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RESEARCH PAPER · Advanced Functional Materials · 2022

Magnetic Properties of Layered Hybrid Organic‐Inorganic Metal‐Halide Perovskites: Transition Metal, Organic Cation and Perovskite Phase Effects

Yaiza Asensio, Sergio Marras, Davide Spirito, Marco Gobbi, Mihail Ipatov, Fèlix Casanova, Aurelio Mateo‐Alonso, Luis E. Hueso, Beatriz Martín‐García

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Magnetic Properties of Layered Hybrid Organic‐Inorganic Metal‐Halide Perovskites: Transition Metal, Organic Cation and Perovskite Phase EffectsOriginalControllable Connection of Fe2Se3 Double Chains and Fe(dien)2 Complexes for Organic–Inorganic Hybrid Ferrimagnet with a Large Coercivity4Understanding structural distortions in hybrid layered perovskites with the n = 1 Ruddlesden–Popper structure22Structure-Related Evolution of Magnetic Order in Anisidinium Tetrachlorocuprates(II)4Intrinsic Ferromagnetic Semiconductors with High Saturation Magnetization from Hybrid Perovskites27Metal-Dependent Antiferromagnetic Interactions in Ba2MCl6 (M2+ = Co, Fe, Mn)5Broadband Achromatic Quarter-Waveplate Using 2D Hybrid Copper Halide Single Crystals18Methanol‐Induced Crystallization of Chiral Hybrid Manganese (II) Chloride Single Crystals for Achieving Circularly Polarized Luminescence and Second Harmonic Generation37Magnetic hybrid transition metal halides17Ferroics in Hybrid Organic–Inorganic Perovskites: Fundamentals, Design Strategies, and Implementation42Tunable Synthesis of Metal–Organic Chalcogenide Semiconductor Nanocrystals25Advancing photovoltaics and optoelectronics: Exploring the superior performance of lead-free halide perovskites12Footprints of scanning probe microscopy on halide perovskites7Unveiling the Influence of Organic Chain Length on the Physical Properties of Two-Dimensional Cobalt-Based Hybrid Perovskites2Research progress of metal halide perovskites in the preparation of nanosemiconductor lasers3Circularly Polarized Photoluminescence in Chiral Hybrid Organic–Inorganic Manganese Halide Perovskites: From Bulk Materials to Exfoliated Flakes17Crystallization management and defect passivation via additive engineering for efficient and stable carbon-based CsPbI2Br perovskite solar cells13Strain in Hybrid Organic‐Inorganic Metal Halide Perovskites Microstructures by Numerical Simulations1Transition Metal-Based Dimeric Metallosurfactants: From Organic–Inorganic Hybrid Structures and Low-Dimensional Magnets to Metallomicelles12Syntheses, Characterization, Crystal Structures and Antimicrobial Properties of a New Organic-Inorganic Hybrid [4FBzTPP]2[CuBr4]1Tailorable Magnetic Exchange and Optical Absorption in 1-D Double Perovskite-like Halides (CH3NH3)2NaMoCl(6–x)Brx6Effect of Mn–Mn Magnetic Ordering on Photoluminescence in 2D Layered Hybrid Perovskite (CH3NH3)2MnCl419Exploring the Feasibility of Copper Incorporation in Halide Perovskites: Impact on CO 2 Photoreduction Performance27Antiferromagnetic Ordering in A One‐Dimensional Organic Copper Chloride Hybrid Insulator8Antiferromagnetic Ordering in A One‐Dimensional Organic Copper Chloride Hybrid Insulator1Low-Temperature Ferromagnetic Order in a Two-Level Layered Co2+ Material2Multimode Luminescence Tailoring in PMA 4 Na(In,Sb)Cl 8 Organic–inorganic Hybrid Metal Halide via Rigid Benzene Ring Induced Local Lattice Distortion58Multimode Luminescence Tailoring in PMA4Na(In,Sb)Cl8 Organic–inorganic Hybrid Metal Halide via Rigid Benzene Ring Induced Local Lattice Distortion2Chirality and Solvent Coassist