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RESEARCH PAPER · Advanced Optical Materials · 2021

Nonlinear Optical Thermometry—A Novel Temperature Sensing Strategy via Second Harmonic Generation (SHG) and Upconversion Luminescence in BaTiO 3 :Ho 3+ ,Yb 3+ Perovskite

Teng Zheng, Marcin Runowski, Inocencio Rafael Martin, Stefan Lis, Mauricio Vega, Jaime Llanos

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Nonlinear Optical Thermometry—A Novel Temperature Sensing Strategy via Second Harmonic Generation (SHG) and Upconversion Luminescence in BaTiO 3 :Ho 3+ ,Yb 3+ PerovskiteOriginalDual-center thermochromic Bi2MoO6:Yb3+, Er3+, Tm3+ phosphors for ultrasensitive luminescence thermometry93Green, red, and near-infrared up-conversion emission of NaY(MoO4)2:Er3+ submicrometric particles obtained by one-step synthesis, and its thermometric application15Afterglow-intensity-ratio-based temperature sensing using a persistent phosphor23Controlling upconversion in emerging multilayer core–shell nanostructures: from fundamentals to frontier applications298Cs2Bi2Sr(P2O7)(PO4)2:Er3+/Yb3+ phosphors for outstanding thermal enhancement of up-conversion under 980 and 1550 nm laser excitations in the 303 to 723 K range8Lanthanide and transition metals doped materials for non-contact optical thermometry with promising approaches95Optical and thermometric properties of K0.3Bi0.7F2.4:Eu3+@g-C3N4 composites for optical thermometers12Solution‐Based Synthesis Routes for the Preparation of Noncentrosymmetric 0‐D Oxide Nanocrystals with Perovskite and Nonperovskite Structures29Manipulating Upconversion Emission and Thermochromic Properties of Ho3+/Yb3+-Codoped Al2Mo3O12 Microparticles by Negative Lattice Expansion for Multimode Visual Optical Thermometry79Supersensitive Ratiometric Thermometry and Manometry Based on Dual‐Emitting Centers in Eu 2+ /Sm 2+ ‐Doped Strontium Tetraborate Phosphors92Intense red up-conversion luminescence and temperature sensing property of Yb3+/Er3+ co-doped BaGd2O4 phosphors24Syntheses, structures, and optical properties of n = 3 layered Dion–Jacobson perovskites, RbEu2-Bi Ti2NbO10 (0 ≤ x ≤ 2)1Europium(III)-Doped Gadolinium(III) Complex for High-Sensitivity Temperature Sensing in the Physiological Range2Metastable γ-Li2TiTeO6: Negative Chemical Pressure Interception and Polymorph Tuning of SHG7New Room-Temperature Molecular Ferroelectric (C 6 H 16 N 2 O)CdBr 4 ·H 2 O with Preferable Luminescent Properties6New Strategies to Improve Thermal Sensitivity and Temperature Resolution in Lanthanide-Doped Luminescent Thermometers4Regulating the crystal and electronic structures and optical properties of hybrid bromoplumbates with alkylated N, S- or P-containing aromatic cations2Noncentrosymmetric Lanthanide-Based MOF Materials Exhibiting Strong SHG Activity and NIR Luminescence of Er3+: Application in Nonlinear Optical Thermometry93A six-mode optical thermometry rooted from the distinct thermal behavior of SrLaLiTeO6: Mn4+, Eu3+ double perovskites and their potential application in wavelength detection22Raman and photoluminescence intensity ratio: A tool for high temperature optical thermometry in Ba2Y2/3TeO6: Eu3+ double perovskites10Enhanced non-contact optical temperature sensing performance based on upconversion luminescence in Ho 3+ /Yb 3+ codoped ferroelectric 0.94Na 0.5 Bi 0.5 TiO 3 -0.06BaTiO 36Infrared to visible upconversion luminescence in Ho3+ doped oxyfluoride glass ceramics8Ultra-high melting point Ho3+, Yb3+ co-doped HfO2 single-crystal fibers for high-precision and robust ratiometric thermometry towards harsh environments9Energy-looping and photon-avalanche-like phenomena in Nd Y1.00-Al3(BO3)4 powders excited at 1064 nm1Multimodal Optically Nonlinear Nanoparticles Exhibiting Simultaneous Higher Harmonics Generation and Upconversion Luminescence for Anticounterfeiting and 8‐bit Optical Coding59Towards accurate real-time luminescence thermometry: An automated machine learning approach34Crystal Structure and Thermophosphorochromic Property of One-Dimensional Hybrid Haloplumbates with Alkylated Benzothiazole Counter Cations6Temperature and Pressure Sensing Using an Optical Platform Based on Upconversion Luminescence in NaSrY(MoO4)3 Codoped with Er3+ and Yb3+ Nanophosphors46Recyclable