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RESEARCH PAPER · Angewandte Chemie · 2018

An Asymmetric Anion‐Pillared Metal–Organic Framework as a Multisite Adsorbent Enables Simultaneous Removal of Propyne and Propadiene from Propylene

Lifeng Yang, Xili Cui, Zhaoqiang Zhang, Qiwei Yang, Zongbi Bao, Qilong Ren, Huabin Xing

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An Asymmetric Anion‐Pillared Metal–Organic Framework as a Multisite Adsorbent Enables Simultaneous Removal of Propyne and Propadiene from PropyleneOriginalA Metal–Organic Framework with Suitable Pore Size and Specific Functional Sites for the Removal of Trace Propyne from Propylene178A Metal–Organic Framework with Suitable Pore Size and Specific Functional Sites for the Removal of Trace Propyne from Propylene108Simultaneous Trapping of C2H2 and C2H6 from a Ternary Mixture of C2H2/C2H4/C2H6 in a Robust Metal–Organic Framework for the Purification of C2H4337Simultaneous Trapping of C2H2 and C2H6 from a Ternary Mixture of C2H2/C2H4/C2H6 in a Robust Metal–Organic Framework for the Purification of C2H485Integrating multiple adsorption sites and tortuous diffusion paths into a metal–organic framework for C 3 H 4 /C 3 H 6 separation31Anion Pillared Metal–Organic Framework Embedded with Molecular Rotors for Size-Selective Capture of CO 2 from CH 4 and N 275A Microporous Metal‐Organic Framework Supramolecularly Assembled from a CuII Dodecaborate Cluster Complex for Selective Gas Separation284A Microporous Metal‐Organic Framework Supramolecularly Assembled from a CuII Dodecaborate Cluster Complex for Selective Gas Separation60A water-stable fcu-MOF material with exposed amino groups for the multi-functional separation of small molecules53Robust Microporous Metal–Organic Frameworks for Highly Efficient and Simultaneous Removal of Propyne and Propadiene from Propylene91Robust Microporous Metal–Organic Frameworks for Highly Efficient and Simultaneous Removal of Propyne and Propadiene from Propylene20Efficient Separation of n‐Butene and iso‐Butene by Flexible Ultramicroporous Metal‐Organic Frameworks with Pocket‐like Cavities32Current Status of Microporous Metal–Organic Frameworks for Hydrocarbon Separations41Separation of Xe from Kr with Record Selectivity and Productivity in Anion‐Pillared Ultramicroporous Materials by Inverse Size‐Sieving137Separation of Xe from Kr with Record Selectivity and Productivity in Anion‐Pillared Ultramicroporous Materials by Inverse Size‐Sieving59Halogen–C2H2 Binding in Ultramicroporous Metal–Organic Frameworks (MOFs) for Benchmark C2H2/CO2 Separation Selectivity89Metal-organic frameworks chelated by zinc fluorides for ultra-high affinity to acetylene during C2/C1 separations11Molecular Sieving of C2‐C3 Alkene from Alkyne with Tuned Threshold Pressure in Robust Layered Metal–Organic Frameworks128Molecular Sieving of C2‐C3 Alkene from Alkyne with Tuned Threshold Pressure in Robust Layered Metal–Organic Frameworks15Synthesis of Ionic Ultramicroporous Polymers for Selective Separation of Acetylene from Ethylene107Rational Design of Microporous MOFs with Anionic Boron Cluster Functionality and Cooperative Dihydrogen Binding Sites for Highly Selective Capture of Acetylene184Rational Design of Microporous MOFs with Anionic Boron Cluster Functionality and Cooperative Dihydrogen Binding Sites for Highly Selective Capture of Acetylene40Simultaneous interlayer and intralayer space control in two-dimensional metal−organic frameworks for acetylene/ethylene separation163Separation of Xylene Isomers in the Anion‐Pillared Square Grid Material SIFSIX‐1‐Cu20Interpenetration Symmetry Control Within Ultramicroporous Robust Boron Cluster Hybrid MOFs for Benchmark Purification of Acetylene from Carbon Dioxide213Interpenetration Symmetry Control Within Ultramicroporous Robust Boron Cluster Hybrid MOFs for Benchmark Purification of Acetylene from Carbon Dioxide25Control of Functionalized Pore Environment in Robust Ionic Ultramicroporous Polymers for Efficient Removal of Trace Propyne from Propylene13A Solid Transformation into Carboxyl Dimers Based on a Robust Hydrogen‐Bonded Organic Framework for Propyne/Propylene Separation139A Solid Transformation into Carboxyl Dimers Based on a Robust Hydrogen‐Bonded Organic Framework for Propyne/Propylene Separation22Comprehensive Pore Tuning in an Ultrastable Fluorinated Anion Cross‐Linked Cage‐Like MOF for Simultaneous Benchmark Propyne Recovery and Propylene Purification17Comprehensive Pore Tuning in an Ultrastable Fluorinated Anion Cross‐Linked Cage‐Like MOF for Simultaneous Benchmark Propyne Recovery and Propylene Purification110One-step removal of alkynes and propadiene from cracking gases using a multi-functional molecular separator42Crystalline Molecular Assemblies of Complexes Showing Eightfold Coordinated Niobium(IV) Dodecahedral Geometry in the Pyridine-Dicarboxylic Acid System2Dynamical and electronic properties of anion-pillared metal–organic frameworks for natural gas separation6The Chemistry of Metal–Organic Frameworks for Multicomponent Gas Separation62The Chemistry of Metal–Organic Frameworks for Multicomponent Gas Separation11Separation of xylene isomers using metal-organic frameworks: Addressing challenges in the petrochemical industry35One-step propylene purification from a quaternary mixture by a single physisorbent11Crystal Engineering of Reticular Materials for Gas‐ and Liquid‐Phase Hydrocarbon Separation4Recent advances in metal–organic frameworks for xylene isomers separation: Performance and mechanism insights0Aromaticity Regulation in Isostructural Metal‐Organic Frameworks for Propyne Storage and Propylene Purification0