the Structural Evolution of Hybrid Manganese Chlorides with Second-Harmonic-Generation Response7Enhancing Optical Properties of Zn‐Mn Solid Solution Hybrid Halides for Wide Color Gamut Backlight Displays11Aqueous alkaline pH stable halide ((PEA) 2 CoCl 4 ) perovskite for oxygen reaction electrocatalysis8Engineering magnetism in hybrid organic–inorganic metal halide perovskites27One-dimensional magnetic halide double perovskites [N(CH 3 ) 4 ] 2 M I MoCl 6 (M I = Na, Ag) with large A-site cations1Tuning the Properties of Dodecylpyridinium Metallosurfactants: The Role of Iron-Based Counterions3Synergistic electronic modulation of active sites in CsCuCl3 via Zn doping for photocatalytic oxidation of toluene to benzaldehyde11Mixed A-Site Organic Cation Copper Chloride Perovskite-like: From Thermochromism to Mixed-Valence Cu for Redox Switching5Effect of the transition metal on the structure and order–disorder phase transition in layered hybrid metal halides (CH 3 CH 2 NH 3 ) 2 [ M Cl 4 ] ( M = Mn and Co)2Interstitial Copper Doping in Cs3Bi2Br9: A Pathway to Enhanced Radiation Detection Performance6Enhancing Magnon–Magnon Coupling Strength to 0.6 GHz in Dion–Jacobson Cu(II)-Hybrid Perovskites by Tuning the Topology of Ligands0Magnetic Organic–Inorganic Hybrid Halide Perovskites: Fundamental Physics, Properties, and Applications14Mixed-Valence Trimers in Organic–Inorganic Hybrid Chromium and Vanadium Chlorides0Alkaline Earth Metal‐Based Hybrid Organic‐Inorganic Perovskite‐Like Ferroelectrics11Alkaline Earth Metal‐Based Hybrid Organic‐Inorganic Perovskite‐Like Ferroelectrics3Interplay of Crystal Structures, Thermal Properties, and Magnetism in Zero‐Dimensional Hybrid Transition Metal Bromides2Synthesis, crystal structure, Hirshfeld surface analysis, optical properties and bacterial activity of bis( N -(4-bromobenzyl)piperidinium) tetrabromocuprate(II)0Doping Effects on Magnetic Layered Hybrid Organic–Inorganic Transition Metal Halide Perovskites5Ligand tunability of emergent noncollinear magnetism in Cu-based layered hybrid perovskites1Deciphering cation-driven structure–property correlations in 0D hybrid ruthenium halide perovskites0Unveiling Photoluminescence Signatures of Magneto‐Optical Coupling in Layered Hybrid Manganese Chloride Perovskites1Mn-doped Cu-based 2D hybrid perovskites with enhanced ferroelectric energy storage performance0Composition-Dependent Antiferromagnetism in Low-Dimensional Hybrid Organic Cobalt-Halide Semiconductors0Unravelling the origin of ferromagnetism and critical scaling behavior in orbital altermagnetic candidate CuBr 2 derived lead free Ruddlesden–Popper halide perovskite (PEA) 2 CuBr 40Perspective on Ferroelectric and Nonferroelectric Low‐Dimensional Metal Halide Perovskites for Memristor Technology1Metal-ion-driven structural modulation of barocaloric and magnetocaloric effects in two-dimensional hybrid perovskites1Investigation of Magnetic and Structural Transitions in Hybrid Molybdenum(III) 2D Halide Double Perovskites0Composition-Driven Control of Magnetic Anisotropy in Hybrid Organic–Inorganic Metal Halides0Structural Flexibility Driven Crystal‐to‐Glass Transition and Long‐Afterglow in Mechanochemically Synthesized Zn(II) Hybrids0Review: structure–magnetism interplay in organic–inorganic hybrid perovskites—design principles, stability challenges, and emerging spintronic implications0Synthetic Control of Structure and Magnetism in Low‐Dimensional Organic Copper(II) Chloride Hybrids0Multiferroic Semiconducting Behavior in Quasi-2D Cu-Based Hybrid Perovskites0

