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RESEARCH PAPER · Advanced Materials · 2023

Ferroics in Hybrid Organic–Inorganic Perovskites: Fundamentals, Design Strategies, and Implementation

Haining Zheng, Kian Ping Loh

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Ferroics in Hybrid Organic–Inorganic Perovskites: Fundamentals, Design Strategies, and ImplementationOriginalFootprints of scanning probe microscopy on halide perovskites7Enhanced magnetoelectric properties of the composite films of Bi0.5Na0.5Ti0.98Fe0.02O3-δ-NiFe1.98Nd0.02O4 with different deposition sequences2Giant Anisotropic Thermal Expansion Phase Transition of Silver Iodide Anionic Organic–Inorganic Hybrid7Chiral multiferroicity in two-dimensional hybrid organic-inorganic perovskites59Preparation, Crystal Structure, Optical Properties, Hirshfeld Surface Analysis and Antibacterial Activity of 4-Nitrobenzyl-4-aminopyridinium Tetrachlorocuprate(II)4Experimental Observation of the Fully Ferroelectric–Fully Ferroelastic Effect in Multiferroic Hybrid Perovskites90Near‐Unity Narrow Green Emitting in Manganese Halides Realized by Direct Precipitation Synthesis12CsPbBr3 perovskite quantum dots/p-GaN heterojunction for ultraviolet-visible spectrum photodetectors7Strong Correlation Between A‐Site Cation Order and Self‐Trapped Exciton Emission in 0D Hybrid Perovskites11Supramolecular Rotor Assembly for the Design of a Hybrid Ferroelectric‐Antiferromagnetic Multiferroic Semiconductor0Supramolecular Rotor Assembly for the Design of a Hybrid Ferroelectric‐Antiferromagnetic Multiferroic Semiconductor9Engineering magnetism in hybrid organic–inorganic metal halide perovskites27High phase transition temperature and photoluminescence properties in low-dimensional molecular perovskite ferroelastic crystals2Retainable large magnetoelectric coupling in BiFeO3@CoFe2O4 core-shell nanoparticle embedded P(VDF-TrFE) matrix3Butylammonium Hexachlorostannate for Lithium-Ion Batteries: An Experimental Application1Advances in Nanoelectronics: Carbon Nanotubes, Graphene, and Smart Polymers: A review10Magnetic Organic–Inorganic Hybrid Halide Perovskites: Fundamental Physics, Properties, and Applications14Unraveling Lattice Void Occupancy Engineering for Regulating Optical/Dielectric Responses in Hybrid Crystals2A Perspective on Spatiotemporal Engineering of Multidimensional Heterointerfaces in Perovskite Solar Cells14Recovery of Lead‐Zinc Slags to Methyl‐Ammonium Lead Tri‐Iodide With Single‐Atom Fe–N4 Sites for Piezocatalytic Hydrogen Evolution3Alkaline Earth Metal‐Based Hybrid Organic‐Inorganic Perovskite‐Like Ferroelectrics11Alkaline Earth Metal‐Based Hybrid Organic‐Inorganic Perovskite‐Like Ferroelectrics3Halogen substitution strategy of spacer cations in two-dimensional perovskite ferroelectrics gives giant anomalous photovoltaic effect14Organic cation functionalization of zinc-based hybrid perovskite materials on synergistic modulation of phase transition and nonlinear optical properties3Doping Effects on Magnetic Layered Hybrid Organic–Inorganic Transition Metal Halide Perovskites5High-Frequency Switchable Dielectric Properties of a Molecule-Based Hybrid Perovskite in a Microwave Band3The Impact of Supramolecular Forces on the Magnetic and Optical Properties of Bis(2-amino-6-bromopyridinium) Tetrachloridocuprate (C5H6BrN2)2[CuCl4]3Empirical equations to estimate tetragonal to cubic phase transitions in lead iodide perovskites1Engineering Thermoresponsive Dielectric Properties and Phase Transitions via Confinement of Polar Cations in Photoisomerizable Nitroprusside Frameworks3Anion···π interactions and hydrogen bonds in cyanidometallate-based co-crystal systems: novel synthons, functional properties, and stories behind them2In-situ organic cation evolution driven sequential crystal transformation in hybrid metal halides1Dimensionality Engineering: A Pathway to Ferroelectric Halide Perovskites3Emerging Molecular Antiferroelectrics: Advances and Prospects3Isopropylammonium as a Dual-Role Cation: Spacer and Perovskitizer in Ruddlesden–Popper Lead Bromides1Ion Migration in Two-Dimensional Organic–Inorganic Hybrid Perovskite Heterostructures: Interface Evolution, Migration Mechanisms and Device Implications1Direct Observation of Noncollinear Ferrielectricity in a Two-Dimensional Hybrid Germanium Perovskite1Metal Halide Perovskites for Violet and Ultraviolet Light Emission0Mixed-Ligand Engineering of Manganese Perovskite-like Materials with Tunable Solid−Solid Phase Transitions0Ferroic Phase Transition‐Triggered Large Anisotropic Actuation in 1D Chiral Hybrid Metal Halides0Halide Perovskites for Photo(electro)catalytic Sustainable Energy: Recent Advances and Challenges1How Polarization Switch Influences Both Charge Separation and Carrier Recombination in Hybrid Perovskites1Enhanced Bulk Photovoltaics in Polar 2D Hybrid Perovskite via Pressure‐Strengthened Organic‐Inorganic Interactions0

