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RESEARCH PAPER · Chemistry of Materials · 2021

Structural Confinement toward Controlling Energy Transfer Path for Enhancing Near-Infrared Luminescence

Fangyi Zhao, Hao Yuan Cai, Zhen Song, Quanlin Liu

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Structural Confinement toward Controlling Energy Transfer Path for Enhancing Near-Infrared LuminescenceOriginalOctahedron-dependent near-infrared luminescence in Cr3+-activated phosphors99Consequence of optimal bonding on cation ordering and enhanced near-infrared luminescence in Cr 3+ -doped pyroxene oxides49High photoluminescence quantum yield near-infrared emission from a lead-free ytterbium-doped double perovskite39Ultra-Broadband Near-Infrared Gd3mgscga2sio12: Cr, Yb Phosphors: Photoluminescence Properties and Led Applications73Broadband NIR Garnet Phosphors with Improved Thermal Stability via Energy Transfer49Chromium(III)-Doped Phosphors of High-Efficiency Two-Site Occupation Broadband Infrared Emission for Vessel Visualization Applications32Superb thermal stability purple-blue phosphor through synergistic effect of emission compensation and nonradiative transition restriction of Eu2+31Rapid Nondestructive Detection Enabled by an Ultra‐Broadband NIR pc‐LED137Broadband Near-Infrared-Emitting Phosphors with Suppressed Concentration Quenching in a Two-Dimensional Structure47Blue LED-pumped intense short-wave infrared luminescence based on Cr3+-Yb3+-co-doped phosphors294Activators lattice migration strategy customized for tunable luminescence of Ce3+ doped β-Ca3(PO4)226Efficient, Stable, and Ultra‐Broadband Near‐Infrared Garnet Phosphors for Miniaturized Optical Applications89Modulation of Thermally Stable Photoluminescence in Cr 3+ -Based Near-Infrared Phosphors201Blue LED‐Pumped Broadband Short‐Wave Infrared Emitter Based on LiMgPO4:Cr3+,Ni2+ Phosphor97Enhancement of Near‐Infrared Phosphor Luminescence Properties via Construction of Stable and Compact Energy Transfer Paths54Ultra‐Wide Vis–NIR Mg2Al4Si5O18:Eu2+,Cr3+ Phosphor Containing Unusual NIR Luminescence Induced by Cr3+ Occupying Tetrahedral Coordination for Hyperspectral Imaging66Molten Salt Synthesis of Broad-Band Near-Infrared InBO 3 :Cr 3+ Submicron Phosphor and Its Luminescent Enhancement by Lanthanide Ion Codoping23Sr-substitution-guided Eu2+ site engineering of Ca9Nd(PO4)7:Eu2+ for high-efficiency white light-emitting diodes9Advances in Chromium‐Activated Phosphors for Near‐Infrared Light Sources489Enhancement of the NIR Emission of Cr3+–Yb3+ Co-doped La3GaGe5O16 Phosphors by Doping Nd3+ Ions via Efficient Energy Transfer for NIR Spectroscopy Regulation20Enhanced Thermal Stability and Energy Transfer by Crystal‐Field Engineering in a Garnet Phosphor for Thermometry and NIR‐LED48Mechanochemical Fabrication of a Mn4+-Activated Inorganic Rb2KTiOF5 Perovskite Red Phosphor for White Light-Emitting Diodes3Site-Selective Occupancy Control of Cr Ions toward Ultrabroad-Band Infrared Luminescence with a Spectral Width up to 419 nm79Site-selective occupation of Cr3+ ions toward ultra-broadband near-infrared emission stannate phosphors23Blue-light-excitable pure and efficient short-wave infrared luminescence via Cr 3+ → Yb 3+ energy transfer in a KYbP 2 O 7 :Cr 3+ phosphor24Cationic composition engineering in double perovskite XLaLiTeO 6 :Eu 3+ (X = Ba, Sr, Ca, and Mg) toward efficient and thermally stable red luminescence for domestic white-LEDs35Modulation of Bi 3+ luminescence from broadband green to broadband deep red in Lu 2 WO 6 by Gd 3+ doping and its applications in high color rendering index white LED and near-infrared LED18Near-infrared Sr 7 NaGa(PO 4 ) 6 :Cr 3+ ,Ln 3+ (Ln = Nd, Er, and Yb) phosphors with different energy transfer paths: photoluminescence enhancement and versatility39Spectrally tunable near-infrared photoluminescence in MP 3 O 9 :Cr 3+ (M = Al, Ga, In) phosphate phosphors13Structural confinement toward suppressing concentration and thermal quenching for improving near-infrared luminescence of Fe 3+69Enhanced and Broadened NIR Emission of CaZnGe2O6:Cr3+ by Yb3+ Codoping for NIR Applications11Near-Infrared LuCa 2 ScZrGa 2 GeO 12 :Cr 3+ Garnet Phosphor with Ultra-broadband Emission for NIR LED Applications60Broadband Short-Wave Infrared-Emitting MgGa2O4:Cr3+, Ni2+ Phosphor with Near-Unity Internal Quantum Efficiency and High Thermal Stability for Light-Emitting Diode Applications115Soft X-ray induced color-tunable long afterglow phosphors Ca9-xTb(PO4)7:xMn2+ based on Mn2+ modulation and energy transfer13Enabling Yb3+ Luminescence with Visible Light Response in Mg2GeO4 via Energy Transfer11Structural Confinement Induced Near‐Unity Quantum Yield for Single‐Band Ratiometric Thermometry36Valence conversion and site reconstruction in near-infrared-emitting chromium-activated garnet for simultaneous enhancement of quantum