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RESEARCH PAPER · Inorganic Chemistry · 2021

Fluorine: A Very Special Element and Its Very Special Impacts on Chemistry

Stefanie Dehnen, Laurel L. Schafer, Thomas Lectka, Antonio Togni

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Fluorine: A Very Special Element and Its Very Special Impacts on ChemistryOriginalCharge Photogeneration and Recombination in Fluorine-Substituted Polymer Solar Cells1Catalytic and Chemodivergent Synthesis of 1-Substituted 9H-Pyrrolo[1,2-a]indoles via Annulation of β-CF3 Enones with 3-Substituted Indoles10Direct Quantitative Analysis of Fluorine in Solid Samples by Cryogenic Laser Ablation and Ionization Time-of-Flight Mass Spectrometry4Photoinduced regioselective difluorination of secondary inert C(sp 3 )–H bonds in sulfonamides via 1,5-hydrogen-atom transfer16Quantitative imaging of fluorine in human teeth by cryogenic laser ionization time-of-flight mass spectrometry3Ultraviolet-curable Material with High Fluorine Content for Biomimetic Functional Structures Achieved by Nanoimprint Lithography with Gas-permeable Template for Life Science and Electronic Applications3Fe-Promoted C–F Activation of Aryl Fluorides Enables Heck-Type Coupling with Alkenes and One-Pot Synthesis of Indenes6Fluoride distribution, contamination, toxicological effects and remedial measures: a review21An Extrusion Strategy for On-Demand SF 5 Cl Gas Generation from a Commercial Disulfide26Biosynthesis of Diverse Ephedra-Type Alkaloids via a Newly Identified Enzymatic Cascade13Synthesis of C–C bonded trifluoromethyl-based high-energy density materials via the ANRORC mechanism2Fluorine doping induced fluorescence emission redshift of CDs12Fabrication strategies for chiral self-assembly surface10Direct Synthesis of Monofluoromethylthioesters from Acyl Chlorides with Elemental Sulfur and Fluoroiodomethane4Reconciling Environmental Safety and Economic Feasibility: A Review of Soil Fluorine Management Strategies in South Korea1Development of a new type of highly effective etchant solution for glue residue in wafer-level packaging process4Crystalline liquids: Dynamic responsive materials for future devices6Balancing Environmental Safety and Economic Feasibility: A Review of Soil Fluorine Management Strategies in South Korea8Visible Light‐Driven Metal‐ and Photocatalyst‐Free Synthesis of β‐Trifluoromethylated Enamines via Trifluoromethyl Thianthrenium Salts4Data-Driven Analysis of High-Temperature Fluorocarbon Plasma for Semiconductor Processing3Photocatalytic regioselective C–H bond functionalizations in arenes37Electronic effects in early transition metal catalyzed olefin polymerization: challenges in featurization and descriptor strengths and weaknesses1New synthetic approaches for the construction of difluoromethylated architectures18Elucidating Fluorine Steering Effects in Diels‐Alder Reactions Interfaced with Charge‐Enhanced Reactivity1HF‐Free Manufacturing of Fluorochemicals from Fluorspar0HF‐Free Manufacturing of Fluorochemicals from Fluorspar0Comparative Study on Pervaporation Performance of Polyphosphazene Membranes with Different Fluorine Side Groups for Thiophene/n-Heptane Separation2Beyond Presumptions: Toward Mechanistic Clarity in Metal‐Free Carbon Catalysts for Electrochemical H 2 O 2 Production via Data Science19Synthesis, Characterization, and Antimicrobial Evaluation of Some Novel Hydrazinecarbothioamides3Photoredox‐Catalyzed Synthesis of a Novel Class of Fluoroalkyl Pyrazolones9Degradation‐Free High‐Efficiency Fluoride‐Coating Solar Cells via Precision Interface Engineering1Regioselective Addition of Organolithium Reagents to Fluorinated Proline Amides: Insights from Experiment and Theory0Hygienic assessment of the fluorine content in the soil of territories to be serviced by the Federal medical and biological agency0Recent progress in Pt( ii )- and Ir( iii )-complex-based chemical sensors for detecting picric acid2Photoredox decarbonylative Truce–Smiles rearrangement of N -sulfonylbenzamides with BrF 2 COR0Electrochemical Direct Monofluoromethylthiolation of Imidazopyridines Using Bunte Salt as Monofluoromethylthiolating Agent0Influence of Na+/Li+ Co-doping on the structure, thermal behavior, and ionic conductivity of fluorapatite-based materials1Structural bias effect on fluorination at C-1 and C-2 of alkyl-3,6-anhydro-D-hexofuranosides: Syntheses of 2-fluoro sauropunols and glycosyl fluorides1Theoretical Investigation of the Electronic Structure and Reactivity of F-, Cl-, and Br- Substituted DL-Norvaline Derivatives: A DFT and Molecular Docking Study1Flow‐Enabled Direct Photochemical Functionalization of Aryl Fluorides0

