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RESEARCH PAPER · Chemical Society Reviews · 2025

Enabling high-performance multivalent metal-ion batteries: current advances and future prospects

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Enabling high-performance multivalent metal-ion batteries: current advances and future prospectsOriginalComputational insights into the electrochemical performance of As 4 O 6 as a novel anode material for Li-ion and Mg-ion batteries4Non-free water dominated electrolyte architectures for zinc-based batteries: toward sustainable long-life zinc-based energy storage solutions4Oxygen Vacancy Engineering Via Lattice Lithium Pre-Doping Enhanced Li-Ion Diffusion and Cycling Stability in High-Entropy Spinel Anodes0Smart batteries: materials, monitoring, and artificial intelligence21Layered Potassium Vanadate K 0.5 V 2 O 5 as a Robust Cathode Material for Aqueous Zinc‐Ion Batteries12Cationic doping engineering of vanadium-incorporated MnO₂ enables high-energy-density ammonium-ion hybrid capacitors13Succinonitrile-driven cathode-electrolyte interface modulation for stable and high-rate Prussian white cathode in potassium-ion batteries5Multiscale porous structured MXene: Synthesis, design and applications in batteries and supercapacitors45Advances and Challenges in Li-Excess Cathode Additives for Next-Generation Li Rechargeable Batteries7Unveiling the impact of Cu doping on charge carrier density and transfer in ZnO/ZnSe heterojunctions for PEC applications5MOF-derived high-entropy oxide-modified graphite felt for enhanced electrochemical performance in vanadium redox flow batteries21Dielectric barrier discharge plasma sulfonated carbon nanotube modified PVDF-TrFE-CFE copolymer electrolyte for high-performance flexible solid-state lithium metal batteries8In Situ Electrochemical Atomic Force Microscopy Study of Interfacial Reactions on a Graphite Negative Electrode for Magnesium-Ion Batteries0Plasma-driven electrode architecture engineering: A transformative paradigm for high-efficiency energy storage2Progress on the Attenuation Mechanism and Modification of the Cobalt‐Free Spinel LiNi 0.5 Mn 1.5 O 421Multifunctional Metal Halide Perovskite‐Modified Aqueous Electrolytes for Zinc Metal Batteries3Cu-Li Co-Doped Mn3O4 cathode materials employed in aqueous zinc-ion batteries3Superionic Glasses: Potential and Challenges in Solid‐State Batteries and Fuel Cells2Thermo‐Electrochemical Tuning of V 2 O 5 to ZnV 3 O 8 Enables Ultra‐Stable Zinc‐Ion Battery392D TiB2 monolayer as a promising anode material for high-performance magnesium-ion batteries4Research Progress on Corrosion Behavior of Magnesium Alloy Composites in Practical Service Conditions12Electrolyte-dependent mechanism and multifunctional cathode design for Li-Se batteries and beyond5Open frameworks materials towards stable aqueous zinc-ion batteries1Dual-regulation tailoring of tunnel-structured hexagonal tungsten oxide for high-performance ammonium-ion hybrid supercapacitors13First-Principles Study of a 2-D C-Silicyne Monolayer for the Anode Material in Magnesium-Ion Batteries2Multivalent Ion-Conducting Metal- and Covalent- Organic Frameworks7Atomic Layer Deposition for Sodium‐Ion Batteries28The built-in atmospheric pressure aqueous solution co-precipitation equilibrium mechanism helps to synthesize high-capacity LiMn0.5Fe0.5PO4/C cathode material9Covalent organic framework-based solid polymer electrolytes for metal-ion batteries: pioneering the future of DFT, MD, and ML techniques4High crystalline VSe2@PANI collaborating with ether electrolyte to construct efficient sodium-ion storage interface4Enhanced Na₂V₆O₁₆ cathode via chlorine doping for zinc-ion batteries2Hexagonal Cadmium Sulfide Cathode for Aqueous Zinc-Ion Battery: Study of Zinc-Sulfide Formation and Zn/CdS Battery Stability1Design of Cryogenic Electrolyte with Organic‐Free Solvation Structure for Wide‐Temperature Zinc Metal Batteries4Design of Cryogenic Electrolyte with Organic‐Free Solvation Structure for Wide‐Temperature Zinc Metal Batteries39Liberating Ca 2+ Storage