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RESEARCH PAPER · ACS Nano · 2024

Exploring the Specificity of Nanozymes

Huizhen Fan, Ruofei Zhang, Kelong Fan, Lizeng Gao, Xiyun Yan

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Exploring the Specificity of NanozymesOriginalAdvanced nanocatalytic strategies for pretreatment and saccharification of lignocellulosic biomass towards green-like processing10Approach of a small protein to the biomimetic bis-(μ-oxo) dicopper active-site installed in MOF-808 pores with restricted access perturbs substrate selectivity of oxidase nanozyme17Construction of a novel cuboid-shape Mn-Urea nanozyme with arsenic( v )-enhanced oxidase-like activity as a colorimetric probe for the selective detection of inorganic arsenic8Effect of Bsa Surface Modification on Enzyme-Mimetic Activity of Ceo2 Nanozyme2Silicon dioxide-protection boosting the peroxidase-like activity of Fe single-atom catalyst for combining chemo-photothermal therapy16On the Specificity of Nanozymes: A Perspective77Nanomaterials for co‐immobilization of multiple enzymes64Nanomaterials as protein mimics or nanologicals2Molecular Network-Bearing Fe–N–C Single-Atom Nanozymes for Monitoring Intracellular Glutathione Fluctuations9Heterojunction‐Mediated Co‐Adjustment of Band Structure and Valence State for Achieving Selective Regulation of Semiconductor Nanozymes23Spatially Decoupled H2O2 Activation Pathways and Multi‐Enzyme Activities in Rod‐Shaped CeO2 with Implications for Facet Distribution28Autonomous, temperature-enhanced oxidase-mimic multimodal antimicrobial film for prolonged preservation of perishable products18A dual-mode sensing system for xanthine oxidase detection based on nitrogen-doped carbon dots and iron-cobalt oxide nanosheets15Cascade catalysis nanozyme for interfacial functionalization in combating implant infections associated with diabetes via sonodynamic therapy and adaptive immune activation49Biomedical potential of nanozymes: Harnessing redox enzyme mimicry for theranostic applications90Cascading oxidoreductases-like nanozymes for high selective and sensitive fluorescent detection of ascorbic acid16Doughnut-shaped bimetallic Cu–Zn-MOF with peroxidase-like activity for colorimetric detection of glucose and antibacterial applications36Niobium Carbide Protects Myocardial Ischemia/Reperfusion Injury by Scavenging Reactive Oxygen Species and Improving Mitochondrial Function2Tailoring metal oxide nanozymes for biomedical applications: trends, limitations, and perceptions29Revolutionizing drug delivery: The power of stimulus-responsive nanoscale systems38Electrochemical identification of reductive enantiomers in wood channels: A low-cost and scalable platform for chiral sensing2Laminarin-modulated osmium nanozymes with high substrate-affinity and selective peroxidase-like behavior engineered colorimetric assay for hydroxyl radical scavenging capacity estimation13Unleashing the Potential of Single-Atom Nanozymes: Catalysts for the Future55Bimetallic Single-Atom Nanozyme-Based Electrochemical-Photothermal Dual-Function Portable Immunoassay with Smartphone Imaging237Fe-doped herbal medicine-based carbon dots nanozyme as safe and effective antimicrobial and wound healing agent7Thiadiazol ligand-based laccase-like nanozymes with a high Cu+ ratio for efficient removal of tetracyclines through polymerization47Copper-doped carbon dots nanozymes for multi-signal specific hydrogen sulfide assay and broad-spectrum antibacterial13Oxidase mimicking nanozyme: Classification, catalytic mechanisms and sensing applications137An integrated bipolar electrode with shared cathode for dual-mode detection and imaging of CEA9Promotes M1-polarization and diabetic wound healing using Prussian blue nanozymes11Facile Preparation of Tannic Acid-Gold Nanoparticles for Catalytic and Selective Detection of Mercury(II) and Iron(II) Ions in the Environmental Water Samples and Commercial Iron Supplement123D Film-Like Nanozyme with a Synergistic Amplification Effect for the Ultrasensitive Immunochromatographic Detection of Respiratory Viruses76Unveiling Generally‐ignored Co‐substrate Effect of Catalase‐inherent Peroxidase Mimic for Self‐verifiable Detection of High‐concentration Hydrogen Peroxide6In-situ nanozyme catalytic amplification coupled with a universal antibody orientation