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  1. Footprints of scanning probe microscopy on halide perovskites

    Chemical Communications · 2024-01-01

    Shresth Gupta, Sayan Bhattacharyya

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  2. Enhanced magnetoelectric properties of the composite films of Bi0.5Na0.5Ti0.98Fe0.02O3-δ-NiFe1.98Nd0.02O4 with different deposition sequences

    Materials Today Communications · 2024-04-17

    Min Shi, Shushu Du, Wu Chen, Hao Chen, Yudong Xu, Ruzhong Zuo, Tiancheng Bai

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  3. Giant Anisotropic Thermal Expansion Phase Transition of Silver Iodide Anionic Organic–Inorganic Hybrid

    Inorganic Chemistry · 2024-06-18

    N. L. Wang, Weiwei Wang, Xiaowen Liang, Pu-Yue Wang, Tong Liu, Zhao‐Quan Yao, Jiong‐Peng Zhao, Fu‐Chen Liu

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  4. Chiral multiferroicity in two-dimensional hybrid organic-inorganic perovskites

    Nature Communications · 2024-07-02

    Haining Zheng, Arup K. Ghosh, M. J. Swamynadhan, Qihan Zhang, Walter P. D. Wong, Zhenyue Wu, Rongrong Zhang, Jingsheng Chen, Fanica Cimpoesu, Saurabh Ghosh, Branton J. Campbell, Kai Wang, Alessandro Stroppa, R. Mahendiran, Kian Ping Loh

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  5. Preparation, Crystal Structure, Optical Properties, Hirshfeld Surface Analysis and Antibacterial Activity of 4-Nitrobenzyl-4-aminopyridinium Tetrachlorocuprate(II)

    Journal of Chemical Crystallography · 2024-07-17

    Yuting Li, Lin Huang, Xinran Li, Bao-Yi Hu, Xiang‐Ling Li, Yan Jiang, Jia-Yu Yu, Chun‐Lin Ni

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  6. Experimental Observation of the Fully Ferroelectric–Fully Ferroelastic Effect in Multiferroic Hybrid Perovskites

    Journal of the American Chemical Society · 2024-07-22

    Qiang‐Qiang Jia, Gele Teri, Jia‐Qi Luo, Hao‐Fei Ni, Pei‐Zhi Huang, Meng‐Meng Lun, Zhi‐Xu Zhang, Yi Zhang, Da‐Wei Fu

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  7. Near‐Unity Narrow Green Emitting in Manganese Halides Realized by Direct Precipitation Synthesis

    Laser & Photonics Review · 2024-08-20

    Huimin Dong, Yiqun Sun, Liangliang Zhang, Dan Wu, Heping Shen, Guohui Pan, Hao Wu, Huajun Wu, Zhendong Hao, Jiahua Zhang

