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RESEARCH PAPER · ACS Energy Letters · 2023

Nanostructured Metal Chalcohalide Photocatalysts: Crystal Structures, Synthesis, and Applications

Sanjib Shyamal, Narayan C. Pradhan

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Nanostructured Metal Chalcohalide Photocatalysts: Crystal Structures, Synthesis, and ApplicationsOriginal2023 Nobel Prize in Chemistry: A Mega Recognition for Nanosized Quantum Dots36Advancements in semiconductor quantum dots: expanding frontiers in optoelectronics, analytical sensing, biomedicine, and catalysis138Lead-Free Semiconductors: Phase-Evolution and Superior Stability of Multinary Tin Chalcohalides1Lead-Free Semiconductors: Phase-Evolution and Superior Stability of Multinary Tin Chalcohalides2Photoactive metal chalcogenides towards CO2 reduction–a review8Lead-Free Semiconductors: Phase-Evolution and Superior Stability of Multinary Tin Chalcohalides19Ultrasmall CsPbBr3 Blue Emissive Perovskite Quantum Dots Using K-Alloyed Cs4PbBr6 Nanocrystals as Precursors27Solution-processed ZnBi2S4 polycrystalline thin films for low noise photodetection3Ultrathin, High‐Aspect‐Ratio Bismuth Sulfohalide Nanowire Bundles for Solution‐Processed Flexible Photodetectors11A review of chalcogenide-based perovskites as the next novel materials: Solar cell and optoelectronic applications, catalysis and future perspectives111Design of a High-Performance Near-Infrared Scintillator through Metal-Atom Substitution in Metal Chalcogenide5Recent progress on bismuth-based materials for full-spectrum-driven photocatalysis14Advancements in metal selenide nanocomposites for efficient photocatalytic water splitting applications8A chemical vapor-assisted highly crystalized SbSI solar cell and a photodetector with bifacial passivation to mitigate the charge transport loss1A new helical InSeI polymorph: crystal structure and polarized Raman spectroscopy study3Controlled colloidal synthesis of anisotropic mixed-metal chalcohalides: insights into morphology and phase evolution0A facile ultrasound-assisted synthesis and DFT evaluation of 3D hierarchical tin disulfide nanoflowers1Synthesis, Growth Mechanism, and Photocatalytic Properties of Metallic-Bi/Bi 13 S 18 Br 2 Nano-Bell Heterostructures5The Rise of Chalcohalide Solar Cells: Comprehensive Insights From Materials to Devices20Halide Perovskite Photocatalysts for Clean Fuel Production and Organic Synthesis: Opportunities and Challenges68Tuning the Reaction Chemistry for the Sulfo-Bromination of Bismuth, Leading to Dual-Tapered Bi-Sulfobromide Platelet Nanocrystals and Their Heterostructures7Cs3Bi2Br9/Bi19Br3S27 Z-scheme heterojunction for visible-to-near-infrared light-driven photocatalytic CO2 reduction19Composition-Dependent Photoelectrochemical Properties of Low-Toxic Bismuth Chalcohalide Nanorods Synthesized via a Solution-Phase Method0Controlling the Microstructure, Evolution of Phases, and Optical Properties of Spark Plasma Sintered Nd3+-Doped KLaF4 Oxyfluoride Glass-Ceramics0Controlling the Microstructure, Evolution of Phases, and Optical Properties of Spark Plasma Sintered Nd³⁺-Doped KLaF₄ Oxyfluoride Glass-Ceramics0Layered mixed-anion chalcohalides Pb 4 Sb 4 Q 9 Cl 2 (Q = S, Se): puckered 2D frameworks, indirect band gaps, and low thermal conductivity0Quasi-1D selenohalides: first-principles insights into thermoelectric and photovoltaic applications1Structural chemistry and applications of heteroanionic rare-earth metal chalcogenide halides1Machine Learning for the Prediction of Chalcohalide Energy Band Gaps: A Tool for Identifying New Photovoltaic and Photosensitive Materials1Alloyed Quantum Dots with Tuned Exciton Wave Function Delocalization for Enhanced Energy Transfer0Silyl Hot-Injection Versus Thiocyanate Heat-Up Synthesis of Chalcohalides: Pushing the Size and Composition Envelope0Self-Trapped Excitons and Room-Temperature Ferroelectricity in Quasi-One-Dimensional Semiconductor BiSeBr for Polarization-Sensitive Optoelectronics0Cation-substitution-driven electronic, nonlinear optical, elastic, and thermal transport properties of layered AeHgGeSe4 (Ae = Ba, Sr): A first-principles study0Directing Near‐Perfect (001) Orientation in Wafer‐Scale BiOI Thin Films via Halide‐Mediated van der Waals Stacking0