strategy based electrochemical immunosensor for AD-related biomarker47Peptide nanozymes: An emerging direction for functional enzyme mimics49Bimetallic Nanozyme-Assisted Immunoassay for the Detection of Acetamiprid in Vegetables16Optical and Catalytic Properties of Nanozymes for Colorimetric Biosensors: Advantages, Limitations, and Perspectives85Auriferous nanozymes: advances in diagnostic and therapeutic applications18Single‐Atom Iridium Nanozyme‐Based Persistent Luminescence Nanoparticles for Multimodal Imaging‐Guided Combination Tumor Therapy11Dual-electrode signal amplification self-powered biosensing platform based on nanozyme boosting target-induced DNA nanospace array for ultrasensitive detection of sugarcane Pokkah Boeng disease pathogenic bacteria4Frontiers in laccase nanozymes-enabled colorimetric sensing: A review56Recent Advances in Nanozyme-Based Sensing Technology for Antioxidant Detection14Developing oxygen vacancy-rich CuMn2O4/carbon dots dual-function nanozymes via Chan-Lam coupling reaction for the colorimetric/fluorescent determination of D-penicillamine25Edible ultrasmall polyphenolic nanozymes for oral treatment of alcohol-induced acute gastritis24A Cardiac‐Targeting and Anchoring Bimetallic Cluster Nanozyme Alleviates Chemotherapy‐Induced Cardiac Ferroptosis and PANoptosis35pH-activated metal–organic layer nanozyme for ferroptosis tumor therapy12Nanoscale synthetic biology with innovative medicinal applications17A Fe/Zn Dual Single-Atom Nanozyme with High Peroxidase Activities for Detection of Penicillin G31Biomimetic Materials for Antibacterial Applications243D multilayered sheet-like nanozyme enables the multiplex, flexible, and ultrasensitive detection of small-molecule drugs by immunochromatographic assay21Self-reduction of gold@platinum bimetallic nanoparticles on Ti 3 C 2 T x MXene nanoribbons coupled with hydrogel and smartphone technology for colorimetric detection of silver ions7Molecularly Imprinted Nanozymes with Substrate Specificity: Current Strategies and Future Direction41One‐Pot and Gram‐Scale Synthesis of Fe‐Based Nanozymes with Tunable O2 Activation Pathway and Specificity Between Associated Enzymatic Reactions12Regulation of graphdiyne-based nanozymes with enhanced oxidase-like activity by cobalt and nitrogen codoping5Hyaluronan-modified nanoceria for dry eye disease treatment7Nanozymes and Their Potential Roles in the Origin of Life34Smart multifunctional Cu2O@RuO2 nanozyme for angiogenesis and osteogenesis in periodontitis35Biodegradable Enzyme-Mimic Nanocatalysts: From Degradation Behavior to Theranostic Applications0Fe-porphyrin-derived carbon nanofiber-based nanozymes: enhanced peroxidase-like activity for ultrasensitive glucose and ascorbic acid sensing7Graphene-based nanozymes for revolutionizing biomedical research21Nanozymes: recent advances for sustainable agricultural development17Oxygen vacancy-enriched NiO nanozymes achieved via facile annealing in argon for detection of l -Cys5Recent advances in nanozyme–CRISPR/Cas biosensors8Recent advances in nanozymes for organophosphorus pesticide detection in food14Recent developments and prospects of inorganic nanozymes for biomedical applications4Recent progress of noble metal-based nanozymes: structural engineering and biomedical applications61Silicon-based bimetallic nanozyme-enhanced immunochromatographic strips for highly sensitive simultaneous detection of multiple environmental pollutants18Research progress on the synthesis, performance regulation, and applications of Prussian blue nanozymes14Recent advances on biomedical applications of zirconium-based Nanozymes: A review30Integrated Microneedles and Hydrogel Biosensor Platform: Toward a Diagnostic Device for Collection and Dual-Mode Sensing of Monkeypox Virus A29 Protein18Integrated Modulation of Fe, Co-MOF Nanozymes for Expressing Peroxidase-like Activity: Enhanced Affinity for H2O2 and Analysis of Isoniazid11Nanozymes meet hydrogels: Fabrication, progressive applications, and perspectives39Nanozyme-Based Cancer Nanotheranostics: Emerging Applications and Challenges in Brain Cancer Therapeutics15Zinc Single-Atom Nanozyme As Carbonic Anhydrase Mimic for CO2 Capture and Conversion32Supramolecular Nanozymes Based on Self-Assembly of Biomolecule for Cancer Therapy4Mannose-modified multifunctional iron-based nanozyme