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  1. Controllable Connection of Fe2Se3 Double Chains and Fe(dien)2 Complexes for Organic–Inorganic Hybrid Ferrimagnet with a Large Coercivity

    Nanomaterials · 2023-01-25

    Xiaolei Shang, Xiaoling Men, Qifeng Kuang, Shaojie Li, Da Li, Zhang Zhi-dong

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  2. Understanding structural distortions in hybrid layered perovskites with the n = 1 Ruddlesden–Popper structure

    IUCrJ · 2023-04-28

    Tianyu Liu, Noah P. Holzapfel, Patrick M. Woodward

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  3. Structure-Related Evolution of Magnetic Order in Anisidinium Tetrachlorocuprates(II)

    Crystal Growth & Design · 2023-05-09

    Edi Topić, Pavla Šenjug, Dario Barišić, Ivor Lončarić, Damir Pajić, Mirta Rubčić

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  4. Intrinsic Ferromagnetic Semiconductors with High Saturation Magnetization from Hybrid Perovskites

    Advanced Materials · 2023-07-24

    Bing Sun, Ze Yan, Yang Cao, Shuaishuai Ding, Rongjin Li, Bo Ma, Xiangyang Li, Huan Yang, Wei Yin, Yamin Zhang, Qiang Wang, Xiangfeng Shao, Dezheng Yang, Desheng Xue, Hao‐Li Zhang

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  5. Metal-Dependent Antiferromagnetic Interactions in Ba2MCl6 (M2+ = Co, Fe, Mn)

    Chemistry of Materials · 2023-07-25

    Kurt P. Lindquist, Xianghan Xu, R. J. Cava

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  6. Broadband Achromatic Quarter-Waveplate Using 2D Hybrid Copper Halide Single Crystals

    Journal of the American Chemical Society · 2023-08-04

    Yixuan Dou, Marie Solange Tumusange, Jianbo Jin, Xiaoming Wang, Erin R. Crater, Sunhao Liu, Liyan Zhu, Samir Zuberi, Gavin Harman, Conner Weaver, Balaji Ramanujam, Ambalanath Shan, Robert B. Moore, Nikolas J. Podraza, Yanfa Yan, Li Na Quan

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  7. Methanol‐Induced Crystallization of Chiral Hybrid Manganese (II) Chloride Single Crystals for Achieving Circularly Polarized Luminescence and Second Harmonic Generation

    Advanced Optical Materials · 2023-08-17

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  8. Magnetic hybrid transition metal halides

    Materials Chemistry Frontiers · 2023-09-25

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  9. Ferroics in Hybrid Organic–Inorganic Perovskites: Fundamentals, Design Strategies, and Implementation

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  10. Tunable Synthesis of Metal–Organic Chalcogenide Semiconductor Nanocrystals

    Chemistry of Materials · 2023-10-31

    Alexander C. Hernandez Oendra, Maximilian A. Aspect, Julia L. Jaeggi, Janik Baumann, Carin R. Lightner, Andrew B. Pun, David J. Norris

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  11. Advancing photovoltaics and optoelectronics: Exploring the superior performance of lead-free halide perovskites

    Optical Materials · 2023-12-20

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  12. Footprints of scanning probe microscopy on halide perovskites

    Chemical Communications · 2024-01-01

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  13. Unveiling the Influence of Organic Chain Length on the Physical Properties of Two-Dimensional Cobalt-Based Hybrid Perovskites

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  14. Research progress of metal halide perovskites in the preparation of nanosemiconductor lasers

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    Ke Xu, Honghao Qian

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  15. Circularly Polarized Photoluminescence in Chiral Hybrid Organic–Inorganic Manganese Halide Perovskites: From Bulk Materials to Exfoliated Flakes