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  1. 2023 Nobel Prize in Chemistry: A Mega Recognition for Nanosized Quantum Dots

    ACS Energy Letters · 2023-12-08

    D. D. Sarma, Prashant V. Kamat

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  2. Advancements in semiconductor quantum dots: expanding frontiers in optoelectronics, analytical sensing, biomedicine, and catalysis

    Journal of Materials Chemistry C · 2024-01-01

    Jiban Mondal, Rohan Lamba, Yukta Yukta, Rohit Kumar Yadav, Ram Kumar, Balaram Pani, Bholey Singh

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  3. Lead-Free Semiconductors: Phase-Evolution and Superior Stability of Multinary Tin Chalcohalides

    ChemRxiv · 2024-01-24

    Alison N. Roth, Andrew P. Porter, Sarah Horger, Kerly Ochoa-Romero, Gonzalo Guirado, Aaron J. Rossini, Javier Vela

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  4. Lead-Free Semiconductors: Phase-Evolution and Superior Stability of Multinary Tin Chalcohalides

    ChemRxiv · 2024-01-24

    Alison N. Roth, Andrew P. Porter, Sarah Horger, Kerly Ochoa-Romero, Gonzalo Guirado, Aaron J. Rossini, Javier Vela

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  5. Photoactive metal chalcogenides towards CO2 reduction–a review

    Colloid & Polymer Science · 2024-02-23

    Shweta Gomey, Eksha Guliani, Kajal Choudhary, Sucheta Sengupta, Biswarup Chakraborty, Manoj Raula

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  6. Lead-Free Semiconductors: Phase-Evolution and Superior Stability of Multinary Tin Chalcohalides

    Chemistry of Materials · 2024-04-19

    Alison N. Roth, Andrew P. Porter, Sarah Horger, Kerly Ochoa-Romero, Gonzalo Guirado, Aaron J. Rossini, Javier Vela

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  7. Ultrasmall CsPbBr3 Blue Emissive Perovskite Quantum Dots Using K-Alloyed Cs4PbBr6 Nanocrystals as Precursors

    ACS Energy Letters · 2024-04-23

    Clara Otero‐Martínez, Matteo L. Zaffalon, Yurii P. Ivanov, Nikolaos Livakas, Luca Goldoni, Giorgio Divitini, Sankalpa Bora, Gabriele Saleh, Francesco Meinardi, Andrea Fratelli, Sudip Chakraborty, Lakshminarayana Polavarapu, Sergio Brovelli, Liberato Manna

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  8. Solution-processed ZnBi2S4 polycrystalline thin films for low noise photodetection

    Applied Physics Letters · 2024-06-03

    Haoyu Zhao, Zhenglin Jia, Yujie Yang, Yong Liu, Qianqian Lin

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  9. Ultrathin, High‐Aspect‐Ratio Bismuth Sulfohalide Nanowire Bundles for Solution‐Processed Flexible Photodetectors

