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RESEARCH PAPER · Inorganic Chemistry · 2024

[C(NH2)3][B(C2O2H4)2]: An Organic–Inorganic Hybrid Borate Containing Nonlinear-Optical Active Unit [B(C2O2H4)2]− with Solar-Blind-Region Optical Nonlinearity

Jiaxin Wang, Shu‐Fang Li, Meng-Meng Ren, Meng-Han Lv, Ru‐Ling Tang, Jin Chen, Hongbo Huang, Bingbing Zhang, Dong Yan

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[C(NH2)3][B(C2O2H4)2]: An Organic–Inorganic Hybrid Borate Containing Nonlinear-Optical Active Unit [B(C2O2H4)2]− with Solar-Blind-Region Optical NonlinearityOriginalResearch progress in optical materials with cationic organic planar π-conjugated groups containing CN bonds34Strategically designed metal-free deep-ultraviolet birefringent crystals with superior optical properties18Old tree blossoms anew: Research progress on the structures and optical properties of ultraviolet selenites56Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units66Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering61Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering4[C(NH2)3]2S2O6: A SBBO-Like Dithionate Crystal with Large Optical Anisotropy14Inch‐sized K[NH2(CH2COO)2]: a High‐Performance UV Nonlinear Optical Crystal Enabled by Novel Flexible π‐Conjugated Building Units, [NH2(CH2COO)2]−13Giant Birefringence and Strong Third-Order Nonlinear Optical Response in a Hybrid Crystal Templated by a Push–Pull π-Conjugated System6Engineered Integration of Diverse Functional Units Induces Multifunctionality in Malonate‐Borate Hybrids44Remarkable Birefringence Enhancement Enabled by π-Conjugated Cyanoguanidine Group Based on Anisotropic Molecule Coordination Approach8Chirality-induced second harmonic generation in supramolecular 4-nitro- d -phenylalanine hybrid crystals2Transition metal (Co, Ni, Cu) 1-vinylimidazole templated borates as high-efficiency oxygen reduction catalysts for zinc–air battery0Cation‐Dominated Second‐Order Nonlinear Optical Response Enabled by π‐Conjugated Guanidinium Derivatives5Cation‐Dominated Second‐Order Nonlinear Optical Response Enabled by π‐Conjugated Guanidinium Derivatives0Enhancing Birefringence of Sulphates by Polarity Modification in Planar Cations0

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  1. Research progress in optical materials with cationic organic planar π-conjugated groups containing CN bonds

    Inorganic Chemistry Frontiers · 2024-01-01

    Hangwei Jia, Xueling Hou, Shilie Pan

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  2. Strategically designed metal-free deep-ultraviolet birefringent crystals with superior optical properties

    Chemical Science · 2024-01-01

    Yang Li, Xinglong Chen, Kang Min Ok

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  3. Old tree blossoms anew: Research progress on the structures and optical properties of ultraviolet selenites

    Coordination Chemistry Reviews · 2024-06-15

    Pengfei Li, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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  4. Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units

    Coordination Chemistry Reviews · 2024-07-03

    Bo Zhang, Mao‐Yin Ran, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  5. Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering

    Angewandte Chemie International Edition · 2024-08-15

    Huan Zhou, Meng Cheng, Dongdong Chu, Xu Liu, Ran An, Shilie Pan, Shilie Pan, Zhihua Yang

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  6. Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering

    Angewandte Chemie · 2024-08-15

    Huan Zhou, Meng Cheng, Dongdong Chu, Xu Liu, Ran An, Shilie Pan, Zhihua Yang

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  7. [C(NH2)3]2S2O6: A SBBO-Like Dithionate Crystal with Large Optical Anisotropy

    Inorganic Chemistry · 2024-12-11

    Siyu Li, Danyang Dou, Cheng Chen, Qi Shi, Bingbing Zhang, Ying Wang

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  8. Inch‐sized K[NH2(CH2COO)2]: a High‐Performance UV Nonlinear Optical Crystal Enabled by Novel Flexible π‐Conjugated Building Units, [NH2(CH2COO)2]−

    Laser & Photonics Review · 2025-03-05

    Yujie Fan, Lingli Wu, Chensheng Lin, Haotian Tian, Chao Wang, Tao Yan, Min Luo

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  9. Giant Birefringence and Strong Third-Order Nonlinear Optical Response in a Hybrid Crystal Templated by a Push–Pull π-Conjugated System

    ACS Materials Letters · 2025-08-01

    V. Sivasubramani, Zilong Chen, Xu Die, Zhihua Yang, Luyong Zhang, Xueling Hou, Fangfang Zhang, Muthu Senthil Pandian, P. Ramasamy

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  10. Engineered Integration of Diverse Functional Units Induces Multifunctionality in Malonate‐Borate Hybrids

    Aggregate · 2025-08-18

    Ziqi Chen, Chenxu Li, Xiaoyu Wu, Juanjuan Lu, Zhihua Yang, Xueling Hou, Miriding Mutailipu

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  11. Remarkable Birefringence Enhancement Enabled by π-Conjugated Cyanoguanidine Group Based on Anisotropic Molecule Coordination Approach

    The Journal of Physical Chemistry Letters · 2025-10-24

    Xinyue Shi, Xueqing Liu, Ying Su, Yangkai Zhang, Yong Wu, Run Li, Degao Zhong, Bing Teng, Yisheng Huang, Zhoubin Lin, Shijia Sun

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  12. Chirality-induced second harmonic generation in supramolecular 4-nitro- d -phenylalanine hybrid crystals

    Inorganic Chemistry Frontiers · 2026-01-01

    Ye Tan, Qing-Ju Gao, Wen-Shuang Mu, Xing-Guo Xiang, Gao-yu Zhao, Jingyu Guo, Zhihua Yang, Ling Chen

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  13. Transition metal (Co, Ni, Cu) 1-vinylimidazole templated borates as high-efficiency oxygen reduction catalysts for zinc–air battery

    Dalton Transactions · 2026-01-01

    Jiayue Yuan, Zhen-Ping Liao, Bo-Wei Liao, Chun‐Yang Pan

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  14. Cation‐Dominated Second‐Order Nonlinear Optical Response Enabled by π‐Conjugated Guanidinium Derivatives

    Angewandte Chemie International Edition · 2026-04-09

    Bohui Xu, Pifu Gong, Deshuai Xiao, Xuanlin Pan, Fan Liu, Xinyuan Zhang, Z. Sheng Z. Lin

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  15. Cation‐Dominated Second‐Order Nonlinear Optical Response Enabled by π‐Conjugated Guanidinium Derivatives

    Angewandte Chemie · 2026-04-09

    Bohui Xu, Pifu Gong, Deshuai Xiao, Xuanlin Pan, Fan Liu, Xinyuan Zhang, Z. Sheng Z. Lin

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  16. Enhancing Birefringence of Sulphates by Polarity Modification in Planar Cations

    Small · 2026-07-02

    Bohui Xu, Pifu Gong, Deshuai Xiao, Linfeng Dong, Xiaodong Zhang, Qian Huang, Siya Zhu, Xinyuan Zhang, Zheshuai Lin

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