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RESEARCH PAPER · Acta Materialia · 2025

Apatite-type gadolinium-based dense MGd4Si3O13 (M = Mg, Ca, and Sr) ceramics: An emerging class of sub-liquid helium temperature magnetic refrigerant

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Apatite-type gadolinium-based dense MGd4Si3O13 (M = Mg, Ca, and Sr) ceramics: An emerging class of sub-liquid helium temperature magnetic refrigerantOriginalRare earth-free magnetocaloric material Fe 82 Hf 6 Zr 7 B 4 Cu 1 for high-temperature applications7Recent developments and perspective of zero thermal expansion magnetic materials0Synthesis of Triazine-Phosphonitrile Porous Polymers for High Efficiency Gd(Ⅲ) Recovery0Unveiling the structural and magnetic properties of RENaGeO 4 (RE = Gd, Dy, and Ho) oxides and remarkable low-temperature magnetocaloric responses in GdNaGeO 4 oxide63Magnetic properties and cryogenic magnetocaloric effects in RE2Zr2O7 (RE = Gd, Dy, Ho and Er) ceramics48Significant low-temperature conventional and inverse magnetocaloric effects in ErSb and HoSb compounds4Structural, magnetic, and cryogenic magnetocaloric properties of Gd11O10(SiO4)(PO4)3 phosphosilicate40Exploring the structural, magnetic, magnetocaloric and magnetoresistance behaviour of La2/3Sr1/3Mn(1-x)CrxO3 with varying Cr content8Structural and magnetic characterization of weberite-type RE3NbO7 (RE = Gd, Dy, Ho, and Er) ceramics with notable cryogenic magnetocaloric responses58Glass forming ability and critical exponents in Hf-Modified Fe-Zr-B-Cu amorphous alloys for near room temperature magnetocaloric application3Crystal structure, magnetic properties and cryogenic magnetocaloric performance of garnet RE3Al5O12 (RE = Tb, Dy and Ho) compounds26Influence of K+ introduction on ultra-low-temperature magnetocaloric effects in rare-earth fluorides1Correlation between chromium concentration, magnetic order, and magnetocaloric performance in FeCoNi-based rare earth free medium-entropy alloys2Ab initio and Monte Carlo study of Mn2TiGa and Mn2TiIn: structural, electronic, thermodynamic, magnetic, and magnetocaloric properties1Thermodynamic analysis of magnetocaloric properties of ferromagnet undergoing structural phase transition near Curie temperature3Exploring Zero Thermal Expansion in Magnetocaloric Materials5The martensitic transition, magnetocaloric effect, exchange bias effect, and magnetic properties in Mn-rich Mn-Ni-Ge-Sn Heusler alloys1Recent progresses of the rare earth based intermetallics and alloys for hydrogen liquefaction3Crystal structure, magnetic phase transition and magnetocaloric effect in Fe2Hf1-Ta (x = 0.20–0.24) alloys0Exploring novel Ni-Mn-X based magnetocaloric materials via machine learning with physical descriptors0Magnetic Properties and Cryogenic Magnetocaloric Performance of Gd7BP2O17 Oxide2Multiple transition-driven magnetocaloric effect of nanoscale Ni48Mn37In15 thin films grown by molecular beam epitaxy2Magnetism and cryogenic magnetocaloric effect in heavy rare-earth RE6MoO12 (RE = Tb, Dy, Ho, and Er) compounds5Structural and magnetic characterizations of antiferromagnetic RE3PO7 (RE = Gd, Tb, Dy, Ho) phosphates featuring large conventional and inverse cryogenic magnetocaloric effects11Magnetic phase transition and magnetocaloric properties in ErB2C compound14Unprecedented enhancement of martensitic transformation temperature by doping 4d or 5d transition metals in all-d-metal Ni–Co–Mn–Ti Heusler compounds0Effect of rare‐earth ion substitution on structural, magnetic, and magnetocaloric properties of GdCrO 3 orthochromites3Investigation of critical phenomena and magnetocaloric effect (MCE) in amorphous Tb₈₀Au₂₀ foils0Giant Magnetocaloric Effect in Cr- and Fe-Substituted Frustrated Magnet Gadolinium Gallium Garnets, Gd 3 Ga 5 O 12 , for Magnetic Cooling at Cryogenic Temperatures0A novel heterometallic [NiII5GdIII] compound showing large magnetocaloric effect and efficient catalytic property for converting of CO23Coefficient of thermal expansion and heat capacity of C14-Fe2Nb laves phase intermetallic compound: Experimental and modelling approach4Zero thermal expansion and magnetocaloric effect in B doped Fe2(Hf,Ta) Laves phase compounds22Synthesis, magnetocaloric properties, and DFT calculations of rare earth-based Ho2FeMnO6 