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RESEARCH PAPER · Laser & Photonics Review · 2025

Near‐Unity Internal Quantum Efficiency and High Thermal Stability of Sr3MgGe5O14: Cr3+ Phosphor for Plant Growth

Qiuming Lin, Xiaozhong Wu, Jiaqing Peng, Weixiong You, Xinyu Ye, Decai Huang

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Near‐Unity Internal Quantum Efficiency and High Thermal Stability of Sr3MgGe5O14: Cr3+ Phosphor for Plant GrowthOriginalAchieving tunable ultra-broadband NIR emission originating from the two-site occupation of Cr 3+ ions in Mg 3 Ga 2 SnO 8 :Cr 3+17Lithiation-Driven Phase Engineering Unlocking Broadband NIR Emission in Cr-Doped Zinc Tantalate1Structural Rigidity Control via Non-Primary Lattice Substitution toward Thermally Stable Cr3+-Doped Near-Infrared Phosphors for pc-LED Applications16Triple Emission Modes in Cs2NaGdCl6:Yb3+,Nd3+ double perovskite2Ionic substitution combined with flux doping triggered near-unity efficiency and thermally stable NIR luminescence in Al6Ge2O13: Cr3+, Si4+ phosphor for NIR spectroscopy applications6Tuning the Near Infrared Emission of MgO:Cr3+ Phosphors by Inducing Ti4+ Ions1Achieving near-unity efficiency and exceptional stability luminescence in Ca3Sc2Ge3O12: Cr3+, Si4+ phosphor through ion exchange and flux doping strategies for NIR spectroscopy applications2Achieving Real "Near Zero" Thermal Quenching: A Doping‐Controlled Order‐Disorder Transition in Sm 3+ ‐Doped Double Perovskites7Achieving enhanced, tunable and broadened NIR-II emission in Ni2+ doped Li₂Mg₃TiO₆ via cationic substitution strategy36Blue-light-excited NIR-I to NIR-III emitting NaY2Ga2InGe2O12:Ni2+, Cr3+ phosphor for multifunctional applications11Composition-driven conversion between isomorphous compounds for modulating crystal field environment and controlling luminescent properties1Structure and luminescence of Gd3Ga3MgSiO12:Cr3+ garnet phosphor with highly efficient broadband near-infrared emitting toward pc-LED application7Structural evolution-facilitated broadband near-infrared emission of multifunctional Sc-based phosphor with long wavelength5Constructing efficient and thermally-stable far red emitting phosphor with excellent response to phytochrome Pfr for indoor agriculture5Developing a Near-Infrared Garnet Phosphor with Near-Unity Internal Quantum Efficiency and Wide-Range Spectral Tunability26Applications of Inorganic Hybrid Rare‐Earth Materials in Biological Diagnostics, X‐Ray Imaging, and Lighting Display3Highly Efficient Near‐Infrared Emission (IQE 85%/EQE 75%) From [(Mo 6 I 8 )I 6 ] 2− Cluster‐Doped (ETP) 2 SbCl 5 0D Metal Halide Glass for Multifunctional Optoelectronic Applications2High-performance Cr3+-doped Ca2GdGa3Ge2O12 near-infrared phosphors toward multifunctional applications5Phase transition regulation and enhancement of optical properties in YPO4:Eu3+ through the influence of alkali metal ions1Enhancing Abnormal Thermal Quenching Characteristics of Y 1– x La x NbO 4 :Pr 3+ Phosphors through Energy Transfer Enhancement and Intervalence Charge Transfer Modulation Synergistic Strategy0Insight into Site Environment and Photoluminescence Properties of Cr3+-doped Gallogermanate Toward NIR pc-LEDs Applications0Achieving high-performance near-infrared Cr3+-activated phosphor via A&C lattice sites cosubstitution strategy in garnet for plant lighting6Synthesis and luminescence properties of deep-red-emitting Sc1.6Al0.4W3O12: Cr3+ phosphor for plant growth lighting1Efficient and Stable Metaphosphate Composite Ceramics for High‐Power‐Driven Near‐Infrared Light Sources4Broadband near-infrared phosphor Na2Mg5Si12O30: Cr3 + for versatile applications4Broadband near-infrared emission in LiMg6AlO8: Cr3+ phosphors based on Cr3+ magnetic exchange interactions for multifunctional spectroscopic applications3Boosting internal quantum efficiency to near-unity in Fe3+-doped NIR phosphors: Structural engineering and energy transfer in A2LuSbO6 (A = Ba/Sr/Ca) double perovskites15Crystallographically altered (Mg,Sr) 3 (Al,Ga) 2 GeO 8 :Cr 3+ phosphors with tuned emission width from the ultra-sharp red to profound NIR band2Recent advances in Cr 3+ -doped near-infrared phosphors: preparation, luminescence, and LED applications5Boosting near-infrared luminescence in La2MgTiO6:Cr3+ through non-Stoichiometric design: A defect-mediated strategy for advanced plant cultivation1Emergence of Unusual Cr 3+ Emission and Exceptional Thermal Stability in Ca 3 Ga 2 Ge 3 O 12 : Cr 3+ /Yb 3+ Garnet Phosphors for High-Performance Optical Thermometry and NIR pc-LEDs4Breaking the Absorption‐Efficiency Paradigm: 270% EQE Gain in Cr 3+ ‐Doped Phosphors via Crystal Field Engineering2Broadband Near-Infrared emission from Cr3+-Activated La3Ga5.54Ta0.46O14 phosphors spanning the NIR-I and NIR-II regions5Polyhedral Symmetry Breaking Strategy Enabled High‐Performance Broadband Near‐Infrared Emission in Cr 3+ ‐Doped Garnet Phosphors1Mn4+ and Ni2+-based near infrared emitting phosphors for temperature sensing in the biological windows26A highly efficient near-infrared emitting garnet phosphor for plant growth lighting1A novel Cr3+ -activated Rb2KWO3F3 oxyfluoride phosphor with enhanced broadband near-infrared emission via energy transfer engineering0Tunable NIR emission in Y2SrGa4SiO12:Cr3+ phosphor: unlocking 96.6% IQE and 81%@423 K thermal stability1Pushing the Limits of Fe 3+ Luminescence: An F − Regulation Strategy for NIR Phosphors With 88% IQE and Anti‐Thermal‐Quenching Behavior11Intense deep-red emissions of Sm2+ doped SrB6O10 phosphor for plant growth lighting0Structural Insights and Multi-center Luminescence in Cr 3+ -Doped Gallogermanate for High-Efficiency Near-Infrared pc-LEDs7Luminescence properties and potential application of CaMg2Al16O27:Cr3+ via Cr3+ - Cr3+ pairing and multi-site engineering2Realization of near infrared luminescence of Fe3+ under visible light excitation via Cr3+→Fe3+ energy transfer pathway1Zero‐Concentration Quenching in Ce 3+ ‐Doped Ca 2 Y 8 (SiO 4 ) 6 O 2 Phosphors: From Multifunctional Lighting to Plant Growth Promotion and Viral Resistance Attenuation1Enhancing near‑infrared luminescence in Fe3+‑doped Na‑β‑Al2O3 phosphors via cation substitution for LED application0A Thermally Robust Beryl‐Structure Be 3 Al 2 Si 6 O 18 :Cr 3+ Phosphor for Broadband NIR pc‐LEDs0Broadband Near-Infrared Emitting Phosphor CaLaMgTaO6:Cr3+ toward Multiscenario Light-Emitting Diode Applications0Garnet-structured Y2CaGa4ZrO12:Cr3+ NIR phosphor with combined high efficiency and thermal stability toward constructing high-performance pc-NIR-LED1Lu/Mg co-substitution boosts NIR-II/III regional luminescence of Ni2+ activated Ca3Sc2Si3O12: Properties, mechanism, and applications0Crystal field engineering and energy transfer strategy for enhancing broadband near-infrared luminescence of Sm2+ activated oxynitride phosphors0Cr3+-activated phosphors with tunable near-infrared emission for multifunctional application0Site occupation engineering enables tunable luminescence of Ce3+-doped Na3ScSi2O7 phosphors for full-spectrum white light-emitting diode and plant growth0Moisture-resistant Mn4+-activated oxyfluoride red phosphors for blue-red dual-emission plant lighting devices0Realization of blue-red dual-emission via energy transfer in Ca9ZnK(PO4)7: Eu2 +, Mn2+ phosphors for plant cultivation and warm white illumination0Enhancement of near-infrared luminescence of Ni2+ in Li3Mg2SbO6 induced by Mn4+ sensitization0

