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RESEARCH PAPER · Angewandte Chemie International Edition · 2021

Highly Efficient Spin‐Filtering Transport in Chiral Hybrid Copper Halides

Ying Lü, Qian Wang, Ruilin He, Foxin Zhou, Xia Yang, Dong Wang, Hui Cao, Wanli He, Feng Pan, Zhou Yang, Cheng Song

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Highly Efficient Spin‐Filtering Transport in Chiral Hybrid Copper HalidesOriginalSpin-polarized excitons and charge carriers in chiral metal halide semiconductors23Advances in single crystals and thin films of chiral hybrid metal halides38The Renaissance of Functional Hybrid Transition-Metal Halides96Leveraging Hierarchical Chirality in Perovskite(‐Inspired) Halides for Transformative Device Applications41Direct Detection of Near-Infrared Circularly Polarized Light via Precisely Designed Chiral Perovskite Heterostructures37Chiral 2D Cu(I) Halide Frameworks53Unusual Spin Polarization in the Chirality-Induced Spin Selectivity75Spin Selectivity in Chiral Hybrid Cobalt Halide Films with Ultrasmooth Surface27Second-order nonlinear optical properties of copper-based hybrid organic–inorganic perovskites induced by chiral amines30Chiral-induced spin selectivity in biomolecules, hybrid organic–inorganic perovskites and inorganic materials: a comprehensive review on recent progress54Chirality in luminescent Cs 3 Cu 2 Br 5 microcrystals produced via ligand-assisted reprecipitation3Centimeter‐Sized Piezoelectric Single Crystal of Chiral Bismuth‐Based Hybrid Halide with Superior Electrostrictive Coefficient26Strain-Driven Solid–Solid Crystal Conversion in Chiral Hybrid Pseudo-Perovskites with Paramagnetic-to-Ferromagnetic Transition41Exploration of new chiral hybrid semiconducting palladium halide complexes: [(R)/(S)-2-Methylpiperazinediium]PdCl49Unique Chiro-optical Properties of the Weakly-2D (R-/S-MBA)2CuBr4 Hybrid Material31Chirality‐Induced Spin Selectivity: An Enabling Technology for Quantum Applications121Unraveling chirality transfer mechanism by structural isomer-derived hydrogen bonding interaction in 2D chiral perovskite167Chiral Hybrid Perovskites (R-/S-CLPEA)4Bi2I10 with Enhanced Chirality and Spin–Orbit Coupling Splitting for Strong Nonlinear Optical Circular Dichroism and Spin Selectivity Effects36Emerging Spintronic Materials and Functionalities106Spin Control and Multifunctional Photocurrent Switch in Chiral Hybrid Organic–Inorganic Perovskites5Multiple Stimuli‐Responsive Luminescent Chiral Hybrid Antimony Chlorides for Anti‐Counterfeiting and Encryption Applications14Multiple Stimuli‐Responsive Luminescent Chiral Hybrid Antimony Chlorides for Anti‐Counterfeiting and Encryption Applications114Research progress in spintronics of chiral perovskite materials4(R/S-ClMBA)3GeI5: A Novel Low-Dimensional Ge-Containing Chiral Perovskite1Structural, vibrational, optical properties and DFT calculations of a zinc(II) chloride hybrid based on substituted bipyridinium cation4Chiral-induced spin selectivity in photo-induced electron transfer: Investigating charge and spin dynamics in a master equation framework5Chiral Hybrid Germanium(II) Halide with Strong Nonlinear Chiroptical Properties114Chiral Hybrid Germanium(II) Halide with Strong Nonlinear Chiroptical Properties12A study on light sensitization behavior in (Mph)2CuCl4 low-dimensional hybrid material with tetrahedral units and extended absorption up to the NIR region3Chiral induction and Sb3+ doping in indium halides to trigger second harmonic generation and circularly polarized luminescence22Chiral Ruthenium Halide Semiconductor with Strong Antiferromagnetic Coupling28Magnetic hybrid transition metal halides17Ferroics in Hybrid Organic–Inorganic Perovskites: Fundamentals, Design Strategies, and