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  8. CsPbBr3 perovskite quantum dots/p-GaN heterojunction for ultraviolet-visible spectrum photodetectors

    Applied Physics Letters · 2024-11-11

    Yushen Liu, Bingjie Ye, Yang Gao, Xifeng Yang, Mingfa Peng, Guofeng Yang

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  9. Strong Correlation Between A‐Site Cation Order and Self‐Trapped Exciton Emission in 0D Hybrid Perovskites

    Small Science · 2024-11-22

    Feier Fang, Yongwang Shen, Yu Li, Kaimin Shih, Hanlin Hu, Haizhe Zhong, Yumeng Shi, Tom Wu

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  10. Supramolecular Rotor Assembly for the Design of a Hybrid Ferroelectric‐Antiferromagnetic Multiferroic Semiconductor

    Angewandte Chemie · 2024-12-02

    Na Wang, Hua‐Kai Li, H. M. Shen, Le Ye, Ze‐Jiang Xu, Mei-Ling Ren, Nian‐Tao Yao, Chao Yi Shi, Heng‐Yun Ye, Le‐Ping Miao

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  11. Supramolecular Rotor Assembly for the Design of a Hybrid Ferroelectric‐Antiferromagnetic Multiferroic Semiconductor

    Angewandte Chemie International Edition · 2024-12-02

    Na Wang, Hua‐Kai Li, H. M. Shen, Le Ye, Ze‐Jiang Xu, Mei-Ling Ren, Nian‐Tao Yao, Nian‐Tao Yao, Chao Yi Shi, Chao Yi Shi, Heng‐Yun Ye, Heng‐Yun Ye, Le‐Ping Miao

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  12. Engineering magnetism in hybrid organic–inorganic metal halide perovskites

    Materials Horizons · 2025-01-01

    Yaiza Asensio, Lucía Olano‐Vegas, Samuele Mattioni, Marco Gobbi, Fèlix Casanova, Luis E. Hueso, Beatriz Martín‐García

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  13. High phase transition temperature and photoluminescence properties in low-dimensional molecular perovskite ferroelastic crystals

    CrystEngComm · 2025-01-01

    Jiamei Zhang, Zhe‐Kun Xu, Yan Fang Qin, Peng-Fei Li, Zhong-Xia Wang

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  14. Retainable large magnetoelectric coupling in BiFeO3@CoFe2O4 core-shell nanoparticle embedded P(VDF-TrFE) matrix

    Applied Physics Letters · 2025-02-24

    Chenyang Wang, Xu Ling-Fang, Xiang Lv, Yalong Ge, Ruilong Wang, Shiheng Liang, Haibo Xiao, C.P. Yang

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  15. Butylammonium Hexachlorostannate for Lithium-Ion Batteries: An Experimental Application

    Journal of Electronic Materials · 2025-04-17

    Alfredo Romero-Contreras, Edgar González-Juaréz, Ricardo Briones-Martínez, Eduardo M. Sánchez

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  16. Advances in Nanoelectronics: Carbon Nanotubes, Graphene, and Smart Polymers: A review

    Trends in Sciences · 2025-05-20

    Ehsan Kianfar

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  17. Magnetic Organic–Inorganic Hybrid Halide Perovskites: Fundamental Physics, Properties, and Applications

    ACS Nano · 2025-06-16

    Bing Sun, Haolin Lu, Dezheng Yang, Guankui Long, Hao‐Li Zhang, Desheng Xue

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  18. Unraveling Lattice Void Occupancy Engineering for Regulating Optical/Dielectric Responses in Hybrid Crystals

    Crystal Growth & Design · 2025-07-14

    Linmei Li, Cha‐Hui Du, Linyi Wu, Peng-Cheng Zhuge, Ji Liu, Zeng-Jie Xiao, Gele Teri, Hao‐Fei Ni, Qiang‐Qiang Jia, Zhi‐Xu Zhang, Yi Zhang, Da‐Wei Fu

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  19. A Perspective on Spatiotemporal Engineering of Multidimensional Heterointerfaces in Perovskite Solar Cells