and flexible Bi(Ho3+-Yb3+)OBr/g-C3N4 composite porous fiber for efficient water purification and real-time temperature sensing0Directional and lattice engineering growth of sapphire fibers for ultrasonic ultra-high-temperature sensors7Outstanding nonlinear optical properties of all-inorganic perovskite CsPbX3 (X=Cl, Br, I) precursor solutions and polycrystalline films19Polarization-resolved second-harmonic generation: a Jones matrix approach3Ultrasensitive Colorimetric Luminescence Thermometry by Progressive Phase Transition78Excitation wavelength and pumping power dependent temperature sensing property of Nd3+/Yb3+/Er3+ triply-doped LaNbO4 phosphor11Pressure-induced investigation of structural, electronic, optical, and mechanical properties of BaCeO343Two-Dimensional Hybrid Perovskite with High-Sensitivity Optical Thermometry Sensors7Sensitive Luminescence Thermometry through Excitation Intensity Ratio in Eu-Doped BaTiO 323YAG:Tb@YAG:Pr Single Crystalline Dual‐Layer Phosphor. An Alternative Approach to Multimodal Wide Range Luminescence Thermometry14Broadband nonlinear conversion and random quasi-phase-matching in transparent glass composite3Monitoring of the heating rate of a motorized gear system using UV-curable resin containing Y2WO6:Yb3+-Er3+ up-converting nanoparticles as optical temperature sensor9High-sensitivity ratiometric thermometers of Yb3+/Er3+/Tm3+ co-doped LuScO3 single crystal fibers based on non-thermally coupled energy levels15Enhanced optical temperature sensing performance based on dual emission centers of Y2O3: Yb3+, Tm3+, Ho3+ upconversion phosphor26Persistent Photoluminescence and Mechanoluminescence of a Highly Sensitive Pressure and Temperature Gauge in Combination with a 3D‐Printable Optical Coding Platform51Ratiometric luminescent thermometry with excellent sensitivity in the visible and near-infrared (NIR-II/III) based on thermally coupled and non-thermally coupled energy levels of Er3+ and Ho3+ ions33Equatorial–Axial Conformational Dynamics Enabling Thermoresponsive SHG Switch in a Homochiral Hybrid Compound7Megamerger of porphyrin (phthalocyanine) with azulene-based graphene nanosheets for high-performance nonlinear optical materials5First-principles calculations to investigate the impact of hydrostatic pressure on the physical properties of LiXCl3 (X = Be, Mg) chloroperovskites: An insight for optoelectronics application3Thermal‐Energy‐Boosted Luminescence for Precise Optical Thermometry in Eu/Tb‐Doped ScNbO416Development of an Optical Current Sensor Using Luminescent Materials for Remote Sensing1NIR grating harmonic excitation of Dy-doped CaWO4 phosphors for a new ratiometric thermometry strategy0Bi2Mo2O9: Yb3+/Tm3+/Ho3+ phosphors for high-sensitivity optical thermometry and white-light upconversion0A novel negative thermal expansion Sc2W3O12: Yb, Ho phosphor showing remarkable emission color shifting from green to red with increasing temperature for favorable visual optical thermometry9Microstructured Y3Al5O12 single-crystal fibers for high-sensitivity quasi-distributed ultrasonic thermometry based on acoustic anisotropy engineering1Resonant Second-Harmonic Generation in a Hybrid Manganese Bromide: [3-Quinuclidinone]2MnBr43Pressure‐Driven Phase Transition Unlocking Unique Eu 2+ Luminescence in Li 2 SrSiO 4 for Optical Sensing and White‐LEDs0Lattice structure and pure green upconversion luminescence of CaTa4O11:Er3+/Yb3+ single crystal0Nanothermometer Performance Prediction via Fluorescence Dynamics Model0Simultaneous Second Harmonic Generation (SHG) and Upconversion Luminescence Enabling Fully Non‐Linear Optical Thermometry in Ferroelectric Ceramics1Significant second-harmonic generation enhancement in ZrCl4-BDC MOFs-CDs nanocomposite via synergistic interfacial engineering0Ratiometric Luminescent Thermo‐Hygrometry, Metal‐Dependent Second Harmonic Generation, and Humidity‐Variable Magnetic Relaxation in a Manganese(II)‐Doped Zinc(II) Molecular Halide0Ratiometric Luminescent Thermo‐Hygrometry, Metal‐Dependent Second Harmonic Generation, and Humidity‐Variable Magnetic Relaxation in a Manganese(II)‐Doped Zinc(II) Molecular Halide0Acoustic-anisotropy-engineered sapphire fibers for high-sensitivity quasi-distributed ultrasonic thermometry beyond 1800 °C0