from Lattices: Amorphous FePO x Unveiling an Inside‐Out Adaptive Cathode Paradigm6Electric field-induced gradient polyanionic hydrogel electrolytes with zinc-ion selective transport for stable zinc-ion batteries18Sustainable polymers for battery applications7Multivalent metal-ion-based energy storage: A comprehensive review of challenges and technological prospects9A mini review: Efficacy of fillers in polymer-based composite solid-state electrolytes for lithium-metal batteries8Electroactive Chelating Groups Enable High‐Performance Aqueous Zinc‐Organic Batteries9Electroactive Chelating Groups Enable High‐Performance Aqueous Zinc‐Organic Batteries0Quantum batteries: Unlocking the future of high-tech energy storage1Tailoring interfacial chemistry of aluminum alloy anodes for high-performance aqueous aluminum-ion batteries12A high-sulfur-loading freestanding SPANI/MWCNT electrode for high-performance lithium–sulfur batteries1Hierarchical PANI-Modified Ni–Co Sulfides/Oxide Nanostructures on Nickel Foam as Binder-Free Electrodes for High-Performance Asymmetric Supercapacitors6Facet-selective regulation of Zn (002) planes by iohexol electrolyte additive for stable and dendrite-free zinc anodes2Lattice engineering in MnO 2 via V 5+ doping for high-performance aqueous Te–MnO 2 batteries7High-performance SiOx anode based on a pre-lithiation sodium alginate binder4Dual-Ion Batteries: Efficient and Environmentally Friendly Energy Storage for the Future2Carbon Quantum Dots in Energy Storage0Development and Analysis of Polyvinyl Alcohol‐Based Polymer Electrolytes for Improved Ionic Conductivity and Photostability in Perovskite Solar Cells1A Review of Recent Advances in Multivalent Ion Batteries for Next Generation Energy Storage6From Materials to Devices: All‐MXene Platforms for Advanced Energy Storage5Recent Advances and Perspectives of Tunnel‐Structured Nanomaterials for Zn‐Ion Batteries12Curvature defect engineering towards a high-performance COF-based cathode in lithium-ion batteries7Dual carbon grafted Li3VO4 nanoparticles as a high-rate negative electrode for Li-ion batteries3Hierarchical CuS Nanoflowers enable efficient photo-assisted Cu2+ reversible storage for advanced aqueous copper ion batteries14d orbital ruthenium doping enables high-capacity and stable α-MnO 2 cathodes for aqueous zinc-ion batteries1A comparative theoretical study on the vibrational spectra of V 2 O 5 · n H 2 O0AI for battery-accelerated discovery of high-voltage electrolytes for advanced lithium batteries0Artificial intelligence-driven electrolyte chemistry for lithium-ion batteries: mechanisms, progress and strategic perspectives0Beyond the slurry: architecting binder-free tin anodes for high-energy lithium-ion batteries—a review3Bipolar conjugated microporous polymer with intrinsically fast reaction kinetics for high-energy-density and high-rate-capacity symmetric all-organic lithium-ion batteries1Choice of the electron-conducting additive for P2–layered sodium-manganese-cobalt oxide in Na-ion batteries for better electrochemical performance0First-principles calculations to investigate structural, electronic, optical, elastic, mechanical and phonon properties of novel Q 3 GaBr 6 (Q = Na and K) for next-generation lead-free solar cells8Fundamentals and mechanistic insights for ammonium-ion energy storage: spotlight on metal–organic frameworks0High-stability aqueous Ca-ion batteries featuring hydrated eutectic electrolytes and small-molecule conjugated anodes0Metal-ions and H 2 O co-intercalation adjusted the interplanar spacing of vanadium pentoxide for enhanced aqueous zinc-ion batteries0Preserving chloroaluminate solvation structures while constructing stable solid electrolyte interphase layers: methyl carbamate additive for highly reversible aluminum metal batteries0Revealing potassium ion storage in individual Prussian blue nanoparticles with distinct crystallinity via scanning electrochemical cell microscopy0Simultaneous construction of robust solid-electrolyte interphases by trifluoromethyl- and isocyanate-functionalized additives for sodium-ion