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  1. A Metal–Organic Framework with Suitable Pore Size and Specific Functional Sites for the Removal of Trace Propyne from Propylene

    Angewandte Chemie International Edition · 2018-09-22

    Libo Li, Hui‐Min Wen, Chaohui He, Rui‐Biao Lin, Rajamani Krishna, Hui Wu, Wei Zhou, Jinping Li, Bin Li, Banglin Chen

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  2. A Metal–Organic Framework with Suitable Pore Size and Specific Functional Sites for the Removal of Trace Propyne from Propylene

    Angewandte Chemie · 2018-09-22

    Libo Li, Hui‐Min Wen, Chaohui He, Rui‐Biao Lin, Rajamani Krishna, Hui Wu, Wei Zhou, Jinping Li, Bin Li, Banglin Chen

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  3. Simultaneous Trapping of C2H2 and C2H6 from a Ternary Mixture of C2H2/C2H4/C2H6 in a Robust Metal–Organic Framework for the Purification of C2H4

    Angewandte Chemie International Edition · 2018-10-19

    Hongguo Hao, Yunfeng Zhao, Di‐Ming Chen, Jiamei Yu, Kui Tan, Shengqian Ma, Yves Jean Chabal, Zhiming Zhang, Jianmin Dou, Zihui Xiao, Gregory S. Day, Hong-Cai “Joe” Zhou, Tong‐Bu Lu

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  4. Simultaneous Trapping of C2H2 and C2H6 from a Ternary Mixture of C2H2/C2H4/C2H6 in a Robust Metal–Organic Framework for the Purification of C2H4

    Angewandte Chemie · 2018-10-19

    Hongguo Hao, Yunfeng Zhao, Di‐Ming Chen, Jiamei Yu, Kui Tan, Shengqian Ma, Yves Jean Chabal, Zhiming Zhang, Jianmin Dou, Zihui Xiao, Gregory S. Day, Hong-Cai “Joe” Zhou, Tong‐Bu Lu

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  5. Integrating multiple adsorption sites and tortuous diffusion paths into a metal–organic framework for C 3 H 4 /C 3 H 6 separation

    Journal of Materials Chemistry A · 2019-01-01

    Xue‐Qian Wu, Ya-Bo Xie, Jing-Hao Liu, Tao He, Yong‐Zheng Zhang, Jiamei Yu, Xiang‐Jing Kong, Jian‐Rong Li

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  6. Anion Pillared Metal–Organic Framework Embedded with Molecular Rotors for Size-Selective Capture of CO 2 from CH 4 and N 2

    ACS Sustainable Chemistry & Engineering · 2019-01-03

    Lifeng Yang, Xili Cui, Yuanbin Zhang, Qingju Wang, Zhaoqiang Zhang, Xian Suo, Huabin Xing

