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RESEARCH PAPER · Inorganic Chemistry · 2023

(C(NH2)3)2(I2O5F)(IO3)(H2O) and C(NH2)3IO2F2: Two Guanidine Fluorooxoiodates with Wide Band Gap and Large Birefringence

Juhui Cui, Shi‐Bin Wang, Abudukadi Tudi, Minqiang Gai, Zhihua Yang, Shilie Pan

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(C(NH2)3)2(I2O5F)(IO3)(H2O) and C(NH2)3IO2F2: Two Guanidine Fluorooxoiodates with Wide Band Gap and Large BirefringenceOriginalResearch progress in optical materials with cationic organic planar π-conjugated groups containing CN bonds34Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering61Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering4π-Lone pair synergy in (C7H4NO4)(IO3): Optimal balance among SHG, birefringence, and bandgap performance29(C10N2H10)(HI2O6)(HIO3)(IO3): A Birefringent Material Featuring Large π-Conjugated Organic Cation and Two Types of Iodate Anions2[C(NH2)3]2S2O6: A SBBO-Like Dithionate Crystal with Large Optical Anisotropy14(C 5 N 2 H 7 )IO 2 F 2 and (C 3 N 6 H 8 )(IO 2 F 2 ) 2 : two new organic–inorganic hybrid fluoroiodate birefringent crystals7(C 7 H 3 NO 4 ) 2 Sb 2 F 2 ·2H 2 O: a pyridine-based compound shows large optical anisotropy4(CN 4 H 7 ) 2 SO 4 ·H 2 O: high-performance metal-free ultraviolet birefringent crystal with KBBF-like configuration5[C 2 N 4 H 7 O][NH 2 SO 3 ]: High‐Performance Ultraviolet Nonlinear Optical Crystal with Ditrigon Coupled Guanylurea Group9[C 2 N 4 H 7 O][NH 2 SO 3 ]: High‐Performance Ultraviolet Nonlinear Optical Crystal with Ditrigon Coupled Guanylurea Group48[C(NH2)3]Y(HCOO)4: Constructing 3D Framework for Guanidine-Based UV Nonlinear Optical Crystals with Good Performance8[C( NH2 )3] 2SiF6 : Design of Deep Ultraviolet Crystals with Large Birefringence Based on a Fluorination‐Oriented Strategy13Enhancing Birefringence via a Planar‐Conformation‐Locking Strategy3Hydrogen-bond-driven noncentrosymmetric structure formation in π-conjugated (C3H7N6)(IO3): achieving both strong SHG response and wide bandgap5Remarkable Birefringence Enhancement Enabled by π-Conjugated Cyanoguanidine Group Based on Anisotropic Molecule Coordination Approach8Ba2CrIO3F6: a magnetic alkaline-earth chromium fluoroiodate with ferromagnetic exchange interactions1NaNO 3 [(NH 2 ) 2 SO 2 ] 2 : A Halogen‐Free KBBF‐Type Nitrate Crystal with Record Birefringence for Ultraviolet Applications0Steric hindrance and hydrogen-bond networks synergistically directing molecular alignment for high-performance ultraviolet birefringent1Enhancing Birefringence of Sulphates by Polarity Modification in Planar Cations0

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  1. Research progress in optical materials with cationic organic planar π-conjugated groups containing CN bonds

    Inorganic Chemistry Frontiers · 2024-01-01

    Hangwei Jia, Xueling Hou, Shilie Pan

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  2. Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering

    Angewandte Chemie International Edition · 2024-08-15

    Huan Zhou, Meng Cheng, Dongdong Chu, Xu Liu, Ran An, Shilie Pan, Shilie Pan, Zhihua Yang

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  3. Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering

    Angewandte Chemie · 2024-08-15

    Huan Zhou, Meng Cheng, Dongdong Chu, Xu Liu, Ran An, Shilie Pan, Zhihua Yang

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  4. π-Lone pair synergy in (C7H4NO4)(IO3): Optimal balance among SHG, birefringence, and bandgap performance

    Chinese Chemical Letters · 2024-09-27

    Miao‐Bin Xu, Qianqian Chen, Qian-Qian Chen, Bingxuan Li, Ke-Zhao Du, Jin Chen

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  5. (C10N2H10)(HI2O6)(HIO3)(IO3): A Birefringent Material Featuring Large π-Conjugated Organic Cation and Two Types of Iodate Anions

    Inorganic Chemistry · 2024-10-19

    Yuhang Wang, De-Xuan Jiang, De‐Xuan Liu, Fu-Ying Li, He Zhao, Jie Pan, Qi Wei, Li Wei, Guo‐Yu Yang

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  6. [C(NH2)3]2S2O6: A SBBO-Like Dithionate Crystal with Large Optical Anisotropy

    Inorganic Chemistry · 2024-12-11

    Siyu Li, Danyang Dou, Cheng Chen, Qi Shi, Bingbing Zhang, Ying Wang

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  7. (C 5 N 2 H 7 )IO 2 F 2 and (C 3 N 6 H 8 )(IO 2 F 2 ) 2 : two new organic–inorganic hybrid fluoroiodate birefringent crystals

