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RESEARCH PAPER · Nature Communications · 2024

Chiral multiferroicity in two-dimensional hybrid organic-inorganic perovskites

Haining Zheng, Arup K. Ghosh, M. J. Swamynadhan, Qihan Zhang, Walter P. D. Wong, Zhenyue Wu, Rongrong Zhang, Jingsheng Chen, Fanica Cimpoesu, Saurabh Ghosh, Branton J. Campbell, Kai Wang, Alessandro Stroppa, R. Mahendiran, Kian Ping Loh

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Chiral multiferroicity in two-dimensional hybrid organic-inorganic perovskitesOriginalChiral Ionic Liquids Enable High‐Performance Room Temperature Single Junction Spin‐Light Emitting Diodes21The role of metal-halide bond in the distortions and asymmetric non-covalent interactions in chiral hybrid perovskites11Deconvolution of X-ray natural and magnetic circular dichroism in chiral Dy-ferroborate3Electric toroidal dipole order and hidden spin polarization in ferroaxial materials13Chirality‐Dependent Anisotropic Nonlinear Optical Effect in Low‐Dimensional Hybrid Metal Halides10Supramolecular Rotor Assembly for the Design of a Hybrid Ferroelectric‐Antiferromagnetic Multiferroic Semiconductor0Supramolecular Rotor Assembly for the Design of a Hybrid Ferroelectric‐Antiferromagnetic Multiferroic Semiconductor9Dynamic control of halide perovskite structures for tailored ferroelectric and second-order nonlinear optical functionalities39Stepwise kinetics of the early-stage nucleation in chiral perovskites via ab initio molecular dynamics and free-energy calculations4Hafnium-Based Chiral 2D Organic–Inorganic Hybrid Metal Halides: Engineering Polarity and Nonlinear Optical Properties via Para -Substituent Effects86The First Kleinman‐type Second‐Harmonic Generation Circular Dichroism On/Off Switchable Ferroelectrics28The First Kleinman‐type Second‐Harmonic Generation Circular Dichroism On/Off Switchable Ferroelectrics4The First Recyclable Molecular Ferroelectric Can Catalyze Difunctionalization of Olefin7Spatial Symmetry Operation Breaking Sulfur-Chiral Photoswitchable Ferroelectrics22Chiral europium halides with high-performance magnetic field tunable red circularly polarized luminescence at room temperature49Electrical Control of Spin Polarization in a Multiferroic Heterojunction Based on One-Dimensional Chiral Hybrid Metal Halide10Above room temperature T C , 100% spin-polarization, and a high thermoelectric response in the ordered CaCu 3 Mn 2 Ir 2 O129Ordered assembly of templated chiral/achiral organic cations toward efficient circularly polarized emission in hybrid antimony chlorides11Application of Molecular Ferroelectric in Photocatalytic Selective Oxidization of C(sp 3 )─H Bonds9Application of Molecular Ferroelectric in Photocatalytic Selective Oxidization of C(sp 3 )─H Bonds0Alkali Metal Substitution for Modulating Three-Dimensional Halide Double Perovskite Ferroelectric3Enantiomeric Ferroelectric Chiral Domains18Spatial Confinement-Assisted Vapor-Phase Synthesis of Two-Dimensional Cs3Sb2I9 for Photodetection Application4Magnetic Organic–Inorganic Hybrid Halide Perovskites: Fundamental Physics, Properties, and Applications14Mathematical Double‐Matrix Switchable Homochiral Ferroelectric18Mathematical Double‐Matrix Switchable Homochiral Ferroelectric6Chiral Multiferroics for Detection and Imaging of Circularly Polarized Light3Lone pair expression in fluorinated two-dimensional hybrid perovskite enables multiaxial ferroelectricity and nonlinear optical response24The First Ferrocene‐Based Molecular Ferroelectric Accompanied by Spatial Symmetry Operation Breaking2The First Ferrocene‐Based Molecular Ferroelectric Accompanied by Spatial Symmetry Operation Breaking7Chiral Terbium Halide for Narrow-Band X-ray Scintillation21Strain-Induced Interlayer Interactions under Hydrostatic Pressure Can Boost Circularly Polarized Luminescence in Chiral Hybrid Halide Perovskites3Organic–inorganic perovskite ferroelectric catalytic selective alkyne coupling under ultrasound sonication2Two-dimensional mixed tetrahedral–octahedral hybrid perovskites with coexisting ferroelectricity and intralayer antiferromagnetism6Studies of magnetic ferroelectricity in two-dimensional CuO using Green’s function method0Coupling structural phase transition, thermochromism and magnetic circular dichroism in a Cu( ii )-based hybrid perovskite0Internally and externally induced chiral hybrid metal halide materials for advanced chiroptoelectronic applications23Metal atom-induced electronic and magnetic properties in racemic metal–organic crystals0Molecular modification in hybrid materials induces multiple ferroic ordering1Rotational symmetry dication assembling ferroelectric, thermochromic and circularly polarized luminescent multifunctional manganese( ii ) bromide hybrid6Symmetry Breaking in High-Speed Synthesized Chiral Two-Dimensional Perovskite Single Crystals Enabling Polarization-Sensitive Advanced Optoelectronics1Optical Magnetoelectric Effect in a Polar Ferromagnetic Two-Dimensional Organic–Inorganic Hybrid Perovskite1Chiral-deformation-induced polarons as a design principle for white-light emission in 2D organic halide perovskites0Homocentric Chirality and Magnetism Enable Strong NIR Magneto-Optical Activity in a Chiral DyFe 3 Cluster5Organic-inorganic zinc halide multiferroic designed by tetrahedral halogen engineering0Dimensionality-Mixed Phases Facilitate Chirality Transfer and Spin-Orbit Coupling for Chiral Perovskite Red Spin-LEDs3Zero-Dimensional Chiral Copper Halides with Strong Circular Dichroism and Low-Temperature Ferromagnetism0Exploring Hybrid Metal Halide Materials beyond Halide Perovskites7Second-harmonic generation circular dichroism of chiral organic–inorganic hybrid metal halides: Insights and perspectives2Composition-Dependent Antiferromagnetism in Low-Dimensional Hybrid Organic Cobalt-Halide Semiconductors0Chiral Molecular Intercalation Enables Light-Controlled 2D Multiferroic Heterostructures2Dual tuning of second-harmonic generation and Rashba-Dresselhaus spin-splitting in chiral hybrid perovskites via halogen-site engineering1Exploring spin-phonon coupling, barocaloric, and polar phonon features in the multiferroic [(CH3)2NH2][Mn(N3)3] hybrid perovskite0Synergistic Paramagnetic, Piezoelectric, and Chiral Optical Effects in Fe- and Mn- Hybrid Metal Halides0Chirality Transfer to the Magnetic Sublattice in the Hybrid Perovskite (R)-/(S)-3-Fluoropyrrolidinium Copper(II) Chloride0Coupled Molecular and Framework Descriptors for Band-Edge Spin Splitting in Chiral Hybrid Organic–Inorganic Perovskites0Tracing the Origin of Chiropticity in Lead-Halide Perovskite Nanomaterials0Enabling coherence of polarized spin and photon in chiral nanoclusters through chirality-mediated magnetization control0Multiferroic Semiconducting Behavior in Quasi-2D Cu-Based Hybrid Perovskites0