    ACS Nano · 2025-07-29

    Ziyue Feng, Mingrui He, Zhen Li, Xiaojing Hao

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  20. Recovery of Lead‐Zinc Slags to Methyl‐Ammonium Lead Tri‐Iodide With Single‐Atom Fe–N4 Sites for Piezocatalytic Hydrogen Evolution

    Carbon Energy · 2025-07-30

    Fangyan Liu, Mengye Wang, Jiawen Liu, Gao Feng, Jiahui Lin, Jiaqing He, Feng Zhu, Chuan Liu, Zhang Lin

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  21. Alkaline Earth Metal‐Based Hybrid Organic‐Inorganic Perovskite‐Like Ferroelectrics

    Angewandte Chemie International Edition · 2025-07-31

    Qi‐Fang Zhou, Lei Pan, Hao‐Fei Ni, Lou‐Kai Ye, Yan‐Ping Zhao, Qing‐Ke Luo, Gele Teri, Jia‐Qi Luo, Da‐Wei Fu, Zhi‐Xu Zhang, Chao Yi Shi, Yi Zhang

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  22. Alkaline Earth Metal‐Based Hybrid Organic‐Inorganic Perovskite‐Like Ferroelectrics

    Angewandte Chemie · 2025-07-31

    Qi‐Fang Zhou, Lei Pan, Hao‐Fei Ni, Lou‐Kai Ye, Yan‐Ping Zhao, Qing‐Ke Luo, Gele Teri, Jia‐Qi Luo, Da‐Wei Fu, Zhi‐Xu Zhang, Chao Yi Shi, Yi Zhang

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  23. Halogen substitution strategy of spacer cations in two-dimensional perovskite ferroelectrics gives giant anomalous photovoltaic effect

    Nature Communications · 2025-08-14

    Wenjing Li, Yu Ma, Yi Liu, Haojie Xu, Wuqian Guo, Qingshun Fan, Liwei Tang, Hao Rong, Junhua Luo, Zhihua Sun

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  24. Organic cation functionalization of zinc-based hybrid perovskite materials on synergistic modulation of phase transition and nonlinear optical properties

    Journal of Molecular Structure · 2025-08-18

    Xiuli You, Siqi Yang, Feiyan Liu, Guoyong Chen, Mingjun Zou, Guobing Yan, Xing‐Cong Wang, Zhenhong Wei

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  25. Doping Effects on Magnetic Layered Hybrid Organic–Inorganic Transition Metal Halide Perovskites

    ACS Applied Materials & Interfaces · 2025-09-16

    Samuele Mattioni, Yaiza Asensio, Pavlo Solokha, Lucía Olano‐Vegas, Mirko Prato, Serena DE NEGRI, Marco Gobbi, Fèlix Casanova, Aurelio Mateo‐Alonso, Luis E. Hueso, Beatriz Martín‐García

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  26. High-Frequency Switchable Dielectric Properties of a Molecule-Based Hybrid Perovskite in a Microwave Band

    Inorganic Chemistry · 2025-09-25

    Ya-Ru Hou, Yi-Lin Zhan, Zhe‐Kun Xu, Xiao‐Gang Chen, Zhong‐Xia Wang, Hui‐Peng Lv

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  27. The Impact of Supramolecular Forces on the Magnetic and Optical Properties of Bis(2-amino-6-bromopyridinium) Tetrachloridocuprate (C5H6BrN2)2[CuCl4]

    Inorganics · 2025-10-16

    Lokmen Ghorbali, Vladimir Kjartan Stojadinovic, Axel Klein, Hammouda Chebbi

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  28. Empirical equations to estimate tetragonal to cubic phase transitions in lead iodide perovskites

    Physical Chemistry Chemical Physics · 2026-01-01

    Fernando B. Minussi, Rogério M. da Silva, Thays Brondani Abreu, Jose A. Eiras, Eudes Borges Araújo

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  29. Engineering Thermoresponsive Dielectric Properties and Phase Transitions via Confinement of Polar Cations in Photoisomerizable Nitroprusside Frameworks

