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RESEARCH PAPER · Advanced Science · 2025

The Rise of Chalcohalide Solar Cells: Comprehensive Insights From Materials to Devices

Hongrui Zhang, Yiming Xia, Yangfan Zhang, Uma V. Ghorpade, Mingrui He, Seung Wook Shin, Xiaojing Hao, Mahesh P. Suryawanshi

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The Rise of Chalcohalide Solar Cells: Comprehensive Insights From Materials to DevicesOriginalA chemical vapor-assisted highly crystalized SbSI solar cell and a photodetector with bifacial passivation to mitigate the charge transport loss1Controlled colloidal synthesis of anisotropic mixed-metal chalcohalides: insights into morphology and phase evolution0Parallel exploration of the optoelectronic properties of (Sb,Bi)(S,Se)(Br,I) chalcohalides11Composition-Dependent Photoelectrochemical Properties of Low-Toxic Bismuth Chalcohalide Nanorods Synthesized via a Solution-Phase Method0Wide bandgap top cells above 1.8 eV for reliable silicon-based tandem solar cells1In Silico Investigations of the Performance Characteristics of Agbis2 Solar Cell using Solar Cell Capacitance Simulator – 1 Dimension (SCAPS-1D)0Tailoring optical and ferroelectric properties in Sb 1− x Bi x SI van der Waals chalcohalides towards solar absorber applications4AgBiS 2 nanocrystal synthesis from molecular precursors: insights into the acid-catalyzed decomposition of dialkyldithiocarbamate ligands1Electronic, structural, optical and thermoelectric properties of potassium chalcohalide antiperovskites from first-principles calculations and machine learning0Layered mixed-anion chalcohalides Pb 4 Sb 4 Q 9 Cl 2 (Q = S, Se): puckered 2D frameworks, indirect band gaps, and low thermal conductivity0Low-temperature synthesis of crystalline, single-phase SbSeI thin films for optoelectronic applications0Quasi-1D selenohalides: first-principles insights into thermoelectric and photovoltaic applications1Quasi-one-dimensional Bi-based chalcohalide electrodes for high-photocurrent photoelectrochemical water oxidation0Cu 7.62 Bi 6 Se 12 Cl 6 I: Discovery of a Low Band Gap, Low Thermal Conductivity Mixed-Anion Material0Silyl Hot-Injection Versus Thiocyanate Heat-Up Synthesis of Chalcohalides: Pushing the Size and Composition Envelope0Unveiling the Electronic Landscape in Lead-Free Silver (Copper)–Bismuth–Sulfide (Halide) Semiconductors: Insights into Charge Carrier Transport and Trapping Characteristics1The Reemergence of Selenium Solar Cells2Overcoming Charge-Carrier Localization in Metal Chalcohalides0Photocorrosion, Protection, and Predictive Design in Solar Water Splitting0First-principles DFT and SCAPS-1D simulation study of BiTeX (X = Cl, Br, I) chalcohalides for efficient lead-free solar cells0

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  1. A chemical vapor-assisted highly crystalized SbSI solar cell and a photodetector with bifacial passivation to mitigate the charge transport loss

    Journal of Materials Chemistry C · 2025-01-01

    Shosuke Murayama, Ryosuke Nishikubo, Tai Kobayashi, Saeki Akinori

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  2. Controlled colloidal synthesis of anisotropic mixed-metal chalcohalides: insights into morphology and phase evolution

    Nanoscale · 2025-01-01

    Davide Pratolongo, Ankita Bora, Suvodeep Sen, Niraj Nitish Patil, Stefano Alberti, Manoj Palabathuni, Federico Locardi, Shalini Singh

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  3. Parallel exploration of the optoelectronic properties of (Sb,Bi)(S,Se)(Br,I) chalcohalides

    Journal of Materials Chemistry A · 2025-01-01

    Rasmus Nielsen, Ángel Labordet Álvarez, Axel Gon Medaille, Iván Caño, Alejandro Navarro-Güell, Cibrán L. Álvarez, Claudio Cazorla, David R. Ferrer, Zacharie Jehl Li‐Kao, Edgardo Saucedo, Mirjana Dimitrievska

    Read original paper ↗ ·

  4. Composition-Dependent Photoelectrochemical Properties of Low-Toxic Bismuth Chalcohalide Nanorods Synthesized via a Solution-Phase Method

    Electrochemistry · 2025-07-09

    Wentao ZHANG, Yumeno KASUGA, Kazutaka Akiyoshi, Tatsuya Kameyama, Tsukasa Torimoto

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  5. Wide bandgap top cells above 1.8 eV for reliable silicon-based tandem solar cells

    Solar Energy Materials and Solar Cells · 2025-08-08

    Daniel Walter, Lachlan E. Black, Thomas P. White, Daniel Macdonald, Andrew W Blakers

    Read original paper ↗ ·

  6. In Silico Investigations of the Performance Characteristics of Agbis2 Solar Cell using Solar Cell Capacitance Simulator – 1 Dimension (SCAPS-1D)