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  7. A Microporous Metal‐Organic Framework Supramolecularly Assembled from a CuII Dodecaborate Cluster Complex for Selective Gas Separation

    Angewandte Chemie International Edition · 2019-04-12

    Yuanbin Zhang, Lifeng Yang, Lingyao Wang, Simon Duttwyler, Huabin Xing

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  8. A Microporous Metal‐Organic Framework Supramolecularly Assembled from a CuII Dodecaborate Cluster Complex for Selective Gas Separation

    Angewandte Chemie · 2019-04-12

    Yuanbin Zhang, Lifeng Yang, Lingyao Wang, Simon Duttwyler, Huabin Xing

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  9. A water-stable fcu-MOF material with exposed amino groups for the multi-functional separation of small molecules

    Science China Materials · 2019-04-28

    Ke Jiang, Ling Zhang, Tifeng Xia, Yu Lin Yang, Bin Li, Yuanjing Cui, Guodong Qian

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  10. Robust Microporous Metal–Organic Frameworks for Highly Efficient and Simultaneous Removal of Propyne and Propadiene from Propylene

    Angewandte Chemie International Edition · 2019-05-06

    Yun‐Lei Peng, Chaohui He, Tony Pham, Ting Wang, Pengfei Li, Rajamani Krishna, Katherine A. Forrest, Adam Hogan, Shanelle Suepaul, Brian Space, Ming Fang, Yao Chen, Michael John Zaworotko, Jinping Li, Libo Li, Zhenjie Zhang, Peng Cheng, Banglin Chen

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  11. Robust Microporous Metal–Organic Frameworks for Highly Efficient and Simultaneous Removal of Propyne and Propadiene from Propylene

    Angewandte Chemie · 2019-05-06

    Yun‐Lei Peng, Chaohui He, Tony Pham, Ting Wang, Pengfei Li, Rajamani Krishna, Katherine A. Forrest, Adam Hogan, Shanelle Suepaul, Brian Space, Ming Fang, Yao Chen, Michael John Zaworotko, Jinping Li, Libo Li, Zhenjie Zhang, Peng Cheng, Banglin Chen

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  12. Efficient Separation of n‐Butene and iso‐Butene by Flexible Ultramicroporous Metal‐Organic Frameworks with Pocket‐like Cavities

    Chemistry - An Asian Journal · 2019-07-06

    Jiyu Cui, Zhaoqiang Zhang, Bin Tan, Yuanbin Zhang, Pengcheng Wang, Xili Cui, Huabin Xing

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  13. Current Status of Microporous Metal–Organic Frameworks for Hydrocarbon Separations

    Topics in Current Chemistry · 2019-10-29

    Jiyan Pei, Kai Shao, Ling Zhang, Hui‐Min Wen, Bin Li, Guodong Qian

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  14. Separation of Xe from Kr with Record Selectivity and Productivity in Anion‐Pillared Ultramicroporous Materials by Inverse Size‐Sieving

    Angewandte Chemie International Edition · 2019-11-20

    Qingju Wang, Tian Ke, Lifeng Yang, Zhaoqiang Zhang, Xili Cui, Zongbi Bao, Qilong Ren, Qiwei Yang, Huabin Xing

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  15. Separation of Xe from Kr with Record Selectivity and Productivity in Anion‐Pillared Ultramicroporous Materials by Inverse Size‐Sieving

    Angewandte Chemie · 2019-11-20

    Qingju Wang, Ke Tian, Lifeng Yang, Zhaoqiang Zhang, Xili Cui, Zongbi Bao, Qilong Ren, Qiwei Yang, Huabin Xing

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  16. Halogen–C2H2 Binding in Ultramicroporous Metal–Organic Frameworks (MOFs) for Benchmark C2H2/CO2 Separation Selectivity

    Chemistry - A European Journal · 2020-01-07

    Soumya Mukherjee, Yonghe He, Douglas Franz, Shi‐Qiang Wang, Wan‐Ru Xian, Andrey A. Bezrukov, Brian Space, Zhengtao Xu, Jun Hui He, Michael John Zaworotko

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  17. Metal-organic frameworks chelated by zinc fluorides for ultra-high affinity to acetylene during C2/C1 separations