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  2. Lithiation-Driven Phase Engineering Unlocking Broadband NIR Emission in Cr-Doped Zinc Tantalate

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  3. Structural Rigidity Control via Non-Primary Lattice Substitution toward Thermally Stable Cr3+-Doped Near-Infrared Phosphors for pc-LED Applications

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  4. Triple Emission Modes in Cs2NaGdCl6:Yb3+,Nd3+ double perovskite

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  5. Ionic substitution combined with flux doping triggered near-unity efficiency and thermally stable NIR luminescence in Al6Ge2O13: Cr3+, Si4+ phosphor for NIR spectroscopy applications

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  6. Tuning the Near Infrared Emission of MgO:Cr3+ Phosphors by Inducing Ti4+ Ions

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  7. Achieving near-unity efficiency and exceptional stability luminescence in Ca3Sc2Ge3O12: Cr3+, Si4+ phosphor through ion exchange and flux doping strategies for NIR spectroscopy applications

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  10. Blue-light-excited NIR-I to NIR-III emitting NaY2Ga2InGe2O12:Ni2+, Cr3+ phosphor for multifunctional applications

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  14. Constructing efficient and thermally-stable far red emitting phosphor with excellent response to phytochrome Pfr for indoor agriculture

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  16. Applications of Inorganic Hybrid Rare‐Earth Materials in Biological Diagnostics, X‐Ray Imaging, and Lighting Display

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  17. Highly Efficient Near‐Infrared Emission (IQE 85%/EQE 75%) From [(Mo 6 I 8 )I 6 ] 2− Cluster‐Doped (ETP) 2 SbCl 5 0D Metal Halide Glass for Multifunctional Optoelectronic Applications

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  18. High-performance Cr3+-doped Ca2GdGa3Ge2O12 near-infrared phosphors toward multifunctional applications

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  19. Phase transition regulation and enhancement of optical properties in YPO4:Eu3+ through the influence of alkali metal ions

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  20. Enhancing Abnormal Thermal Quenching Characteristics of Y 1– x La x NbO 4 :Pr 3+ Phosphors through Energy Transfer Enhancement and Intervalence Charge Transfer Modulation Synergistic Strategy

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  21. Insight into Site Environment and Photoluminescence Properties of Cr3+-doped Gallogermanate Toward NIR pc-LEDs Applications

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  31. Emergence of Unusual Cr 3+ Emission and Exceptional Thermal Stability in Ca 3 Ga 2 Ge 3 O 12 : Cr 3+ /Yb 3+ Garnet Phosphors for High-Performance Optical Thermometry and NIR pc-LEDs

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  50. Crystal field engineering and energy transfer strategy for enhancing broadband near-infrared luminescence of Sm2+ activated oxynitride phosphors

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