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RESEARCH PAPER · Journal of the American Chemical Society · 2024

Giant Low-Field Cryogenic Magnetocaloric Effect in a Polycrystalline EuB 4 O 7 Compound

Yuanpeng Wang, Junsen Xiang, Lei Zhang, Jianjian Gong, Wei Li, Zhaojun Mo, Jun Shen

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Giant Low-Field Cryogenic Magnetocaloric Effect in a Polycrystalline EuB 4 O 7 CompoundOriginalDesign of Excellent Mechanical Performances and Magnetic Refrigeration via In Situ Forming Dual‐Phase Alloys35Geometrically frustrated Gd2Ti2O7 oxide: A comprehensive exploration of structural, magnetic, and magnetocaloric properties for cryogenic magnetic cooling applications100Designing gadolinium-transition metals-based perovskite type high entropy oxides with good cryogenic magnetocaloric performances78Structure, magnetism and magnetocaloric properties in performance GdClWO4 compound6Accurate Prediction of the Magnetic Ordering Temperature of Ultralow-Temperature Magnetic Refrigerants9Achieving Magnetic Refrigerants with Large Magnetic Entropy Changes and Low Magnetic Ordering Temperatures31Unusual Magnetocaloric Effect Triggered by Spin Reorientation17Excellent Barocaloric Effect by Modulating Geometrical Frustrations in Mn3Pt1The crystal structures, magnetic interactions and cryogenic magnetocaloric effects for NaGdXO4 (X=Si, Ti) compounds5Unveiling the Structural, Electronic and Magnetic Properties of Gd4.5A0.5Si3O13 (A = K, Na, and Li) Oxides With Promising Potential for Low‐Temperature Magnetic Cooling22A Record-High Cryogenic Magnetocaloric Effect Discovered in EuCl2 Compound41Cryogenic magnetic and magnetocaloric properties in anhydrous rare-earth sulfate RE2(SO4)3 (RE = Tb, Dy, Ho, Er)19Giant magnetocaloric effect of the K 3 Gd 5 (PO 4 ) 6 compound at ultra-low temperature4Structural, magnetic, and anisotropic magnetocaloric properties in antiferromagnetic compounds MBaYb(BO 3 ) 2 (M = K, Na)2Unveiling the structural and magnetic properties of RENaGeO 4 (RE = Gd, Dy, and Ho) oxides and remarkable low-temperature magnetocaloric responses in GdNaGeO 4 oxide63Impact of lattice distortion and vacancies on magnetism and magnetocaloric effect in Ho3BxC4-x compounds for hydrogen liquefaction3High Entropy: A General Strategy for Broadening the Operating Temperature of Magnetic Refrigeration8Exceptional Cooling Capacity of LiGd0.1Yb0.9F4 at Sub‐Kelvin Temperatures11Design of hydrogen-liquefied magnetic refrigeration materials by elemental regulation in RE3–Ho B0.5C3.5 (RE=Dy, Tb) compounds1Mean-Field Study of Magnetic Properties and Magnetocaloric Effect in Iron(III) Nitride-Based Antiperovskite Materials10Magnetism and Low-Temperature Magnetocaloric Effect in Gd7(BO3)(PO4)2O6 Compound with Monoclinic Lattice1Apatite-type gadolinium-based dense MGd4Si3O13 (M = Mg, Ca, and Sr) ceramics: An emerging class of sub-liquid helium temperature magnetic refrigerant74Large magnetocaloric effect in triangular antiferromagnet ErPd2Sb4Large reversible magnetocaloric effect in GdPO4 nano-spherical particles at ultralow temperatures6Magnetocaloric effect in frustrated magnetic oxides4Coexistence of Antiferromagnetic and Ferromagnetic Interactions in Dimer‐Like Arranged EuAl 2 O 4 Systems: Regulatory Strategy to Giant Low Field Cryogenic Magnetocaloric Effects13Magnetocaloric Effect of Gd1-xDyxScO3 (x = 0, 0.1, 0.2 and 1) Polycrystalline Compounds0Temperature Below 30 mK Achieved by Adiabatic Demagnetization Refrigeration7Cryogenic magnetic properties and magnetocaloric effects in orthorhombic EuZrO3-based ceramics3Giant Magnetocaloric Effect in a Honeycomb Spiral Spin‐Liquid Candidate5Ultralow-Temperature Magnetic Refrigeration Inorganic Materials: From Designed Synthesis to Adiabatic Demagnetization Refrigeration8Giant Low-Field Magnetocaloric Effect at Sub-Kelvin Temperatures in Ferromagnetic NH4GdF410Adiabatic demagnetization refrigeration to mK temperatures in NaGdGeO4 crystal7Cryogenic magnetocaloric properties of zinc-based