Implementation42Chemically Controlled Reversible Magnetic Phase Transition in Two-Dimensional Organometallic Lattices13Spin Polarization in Transport Studies of Chirality-Induced Spin Selectivity57Free Halogen Substitution of Chiral Hybrid Metal Halides for Activating the Linear and Nonlinear Chiroptical Properties140Rational design of enantiomeric lead-free double perovskites by achiral-chiral cation intercalation28Dual-ligand quasi-2D perovskites with chiral-induced spin selectivity for room temperature spin-LEDs29Synthesis, optical, electronic and magnetic studies of air-stable chiral Cu( ii ) chlorides3Ligand‐Induced Chirality in ClMBA2SnI4 2D Perovskite**38Family of Chiral Ferroelectric Compounds with Widely Tunable Band Gaps15Ligand‐Induced Chirality in ClMBA2SnI4 2D Perovskite**6Molecular nanomagnets: a viable path toward quantum information processing?86Chiral Induced Spin Selectivity603Covalent Organic Frameworks with Tunable Chirality for Chiral-Induced Spin Selectivity70Spintronic Phenomena and Applications in Hybrid Organic–Inorganic Perovskites64Efficient Quasi-2D Perovskite Spin Light-Emitting Diodes Based on Chiral-Induced Spin Selectivity47Structural Asymmetry and Chiral-Induced Spin Selectivity in Chiral Palladium-Halide Semiconductors27Copper-based perovskites and perovskite-like halides: A review from the perspective of molecular level86A chemical perspective on the chiral induced spin selectivity effect56Highly Emissive Chiral Indium‐Based Perovskite Single Crystals for Efficient Optoelectronic Applications25Expanding the Family of Magnetic Vacancy-Ordered Halide Double Perovskites7Charge Transport Phenomena Driven by the Polarity and Chirality in Noncentrosymmetric Layered Organic–Inorganic Hybrid Perovskites8Chiral Zero-Dimensional Transition Metal Halide Hybrid Perovskite with Ehanced Circular Dichroism and Magnetism3Chirality‐Induced Magnetic Polarization by Charge Localization in a Chiral Supramolecular Crystal6Reversible Local Protonation‐Deprotonation: Tuning Stimuli‐Responsive Circularly Polarized Luminescence in Chiral Hybrid Zinc Halides for Anti‐Counterfeiting and Encryption9Reversible Local Protonation‐Deprotonation: Tuning Stimuli‐Responsive Circularly Polarized Luminescence in Chiral Hybrid Zinc Halides for Anti‐Counterfeiting and Encryption47Homochiral Covalent Organic Frameworks with Superhelical Nanostructures Enable Efficient Chirality‐Induced Spin Selectivity7Homochiral Covalent Organic Frameworks with Superhelical Nanostructures Enable Efficient Chirality‐Induced Spin Selectivity31Lead-Free Hybrid Perovskite: An Efficient Room-Temperature Spin Generator via Large Interfacial Rashba Effect10Switchable circularly polarized luminescent Mn-based hybrid metal halides14Chirality of Lead-Free Organic-Inorganic Metal Halides: A Tool to Enhance Their Solar Harvesting Properties0Engineering magnetism in hybrid organic–inorganic metal halide perovskites27Strain-relaxed chiral bismuth halide perovskites for enhanced spin selectivity and magnetoresistance0Hafnium-Based Chiral 2D Organic–Inorganic Hybrid Metal Halides: Engineering Polarity and Nonlinear Optical Properties via Para -Substituent Effects861.5D Chiral Perovskites Mediated by Hydrogen‐Bonding Network with Remarkable Spin‐Polarized Property21.5D Chiral Perovskites Mediated by Hydrogen‐Bonding Network with Remarkable Spin‐Polarized Property18Dramatical enhancement of circular dichroism in chiral hybrid perovskites via carboxylic hydrogen bond engineering6Chiral-induced spin selectivity in electrocatalysis39Highly Conductive Chiral Organic Cages and Their Helical Assemblies Enable Efficient Spin Filtering23Copper Mixed‐halide Hybrids with Intrinsic Broadband White‐Light Emission for WLED Application with Ultrahigh Color Rendering