    Advanced Science · 2024-07-04

    Da Won Lee, Seongkeun Oh, Seongkeun Oh, Dong Hyun David Lee, Ho Young Woo, Junhyuk Ahn, Seung Hyeon Kim, Byung Ku Jung, Yoonjoo Choi, Dagam Kim, Mi Yeon Yu, Chun Gwon Park, Hongseok Yun, Taehyung P. Kim, Myung Joon Han, Soong Ju Oh, Soong Ju Oh, Taejong Paik

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  10. A review of chalcogenide-based perovskites as the next novel materials: Solar cell and optoelectronic applications, catalysis and future perspectives

    Next Nanotechnology · 2024-09-11

    George G. Njema, Joshua Kiprotich Kibet

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  11. Design of a High-Performance Near-Infrared Scintillator through Metal-Atom Substitution in Metal Chalcogenide

    Inorganic Chemistry · 2024-11-15

    Liangwei Yang, Zhuolei Zhang, Rensheng Wang, Menglin Qiu, Yumin Wang, Yumin Wang, Ming Li, Siyan Huang, Zhidong Wu, Linwei He, Xing Dai, Zhifang Chai, Shuao Wang, Yaxing Wang, Yaxing Wang

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  12. Recent progress on bismuth-based materials for full-spectrum-driven photocatalysis

    Journal of environmental chemical engineering · 2024-11-17

    Jing Liu, Shuo Du, Qiuhui Zhu, Abdelkader Labidi, Hongfang Wang, Chuanyi Wang, Chuanyi Wang

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  13. Advancements in metal selenide nanocomposites for efficient photocatalytic water splitting applications

    Fuel · 2024-11-28

    Zeshan Ali Sandhu, Soha Ghaffar, Muhammad Asam Raza, Noor ul Huda, Sufyan Ashraf, Umair Talat, Areej Chauhdary, Hamza Gulzarab, Abdullah Godran Al-Sehemi

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  14. A chemical vapor-assisted highly crystalized SbSI solar cell and a photodetector with bifacial passivation to mitigate the charge transport loss

    Journal of Materials Chemistry C · 2025-01-01

    Shosuke Murayama, Ryosuke Nishikubo, Tai Kobayashi, Saeki Akinori

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  15. A new helical InSeI polymorph: crystal structure and polarized Raman spectroscopy study

    Journal of Materials Chemistry C · 2025-01-01

    Lucía Olano‐Vegas, Davide Spirito, Evgeny B. Modin, P. Solokha, Sergio Marras, Marco Gobbi, Fèlix Casanova, Serena DE NEGRI, Luis E. Hueso, Beatriz Martín‐García

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  16. Controlled colloidal synthesis of anisotropic mixed-metal chalcohalides: insights into morphology and phase evolution

    Nanoscale · 2025-01-01

    Davide Pratolongo, Ankita Bora, Suvodeep Sen, Niraj Nitish Patil, Stefano Alberti, Manoj Palabathuni, Federico Locardi, Shalini Singh

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  17. A facile ultrasound-assisted synthesis and DFT evaluation of 3D hierarchical tin disulfide nanoflowers

    Next Materials · 2025-03-08

    Bayu Tri Murti, Athika Darumas Putri, Ma’rifatun Izati, Mazaya Sulaekhah, Ching‐Yun Chen, Po‐Kang Yang

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  18. Synthesis, Growth Mechanism, and Photocatalytic Properties of Metallic-Bi/Bi 13 S 18 Br 2 Nano-Bell Heterostructures

    ACS Materials Letters · 2025-04-01

    Anna Cabona, Stefano Toso, Andrea Griesi, Martina Rizzo, Michele Ferri, Pascal Rusch, Giorgio Divitini, Julia Pérez‐Prieto, Raquel E. Galian, Ilka Kriegel, Liberato Manna

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  19. The Rise of Chalcohalide Solar Cells: Comprehensive Insights From Materials to Devices

    Advanced Science · 2025-04-17

    Hongrui Zhang, Yiming Xia, Yangfan Zhang, Uma V. Ghorpade, Mingrui He, Seung Wook Shin, Xiaojing Hao, Mahesh P. Suryawanshi