    Fuel · 2020-01-13

    Chenkai Gu, Jing Liu, Jianbo Hu, Dawei Wu

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  18. Molecular Sieving of C2‐C3 Alkene from Alkyne with Tuned Threshold Pressure in Robust Layered Metal–Organic Frameworks

    Angewandte Chemie International Edition · 2020-04-24

    Ke Tian, Qingju Wang, Jin Shen, Jingyi Zhou, Zongbi Bao, Qiwei Yang, Qilong Ren

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  19. Molecular Sieving of C2‐C3 Alkene from Alkyne with Tuned Threshold Pressure in Robust Layered Metal–Organic Frameworks

    Angewandte Chemie · 2020-04-24

    Ke Tian, Qingju Wang, Jin Shen, Jingyi Zhou, Zongbi Bao, Qiwei Yang, Qilong Ren

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  20. Synthesis of Ionic Ultramicroporous Polymers for Selective Separation of Acetylene from Ethylene

    Advanced Materials · 2020-06-11

    Xian Suo, Xili Cui, Lifeng Yang, Nan Xu, Yuqi Huang, Yi He, Sheng Dai, Huabin Xing

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  21. Rational Design of Microporous MOFs with Anionic Boron Cluster Functionality and Cooperative Dihydrogen Binding Sites for Highly Selective Capture of Acetylene

    Angewandte Chemie International Edition · 2020-06-27

    Yuanbin Zhang, Jianbo Hu, Rajamani Krishna, Lingyao Wang, Lifeng Yang, Xili Cui, Simon Duttwyler, Huabin Xing

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  22. Rational Design of Microporous MOFs with Anionic Boron Cluster Functionality and Cooperative Dihydrogen Binding Sites for Highly Selective Capture of Acetylene

    Angewandte Chemie · 2020-06-27

    Yuanbin Zhang, Jianbo Hu, Rajamani Krishna, Lingyao Wang, Lifeng Yang, Xili Cui, Simon Duttwyler, Huabin Xing

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  23. Simultaneous interlayer and intralayer space control in two-dimensional metal−organic frameworks for acetylene/ethylene separation

    Nature Communications · 2020-12-07

    Jin Shen, Xin He, Ke Tian, Rajamani Krishna, Jasper M. van Baten, Rundao Chen, Zongbi Bao, Huabin Xing, Mircea Dincă, Zhiguo Zhang, Qiwei Yang, Qilong Ren

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  24. Separation of Xylene Isomers in the Anion‐Pillared Square Grid Material SIFSIX‐1‐Cu

    Chemistry - A European Journal · 2021-01-20

    Liping Yang, Hanbang Liu, Jiacheng Xing, Danhua Yuan, Yunpeng Xu, Zhongmin Liu

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  25. Interpenetration Symmetry Control Within Ultramicroporous Robust Boron Cluster Hybrid MOFs for Benchmark Purification of Acetylene from Carbon Dioxide

    Angewandte Chemie International Edition · 2021-08-12

    Lingyao Wang, Wanqi Sun, Yuanbin Zhang, Nuo Xin Xu, Rajamani Krishna, Jianbo Hu, Yunjia Jiang, Yabing He, Huabin Xing

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  26. Interpenetration Symmetry Control Within Ultramicroporous Robust Boron Cluster Hybrid MOFs for Benchmark Purification of Acetylene from Carbon Dioxide

    Angewandte Chemie · 2021-08-12

    Lingyao Wang, Wanqi Sun, Yuanbin Zhang, Nuo Xin Xu, Rajamani Krishna, Jianbo Hu, Yunjia Jiang, Yabing He, Huabin Xing

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  27. Control of Functionalized Pore Environment in Robust Ionic Ultramicroporous Polymers for Efficient Removal of Trace Propyne from Propylene

    ACS Applied Materials & Interfaces · 2021-09-03

    Xian Suo, Hanqian Pan, Liyuan Chen, Xili Cui, Huabin Xing

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  28. A Solid Transformation into Carboxyl Dimers Based on a Robust Hydrogen‐Bonded Organic Framework for Propyne/Propylene Separation

    Angewandte Chemie International Edition · 2021-09-09

    Baoqiu Yu, Shubo Geng, Hailong Wang, Wei Zhou, Zhenjie Zhang, Banglin Chen, Jianzhuang Jiang

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  29. A Solid Transformation into Carboxyl Dimers Based on a Robust Hydrogen‐Bonded Organic Framework for Propyne/Propylene Separation