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  1. Dual-center thermochromic Bi2MoO6:Yb3+, Er3+, Tm3+ phosphors for ultrasensitive luminescence thermometry

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  2. Green, red, and near-infrared up-conversion emission of NaY(MoO4)2:Er3+ submicrometric particles obtained by one-step synthesis, and its thermometric application

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  3. Afterglow-intensity-ratio-based temperature sensing using a persistent phosphor

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  4. Controlling upconversion in emerging multilayer core–shell nanostructures: from fundamentals to frontier applications

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  5. Cs2Bi2Sr(P2O7)(PO4)2:Er3+/Yb3+ phosphors for outstanding thermal enhancement of up-conversion under 980 and 1550 nm laser excitations in the 303 to 723 K range

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  6. Lanthanide and transition metals doped materials for non-contact optical thermometry with promising approaches

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  7. Optical and thermometric properties of K0.3Bi0.7F2.4:Eu3+@g-C3N4 composites for optical thermometers

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  8. Solution‐Based Synthesis Routes for the Preparation of Noncentrosymmetric 0‐D Oxide Nanocrystals with Perovskite and Nonperovskite Structures

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  9. Manipulating Upconversion Emission and Thermochromic Properties of Ho3+/Yb3+-Codoped Al2Mo3O12 Microparticles by Negative Lattice Expansion for Multimode Visual Optical Thermometry

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  11. Intense red up-conversion luminescence and temperature sensing property of Yb3+/Er3+ co-doped BaGd2O4 phosphors

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  13. Europium(III)-Doped Gadolinium(III) Complex for High-Sensitivity Temperature Sensing in the Physiological Range

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  14. Metastable γ-Li2TiTeO6: Negative Chemical Pressure Interception and Polymorph Tuning of SHG

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  15. New Room-Temperature Molecular Ferroelectric (C 6 H 16 N 2 O)CdBr 4 ·H 2 O with Preferable Luminescent Properties

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  16. New Strategies to Improve Thermal Sensitivity and Temperature Resolution in Lanthanide-Doped Luminescent Thermometers

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  18. Noncentrosymmetric Lanthanide-Based MOF Materials Exhibiting Strong SHG Activity and NIR Luminescence of Er3+: Application in Nonlinear Optical Thermometry

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  19. A six-mode optical thermometry rooted from the distinct thermal behavior of SrLaLiTeO6: Mn4+, Eu3+ double perovskites and their potential application in wavelength detection

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  20. Raman and photoluminescence intensity ratio: A tool for high temperature optical thermometry in Ba2Y2/3TeO6: Eu3+ double perovskites

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  28. Temperature and Pressure Sensing Using an Optical Platform Based on Upconversion Luminescence in NaSrY(MoO4)3 Codoped with Er3+ and Yb3+ Nanophosphors

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  29. Recyclable and flexible Bi(Ho3+-Yb3+)OBr/g-C3N4 composite porous fiber for efficient water purification and real-time temperature sensing

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  40. Monitoring of the heating rate of a motorized gear system using UV-curable resin containing Y2WO6:Yb3+-Er3+ up-converting nanoparticles as optical temperature sensor

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  44. Ratiometric luminescent thermometry with excellent sensitivity in the visible and near-infrared (NIR-II/III) based on thermally coupled and non-thermally coupled energy levels of Er3+ and Ho3+ ions

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  49. Development of an Optical Current Sensor Using Luminescent Materials for Remote Sensing

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  50. NIR grating harmonic excitation of Dy-doped CaWO4 phosphors for a new ratiometric thermometry strategy

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