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  1. Charge Photogeneration and Recombination in Fluorine-Substituted Polymer Solar Cells

    Frontiers in Chemistry · 2022-02-24

    Rong Hu, Yurong Liu, Jun Peng, Jianjun Jiang, Mengyao Qing, Xiaochuan He, Mingming Huo, Wei Zhang

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  2. Catalytic and Chemodivergent Synthesis of 1-Substituted 9H-Pyrrolo[1,2-a]indoles via Annulation of β-CF3 Enones with 3-Substituted Indoles

    The Journal of Organic Chemistry · 2022-12-12

    Haritha Sindhe, Nehanaz Saiyed, Akshay Kamble, Malladi Mounika Reddy, Amardeep S. G. Singh, Satyasheel Sharma

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  3. Direct Quantitative Analysis of Fluorine in Solid Samples by Cryogenic Laser Ablation and Ionization Time-of-Flight Mass Spectrometry

    Analytical Chemistry · 2022-12-30

    Zhenjian Zhang, Siyuan Ma, Le Hang, Zhouyi Xu, Wei Hang

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  4. Photoinduced regioselective difluorination of secondary inert C(sp 3 )–H bonds in sulfonamides via 1,5-hydrogen-atom transfer

    Organic Chemistry Frontiers · 2023-01-01

    Zhi Chen, Wenkai Zhu, Chaodong Wang, Ning Xu, Qianxi Jin, Xule Huang, Shengjie Song, Jianjun Li

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  5. Quantitative imaging of fluorine in human teeth by cryogenic laser ionization time-of-flight mass spectrometry

    Journal of Analytical Atomic Spectrometry · 2023-01-01

    Siyuan Ma, Zhenjian Zhang, Zhouyi Xu, Xiongwen Qiu, Wei Hang

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  6. Ultraviolet-curable Material with High Fluorine Content for Biomimetic Functional Structures Achieved by Nanoimprint Lithography with Gas-permeable Template for Life Science and Electronic Applications

    Journal of Photopolymer Science and Technology · 2023-06-15

    Rio Yamagishi, Sayaka Miura, Mano Ando, Yuna Hachikubo, Tsugumi Murashita, Naoto Sugino, Takao Kameda, Yoshiyuki Yokoyama, Yuki Kawano, Kaori Yasuda, Satoshi Takei

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  7. Fe-Promoted C–F Activation of Aryl Fluorides Enables Heck-Type Coupling with Alkenes and One-Pot Synthesis of Indenes

    Organometallics · 2023-07-27

    Maxim R. Radzhabov, Neal P. Mankad

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  8. Fluoride distribution, contamination, toxicological effects and remedial measures: a review

    Sustainable Water Resources Management · 2023-08-29

    Anoop Kumar Yadav, Neeraj Kumari, Rajesh Kumar, Manoj Kumar, Sushma Yadav

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  9. An Extrusion Strategy for On-Demand SF 5 Cl Gas Generation from a Commercial Disulfide

    Organic Letters · 2023-12-05

    Reza Kordnezhadian, Tim De Bels, Kexin Su, Luc Van Meervelt, Ermal Ismalaj, Joachim Demaerel, Wim M. De Borggraeve

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  10. Biosynthesis of Diverse Ephedra-Type Alkaloids via a Newly Identified Enzymatic Cascade

    BioDesign Research · 2024-01-01

    Peiling Wu, Ding Luo, Yuezhou Wang, Xiaoxu Shang, Binju Wang, Xianming Deng, Jifeng Yuan

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  11. Synthesis of C–C bonded trifluoromethyl-based high-energy density materials via the ANRORC mechanism

    Dalton Transactions · 2024-01-01

    Parasar Kumar, Ramling Shivanandyya Mathpati, Vikas Dasharath Ghule, Srinivas Dharavath