perovskite Nd2ZnZn(Zn2Sb2)O12 with A-site columnar-type and B-site rock-salt-type orders2Realization of Large Magnetocaloric Effect in the Kagome Antiferromagnet Gd 3 BWO 9 for Sub-Kelvin Cryogenic Refrigeration10Magnetic refrigerants for ultralow temperatures: A mini-review2Unveiling the structure–magnetism interplay in the ferrimagnetic pyrochlore Gd2CrSbO7 with significant cryo–magnetocaloric performance2Divalent Europium Complexes with Phenochalcogenato Ligands: Syntheses, Crystal Structures, and Luminescence Properties1Mixed-valence induced Griffiths phase and large magnetocaloric effect in Eu2B2O5 + δ system1β’-Gd2(MoO4)3: A promising candidate in the sub-Kelvin temperature region0Recent progress on cryogenic magnetocaloric materials3Magnetism and magnetocaloric effect in Eu2SiO3Cl2 compound: a large‑spin Shastry–Sutherl lattice system0Refrigeration down to 0.16 K using a frustrated magnet Gd2B2MoO946Review of the strategies for regulating working temperatures of rare-earth-based low temperature magnetic cooling materials1Geometry‑Guided Ferromagnetic Correlations Between Eu (II) and Gd (III) in Eu 5 Gd(BO 3 ) 4 Cl Orthoborate: Low‑Field Magnetocaloric Response and Ligand Involvement at Liquid‑Helium Temperatures9Magnetic properties and magnetocaloric effect of high-entropy vanadium oxides0Enhancing the Magnetocaloric Effect of Trigonal Eu 3 P 2 O 8 Phosphate Near Liquid Helium Temperature via Ionic Substitution Strategy0Magnetic properties and cryogenic magnetocaloric effect in Dy2Hf2O7 ceramics1Experimental study on the interplay between electrical transport, magnetism, magnetocaloric and magnetoresistive effects in Pr0.75La0.05K0.2MnO3 perovskite0Thermodynamic performance evaluation of three generations of a magnetic air-conditioning prototype0Electrocatalytic Properties of Binary PdSn Nanoparticles for Ethanol Oxidation1EuB2O4: Potential magnetic refrigeration material0Ising Supercriticality and Universal Magnetocalorics in Spiral Antiferromagnet Nd 3 BWO 92Magnetocaloric effect of Tm0.2Y0.8Ga compound at liquid helium temperature0A Geometrically Frustrated LiCaGd 5 (BO 3 ) 6 Oxide with a Record Low‐Field Magnetocaloric Response at Ultra‐Low Temperature3Eu 2 ZnGe 2 OS 6 : A Novel Sub‐Kelvin Magnetic Refrigerant With a High‐Spin Shastry‐Sutherland Lattice1Magnetovolume effects, magnetic critical behavior, and magnetocaloric properties of ThMn12-type RFe10Si2 (R = Er, Ho, Dy) compounds0Li A Nd 2 ( BO 3 ) 3 ( A = Ba , Sr ) : A frustrated spin-hexamer lattice with cluster-liquid-like state and enhanced magnetocaloric effect1Long-range ferromagnetic ordering and universality class analysis of polymorphic SmIr30Enhanced Magnetocaloric Effect in Tb‐Co‐Ni Magnets via Chemical Pressure0Magnetism and sub-100 mK magnetic refrigeration in a large spin-7/2 Eu2+ Shastry-Sutherland antiferromagnet0Microstructure optimization via defect reduction and grain growth unlocks the magnetocaloric potential of polycrystalline EuB6 for liquid helium refrigeration0Considerable Magnetocaloric Effects of Dysprosium-Doped Gadolinium Phosphate Compounds0Magnetism and magnetocaloric effect in Eu2SiO3Cl2 compound: A large‑spin Shastry–Sutherland lattice system0Magnetic and magnetocaloric properties of nanosized Pr0.7Sr0.2A0.1MnO3 (A = K and Na) compounds0Monte Carlo investigation of magnetocaloric properties and critical behavior in Ni-doped GdMnO3 perovskites: a comparative study with experimental data0Complementary-Ligand Pair Strategy toward High-Performance Sub-Kelvin Magnetic Refrigerants0Magnetic and anisotropic magnetocaloric properties of triangular-lattice Ba3REB9O18 (RE = Er, Yb)0Performance assessment of hydrogen liquefaction system using active magnetic regenerative refrigeration0Achieving sharper magnetic-field-driven metamagnetic martensitic transformation via secondary annealing in Mn0.84Fe0.16NiGe alloy0Large magnetocaloric effect in the EuSe1− x S x magnetic semiconductors with coexistence of the magnetic phases0

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