efficiency and thermal stability161How to Achieve Excellent Luminescence Properties of Cr Ion‐Doped Near‐Infrared Phosphors103Cr3+‐Yb3+‐Ni2+ Tri‐Doped NIR Phosphors with Spectral Output Covering NIR‐I and NIR‐II Regions24A highly Mn 2+ -doped narrowband green phosphor toward wide color-gamut display applications26Realizing a broad-scope and high-sensitivity optical thermometer based on dual-emission centers with structure confinement effect-related energy transfer7Awakening the Dumb Site to Realize Ultra‐Broadband NIR Phosphor44Nanoconfined Synthesis of Lead Sulfide Quantum Dots Embedded in Mesoporous Aluminosilicate Glass with Adjustable Near-Infrared Broadband Luminescence9Blueshift and Photoluminescence Enhancement in Broadband Near‐Infrared Emitting Phosphor NaSr2(Al/Ga)Ge5O14: Cr3+ Dependence on the Sc/In Substitution40Structural and optical properties of Cr ion-doped near-infrared long persistent luminescence silicogermanate phosphors with broad emission bands21Key Role of Metal-to-Metal Charge Transfer Transition between Mo6+ and Bi3+ for Enhancement in NIR Luminescence of Gd2MoO6:Bi,Yb Nanophosphor9Thermally Stable Red-Emitting Ca18K3Sc(PO4)14:Mn2+ Phosphor and Enhanced Luminescence by Energy Transfer Between Ce3+-Eu2+-Mn2+22High‐Efficiency Short‐Wave Infrared Emitter Enabled by Cr3+–Yb3+ Co‐Doped Phosphor46Advances in Fe3+-activated luminescent materials for near-infrared light sources64Cr3+ and Yb3+ co-doped perovskite-like phosphor with improved thermal stability by efficient energy transfer14Improved broadband luminescence in Gd2GaSb1-Ta O7:Cr3+,Yb3+ pyrochlore phosphors: Near-infrared spectroscopic applications and dual-mode optical thermometry11Blue‐Light‐Excitable Broadband Ca 3 Ga 2 Ge 3 O 12 :Cr 3+ ,Ni 2+ Phosphor for the Applications in NIR‐II Window82NIR‐II Luminescence With A Recorded 76% EQE Through Energy Extraction From Dark Cr3+40Improving the thermal stability and luminescence of Sr3Ga1.98In0.02Ge4O14:0.03Cr3+ through the efficient energy transfer0Comparative investigation on carbon dots and chloride fluxes modified ZnAl2O4:Cr3+ nanophosphors for temperature sensing, cutting-edge forensic, anti-counterfeiting and w-LEDs applications21Highly Efficient and Thermally Stable Ultra-Broadband NIR-II Emtting Li(Ga, Al) 5 O 8 :Cr 3+ , Ni 2+ Phosphors for Spectroscopy Analysis16Efficient and broadband Na4Al3Ta(PO4)6:Cr3+ phosphors for NIR pc-LED application4Diving into the invisible region—a review of crystallographic-site-dependent ultraviolet and near-infrared luminescence of the garnet structure5On-demand photoswitching and energy transfer by post-synthetically confining Eu 3+ -complex and dithienylethene ligand in Zr-MOF-8084Innovations in phosphate phosphors: Bridging structure-property gaps for enhanced luminescence27Enhanced Short-Wave Infrared Luminescence in Yb 3+ -Doped Cr(PO 3 ) 3 Phosphor with over 60% External Quantum Efficiency9Investigation into the great enhancement of luminescence intensity through K/Na substitution in Nepheline structure for WLED1Ultra-broadband NIR-I/II-emitting Ca4HfGe3O12:Cr³ ⁺, Yb³ ⁺ garnet phosphors for organic material analysis4High Quantum Efficiency and Zero‐Thermal‐Quenching Blue‐Light‐Excited Near‐Infrared‐Emitting Y 3 Ga 5 O 12 :Cr 3+ /Ni 2+ Phosphors30Recent Advances and Emerging Applications of Lanthanide/Transition‐Metal‐Ion‐Doped Short‐Wave Infrared Luminescent Materials10Designing a Double-Perovskite Ca 2 MgTeO 6 :Fe 3+ Near-Infrared Phosphor for Multifunctional Applications11Tunable Near‐Infrared Emission from Silicon Nanocrystals in Amorphous Silicon Dioxide: Structural Evolution and Multifunctional Applications0Chromium-activated phosphors: from theory to applications23Efficient green luminescence from manganese doped zero-dimensional cesium zinc bromide perovskites for advanced optoelectronics3Emergence of Unusual Cr 3+ Emission and Exceptional Thermal Stability in Ca 3 Ga 2 Ge 3 O 12 : Cr 3+ /Yb 3+ Garnet Phosphors for High-Performance Optical Thermometry and NIR pc-LEDs4Enhanced emission in silicon-based erbium doped gallium oxide devices with multi-sensitizers1Recent advances on zinc- and/or sulfur-containing mechanoluminescent materials and their spectroscopic properties toward diverse applications1Efficient Broadband Short‐Wave Infrared Luminescence at 1400 nm Enabled by Cr 3+ ‐Yb 3+ Energy Shuttle Design1Energy extraction from dark Fe3+ in A2Sc2B4O11:Fe3+, Yb3+ (A = Sr, Ba) toward promoted NIR luminescence and pc-LED light source for multifunctional applications8Dual-modulated luminescence in Sr9Ga(PO4)7:Tb/Eu phosphors for excitation-selective multilevel information encryption0In3+- driven crystal field engineering in Ca3Y2Ge3O12:Cr3+,Yb3+ for broadband near-infrared pc-LEDs0A highly efficient NIR phosphor with near-zero thermal quenching for high-performance pc-LEDs0

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