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  1. Chiral Ionic Liquids Enable High‐Performance Room Temperature Single Junction Spin‐Light Emitting Diodes

    Laser & Photonics Review · 2024-09-20

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  2. The role of metal-halide bond in the distortions and asymmetric non-covalent interactions in chiral hybrid perovskites

    Journal of Physics Materials · 2024-10-01

    Mariagrazia Fortino, Alessandro Mattoni, Adriana Pietropaolo

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  3. Deconvolution of X-ray natural and magnetic circular dichroism in chiral Dy-ferroborate

    Scientific Reports · 2024-10-18

    D. Haskel, Choongjae Won, Yves Joly, J. Strempfer, G. Fabbris, Sang-Wook Cheong

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  4. Electric toroidal dipole order and hidden spin polarization in ferroaxial materials

    Physical Review Research · 2024-11-14

    Sayantika Bhowal, Nicola A. Spaldin

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  5. Chirality‐Dependent Anisotropic Nonlinear Optical Effect in Low‐Dimensional Hybrid Metal Halides

    Chemistry - A European Journal · 2024-11-26

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  6. Supramolecular Rotor Assembly for the Design of a Hybrid Ferroelectric‐Antiferromagnetic Multiferroic Semiconductor

    Angewandte Chemie · 2024-12-02

    Na Wang, Hua‐Kai Li, H. M. Shen, Le Ye, Ze‐Jiang Xu, Mei-Ling Ren, Nian‐Tao Yao, Chao Yi Shi, Heng‐Yun Ye, Le‐Ping Miao

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  7. Supramolecular Rotor Assembly for the Design of a Hybrid Ferroelectric‐Antiferromagnetic Multiferroic Semiconductor

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  8. Dynamic control of halide perovskite structures for tailored ferroelectric and second-order nonlinear optical functionalities

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  9. Stepwise kinetics of the early-stage nucleation in chiral perovskites via ab initio molecular dynamics and free-energy calculations

    Nanoscale · 2025-01-01

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  10. Hafnium-Based Chiral 2D Organic–Inorganic Hybrid Metal Halides: Engineering Polarity and Nonlinear Optical Properties via Para -Substituent Effects

    Journal of the American Chemical Society · 2025-01-08

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  11. The First Kleinman‐type Second‐Harmonic Generation Circular Dichroism On/Off Switchable Ferroelectrics

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  12. The First Kleinman‐type Second‐Harmonic Generation Circular Dichroism On/Off Switchable Ferroelectrics

