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RESEARCH PAPER · Proceedings of the National Academy of Sciences · 2022

Reversible and rapid calcium intercalation into molybdenum vanadium oxides

Aniruddha S. Lakhnot, Kevin Bhimani, Varad Mahajani, Reena A. Panchal, Shyam Sharma, Nikhil A. Koratkar

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Reversible and rapid calcium intercalation into molybdenum vanadium oxidesOriginalAnode chemistry in calcium ion batteries: A review91Intercalation Hosts for Multivalent‐Ion Batteries25Molybdenum Vanadium Oxides as Intercalation Hosts for Chloroaluminate Anions4Weak Solvation Effect Enhancing Capacity and Rate Performance of Vanadium‐Based Calcium Ion Batteries: A Strategy Guided by Donor Number57Recent progress in rechargeable calcium-ion batteries for high-efficiency energy storage56Highly Reversible Intercalation of Calcium Ions in Layered Vanadium Compounds Enabled by Acetonitrile–Water Hybrid Electrolyte49Three-dimensional electrodes in hybrid electrolytes for high-loading and long-lasting calcium-ion batteries23K 3 v 2 (Po 4 ) 3 /C as a New High‐Voltage Cathode Material for Calcium‐Ion Batteries with a Water‐In‐Salt Electrolyte21Aromatic Organic Small-Molecule Material with (020) Crystal Plane Activation for Wide-Temperature and 68000 Cycle Aqueous Calcium-Ion Batteries48Unlocking the potential of open-tunnel oxides: DFT-guided design and machine learning-enhanced discovery for next-generation industry-scale battery technologies7Electro-Chemo-Mechanical Modeling of Multiscale Active Materials for Next-Generation Energy Storage: Opportunities and Challenges4Characterizations of structural, optical, and dielectric properties of oxynitride perovskites ACa0.2M0.8O2.6N0.4 (A= Sr, Ba; M = Nb, Ta)4Low-strain layered Zn0.56VOPO4∙2H2O as a high-voltage and long-lifespan cathode material for Zn-ion batteries35Electrode materials for calcium batteries: Future directions and perspectives13A Long‐Range Planar Polymer with Efficient π‐Electron Delocalization for Superior Proton Storage71A universal cooperative assembly-oriented strategy for VS4 nanorod decoration on carbon nanostructures with enhanced magnesium storage properties19Strategically Modulating Proton Activity and Electric Double Layer Adsorption for Innovative All‐Vanadium Aqueous Mn 2+ /Proton Hybrid Batteries60Irradiating the Path to High‐Efficiency Zn‐Ion Batteries: An Electrochemical Analysis of Laser‐Modified Anodes0Molecular Engineering to Construct MoS 2 with Expanded Interlayer Spacing and Enriched 1T Phase for “Rocking-Chair” Aqueous Calcium-Ion Pouch Cells39BiVO 4 /V 2 O 5 heterostructures for durable and highly reversible calcium- and zinc-ion batteries3Enabling high-performance multivalent metal-ion batteries: current advances and future prospects146Enhancement of cycling capacity and stability of Co3O4/Ca4O4 as a cathode material in aqueous calcium-ion electrolytes via the integration of reduced graphene oxide (rGO)3Coulombic-hinderance regulation on pyrovanadates for practicable calcium-ion batteries: a solid-solution strategy17Dopant-ion stabilizes Ca2+ ion intercalation mechanism in a Ni:V6O13 based Ca-ion battery7Multivalent‐Ion Batteries: Magnesium and Beyond0Phase transition-induced optimization approach for magnesium-ion storage in MnO2: Enabling high-performance in aqueous hybrid and asymmetric supercapacitors9An Oxidation‐Resistant High Entropy Alloy for Aqueous Aluminum‐Battery Chemistries12Design and scaling hybrid hard carbon electrodes to balance energy and power performance in Sodium-ion batteries2Electrolytes for rechargeable calcium batteries: Addressing the constraints imposed by battery configuration and electrode materials3Hexagonal Be X ( X : S, Te) Monolayer as Potential Electrode Material for Alkali Metal‐Ion Batteries: A DFT Perspective1Brønsted base-pillared cobalt-nickel layered double hydroxides for aqueous calcium-ion batteries0Green extraction of vanadium pentoxide from industrial solid wastes and its electrochemical calcium storage performance13D‐Mixer‐Assisted High‐Entropy Doping of LiNiO 2 for Co‐Free Ni‐Rich Cathodes in Lithium‐Ion Batteries0Built-in ion-electron highways in tungstate-polyaniline hybrid for overcoming divalent sluggishness in aqueous magnesium-ion batteries0Mild Extraction of Ammonium Metavanadate From Alumina Solid Waste and Its Electrochemical Calcium Storage Application0

