy Conversion Applications: Current Achievements, Bottlenecks, and Future Outlook

    ACS Applied Energy Materials · 2025-05-01

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  7. Synergistic Catalysis for Recycling and Upcycling of Plastics

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  8. Three-stage thermochemical conversion of waste polyvinyl chloride

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  9. Poly(vinyl chloride) degradation: identification of acidic degradation products, their emission rates, and implications for heritage collections

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    Špela Pok, Irena Kralj Cigić, Matija Strlič, Tjaša Rijavec

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  10. Research and Application of Ga-Based Liquid Metals in Catalysis

    Nanomaterials · 2025-07-30

    Yu Zhang, Ying Xin, Qingshan Zhao

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  11. Production of Polymer Monomers through Integrated Catalytic Approaches

    Energy & Fuels · 2025-08-08

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  12. Multifunctional Liquid Metal for Biomimicry Application

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    Yi-Ran Xu, Y.-M. Li, Yu-Kun Yi, Heng-Yang Bao

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  13. Degradation and utilization of polyvinyl chloride (PVC): Challenges and opportunities toward a circular economy

    Green Energy & Environment · 2025-10-28

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  14. High‐Performance Electrochemical Chloride Ion Storage with Hierarchical Ternary Metal Hydroxides for Sustainable Water Purification

    Advanced Materials · 2025-10-29

    Chun‐Miao Zhang, Yun‐Ze Qiu, Hao Bin Wu, Yaqi Jiang, Zhang‐Hong Wan, Wen‐Qing Fei, Qing Li, Wen‐Wei Li, Xue‐Fei Sun

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  15. Chlorine release induced by contact electrification between polyvinyl chloride microplastics and moist air

    Environmental Chemistry and Ecotoxicology · 2025-11-19

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  16. A review of recent advances in thermal-catalytic cracking of plastic waste

    Catalysis Science & Technology · 2025-11-27

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  17. Dechlorination of poly(vinyl chloride): thermal benchmarks and complementary non-thermal pathways toward sustainable recycling

    Polymer Chemistry · 2026-01-01

    Jinho Ko, Woojin Jeon, Daewhan Kim, Min Sang Kwon

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  18. Integrating chemical and biological conversion for waste plastics recycling and upcycling toward a circular bioeconomy

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  19. Microscopic Mechanism of Hydrogen Generation During Pyrolysis of the High-Voltage Cable PVC Outer Sheath

    Lecture notes in electrical engineering · 2026-01-01

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  20. Study on electrical contact of a solid–liquid interface between a copper-based electrode and liquid metal

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    Jiasheng Zu, Yuntao Cui, Chunwei Li, X. Y. Chen, Zhongshan Deng

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  21. Hydrothermal Fenton-like process for dehydrochlorination and recovering of PVC pipe microplastics in aquatic systems

    Water Research · 2026-01-30

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  22. Recent advancements in catalytic processes for plastic upcycling into fuels: a major step in sustainable waste management and energy production

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  23. Elucidating the role of overlooked environmentally persistent free radicals and reactive chlorine species on photoaged chlorine-containing microplastics: New insights into formation mechanisms and health risks

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  24. Aggregation‐Induced Synergy in Photocatalysis: Enhanced Light Harvesting and Efficient Charge Separation

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  25. Electrocatalytic degradation strategies for plastic fibers with sustainable resource recovery potential

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  26. Interfacial configurational entropy tuning strategy enabling liquid alloys for efficient depolymerization of polyolefin waste

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  28. A Resilient In Situ Raman-Based Framework for Identifying Thermally Aged Microplastics: Validation in Waste-to-Energy Incineration

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  29. Phase separation in heritage objects made of plasticised PVC—the case of Joseph Beuys’ multiples

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  30. Upcycling waste thermoplastics into sulfur-doped hard carbon via sulfonation-assisted crosslinking for sodium/potassium-ion storage

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  31. Recent advances in catalytic technologies for plastic conversion: a review

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  32. Enhanced Catalytic Dechlorination of Polyvinyl Chloride (PVC) and H2 Production Enabled by Synergistic Gaδ+/Ga0 Active Sites in Liquid Metal Particles

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  33. Emerging Approaches for Dechlorination of Plastic Waste Prior to Thermochemical Recycling: A Comprehensive Review

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  34. Detoxification of Chlorinated Dioxins and Furans in Soils via One-Step, Self-Sustaining Smoldering

    Environmental Science & Technology · 2026-09-15

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  35. Challenges in polyolefin re/upcycling catalysis specific to polymer feedstock

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