    Angewandte Chemie · 2025-01-28

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  13. The First Recyclable Molecular Ferroelectric Can Catalyze Difunctionalization of Olefin

    Advanced Functional Materials · 2025-03-05

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  14. Spatial Symmetry Operation Breaking Sulfur-Chiral Photoswitchable Ferroelectrics

    Journal of the American Chemical Society · 2025-03-13

    Huanhuan Chen, Hang Peng, Zhe‐Kun Xu, Xian‐Jiang Song, Xiao-Gang Chen, Ren‐Gen Xiong, Wei‐Qiang Liao

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  15. Chiral europium halides with high-performance magnetic field tunable red circularly polarized luminescence at room temperature

    Nature Communications · 2025-03-14

    Xinyi Niu, Yang Li, Haolin Lu, Zhaoyu Wang, Yunxin Zhang, Tianyin Shao, Hebin Wang, Sehrish Gull, Bing Sun, Hao‐Li Zhang, Yongsheng Chen, Kai Wang, Yaping Du, Guankui Long

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  16. Electrical Control of Spin Polarization in a Multiferroic Heterojunction Based on One-Dimensional Chiral Hybrid Metal Halide

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  17. Above room temperature T C , 100% spin-polarization, and a high thermoelectric response in the ordered CaCu 3 Mn 2 Ir 2 O12

    Physica B Condensed Matter · 2025-03-23

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  18. Ordered assembly of templated chiral/achiral organic cations toward efficient circularly polarized emission in hybrid antimony chlorides

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  19. Application of Molecular Ferroelectric in Photocatalytic Selective Oxidization of C(sp 3 )─H Bonds

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  20. Application of Molecular Ferroelectric in Photocatalytic Selective Oxidization of C(sp 3 )─H Bonds

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  21. Alkali Metal Substitution for Modulating Three-Dimensional Halide Double Perovskite Ferroelectric

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  22. Enantiomeric Ferroelectric Chiral Domains

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  23. Spatial Confinement-Assisted Vapor-Phase Synthesis of Two-Dimensional Cs3Sb2I9 for Photodetection Application

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  24. Magnetic Organic–Inorganic Hybrid Halide Perovskites: Fundamental Physics, Properties, and Applications

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  25. Mathematical Double‐Matrix Switchable Homochiral Ferroelectric

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  26. Mathematical Double‐Matrix Switchable Homochiral Ferroelectric

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  27. Chiral Multiferroics for Detection and Imaging of Circularly Polarized Light

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  28. Lone pair expression in fluorinated two-dimensional hybrid perovskite enables multiaxial ferroelectricity and nonlinear optical response

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  29. The First Ferrocene‐Based Molecular Ferroelectric Accompanied by Spatial Symmetry Operation Breaking

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  30. The First Ferrocene‐Based Molecular Ferroelectric Accompanied by Spatial Symmetry Operation Breaking

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  31. Chiral Terbium Halide for Narrow-Band X-ray Scintillation

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  32. Strain-Induced Interlayer Interactions under Hydrostatic Pressure Can Boost Circularly Polarized Luminescence in Chiral Hybrid Halide Perovskites

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  33. Organic–inorganic perovskite ferroelectric catalytic selective alkyne coupling under ultrasound sonication

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  34. Two-dimensional mixed tetrahedral–octahedral hybrid perovskites with coexisting ferroelectricity and intralayer antiferromagnetism

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  35. Studies of magnetic ferroelectricity in two-dimensional CuO using Green’s function method

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  36. Coupling structural phase transition, thermochromism and magnetic circular dichroism in a Cu( ii )-based hybrid perovskite

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  39. Molecular modification in hybrid materials induces multiple ferroic ordering

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  40. Rotational symmetry dication assembling ferroelectric, thermochromic and circularly polarized luminescent multifunctional manganese( ii ) bromide hybrid

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  41. Symmetry Breaking in High-Speed Synthesized Chiral Two-Dimensional Perovskite Single Crystals Enabling Polarization-Sensitive Advanced Optoelectronics

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  42. Optical Magnetoelectric Effect in a Polar Ferromagnetic Two-Dimensional Organic–Inorganic Hybrid Perovskite

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  43. Chiral-deformation-induced polarons as a design principle for white-light emission in 2D organic halide perovskites

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  44. Homocentric Chirality and Magnetism Enable Strong NIR Magneto-Optical Activity in a Chiral DyFe 3 Cluster

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  45. Organic-inorganic zinc halide multiferroic designed by tetrahedral halogen engineering

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  46. Dimensionality-Mixed Phases Facilitate Chirality Transfer and Spin-Orbit Coupling for Chiral Perovskite Red Spin-LEDs

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  48. Exploring Hybrid Metal Halide Materials beyond Halide Perovskites

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  49. Second-harmonic generation circular dichroism of chiral organic–inorganic hybrid metal halides: Insights and perspectives

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  50. Composition-Dependent Antiferromagnetism in Low-Dimensional Hybrid Organic Cobalt-Halide Semiconductors

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