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RESEARCH PAPER · Small · 2023

Controlling the Nonlinear Optical Behavior and Structural Transformation with A‐Site Cation in α‐AZnPO4 (A = Li, K)

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Controlling the Nonlinear Optical Behavior and Structural Transformation with A‐Site Cation in α‐AZnPO4 (A = Li, K)OriginalBa 3 (BS 3 )(PS 4 ): the first alkaline-earth metal thioborate–thiophosphate with strong optical anisotropy originating from planar [BS 3 ] units8Water‐Assisted Growth of Twisted 3R‐Stacked MoSe 2 Spirals and Its Dramatically Enhanced Second Harmonic Generations12Charge compensators achieve controlled self-reduction of Europium in BaMgP2O730Positive and Negative Contribution from Lead–Oxygen Groups and Halogen Atoms to Birefringence: A First Principles Investigation4(C 3 N 6 H 7 )BF 4 ·H 2 O and (C 3 N 6 H 7 )SO 3 CH 3 ·H 2 O with large birefringence induced by coplanar π-conjugated [C 3 N 6 H 7 ] + groups33A-site cation manipulation of exemplary second harmonic generation response and optical anisotropy in rare-earth borates18Equivalent cation-tuning to realize a new Ce( iv ) fluoride with excellent comprehensive nonlinear optical performances12Novel antimony phosphates with enlarged birefringence induced by lone pair cations4Enhancement of Birefringence in π-Conjugated Oxyfluorides Achieved via van der Waals Layered Structural Optimization10Tetrahedra Modification of Phosphates for Optical Anisotropy Enhancement131D Bi ribbon/[PO 4 ] synergy-driven bismuth phosphates for ultraviolet nonlinear optical crystals with large SHG and birefringence0A 3 Sc(PO 4 ) 2 (A = Li, Na): rare earth cations effectively regulate phosphate structures for enhanced birefringence4Stuffed Tridymites A′A″Ga 4 O 8 (A′ = Ba, Sr, Ca; A″ = Pb): Integrating Stereochemically Active Lone Pairs with A-Site Ordering to Design a Polar Structure Featuring Distinctive Ring Topology3The Influence of Different Group Distortions on the Structure–Property Relationship of Alkali Metal Thiophosphate0Three-In-One: A Guanidinium-Containing Niobium Oxyfluoride with a Perovskite-like Structure Revealing Multifunctional Optical Properties2A-Site Cation Substitution toward Structural Transformation in Phosphates Exhibiting Short UV Transparency and Second Harmonic Response3Strategically designed deep-ultraviolet optical crystals with balanced properties by small heteroatom substitution1The condensation of π-conjugated units: a new paradigm for designing high-performance optical crystals4Linear [ICl 2 ] Units Induced Giant Optical Anisotropy in AICl 2 (A = NH 4 , Rb): A Pathway to Advanced Birefringent Materials4Doubly Ordered Stuffed Tridymite CaBaZn2Ge2O8: Structural Dimensionality Reduction via A-Site-Layered Ordering0

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  1. Ba 3 (BS 3 )(PS 4 ): the first alkaline-earth metal thioborate–thiophosphate with strong optical anisotropy originating from planar [BS 3 ] units

    Dalton Transactions · 2023-01-01

    Jiazheng Zhou, Linan Wang, Hongshan Wang, Ling Luo, Junjie Li, Feng Yu

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  2. Water‐Assisted Growth of Twisted 3R‐Stacked MoSe 2 Spirals and Its Dramatically Enhanced Second Harmonic Generations

    Small · 2023-04-24

    Xiangzhuo Wang, Qiuyu Shang, Fang Zhang, Jiepeng Song, Jiatian Fu, Liyun Zhao, Jingyi Hu, Jialong Wang, Wenzhi Quan, Yahuan Huan, Qilong Wu, Tinglu Song, Junfeng Han, Wende Xiao, Qing Zhang, Yanfeng Zhang

    Read original paper ↗ ·
  3. Charge compensators achieve controlled self-reduction of Europium in BaMgP2O7

    Chemical Engineering Journal · 2023-11-17

    Hongling Wang, Ke Su, Bin Ma, Yujia Wang, Lefu Mei, Qingfeng Guo, Libing Liao

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  4. Positive and Negative Contribution from Lead–Oxygen Groups and Halogen Atoms to Birefringence: A First Principles Investigation

    Nanomaterials · 2023-11-28

    Can Deng, Jialong Wang, Mei Hu, Xiuhua Cui, Haiming Duan, Peng Li, Ming‐Hsien Lee

    Read original paper ↗ ·
  5. (C 3 N 6 H 7 )BF 4 ·H 2 O and (C 3 N 6 H 7 )SO 3 CH 3 ·H 2 O with large birefringence induced by coplanar π-conjugated [C 3 N 6 H 7 ] + groups

    Inorganic Chemistry Frontiers · 2024-01-01

    Hangwei Jia, Die Xu, Zi‐Jian Li, Muhammad Sharjeel Arif, Yansheng Jiang, Xueling Hou

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  6. A-site cation manipulation of exemplary second harmonic generation response and optical anisotropy in rare-earth borates