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  20. Halide Perovskite Photocatalysts for Clean Fuel Production and Organic Synthesis: Opportunities and Challenges

    Advanced Materials · 2025-05-09

    Siddharth Singh, Zeinab Hamid, Ramavath Babu, Sergio Gómez‐Graña, Xiaowen Hu, Iain A. McCulloch, Robert L. Z. Hoye, Vishal Govind Rao, Lakshminarayana Polavarapu

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  21. Tuning the Reaction Chemistry for the Sulfo-Bromination of Bismuth, Leading to Dual-Tapered Bi-Sulfobromide Platelet Nanocrystals and Their Heterostructures

    Journal of the American Chemical Society · 2025-05-13

    Sanjib Shyamal, Avijit Patra, Naveen Goyal, Souvik Banerjee, Sumit Kumar Dutta, Narayanan Ravishankar, Narayan C. Pradhan

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  22. Cs3Bi2Br9/Bi19Br3S27 Z-scheme heterojunction for visible-to-near-infrared light-driven photocatalytic CO2 reduction

    Journal of Colloid and Interface Science · 2025-06-18

    Zhihong Liu, Jiale Liu, Jin Wang, Ping Lu, Shishun Xu, Yi Lu, Xiaofei Li, Qiaowen Zhang, Guocan Jiang, Zhengquan Li

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  23. Composition-Dependent Photoelectrochemical Properties of Low-Toxic Bismuth Chalcohalide Nanorods Synthesized via a Solution-Phase Method

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  24. Controlling the Microstructure, Evolution of Phases, and Optical Properties of Spark Plasma Sintered Nd3+-Doped KLaF4 Oxyfluoride Glass-Ceramics

    SSRN Electronic Journal · 2026-01-01

    Qiang Chen Chen

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  25. Controlling the Microstructure, Evolution of Phases, and Optical Properties of Spark Plasma Sintered Nd³⁺-Doped KLaF₄ Oxyfluoride Glass-Ceramics

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  26. Layered mixed-anion chalcohalides Pb 4 Sb 4 Q 9 Cl 2 (Q = S, Se): puckered 2D frameworks, indirect band gaps, and low thermal conductivity

    Dalton Transactions · 2026-01-01

    Yen-Han Huang, Guan-Ruei Chen, Chi‐Shen Lee

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  27. Quasi-1D selenohalides: first-principles insights into thermoelectric and photovoltaic applications

    Journal of Materials Chemistry A · 2026-01-01

    Prakash Govindaraj, Hern Kim

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  28. Structural chemistry and applications of heteroanionic rare-earth metal chalcogenide halides

    Elsevier eBooks · 2026-01-01

    Thimira Kandabadage, Sviatoslav Baranets

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  29. Machine Learning for the Prediction of Chalcohalide Energy Band Gaps: A Tool for Identifying New Photovoltaic and Photosensitive Materials

    Energies · 2026-02-13

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  30. Alloyed Quantum Dots with Tuned Exciton Wave Function Delocalization for Enhanced Energy Transfer

    The Journal of Physical Chemistry Letters · 2026-02-23

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  31. Silyl Hot-Injection Versus Thiocyanate Heat-Up Synthesis of Chalcohalides: Pushing the Size and Composition Envelope

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  32. Self-Trapped Excitons and Room-Temperature Ferroelectricity in Quasi-One-Dimensional Semiconductor BiSeBr for Polarization-Sensitive Optoelectronics

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  33. Cation-substitution-driven electronic, nonlinear optical, elastic, and thermal transport properties of layered AeHgGeSe4 (Ae = Ba, Sr): A first-principles study

    Computational Condensed Matter · 2026-08-12

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  34. Directing Near‐Perfect (001) Orientation in Wafer‐Scale BiOI Thin Films via Halide‐Mediated van der Waals Stacking

    Advanced Materials · 2026-09-23

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