    Nigerian Journal of Physics · 2025-09-22

    Muteeu Abayomi Olopade, Soko Swaray, Abdulai M. Feika

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  7. Tailoring optical and ferroelectric properties in Sb 1− x Bi x SI van der Waals chalcohalides towards solar absorber applications

    Journal of Materials Chemistry A · 2025-11-27

    Sara A. López-Paz, Harish K. Singh, Alba S. J. Méndez, Volodymyr Multian, Jeremie Teyssier, Ulrich Aschauer, Fabian O. von Rohr

    Read original paper ↗ ·

  8. AgBiS 2 nanocrystal synthesis from molecular precursors: insights into the acid-catalyzed decomposition of dialkyldithiocarbamate ligands

    Inorganic Chemistry Frontiers · 2026-01-01

    Annie Regan, Vaishali Kshirsagar, Paul Gramelspacher, Thomas Boggess, Anuraj S. Kshirsagar, Charles Edwin Webster, Sidney E. Creutz

    Read original paper ↗ ·

  9. Electronic, structural, optical and thermoelectric properties of potassium chalcohalide antiperovskites from first-principles calculations and machine learning

    Physical Chemistry Chemical Physics · 2026-01-01

    R.J. Gadha, R.D. Eithiraj

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  10. Layered mixed-anion chalcohalides Pb 4 Sb 4 Q 9 Cl 2 (Q = S, Se): puckered 2D frameworks, indirect band gaps, and low thermal conductivity

    Dalton Transactions · 2026-01-01

    Yen-Han Huang, Guan-Ruei Chen, Chi‐Shen Lee

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  11. Low-temperature synthesis of crystalline, single-phase SbSeI thin films for optoelectronic applications

    Journal of Materials Chemistry C · 2026-01-01

    Deividas Vainauskas, Vidas Pakštas, Marius Franckevičius, Rokas Kondrotas

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  12. Quasi-1D selenohalides: first-principles insights into thermoelectric and photovoltaic applications

    Journal of Materials Chemistry A · 2026-01-01

    Prakash Govindaraj, Hern Kim

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  13. Quasi-one-dimensional Bi-based chalcohalide electrodes for high-photocurrent photoelectrochemical water oxidation

    EES Catalysis · 2026-01-01

    Edoardo Maggi, David Rovira, Daniel Ormart-Cepeda, Cibrán López, Oriol Segura‐Blanch, Alex Jiménez‐Arguijo, Jordi Llorca, Claudio Cazorla, Lluís Soler, Edgardo Saucedo

    Read original paper ↗ ·

  14. Cu 7.62 Bi 6 Se 12 Cl 6 I: Discovery of a Low Band Gap, Low Thermal Conductivity Mixed-Anion Material

    Chemistry of Materials · 2026-02-24

    Cara J. Hawkins, Batoul Almoussawi, Jan P. Scheifers, Manel Sonni, Aeshah A. Almushawwah, Troy D. Manning, Marco Zanella, Craig M. Robertson, Luke M. Daniels, Tim D. Veal, John B. Claridge, Matthew J. Rosseinsky

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  15. Silyl Hot-Injection Versus Thiocyanate Heat-Up Synthesis of Chalcohalides: Pushing the Size and Composition Envelope

    Chemistry of Materials · 2026-03-05

    Eve Stegner, Md Riad Sarkar Pavel, Anuluxan Santhiran, Jack Lawton, Juan‐Pablo Correa‐Baena, Aaron J. Rossini, Javier Vela

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  16. Unveiling the Electronic Landscape in Lead-Free Silver (Copper)–Bismuth–Sulfide (Halide) Semiconductors: Insights into Charge Carrier Transport and Trapping Characteristics

    Chemistry of Materials · 2026-05-12

    Kejing Zhang, Ryosuke Nishikubo, Hiroyuki Tamura, Tai Kobayashi, Akinori Saeki

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  17. The Reemergence of Selenium Solar Cells

    PRX Energy · 2026-05-26

    Rasmus Nielsen

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  18. Overcoming Charge-Carrier Localization in Metal Chalcohalides

    Journal of the American Chemical Society · 2026-06-22

    Bembe C. Mackintosh, Marcello Righetto, Gopal Krishnamurthy Grandhi, Thomas B. Haward, Noolu Srinivasa Manikanta Viswanath, Joshua R. S. Lilly, Siyu Yan, Jae Eun Lee, Snigdha Lal, Alan R. Bowman, Michael B. Johnston, Paola Vivo, Laura M. Herz

    Read original paper ↗ ·

  19. Photocorrosion, Protection, and Predictive Design in Solar Water Splitting

    Small · 2026-08-27

    Seung Wook Shin, Girish U. Kamble, Uma V. Ghorpade, Dong Hyun Kang, Youseong Park, Mahesh P. Suryawanshi, Keeyoung Jung, Donghoon Song, Jin Hyeok Kim

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  20. First-principles DFT and SCAPS-1D simulation study of BiTeX (X = Cl, Br, I) chalcohalides for efficient lead-free solar cells

    Physica B Condensed Matter · 2026-08-30

    Muhammad Irfan, Hussain Ahmed, Surayya Mukhtar

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