nanocrystalline double perovskite4Role of Co spin in exchange interactions and its consequent impact on the magnetization and magnetocaloric effect of YCrO30Direct Observation of Microstructure Effect on Martensitic Transformation in Multifunctional Ni–Co–Mn–Ti Alloy2The Structure, Magnetic Properties and Magnetotransport of 15R-BaMnO3 Manganite17Magnetoelastic transition and magnetocaloric effect in Sn-doped Mn2Sb alloys2Exceptional comprehensive barocaloric performance in three-dimensional hybrid perovskite [Et3P(CH2)2F][Mn(dca)3] compound near room temperature0Flexible electro-spun nanofibers for near room temperature magnetic cooling0Scaling and Landau analysis of the magnetocaloric effect in La0.7Sr0.3Mn1-xNixO3 (x = 0–0.06) manganites3Magnetic refrigerants for ultralow temperatures: A mini-review2Critical behavior and magnetocaloric effect in Cd-doped Mn 5 Ge 2.7 Cd 0.3 alloy for magnetic refrigeration near room temperature1Magnetocaloric properties of Mn (Fe, Ni)5-Si3 for room-temperature magnetic refrigeration1Glass-forming ability and magnetocaloric performance of Gd18.34+Dy18.33Er18.33-Al20Fe25 (x = 0, 3, 6, 9) high-entropy amorphous alloys1Investigation of the structure, magnetic properties, and magnetocaloric effect of Gd2WO6 compound1Phase-dependent structural and magnetic properties of NdPO4 nanorods for cryo-magnetocaloric cooling1Magnetic properties and low-temperature magnetocaloric performances in fluorite-type Tb2Zr2O7 compound7Magnetocaloric effect in Tb31Co69 and Dy31Co69 thin films deposited on Si substrates0Tb-based phosphor BaTb4Si3O13:Eu3+ with high energy transfer efficiency for white LEDs2Multifunctionality of Magnetic La(Fe, Si/Al) 13 ‐Based Materials: Negative Thermal Expansion and Magnetocaloric Effect8Magnetic phase transition and magnetocaloric effect in rare-earth-free high entropy alloys MnCoNiFeCu1Enhanced magnetocaloric application potential of Co-substituted rare-earth Laves-phase TbMn2 compounds3Structure, magnetic properties and magnetocaloric effect of gadolinium-titanium-based B-site low, medium and high-entropy double perovskite oxides2Crystal structure, magnetic properties and cryogenic magnetocaloric performances in Er2Ge2O7 and Ho2Ge2O7 oxides3Refrigeration down to 0.16 K using a frustrated magnet Gd2B2MoO947A criticality-aware design framework for sustainable magnetocaloric high-entropy alloys: the MnFeNiCuSi system5Fe2CrSi thin film as magnetocaloric refrigerant to liquefy/solidify high-boiling-point harmful organic substances and its associated critical phenomena0Review of the strategies for regulating working temperatures of rare-earth-based low temperature magnetic cooling materials1Experimental assessment and comparative analysis of active magnetic regenerative refrigeration for hydrogen liquefaction using HoAl2 and ErAl22Experimental and theoretical insights into cryogenic magnetic and magnetocaloric properties in geometrically frustrated REAgGe (RE = Ho, Er, and Tm) compounds17Structural, magnetic and large magnetocaloric effect in terbium orthophosphate TbPO4 near superfluid helium1A Geometrically Frustrated LiCaGd 5 (BO 3 ) 6 Oxide with a Record Low‐Field Magnetocaloric Response at Ultra‐Low Temperature3Reversal magnetization and dielectric properties in high-entropy multifunctional Gd₁/₅Sm₁/₅Nd₁/₅Pr₁/₅La₁/₅FeO₃ oxide: Optical insights and the role of rare-earth steric hindrance1Geometrically engineered magnetocaloric microwire arrays for magnetic cooling applications0Experimental and theoretical investigation on structural, magnetic, electronic and magnetocaloric properties of RE2Ge2O7 (RE = Tb and Dy) oxides7Large conventional and rotating magnetocaloric effects in anisotropic antiferromagnetic HoCuSb2 single crystal0Fe and B Doping Effects on Electronic Structure and Magnetocaloric Characteristics in MnCo 3 : An Ab Initio Calculations and Monte Carlo Simulations0Influence of magnetic phase transition and magnetic structure on cryogenic magnetocaloric effect in metamagnetic Ho3Si2C2 compound0Hydrogen sorption-induced tuning of magnetocaloric properties of heavy rare-earth-based Laves-phase DyCo2 for hydrogen liquefaction0Structural, thermodynamic, and magnetocaloric investigation of monoclinic KFeP2O7 near the magnetic transition0

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