    Dalton Transactions · 2025-01-01

    Si Yuan, Chun‐Li Hu, Jiang‐Gao Mao

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  8. (C 7 H 3 NO 4 ) 2 Sb 2 F 2 ·2H 2 O: a pyridine-based compound shows large optical anisotropy

    Dalton Transactions · 2025-01-01

    Yaoguo Shen, Jiajia Xiong, Yiman Yang, Zhifeng Tang

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  9. (CN 4 H 7 ) 2 SO 4 ·H 2 O: high-performance metal-free ultraviolet birefringent crystal with KBBF-like configuration

    Inorganic Chemistry Frontiers · 2025-01-01

    Xia Hao, Sijing Xie, Ruijie Wang, Chensheng Lin, Lingli Wu, Guang Peng, Tao Yan, Ning Ye, Min Luo

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  10. [C 2 N 4 H 7 O][NH 2 SO 3 ]: High‐Performance Ultraviolet Nonlinear Optical Crystal with Ditrigon Coupled Guanylurea Group

    Angewandte Chemie · 2025-02-11

    Xin Wen, Yuchen Yan, Jingyao Lu, Xuemei Shi, Piao Tang, Jindong Chen, Guangsai Yang, Guang Peng, Haohai Yu, Huaijin Zhang, Zhanggui Hu, Jiyang Wang, Ning Ye

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  11. [C 2 N 4 H 7 O][NH 2 SO 3 ]: High‐Performance Ultraviolet Nonlinear Optical Crystal with Ditrigon Coupled Guanylurea Group

    Angewandte Chemie International Edition · 2025-02-11

    Xin Wen, Yuchen Yan, Jingyao Lu, Xuemei Shi, Piao Tang, Jindong Chen, Guangsai Yang, Guang Peng, Haohai Yu, Huaijin Zhang, Zhanggui Hu, Jiyang Wang, Ning Ye

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  12. [C(NH2)3]Y(HCOO)4: Constructing 3D Framework for Guanidine-Based UV Nonlinear Optical Crystals with Good Performance

    Inorganic Chemistry · 2025-06-02

    Jiayin Tang, Xin Wen, Huili Zhang, Yuchen Yan, Jindong Chen, Shihui Ma, Min Luo, Chensheng Lin, Ning Ye, Guang Peng

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  13. [C( NH2 )3] 2SiF6 : Design of Deep Ultraviolet Crystals with Large Birefringence Based on a Fluorination‐Oriented Strategy

    Chinese Journal of Chemistry · 2025-06-24

    Shaohua Liu, Xiaoqin Ma, Xifa Long, Yun Mo Yang

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  14. Enhancing Birefringence via a Planar‐Conformation‐Locking Strategy

    Laser & Photonics Review · 2025-09-04

    Yaoguo Shen, Jiajia Xiong, Mengqing Wu, M.-R. Li, Yingwu Zhou, Yanjie Zhang

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  15. Hydrogen-bond-driven noncentrosymmetric structure formation in π-conjugated (C3H7N6)(IO3): achieving both strong SHG response and wide bandgap

    Science China Chemistry · 2025-10-21

    Yu-Wei Kang, Chun‐Li Hu, Jiang‐Gao Mao

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  16. Remarkable Birefringence Enhancement Enabled by π-Conjugated Cyanoguanidine Group Based on Anisotropic Molecule Coordination Approach

    The Journal of Physical Chemistry Letters · 2025-10-24

    Xinyue Shi, Xueqing Liu, Ying Su, Yangkai Zhang, Yong Wu, Run Li, Degao Zhong, Bing Teng, Yisheng Huang, Zhoubin Lin, Shijia Sun

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  17. Ba2CrIO3F6: a magnetic alkaline-earth chromium fluoroiodate with ferromagnetic exchange interactions

    Journal of Solid State Chemistry · 2025-12-24

    Shuaikun Li, Yanhong Wang, Haibo Li, Hang Liu, Yun Lv, Hongcheng Lu

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  18. NaNO 3 [(NH 2 ) 2 SO 2 ] 2 : A Halogen‐Free KBBF‐Type Nitrate Crystal with Record Birefringence for Ultraviolet Applications

    Advanced Optical Materials · 2026-04-25

    Juhui Cui, Feng Yu, Minqiang Gai

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  19. Steric hindrance and hydrogen-bond networks synergistically directing molecular alignment for high-performance ultraviolet birefringent

    Journal of Molecular Structure · 2026-05-07

    Yuqi Qin, Paipai Zhang, Peng Jiang, Xueling Hou, Hu Jiang, Minqiang Gai

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  20. Enhancing Birefringence of Sulphates by Polarity Modification in Planar Cations

    Small · 2026-07-02

    Bohui Xu, Pifu Gong, Deshuai Xiao, Linfeng Dong, Xiaodong Zhang, Qian Huang, Siya Zhu, Xinyuan Zhang, Zheshuai Lin

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