    Chemical Science · 2024-01-01

    Jie Song, Huijian Zhao, Conggang Li, Ning Ye, Zhanggui Hu, Yicheng Wu

    Read original paper ↗ ·
  7. Equivalent cation-tuning to realize a new Ce( iv ) fluoride with excellent comprehensive nonlinear optical performances

    Inorganic Chemistry Frontiers · 2024-01-01

    Beibei Zhang, Wen‐Ye Gao, Wei Lin Xu, L. Ma, Wenlong Liu, Ru‐Ling Tang, Sheng‐Ping Guo

    Read original paper ↗ ·
  8. Novel antimony phosphates with enlarged birefringence induced by lone pair cations

    Dalton Transactions · 2024-01-01

    Mei Hu, Jialong Wang, Nuerbiye Tuerhong, Zhiyuan Zhang, Qun Jing, Zhaohui Chen, Yonglei Yang, Ming‐Hsien Lee

    Read original paper ↗ ·
  9. Enhancement of Birefringence in π-Conjugated Oxyfluorides Achieved via van der Waals Layered Structural Optimization

    Crystal Growth & Design · 2024-04-01

    Wenyao Zhang, Zichen Li, Xudong Leng, Qun Jing, Qiao Wen

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  10. Tetrahedra Modification of Phosphates for Optical Anisotropy Enhancement

    Advanced Optical Materials · 2024-08-29

    Haotian Qiu, Ran An, Junjie Li, Zhihua Yang, Shilie Pan, Miriding Mutailipu

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  11. 1D Bi ribbon/[PO 4 ] synergy-driven bismuth phosphates for ultraviolet nonlinear optical crystals with large SHG and birefringence

    Inorganic Chemistry Frontiers · 2025-01-01

    Lei Wu, Xudong Leng, Bao Jiang, Xueyin Fu, Yi Huang, Xue Yu, Qun Jing, Zhaohui Chen

    Read original paper ↗ ·
  12. A 3 Sc(PO 4 ) 2 (A = Li, Na): rare earth cations effectively regulate phosphate structures for enhanced birefringence

    Dalton Transactions · 2025-01-01

    Hongheng Chen, Xudong Leng, Mei Hu, Yibo Han, Haiming Duan, Qun Jing, Zhaohui Chen, Ming‐Hsien Lee

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  13. Stuffed Tridymites A′A″Ga 4 O 8 (A′ = Ba, Sr, Ca; A″ = Pb): Integrating Stereochemically Active Lone Pairs with A-Site Ordering to Design a Polar Structure Featuring Distinctive Ring Topology

    Chemistry of Materials · 2025-01-31

    Liyang Zhang, Zien Cheng, Guangxiang Lu, Ying Wang, Alicia Maria Manjón-Sanz, Rihong Cong, Tao Yang, Pengfei Jiang

    Read original paper ↗ ·
  14. The Influence of Different Group Distortions on the Structure–Property Relationship of Alkali Metal Thiophosphate

    Crystal Growth & Design · 2025-06-11

    Jiafu Ding, Zhihao He, Yunjie Wang, Xin Su, Yu Chu

    Read original paper ↗ ·
  15. Three-In-One: A Guanidinium-Containing Niobium Oxyfluoride with a Perovskite-like Structure Revealing Multifunctional Optical Properties

    Inorganic Chemistry · 2025-07-07

    Wenyao Zhang, Maiheliya Yahefu, Hongheng Chen, Yaqi Zhu, Qun Jing

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  16. A-Site Cation Substitution toward Structural Transformation in Phosphates Exhibiting Short UV Transparency and Second Harmonic Response

    Inorganic Chemistry · 2025-08-11

    Hanjing Huang, Xianghao Kong, Huijian Zhao, Ning Ye, Zhanggui Hu, Conggang Li

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  17. Strategically designed deep-ultraviolet optical crystals with balanced properties by small heteroatom substitution

    Inorganic Chemistry Frontiers · 2026-01-01

    Mei Hu, Zhencheng Wu, Xin Su, Hongheng Chen, Qun Jing, Zhaohui Chen, Ming‐Hsien Lee

    Read original paper ↗ ·
  18. The condensation of π-conjugated units: a new paradigm for designing high-performance optical crystals

    Chemical Society Reviews · 2026-01-01

    Hangwei Jia, Bailin Chen, Fangfang Zhang, Xueling Hou, Shilie Pan

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  19. Linear [ICl 2 ] Units Induced Giant Optical Anisotropy in AICl 2 (A = NH 4 , Rb): A Pathway to Advanced Birefringent Materials

    Advanced Functional Materials · 2026-05-22

    Du Yinxia, C J Huang, Hongshan Wang, Linan Wang, Z Chen, Miriding Mutailipu, Shilie Pan, J F Li

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  20. Doubly Ordered Stuffed Tridymite CaBaZn2Ge2O8: Structural Dimensionality Reduction via A-Site-Layered Ordering

    Chemistry of Materials · 2026-08-10

    Guangxiang Lu, Liyang Zhang, Zien Cheng, Jöerg C. Neuefeind, Rihong Cong, Tao Yang, Pengfei Jiang

    Read original paper ↗ ·