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  12. Fluorine doping induced fluorescence emission redshift of CDs

    Journal of Molecular Structure · 2024-03-08

    Jianen Zhang, Li Guan, Tao Luo, Tao Yin, Weicai Shi, Xiaojie Ren, Youshi Lan, Fenghe Wang, Xu Li

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  13. Fabrication strategies for chiral self-assembly surface

    Microchimica Acta · 2024-03-16

    Xiaohui Niu, Mei Yuan, Rui Zhao, Lühua Wang, Yongqi Liu, Hongfang Zhao, Hongxia Li, Xing Yang, Kunjie Wang

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  14. Direct Synthesis of Monofluoromethylthioesters from Acyl Chlorides with Elemental Sulfur and Fluoroiodomethane

    European Journal of Organic Chemistry · 2024-04-23

    Chenchen Hu, Yuyang Zhang, Zeguo Fang, Feng‐Ling Qing

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  15. Reconciling Environmental Safety and Economic Feasibility: A Review of Soil Fluorine Management Strategies in South Korea

    Preprints.org · 2024-07-11

    Chang-Hwan Ji, Soon Hong Lee, Gi Seong Bae, Hyun Woo Kim

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  16. Development of a new type of highly effective etchant solution for glue residue in wafer-level packaging process

    Journal of Industrial and Engineering Chemistry · 2024-08-23

    Ha-Yeong Kim, Suk Jekal, Yeon-Ryong Chu, Jisu Lim, Jiwon Kim, Jungchul Noh, Hwa Sung Lee, Zambaga Otgonbayar, Chang‐Min Yoon

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  17. Crystalline liquids: Dynamic responsive materials for future devices

    Journal of Molecular Liquids · 2024-09-07

    Noha Bedowr

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  18. Balancing Environmental Safety and Economic Feasibility: A Review of Soil Fluorine Management Strategies in South Korea

    Sustainability · 2024-09-26

    Chang Hwan Ji, Soon-Hong Lee, Gi Seong Bae, Hyun Woo Kim

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  19. Visible Light‐Driven Metal‐ and Photocatalyst‐Free Synthesis of β‐Trifluoromethylated Enamines via Trifluoromethyl Thianthrenium Salts

    Chemistry - An Asian Journal · 2024-10-29

    Liang Jiang, Yisong Tang, Shuqi Li, Xing Peng, Shiyu Rim, Xiao Yun Chen

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  20. Data-Driven Analysis of High-Temperature Fluorocarbon Plasma for Semiconductor Processing

    Sensors · 2024-11-15

    Sung Kyu Jang, Woosung Lee, Ga In Choi, Jihun Kim, Minji Kang, Seong-Ho Kim, Jong Hyun Choi, Seul-Gi Kim, Seoung‐Ki Lee, Hyeong‐U Kim, Hyeongkeun Kim

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  21. Photocatalytic regioselective C–H bond functionalizations in arenes

    Chemical Science · 2024-12-09

    Jun Hu, Suman Pradhan, Satyadeep Waiba, Shoubhik Das

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  22. Electronic effects in early transition metal catalyzed olefin polymerization: challenges in featurization and descriptor strengths and weaknesses

    Dalton Transactions · 2025-01-01

    Christian Ehm, Gianluigi Galasso, Antonio Vittoria, Pietro Oriente, Luigi Maiale, Peter H. M. Budzelaar, Roberta Cipullo, Vincenzo Busico

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  23. New synthetic approaches for the construction of difluoromethylated architectures

    Organic & Biomolecular Chemistry · 2025-01-01

    Zhou Sun, Xue‐Song Zhang, Shao-Wei Bian, Chun Wei Zhang, Yaping Han, Yong‐Min Liang

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  24. Elucidating Fluorine Steering Effects in Diels‐Alder Reactions Interfaced with Charge‐Enhanced Reactivity

    European Journal of Organic Chemistry · 2025-01-02

    Sabrina Hoford, Julius E. L. Jan, Jeffrey N. Johnston, Jeffrey N. Johnston, Travis C. Dudding

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  25. HF‐Free Manufacturing of Fluorochemicals from Fluorspar

    Angewandte Chemie International Edition · 2025-05-21

    Ricardo I. Rodríguez, Luca Dell’Amico

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  26. HF‐Free Manufacturing of Fluorochemicals from Fluorspar