Index25Chiral metal halide perovskites toward room temperature spin light-emitting diodes: Insights and perspectives9Chirality-Induced Spin Selectivity at the Molecular Level: A Different Perspective to Understand and Exploit the Phenomenon14Disordered and Conductive Chiral Spin‐Selective Strategy to Enhance Small‐Molecule‐Based Spintronic Application7Magnetic Organic–Inorganic Hybrid Halide Perovskites: Fundamental Physics, Properties, and Applications14Crystal growth, structural, optical, thermal and antibacterial analyses of semi-organic (C₅H₇N₂)₂[ZnX₄] non-linear optical single crystal for optoelectronic applications7Multifunctional Chiral Halide Perovskites: Advancing Chiro‐Optics, Chiro‐Optoelectronics, and Spintronics33Crystallization of Low-Dimensional Lead-Free (R/S-MBA)2CuBr4 Chiral Perovskite Thin Films0Spatial mapping of chiral-induced spin selectivity in chiral perovskite via spin-Schottky junction10Design Strategies and Advancements in Organic Spintronics: from Material Engineering and Interfacial Modification to Functional Devices15Anisotropic Second‐Harmonic Generation in Chiral Hybrid Palladium Halides2Anisotropic Second‐Harmonic Generation in Chiral Hybrid Palladium Halides10Long-lived photoinduced polar states in metal halide perovskites10Molecular Engineering of Layered Halide Double Perovskites: Challenges and Opportunities in Optoelectronics and Beyond22Chiral Molecules Induce Enantiomorphic Lattice Helicity in Chiral 0D Tin Bromide Crystals17Chiral Molecules Induce Enantiomorphic Lattice Helicity in Chiral 0D Tin Bromide Crystals6Chiral Molecules in Action: Chemistry of Chiral Perovskite and Perovskite-Inspired Materials26Chiral two-dimensional conjugated metal-organic frameworks with high spin polarization11Principles and advances in spin light-emitting diodes9Chiral-induced spin selectivity effect in chiral nanomaterials: principle, characterization and prospects9Chiral induced spin selectivity effect: A review of materials, mechanisms, and application exploration4Harnessing chirality in nanomaterials: advancing photocatalysis for hydrogen production and beyond4Internally and externally induced chiral hybrid metal halide materials for advanced chiroptoelectronic applications23Topology-Controlled Chirality and Spin Selectivity in Two-Dimensional Covalent Organic Frameworks20Ultrafine Sub-1 nm One-Dimensional Coordination Polymer Nanowires for Boosting Photocatalytic Functionalization of Inert C( sp 3 )–H Bonds5Strain-relaxed chiral hybrid bismuth halides for spin selectivity and magnetoresistance0Chiral Metal Halide Perovskites for Spin‐Polarized Light‐Emitting Diodes9Zero-Dimensional Chiral Copper Halides with Strong Circular Dichroism and Low-Temperature Ferromagnetism0Exploring Hybrid Metal Halide Materials beyond Halide Perovskites7Organic Cation Conformation‐Modulated Dimensionality in Chiral Metal Halides for Enhancing Linear and Nonlinear Chiroptical Properties0Investigation of Magnetic and Structural Transitions in Hybrid Molybdenum(III) 2D Halide Double Perovskites0Impact of Crystal Orientations on the Circular and Linear Dichroism Signals in Chiral Perovskite0Low-Dimensional Chiral Perovskites for Polarization-Sensitive Photodetection0

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  4. Leveraging Hierarchical Chirality in Perovskite(‐Inspired) Halides for Transformative Device Applications

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  15. Unique Chiro-optical Properties of the Weakly-2D (R-/S-MBA)2CuBr4 Hybrid Material

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  17. Unraveling chirality transfer mechanism by structural isomer-derived hydrogen bonding interaction in 2D chiral perovskite

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