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  1. Anode chemistry in calcium ion batteries: A review

    Energy storage materials · 2022-09-27

    Xianming Deng, Linyuan Li, Guobin Zhang, Xu Zhao, Jing Hao, Cuiping Han, Baohua Li

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  2. Intercalation Hosts for Multivalent‐Ion Batteries

    Small Structures · 2022-12-29

    Aniruddha S. Lakhnot, Reena A. Panchal, Joy Datta, Varad Mahajani, Kevin Bhimani, Rishabh Jain, Dibakar Datta, Nikhil A. Koratkar

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  3. Molybdenum Vanadium Oxides as Intercalation Hosts for Chloroaluminate Anions

    Batteries · 2023-01-29

    Kevin Bhimani, Aniruddha S. Lakhnot, Shyam Sharma, Mukul Sharma, Reena A. Panchal, Varad Mahajani, Nikhil A. Koratkar

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  4. Weak Solvation Effect Enhancing Capacity and Rate Performance of Vanadium‐Based Calcium Ion Batteries: A Strategy Guided by Donor Number

    Advanced Functional Materials · 2023-05-11

    Fanbin Zeng, Senlin Li, Sanlue Hu, Minling Qiu, Guobin Zhang, Meilin Li, Caiyun Chang, Hongliang Wang, Minwei Xu, Lirong Zheng, Yongbing Tang, Cuiping Han, Hui–Ming Cheng

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  5. Recent progress in rechargeable calcium-ion batteries for high-efficiency energy storage

    Energy storage materials · 2023-05-20

    Lei Yan, Wenhui Yang, Haoxiang Yu, Liyuan Zhang, Jie Shu

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  6. Highly Reversible Intercalation of Calcium Ions in Layered Vanadium Compounds Enabled by Acetonitrile–Water Hybrid Electrolyte

    ACS Nano · 2023-06-20

    Xiaolu Qin, Xu Zhao, Guobin Zhang, Zhiquan Wei, Linyuan Li, Xiaoke Wang, Chunyi Zhi, Hongfei Li, Cuiping Han, Baohua Li

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  7. Three-dimensional electrodes in hybrid electrolytes for high-loading and long-lasting calcium-ion batteries

    Chemical Engineering Journal · 2023-07-05

    Cao Duy Anh, Y. J. Kim, Yeon Jwoong Kim, Thuan Ngoc Vo, Doosoo Kim, Doosoo Kim, Jaehyun Hur, Hadi Khani, Il Tae Kim

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  8. K 3 v 2 (Po 4 ) 3 /C as a New High‐Voltage Cathode Material for Calcium‐Ion Batteries with a Water‐In‐Salt Electrolyte

    Small Methods · 2023-10-06

    Fan Qiao, Junjun Wang, Ruohan Yu, Yuqiang Pi, Meng Huang, Lianmeng Cui, Ziang Liu, Qinyou An

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  9. Aromatic Organic Small-Molecule Material with (020) Crystal Plane Activation for Wide-Temperature and 68000 Cycle Aqueous Calcium-Ion Batteries

    ACS Nano · 2023-11-07

    Fan Qiao, Junjun Wang, Ruohan Yu, Meng Huang, Lei Zhang, Wei Bo Yang, Hong Wang, Jinsong Wu, Lei Zhang, Yalong Jiang, Qinyou An

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  10. Unlocking the potential of open-tunnel oxides: DFT-guided design and machine learning-enhanced discovery for next-generation industry-scale battery technologies

    Energy Advances · 2024-01-01

    Joy Datta, Nikhil A. Koratkar, Dibakar Datta

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  11. Electro-Chemo-Mechanical Modeling of Multiscale Active Materials for Next-Generation Energy Storage: Opportunities and Challenges