    Angewandte Chemie · 2021-09-09

    Baoqiu Yu, Shubo Geng, Hailong Wang, Wei Zhou, Zhenjie Zhang, Banglin Chen, Jianzhuang Jiang

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  30. Comprehensive Pore Tuning in an Ultrastable Fluorinated Anion Cross‐Linked Cage‐Like MOF for Simultaneous Benchmark Propyne Recovery and Propylene Purification

    Angewandte Chemie · 2022-02-24

    Yunjia Jiang, Jianbo Hu, Lingyao Wang, Wanqi Sun, Nuo Xin Xu, Rajamani Krishna, Simon Duttwyler, Xili Cui, Huabin Xing, Yuanbin Zhang

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  31. Comprehensive Pore Tuning in an Ultrastable Fluorinated Anion Cross‐Linked Cage‐Like MOF for Simultaneous Benchmark Propyne Recovery and Propylene Purification

    Angewandte Chemie International Edition · 2022-02-24

    Yunjia Jiang, Jianbo Hu, Lingyao Wang, Wanqi Sun, Nuo Xin Xu, Rajamani Krishna, Simon Duttwyler, Xili Cui, Huabin Xing, Yuanbin Zhang

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  32. One-step removal of alkynes and propadiene from cracking gases using a multi-functional molecular separator

    Nature Communications · 2022-05-26

    Qingju Wang, Jianbo Hu, Lifeng Yang, Zhaoqiang Zhang, Ke Tian, Xili Cui, Huabin Xing

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  33. Crystalline Molecular Assemblies of Complexes Showing Eightfold Coordinated Niobium(IV) Dodecahedral Geometry in the Pyridine-Dicarboxylic Acid System

    Inorganic Chemistry · 2022-09-16

    Despoina Andriotou, Sylvain Duval, Christophe Volkringer, Ángel M. Arévalo‐López, Pardis Simon, Hervé Vezin, Thierry Loiseau

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  34. Dynamical and electronic properties of anion-pillared metal–organic frameworks for natural gas separation

    Physical Chemistry Chemical Physics · 2023-01-01

    Sabrina Grigoletto, Arthur Gomes dos Santos, Guilherme Ferreira de Lima, Heitor A. De Abreu

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  35. The Chemistry of Metal–Organic Frameworks for Multicomponent Gas Separation

    Angewandte Chemie International Edition · 2024-08-25

    Lifeng Yang, Peixin Zhang, Jiyu Cui, Xili Cui, Huabin Xing

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  36. The Chemistry of Metal–Organic Frameworks for Multicomponent Gas Separation

    Angewandte Chemie · 2024-08-26

    Lifeng Yang, Peixin Zhang, Jiyu Cui, Xili Cui, Huabin Xing

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  37. Separation of xylene isomers using metal-organic frameworks: Addressing challenges in the petrochemical industry

    Coordination Chemistry Reviews · 2024-10-11

    Ying Liu, Chao Wang, Qiwei Yang, Qilong Ren, Zongbi Bao

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  38. One-step propylene purification from a quaternary mixture by a single physisorbent

    Nature Communications · 2025-12-13

    Peixin Zhang, Zhensong Qiu, Yechen Liu, Sen Chen, Lifeng Yang, Xian Suo, Xili Cui, Huabin Xing

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  39. Crystal Engineering of Reticular Materials for Gas‐ and Liquid‐Phase Hydrocarbon Separation

    Advanced Materials · 2026-02-11

    Xia Li, Soumya Mukherjee, Michael John Zaworotko

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  40. Recent advances in metal–organic frameworks for xylene isomers separation: Performance and mechanism insights

    Green Technologies and Sustainability · 2026-03-31

    Kaikai Zhao, Jiajun Zeng, Manqi Liu, Yu Wang, Ying Peng, Yulu Yang, Kai Zheng, Zhikuan Wang, Hongxia Xi, Chongxiong Duan

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  41. Aromaticity Regulation in Isostructural Metal‐Organic Frameworks for Propyne Storage and Propylene Purification

    Angewandte Chemie · 2026-09-23

    Yukun Ye, Lixia Guo, Jiarui Fan, Zhixin Wang, Zhaozhao Hu, Ruohan Li, Siyu Zhou, Lifei Lin, Yiheng Wang, Mark R. Warren, Ben Coulson, Pascal Manuel, Sarah J. Day, Eamonn T. Connolly, Jiangnan Li, Sihai Yang⧫

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