batteries1Synergistic effect between carbon-confined bismuth nanoparticles and K + -ether co-intercalation enables high-rate potassium storage at −50 °C0Transforming Mn 3 O 4 into MnOOH via Electrochemical Reconstruction for Aqueous Ammonium‐Ion Storage0Unraveling the concerted motion of Li ions in argyrodite Li 6+ x As 1− x Si x S 5 I solid electrolytes0Applications of rapid joule heating in rechargeable batteries: Material synthesis, structural engineering, and performance enhancement4A Decade-Long Odyssey of “Rocking-Chair” Zinc-Ion Batteries13A totally metal-free battery using organic electrodes in an aqueous electrolyte0Historical evolution and emerging trends of organometallic compounds in energy storage systems2Structural, Electronic, and Interfacial Pathways Governing the Stability of LiMn 2 O 4 Spinel Cathodes2Anode-Free Batteries: Pioneering Energy Storage Revolution32Non-metallic ion batteries beyond convention: fundamentals, material innovations, and pathways to sustainable energy storage1Methyl Asymmetric Interference‐Enhanced Dipole–Dipole Interaction for High‐Performance Potassium–Graphite Battery Electrolyte Design16Methyl Asymmetric Interference‐Enhanced Dipole–Dipole Interaction for High‐Performance Potassium–Graphite Battery Electrolyte Design1Fullerenes and their functional composites as emerging electrode materials for metal-ion batteries: A comprehensive review0Application of machine learning to rechargeable aqueous zinc-ion batteries: Advancements and prospects3Hierarchical graphene oxide encapsulated NiCo2V2O8 hollow spheres: Structural engineering for high energy density supercapacitor electrodes0Nb-Doped VO 0.9 @Carbon Nanofiber for High Capacitance and Fast Kinetic Zn 2+ Ion Storage1Fe-doped VSy (y = 2 or 4) for magnesium energy storage: improved conductivity, stability, and electrochemical performance0Self-catalytic CuFeS2 cathodes for magnesium batteries0Ion transport mechanisms and diffusion barriers in oxide spinel materials for swift performance of metal-ion supercapacitors2Recent advances in MXene-based batteries: Evolution from aqueous to solid-state systems3Fast-kinetic multivalent ion storage enabled by multiscale structural modulation in two-dimensional magnetic materials0Mechanistic Insights into the Electrochemical Calcium–Tin Alloying Reaction2Reconstructing solvation chemistry in crowded hydrogel electrolytes for stable zinc-ion hybrid capacitors1Anode/Electrolyte Interfacial Engineering Toward Sustainable and Practical Solid‐State Metal‐Sulfur Batteries: A Prospective Review0High‐Entropy Prussian Blue Analogues for Electrochemical Energy Storage0Dual‐Site Catalytic Interfaces Synergistically Boost Desolvation and Redox Kinetics in Zinc‐Ion Batteries2Molecular tailoring modulates coordination of deep eutectic electrolytes for dendrite-free rechargeable aluminum batteries0Molecular-Scale Hybrid Strategy Synergizes Solvation Regulation and SO 4 2– -Derived Inorganic-Rich SEI for Zn Anodes10Synergistic Pre‐Intercalation and Architectural Tuning to Suppress Vanadium Dissolution for Enhanced Aqueous Zinc‐Ion Battery Performance0Covalently Bonded Electrochemical Interfaces for Flexible Aluminum–Graphite Electrodes0Dual Soft‐Gel Electrodes Enabling Near‐Practical and Deployable Aqueous Batteries1Emerging frontiers of MXenes: structure, properties and energy applications3Sustainable and non-destructive separation of spent lithium-ion battery electrodes: Fundamentals, emerging technologies, and closed-loop recycling2Organic electrode materials meet MXenes: From synthesis strategies to electrochemical energy storage applications2Stabilizing zinc-ion battery systems: Cathode materials, recent trends and future directions0Electric Double Layer and Interface Chemistry Regulated by Silicon Trifluoromethanesulfonate for Magnesium Electrolyte at High Current Density of 20 mA cm –21Surfactant assisted sol gel synthesis of BiVO4 nanoparticles for photocatalysis, electrochemical energy storage and charge storage0A High‐Performance Oxidized Graphene for Dendrite‐Free Anodes and Kinetically Enhanced