    Inorganic Chemistry · 2026-01-21

    Zhou-Yu Fu, Zi-Luo Fang, Huan Yang, Ming‐Yu Guo, Wei‐Jian Xu, Wei‐Xiong Zhang

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  30. Anion···π interactions and hydrogen bonds in cyanidometallate-based co-crystal systems: novel synthons, functional properties, and stories behind them

    Coordination Chemistry Reviews · 2026-02-14

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  31. In-situ organic cation evolution driven sequential crystal transformation in hybrid metal halides

    National Science Open · 2026-03-11

    Wenqing Han, Junjie Guan, Xufan Guo, Wenting Liu, Ruijia Zhao, Zhihua Wang, Lin Xu, Puxin Cheng, Minghui Chen, Quanwen Li, Danhong Wang, Jialiang Xu, Xian‐He Bu

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  32. Dimensionality Engineering: A Pathway to Ferroelectric Halide Perovskites

    Small Structures · 2026-04-01

    Hyeongyu Gim, Chiyeong Han, Geon Kim, Hyojung Kim, Kootak Hong, J I Y O N G PARK, Ho Won Jang

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  33. Emerging Molecular Antiferroelectrics: Advances and Prospects

    Advanced Science · 2026-04-02

    Xiaoqi Li, Qianxi Wang, Xiaoyu Zhang, Yating You, Zhihua Sun, Xitao Liu, Junhua Luo

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  34. Isopropylammonium as a Dual-Role Cation: Spacer and Perovskitizer in Ruddlesden–Popper Lead Bromides

    Inorganic Chemistry · 2026-04-29

    Mirosław Mączka, Anna Gągor, Barbara Popanda, Maciej Ptak, Dagmara Stefańska, Katarzyna Fedoruk, Jan K. Zaręba, Adam Sieradzki

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  35. Ion Migration in Two-Dimensional Organic–Inorganic Hybrid Perovskite Heterostructures: Interface Evolution, Migration Mechanisms and Device Implications

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  36. Direct Observation of Noncollinear Ferrielectricity in a Two-Dimensional Hybrid Germanium Perovskite

    Journal of the American Chemical Society · 2026-06-15

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  37. Metal Halide Perovskites for Violet and Ultraviolet Light Emission

    ACS Nano · 2026-06-18

    Sebastian Fernández, Manchen Hu, Tyler Colenbrander, Divine Mbachu, Daniel N. Congreve

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  38. Mixed-Ligand Engineering of Manganese Perovskite-like Materials with Tunable Solid−Solid Phase Transitions

    ACS Applied Energy Materials · 2026-06-25

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  39. Ferroic Phase Transition‐Triggered Large Anisotropic Actuation in 1D Chiral Hybrid Metal Halides

    Advanced Functional Materials · 2026-07-01

    Chao‐Yang Chai, Qiang-Qiang Bi, Ming‐Liang Jin, C H Liu, Shu-Yin Jia, Jia-Hang Wu, Yue Zhao, Zhao‐Rui Hua, Shuo Tan, Wen Zhang

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  40. Halide Perovskites for Photo(electro)catalytic Sustainable Energy: Recent Advances and Challenges

    ChemSusChem · 2026-07-16

    R G Yin, Zhiyan Ying, Yinzhu Shu, Sijie Yang, Shudan Chi, Guangya Diao, Zi Wang, W Z Wang, Yuzhe Chen, Haoying Han, Guohua Gong, Yunfan Qiu, Liwei Xiong, Liang Huang

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  41. How Polarization Switch Influences Both Charge Separation and Carrier Recombination in Hybrid Perovskites

    The Journal of Physical Chemistry Letters · 2026-07-16

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  42. Enhanced Bulk Photovoltaics in Polar 2D Hybrid Perovskite via Pressure‐Strengthened Organic‐Inorganic Interactions

    Advanced Materials · 2026-09-29

    Shiyu Fang, Kejun Bu, Huang Ye, Lijun Xu, Dong Wang, Songhao Guo, Tonghuan Fu, Yuhong Mao, Yuchen Ye, Liwei Tang, Philip Dalladay‐Simpson, Federico Aiace Gorelli, Yiqiang Zhan, Yang Ding, Zhihua Sun, Junhua Luo, Xujie Lü

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