for hepatocellular carcinoma treatment by remodeling the tumor microenvironment9Valence-band hybridization endows the reaction specificity of AgPd nanozyme for exclusive peroxidase mimicking and improved sensing performance7Selenium as a brightening agent for peroxidase-like activity regulation of MXene@CeO2 sensing platform2Biomass spinach-drived metal-free carbon dots-based nanozyme for multimodal nitrite sensing and functionalized by glucose oxidase as ROS amplifiers to enhance tumor therapy10Hierarchical Assembly of Hemin-Peptide Catalytic Systems on Graphite Surfaces10Dual-mode sensing platform based on an iodide ion synergistic covalent triazine frameworks (CTFs) for point-of-care testing (POCT) of acetylcholinesterase8Single cobalt sites on defective carbon nanosheets as efficient oxidase mimics for visual biosensing10Amino-Acid-Engineered Bionanozyme Selectivity for Colorimetric Detection of Human Serum Albumin5Dual-driven selenium Janus single-atom nanomotors for autonomous regulating mitochondrial oxygen imbalance to catalytic therapy of rheumatoid arthritis29Recent progress in the rational design and applications of nanozymes14Sensitive colorimetric sensing of dopamine and TYR based on enhanced HRP-like activity of CuNi/Fe LDHs nanozymes5Preparation of artificial substrate binding sites of nanozyme with “modular structure” strategy used for the construction of visual sensing analysis platform for levodopa120Construction of nanozyme based with mixed valence manganese oxide loaded on defective metal-organic frameworks for sensitive detection of biomarker procalcitonin32The construction of p-n heterojunction in nanozyme for improved peroxidase-like activity and “point-of-use” water disinfection19A catalase-like nanozyme of high activity and stability in acidic solutions for enzyme immobilization and chemoenzymatic cascade conversion of glucose to gluconic acid12The Paradigm of Safe and Sustainable‐by‐Design Synthetic Catalysts for Catalytic Therapies1Reengineering the Tumor Oxygen Microenvironment in Radiotherapy to Enhance T‐Cell Function for Radio‐Immunotherapy14Copper Nanoparticles Loaded on N-Doped Carbon Nanotubes with Enhanced Peroxidase-Like Performance for Gallic Acid Detection in Food9Hyaluronic acid-modified PtPdCo-CQ nanocatalyst with triple enzyme-like activities regulates macrophage polarization and autophagy levels for the treatment of rheumatoid arthritis6Advances of Metal‐Based Nanomaterials in the Prevention and Treatment of Oral Infections13Photosensitive Oxidase Mimics for Spontaneous and Sustainable Pathogen Disinfection in Personal Protective Equipment3Hydrogen Incorporation Selectively Modulates the Catalytic Performance of Pd Nanozymes for Cascade-Catalytic Tumor Therapy38Ligand‐Engineering MoS 2 ‐Osmium Heterostructure as Highly Active and Specific Peroxidase‐Mimic Nanozyme for Interference‐Free and Multimode Biosensing10Dual FeCo single-atom nanozymes with specific oxidase-like activity for sensitive detection of aflatoxin B19Colorimetric detection of fluoroquinolones via MOF inhibition and thiol-response oxidase-mimicking reactions3Nanoarchitectured biomass-waste derived activated charcoal nanozymes and its application in visual analysis of nitrite in pickled food7Novel Nanozymes with Sample Pretreatment Function for Specific Multimodal Detection of Perfluorooctanesulfonate19Spinel metal sulfide CuCo2S4 laccase mimic based colorimetric sensor array for the differentiation of phenolic compounds13Emerging nanoplatforms using molecular imprinted nanozymes for the detection of food hazards: Towards the future techniques of food safety assurance12A Bimetallic Nanozyme Synergistic Effect-Driven Enzyme Cascade Nanoreactor for Instant Immunoassay93pH‐Switchable Multi‐Enzyme‐Mimicking via Liquid Metal Nanozyme20Catalytic Nanozyme: Unlocking new horizons in articular cartilage degeneration treatment6Enhanced multi-enzyme activity and bone-targeted phosphorus-doped carbon dots for precise antioxidant therapy of rheumatoid arthritis3Advances of Nanozyme-Driven Multimodal Sensing Strategies in Point-of-Care Testing33Lewis Acid-Boosted Nanozyme for In Situ Metallization Electrochemical Sensing of Extracellular Vesicles8Carbon dots for reactive oxygen species modulation31Peroxide-Free Hexavalent Chromium Detection via Surface Electron Transfer in a