Cathodes of Aqueous Zn‐Ion Batteries1Defect and Hydration Synergy Enable Intercalation Pseudocapacitance in TiO 2 Anodes for High-Performance Aqueous Calcium-Ion Batteries0High‐Performance, Activation‐Free Magnesium‐Ion Batteries Enabled by Ionic Liquid Electrolyte Additive0High‐Performance, Activation‐Free Magnesium‐Ion Batteries Enabled by Ionic Liquid Electrolyte Additive3Recent progress of textured Zn anode strategies for aqueous zinc-ion batteries0Metal-Ion Batteries in Bioelectrical Signal Simulation: Applications and Challenges0Flexible textile-based aqueous zinc-ion batteries: From energy storage mechanisms to wearable device integration1Unlocking Zn‐Ion Diffusion in Disordered Rocksalt Cathodes for Nonaqueous Zn‐Ion Batteries0Unlocking Zn‐Ion Diffusion in Disordered Rocksalt Cathodes for Nonaqueous Zn‐Ion Batteries0Regulating the Inner Helmholtz Plane Enables Stable Solid Electrolyte Interphase and Oriented Deposition of Al Anodes0Overcoming Interfacial Hurdles in Solid‐State Aluminum Batteries for Safe and Energy‐Dense Storage0A Bicontinuous Viscoelastic Network Solid‐State Electrolyte with Integrated Dual‐Electrode Stabilization and Low‐Pressure Adaptability for Zinc‐Ion Batteries1Synergistic Co‐Solvents Enabled Stable Fast‐Kinetics Calcium Plating/Stripping in Electrolytes With Strongly Coordinating Anions2Vacancy-engineered tuning of the electrochemical performance of B4C3 monolayers as anode material for aluminum-ion battery: A DFT analysis1From polyolefins to functionally integrated materials: A review of lithium-ion battery separator innovations0Insights into Jahn-Teller effect in MnO2 cathodes for aqueous zinc-ion batteries0Defect‐Mediated Mg 2+ Transport and Structural Stability in the Sulfide Cathodes for Rechargeable Magnesium Batteries0Boosting Zinc-Ion Storage via In Situ Electrochemical Balancing of Active Sites and Conjugation in Truxene-Based Cathodes0Decoupling electronic modulation and defect engineering in α-MoO3 cathodes via interstitial boron doping for high-rate aqueous zinc-ion batteries0Impurity-capturing polymers: regulating chemistry and stability in lithium-ion batteries0Unlocking anion-dependent failure mechanisms of zinc electrodes and enhancing cycling stability via asymmetric interlayer0Accelerating ZnS Reversibility via Copper Sulfides Conductive Frameworks for Next‐Generation Aqueous Zn–S Batteries0Low-polarization aqueous zinc-tellurium batteries enabled by hierarchical porous carbon host coupled with iodide additive0Metal–organic frameworks as electrode materials for post-lithium-ion batteries: Coordination chemistry, electrochemical behavior, and performance relationships0Temperature-controlled balance between capacity and cycling stability in PEDOT-intercalated layered V2O5 cathodes for aqueous zinc-ion batteries1Targeted Modulation of Zn Deposition Behavior toward High-Performance Stable Zn Anodes0Carbon additives for P2–layered sodium–manganese–cobalt oxide cathode for Na-ion batteries: percolation characteristics and electrochemical performance0Protective interphases and safety enhancement in high-energy-density batteries: A critical review0V2B MBenes as a high-capacity electrode material for rechargeable metal-ion batteries0Design of Composite Catalysts for Rechargeable Zinc–Air Batteries: Design Strategies and Recent Advances0Engineering electrode materials and interfaces in aqueous and metal-ion batteries for enhanced stability and performance0Rechargeable iron ion battery using low-temperature reduced graphene oxide as cathode and deep eutectic solvent as electrolyte0Battery technologies and electrochemical storage systems0Rising role of multivalent electrolytes for two-dimensional electrode materials for supercapacitors: A comprehensive review0Hierarchical heterostructure engineering of eutectic alloy for dendrite-free and ultralong-lifespan anode in low-temperature aqueous zinc-metal battery0Toward a sustainable future: paradigm shifts, challenges, and convergence in green synthesis strategies for carbon materials0

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