    JOM · 2024-01-03

    Dibakar Datta

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  12. Characterizations of structural, optical, and dielectric properties of oxynitride perovskites ACa0.2M0.8O2.6N0.4 (A= Sr, Ba; M = Nb, Ta)

    Progress in Solid State Chemistry · 2024-01-10

    Jae Won Seol, Jong‐Sook Lee, Maxim Avdeev, Young‐Il Kim

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  13. Low-strain layered Zn0.56VOPO4∙2H2O as a high-voltage and long-lifespan cathode material for Zn-ion batteries

    Energy storage materials · 2024-02-01

    Dong Mei Zhao, Xiangjun Pu, Chunlei Wang, Zibing Pan, Mingyue Ding, Yuliang Cao, Zhongxue Chen

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  14. Electrode materials for calcium batteries: Future directions and perspectives

    EcoEnergy · 2024-07-20

    Titus N. Masese, Godwill Mbiti Kanyolo

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  15. A Long‐Range Planar Polymer with Efficient π‐Electron Delocalization for Superior Proton Storage

    Advanced Materials · 2024-07-30

    Renyuan Wang, Jing J. He, Chao Yan, Renwei Jing, Yüe Zhao, Jun Yang, Minjie Shi, Xingbin Yan

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  16. A universal cooperative assembly-oriented strategy for VS4 nanorod decoration on carbon nanostructures with enhanced magnesium storage properties

    Science China Chemistry · 2024-08-14

    Yuehua Man, An Li, Haowei Tang, Jianlu Sun, Yating Fei, Yichen Du, Xiaosi Zhou

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  17. Strategically Modulating Proton Activity and Electric Double Layer Adsorption for Innovative All‐Vanadium Aqueous Mn 2+ /Proton Hybrid Batteries

    Advanced Materials · 2024-08-17

    Ming Li, Cong Li, Chunli Zuo, Jisong Hu, Chen Li, Wen Luo, Sha Luo, An Duan, Junjun Wang, Xuanpeng Wang, Wei Sun, Liqiang Mai

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  18. Irradiating the Path to High‐Efficiency Zn‐Ion Batteries: An Electrochemical Analysis of Laser‐Modified Anodes

    Global Challenges · 2024-08-29

    Ramona Dūrena, Leonid L. Fedorenko, Ņikita Griščenko, Mārtiņš Vanags, Liga Orlova, Pāvels Onufrijevs, Sandra Stanionytė, T. Malinauskas, Anzelms Zukuls

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  19. Molecular Engineering to Construct MoS 2 with Expanded Interlayer Spacing and Enriched 1T Phase for “Rocking-Chair” Aqueous Calcium-Ion Pouch Cells

    ACS Nano · 2024-12-16

    Wen-Hao Wang, Wenwei Zhang, Ruohan Yu, Fan Qiao, Jilin Wang, Junjun Wang, Qinyou An

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  20. BiVO 4 /V 2 O 5 heterostructures for durable and highly reversible calcium- and zinc-ion batteries

    Sustainable Energy & Fuels · 2025-01-01

    Danish Wazir, Souvik Naskar, Priya R Sharmesh, Partha Ghosal, Melepurath Deepa

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  21. Enabling high-performance multivalent metal-ion batteries: current advances and future prospects

    Chemical Society Reviews · 2025-01-01

    Asif Mahmood, Zhe Bai, Tan Wang, Yaojie Lei, Shijian Wang, Bing Sun, Hajra Khan, Karim Khan, Kening Sun, Guoxiu Wang

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  22. Enhancement of cycling capacity and stability of Co3O4/Ca4O4 as a cathode material in aqueous calcium-ion electrolytes via the integration of reduced graphene oxide (rGO)

    Journal of Alloys and Compounds · 2025-01-12

    Ibnu Syafiq Imaduddin, Nurul Hayati Idris, Mushtaq Ahmad Dar, Siti Rohana Majid

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  23. Coulombic-hinderance regulation on pyrovanadates for practicable calcium-ion batteries: a solid-solution strategy