Redox-Active Bismuth Metal–Organic Framework Nanozyme9Nanozymes for regulation of reactive oxygen species in biomedical applications: Design, enzyme-like activity and therapeutic mechanisms15Atomic-level design of artificial superoxide dismutase with exceptional substrate specificity13Enzyme‐Mimetic Single‐Atom Catalyst Design for Green Ammonia Synthesis24Cerium-Based Nanozyme Functionalized by Conducting Polymers with Dual Enzyme Activities for Intelligent Colorimetric Sensing of Hexavalent Chromium7Spatial Coordination Structure‐Driven Enzyme‐Like Selectivity in Single‐Atom Nanozymes54Nanozymes in the Repair of Fundus Damage1Amorphization-Induced Electronic Modulation of Gd(OH)3 Nanocages with Enhanced Enzymatic Activities for Antitumor Therapy7Specific Peroxidase-like Nanozyme with Boosted Activity at Neutral pH for Antibacterial Application6Biodegradable enzyme-mimicking nanocatalysts: From degradation behavior to theranostic applications15Chlorine Axial Coordination Enables Peroxidase Mimicking and Lignin Depolymerization in Fe–N3O Single-Atom Nanozymes12A Droplet Microfluidic-Derived Pathological Microenvironment-Activated Spore Nanozyme Device for the Precise Regulation and Treatment of Colitis10Laccase-mimicking active inorganic organic hybrid covalent organic framework filtration membrane for rapid removal of drug pollutants6Nanozymes: a dual approach to bacterial colorimetric and luminescent detection and to bacterial pathogen killing17Cascade Catalytic Nanozymes: Design, Classification, and Biomedical Applications45High peroxidase-like activity of CoOx@CNz nanozymes for colorimetric and smartphone-based epinephrine sensing0Hybrid Metal–Organic Framework and Polyoxometalate Nanocomposite for Efficient Detection of Hydrogen Peroxide and Ascorbic Acid2DNA-mediated regulation of nanozymes activity and their applications in biosensing4Design and application of a novel GO-based nanozyme platform with integrated colorimetric-catalytic signal enhancement for rapid contaminant detection5A portable electrochemical sensor for simultaneous voltammetric determination of multiple neurotransmitters using magnetic composite nanozyme4HCl-Protonated Metal–Organic Framework-Confined Au Nanoclusters with Enhanced Catalytic Activity and Specificity for Anti-interference Biosensing7Organic-Dominated Nanozymes for Pesticide Detection: Toward Sustainable Agricultural Monitoring25Highly sensitive and selective ratiometric fluorescence detection of ATP using aptamer-functionalized Fe3O4 nanozymes with tunable activity1Multi‐Dimensional Synergistic Engineering for Boosting Nanozyme Catalysis24Multifunctional nanomaterials combined lateral flow immunoassay for food contaminant detection: A review22Recent progress of rapid detection technologies for mycotoxins21Dendritic Mesoporous SiO2-Based SERS-Nanozyme-Mediated Immunochromatographic Detection of Foodborne Viruses with Enhanced Sensitivity across Multiple Scenarios17Oxygen Vacancy‐Rich Amorphous MOF/Graphene Nanozymes With Self‐Sustaining Catalytic Circuits for Drug‐Resistant Infection Wound Healing8A highly active self-assembled nanozyme based on cascade system for dual-mode detection of sarcosine2Biomedical Applications of Nanozymes: An Enzymology Perspective100Biomedical Applications of Nanozymes: An Enzymology Perspective8Uncovering Analytical Patterns for Hazardous Components in Agricultural Production Systems6Advanced biomaterial-based strategies for craniofacial bone regeneration6Oxidase-mimicking nanozymes: Bridging advanced materials with smart biosensors9A triple-responsive nanozyme platform of AgAu–CeO2 heterojunction integrated with probiotics for precision antibacterial therapy in periodontitis13Mechanistic Insights into Cefaclor Crystallization in Enzymatic Environments: From Nucleation to Morphology0Recent advances in biomimetic nanodelivery systems for the treatment of osteoporosis5Polyphenol oxidase from edible insect Antheraea pernyi pupa: Characterization and browning mechanism2Development of a portable dropper-based biosensor for rapid and cost-effective detection of Salmonella typhimurium in food samples4

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  44. Edible ultrasmall polyphenolic nanozymes for oral treatment of alcohol-induced acute gastritis

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