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  16. Crystallization management and defect passivation via additive engineering for efficient and stable carbon-based CsPbI2Br perovskite solar cells

    Journal of Power Sources · 2024-05-11

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  17. Strain in Hybrid Organic‐Inorganic Metal Halide Perovskites Microstructures by Numerical Simulations

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  18. Transition Metal-Based Dimeric Metallosurfactants: From Organic–Inorganic Hybrid Structures and Low-Dimensional Magnets to Metallomicelles

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  19. Syntheses, Characterization, Crystal Structures and Antimicrobial Properties of a New Organic-Inorganic Hybrid [4FBzTPP]2[CuBr4]

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  20. Tailorable Magnetic Exchange and Optical Absorption in 1-D Double Perovskite-like Halides (CH3NH3)2NaMoCl(6–x)Brx

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  21. Effect of Mn–Mn Magnetic Ordering on Photoluminescence in 2D Layered Hybrid Perovskite (CH3NH3)2MnCl4

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  22. Exploring the Feasibility of Copper Incorporation in Halide Perovskites: Impact on CO 2 Photoreduction Performance

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  23. Antiferromagnetic Ordering in A One‐Dimensional Organic Copper Chloride Hybrid Insulator

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  28. Chirality and Solvent Coassist the Structural Evolution of Hybrid Manganese Chlorides with Second-Harmonic-Generation Response

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  29. Enhancing Optical Properties of Zn‐Mn Solid Solution Hybrid Halides for Wide Color Gamut Backlight Displays

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  30. Aqueous alkaline pH stable halide ((PEA) 2 CoCl 4 ) perovskite for oxygen reaction electrocatalysis

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  31. Engineering magnetism in hybrid organic–inorganic metal halide perovskites

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  32. One-dimensional magnetic halide double perovskites [N(CH 3 ) 4 ] 2 M I MoCl 6 (M I = Na, Ag) with large A-site cations

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  33. Tuning the Properties of Dodecylpyridinium Metallosurfactants: The Role of Iron-Based Counterions

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  34. Synergistic electronic modulation of active sites in CsCuCl3 via Zn doping for photocatalytic oxidation of toluene to benzaldehyde

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  36. Effect of the transition metal on the structure and order–disorder phase transition in layered hybrid metal halides (CH 3 CH 2 NH 3 ) 2 [ M Cl 4 ] ( M = Mn and Co)

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  38. Enhancing Magnon–Magnon Coupling Strength to 0.6 GHz in Dion–Jacobson Cu(II)-Hybrid Perovskites by Tuning the Topology of Ligands

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  39. Magnetic Organic–Inorganic Hybrid Halide Perovskites: Fundamental Physics, Properties, and Applications

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  40. Mixed-Valence Trimers in Organic–Inorganic Hybrid Chromium and Vanadium Chlorides

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  43. Interplay of Crystal Structures, Thermal Properties, and Magnetism in Zero‐Dimensional Hybrid Transition Metal Bromides

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  46. Ligand tunability of emergent noncollinear magnetism in Cu-based layered hybrid perovskites

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  47. Deciphering cation-driven structure–property correlations in 0D hybrid ruthenium halide perovskites

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  48. Unveiling Photoluminescence Signatures of Magneto‐Optical Coupling in Layered Hybrid Manganese Chloride Perovskites

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  49. Mn-doped Cu-based 2D hybrid perovskites with enhanced ferroelectric energy storage performance

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  50. Composition-Dependent Antiferromagnetism in Low-Dimensional Hybrid Organic Cobalt-Halide Semiconductors

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    Shangpu Liu, Jonathan Zerhoch, Stanislav Bodnar, Julia Anthea Gessner, Luca Bischof, Jan Arneth, Franz Bodenmüller, Joachim Ballmann, Frank Röminger, R. Klingeler, Felix Deschler

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