    National Science Review · 2025-02-27

    Junming Cao, Yue Liu, Kai Li, Igor V. Zatovsky, Jialin Yang, Han‐Hao Liu, Zhen‐Yi Gu, Xuan Gao, Kai-Yang Zhang, Shuo‐Hang Zheng, Xing‐Long Wu

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  24. Dopant-ion stabilizes Ca2+ ion intercalation mechanism in a Ni:V6O13 based Ca-ion battery

    Journal of Energy Storage · 2025-02-28

    Danish Wazir, Souvik Naskar, Adnan Amir Banatwala, Partha Ghosal, Melepurath Deepa

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  25. Multivalent‐Ion Batteries: Magnesium and Beyond

    Unknown journal · 2025-02-28

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  26. Phase transition-induced optimization approach for magnesium-ion storage in MnO2: Enabling high-performance in aqueous hybrid and asymmetric supercapacitors

    Journal of Energy Storage · 2025-04-18

    Xinyang Zhang, Yingjun Wei, Xiaoyu Yang, Chunping Hou, Yuhong Chen, Dewei Wang

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  27. An Oxidation‐Resistant High Entropy Alloy for Aqueous Aluminum‐Battery Chemistries

    Small · 2025-07-10

    Apurva Anjan, Adwitiya Rao, Rohit M. Manoj, Varad Mahajani, Kevin Bhimani, Xue Yao, Jonathan D. Poplawsky, Chandra Veer Singh, Nikhil A. Koratkar

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  28. Design and scaling hybrid hard carbon electrodes to balance energy and power performance in Sodium-ion batteries

    Journal of Power Sources · 2025-07-23

    K. Bhawana, Manoj Gautam, Govind Kumar Mishra, Dhruv Kumar, Sagar Mitra

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  29. Electrolytes for rechargeable calcium batteries: Addressing the constraints imposed by battery configuration and electrode materials

    Energy storage materials · 2025-10-15

    Luyang Yu, Ran Zhao, Xiaomin Han, Lihua Wang, Feng Wu, Feng Wu, Ying Bai, Chuan Kun Wu

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  30. Hexagonal Be X ( X : S, Te) Monolayer as Potential Electrode Material for Alkali Metal‐Ion Batteries: A DFT Perspective

    Energy Storage · 2025-12-01

    Hetvi Jadav, Sadhana Matth, Himanshu Pandey

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  31. Brønsted base-pillared cobalt-nickel layered double hydroxides for aqueous calcium-ion batteries

    Chemical Engineering Journal · 2026-05-01

    Mengting Shen, Yuning Peng, Xin Wang, LIU Huan, Xiang Cai

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  32. Green extraction of vanadium pentoxide from industrial solid wastes and its electrochemical calcium storage performance

    Journal of environmental chemical engineering · 2026-06-04

    Hainan Li, Jiaqi Lv, Xi Luo, Zimeng Qu, Feng Liu, Yuehong Zhang, Pengfei Wang, Fa‐Nian Shi, Jiyan Liang, Yuhan Wu

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  33. 3D‐Mixer‐Assisted High‐Entropy Doping of LiNiO 2 for Co‐Free Ni‐Rich Cathodes in Lithium‐Ion Batteries

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    Seung Ri Kim, Thillai Govindaraja Senthamaraikannan, Jun Jae Myeong, Hyung Do Kim, Dong‐Hee Lim, Eun Mi Kim, Sang Mun Jeong

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  34. Built-in ion-electron highways in tungstate-polyaniline hybrid for overcoming divalent sluggishness in aqueous magnesium-ion batteries

    Journal of Alloys and Compounds · 2026-07-13

    Yufei Yang, Zi Wang, Qian Zhang, Xianfang Tan, Fangfang Zhang, Xiaohui Xu, Hanmei Jiang, Chi Huang, Yifu Zhang

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  35. Mild Extraction of Ammonium Metavanadate From Alumina Solid Waste and Its Electrochemical Calcium Storage Application

    Advanced Sustainable Systems · 2026-09-01

    Xi Luo, Xue‐Song Li, Hainan Li, Jiaqi Lv, Yan Ran, Chenglin Zhang, Pengfei Wang, Jiyan Liang, Yuhan Wu

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