    Angewandte Chemie · 2025-05-21

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  27. Comparative Study on Pervaporation Performance of Polyphosphazene Membranes with Different Fluorine Side Groups for Thiophene/n-Heptane Separation

    Polymers · 2025-06-05

    Bingcong Xu, Xingmei Zhang, Wen‐Wen He, Xiaolong Han

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  28. Beyond Presumptions: Toward Mechanistic Clarity in Metal‐Free Carbon Catalysts for Electrochemical H 2 O 2 Production via Data Science

    Advanced Materials · 2025-07-31

    Dayu Zhu, Hsiwen Wu, Xiao Wang, Jie Zhang

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  29. Synthesis, Characterization, and Antimicrobial Evaluation of Some Novel Hydrazinecarbothioamides

    Turkish Journal of Pharmaceutical Sciences · 2025-09-05

    Efe Doğukan Dincel, Ebru Didem Kuran, Harika Öykü Dinç, Faika Başoğlu, Emrah Güler, Nuray Ulusoy-Güzeldemirci

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  30. Photoredox‐Catalyzed Synthesis of a Novel Class of Fluoroalkyl Pyrazolones

    Advanced Synthesis & Catalysis · 2025-09-13

    Emanuele F. Pissinati, Meysam Azizzade, Till Opatz, Márcio W. Paixão

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  31. Degradation‐Free High‐Efficiency Fluoride‐Coating Solar Cells via Precision Interface Engineering

    Progress in Photovoltaics Research and Applications · 2025-09-14

    Yu Bai, Yimin Zhang, Hong Luo, Jianhua Shi, Yuhui Ji, Yu Hu, Wei Long, Fangdan Jiang, Guoqiang Xing, Junsheng Yu, Ying Zhou, Wenzhu Liu, Sheng Meng, Jian Yu

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  32. Regioselective Addition of Organolithium Reagents to Fluorinated Proline Amides: Insights from Experiment and Theory

    ChemistrySelect · 2025-10-31

    Marcin Kaźmierczak, Tomasz Siodła, Monika Bilska‐Markowska

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  33. Hygienic assessment of the fluorine content in the soil of territories to be serviced by the Federal medical and biological agency

    Hygiene and Sanitation · 2025-12-19

    Евсеева Ирина Сергеевна, Olga V. Ushakova, Yury V. Zhernov

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  34. Recent progress in Pt( ii )- and Ir( iii )-complex-based chemical sensors for detecting picric acid

    Dalton Transactions · 2025-12-20

    Xiaoran Yang, Qinglong Zhang, Boyuan Miao, Chun Liu

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  35. Photoredox decarbonylative Truce–Smiles rearrangement of N -sulfonylbenzamides with BrF 2 COR

    Organic & Biomolecular Chemistry · 2026-01-01

    Xinsi Liu, Zheng Liu, Dongfang Jiang, Huawen Huang

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  36. Electrochemical Direct Monofluoromethylthiolation of Imidazopyridines Using Bunte Salt as Monofluoromethylthiolating Agent

    Advanced Synthesis & Catalysis · 2026-02-02

    Bo Li, Yuhuan Zhang, Ruogu Yin, Ruhan Lu, Yongyuan Gao

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  37. Influence of Na+/Li+ Co-doping on the structure, thermal behavior, and ionic conductivity of fluorapatite-based materials

    Ceramics International · 2026-02-24

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  38. Structural bias effect on fluorination at C-1 and C-2 of alkyl-3,6-anhydro-D-hexofuranosides: Syntheses of 2-fluoro sauropunols and glycosyl fluorides

    Carbohydrate Research · 2026-06-16

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  39. Theoretical Investigation of the Electronic Structure and Reactivity of F-, Cl-, and Br- Substituted DL-Norvaline Derivatives: A DFT and Molecular Docking Study

    Journal of Physical Chemistry and Functional Materials · 2026-06-29

    Fermin Ak, Hanifi Kebiroglu

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  40. Flow‐Enabled Direct Photochemical Functionalization of Aryl Fluorides

    Advanced Synthesis & Catalysis · 2026-07-01

    Jesús Sanjosé‐Orduna, Daniele Esposito, Luigi Dolcini, Niccolò Intini, Demi D. Snabilié, Bas de Bruin, Timothy Noël

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