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RESEARCH PAPER · ACS Applied Materials & Interfaces · 2023

Noncentrosymmetric Lanthanide-Based MOF Materials Exhibiting Strong SHG Activity and NIR Luminescence of Er3+: Application in Nonlinear Optical Thermometry

Marcin Runowski, Dawid Marcinkowski, Kevin Soler‐Carracedo, Adam Gorczyński, Ernest Ewert, Przemysław Woźny, Inocencio Rafael Martin

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Noncentrosymmetric Lanthanide-Based MOF Materials Exhibiting Strong SHG Activity and NIR Luminescence of Er3+: Application in Nonlinear Optical ThermometryOriginalRecent progress in high-performance environmental impacts of the removal of radionuclides from wastewater based on metal–organic frameworks: a review75Upconversion luminescence thermal enhancement from visible to near infrared and improving temperature sensitivity under high temperature using a second-harmonic generation response3Modulation of defects in metal organic gels to enhance anhydrous proton conduction from subzero to moderate temperature9A novel near-infrared thermometry based on thermal quenching and negative thermal quenching materials with high sensitivity and accuracy12Enhanced photocatalytic degradation performance of new and stable 2D/3D Ln-MOFs for tetracycline under visible light19Nonlinear Metal–Organic Framework Crystals for Efficient Multicolor Coherent Optical Emission39A two-fold interpenetrated mixed-ligands acentric 3D coordination polymer Zn(OBA)(DIB)·0.5H2O: Topological analysis, fluorescent and second-order NLO properties7Multimodal Optically Nonlinear Nanoparticles Exhibiting Simultaneous Higher Harmonics Generation and Upconversion Luminescence for Anticounterfeiting and 8‐bit Optical Coding59Nonlinear optical response of silver trimer adsorbed para-aminobenzoic acid: A DFT study11Multi-dimensional tailoring of the thermometric behaviors of Er3+/Yb3+-codoped Y2W3O12 polychromatic upconverting microparticles for multi-mode visual optical thermometry38Dual second harmonic generation and up-conversion photoluminescence emission in highly-optimized LiNbO 3 nanocrystals doped and co-doped with Er 3+ and Yb 3+7Enhancing antioxidant properties of CeO 2 nanoparticles with Nd 3+ doping: structural, biological, and machine learning insights18Lanthanide-based nanothermometers for bioapplications: excitation and temperature sensing in optical transparency windows47Mechanism of isosymmetric polar order–disorder phase transition in pyroelectric [CH 3 CH 2 NH 3 ] 2 NaGa(HCOO) 6 double perovskite3SHG-active luminescent thermometers based on chiral cyclometalated dicyanidoiridate( iii ) complexes4Two chiral lanthanide Pr III and Ho III complexes: NIR luminescence and nonlinear optical properties14Swallowed Embedding of Nanopetal-Rich Microflowers in Flexible Photocatalytic and Thermoresponsive Functional Composite Fibers0Luminescence improvement of Gd3Ga5O12:Cr3+,Bi3+ NIR phosphor with superior thermal stability for plant cultivation24Structural features of lanthanide coordination polymers with catalytic properties35On–Off Ratiometric Fluorescence Europium(III) Metal–Organic Framework for Quantitative Detection of the Inflammatory Marker Neopterin51Grayscale to Multicolor Laser Writing Inside a Label‐Free Metal‐Organic Frameworks13Temperature sensing performance of M2La8(SiO4)6O2:Ce3+(M=Ca, Sr, Ba) based on fluorescence intensity ratio of dual emission centers in different coordination environments3Recent Developments in Multifunctional Coordination Polymers8Advanced synthetic routes of metal organic frameworks and their diverse applications13Optical Phenomena in Molecule-Based Magnetic Materials154Advancements in rare earth metal-organic frameworks: Harnessing the power of photonics and beyond60Disproportionation Thermochromic Response in a Luminescent Lanthanide Metal–Organic Framework5Thermal Enhancement of Er3+ NIR‐II Luminescence by Ho3+‐Mediated Energy‐Trapping in Negative Thermal Expansion Nanocrystals49Photochromic Ln-MOFs: A Platform for Metal-Photoswitch Cooperativity12A novel single near-infrared luminescence of negative thermal quenching materials for optical temperature measurement5Selective Detection of Chromate and Permanganate Ions Using Gallic Acid Capped CaF2:Tb3+ Nanocrystals2Applications of luminescent metal-organic frameworks as pioneering biosensors for biological and chemical detection23Integration of Open Metal Sites in an Amino-Functionalized Sm(III)–Organic Framework toward Enhanced Third-Order Nonlinear Optical Property42Proton -conducting lanthanide metal–organic frameworks: a multifunctional platform11Photoluminescent metal-organic frameworks and their composites: Fundamentals, applications, and outlooks48Organic Ligand Exchange: The Chiral Structure–Property Regulation of Cuprous Halides5Deep ultraviolet transparent borophosphates LiAB 2 P 2 O 9 (A = NH 4 , K) and LiNaB 2 P 2 O 8 (OH) 2 ·H 2 O exhibiting a moderate second-harmonic generation response4Advancing Green Photonic Materials: L-Serine Doped Creatininium Benzene Sulphonate Single Crystals0Investigating the impact of Y/Lu ratio on the optical, luminescent, and thermal properties of YLuAG:Yb,Er optical ceramics2A ferroelectric proton conductor with colossal polarization induced by in-plane symmetry breaking in a two-dimensional coordination polymer9In situ growth of luminescent lanthanide coordination nanoparticles inside living plants1Infrared Thermal Sensor Using Electrosprayed Silver Nanowires and Ruthenium Complex0Metal–organic frameworks (MOFs) toward SO 2 detection55Porous Metallophilic Frameworks Incorporating Metal–Organic Chains as Humidity Sensors Exploring Uranyl Photoluminescence7Incorporation of Electron-Deficient Sites into Luminescent Complexes: Photochromism and Chlortetracycline Detection15Lanthanide-bimetallic organic frameworks: from mechanism and sensors design to ratiometric fluorescent applications85Elevating the Optical Nonlinearity: Design, Synthesis, and Properties of a Mixed-Ligand Zinc(II) Metal–Organic Framework51Ultrathin Lanthanide‐Based Metal‐Organic Nanosheets with Thickness‐ and Temperature‐Driven Light Emission5Nanoscale Rhodium(I) Based Metal–Organic Framework Demonstrating Intense NIR-II Luminescence for Bioimaging10UiO‐66(Zr) : Tb 3+ , Eu 3+ /PVDF Composite Films as Dual‐Responsive Optical Thermometers for Wide‐Range Temperature Sensing0NanoMOF‐Based Multilevel Anti‐Counterfeiting by a Combination of Visible and Invisible Photoluminescence and Conductivity9Enhanced green and NIR emissions in Yb2Mo4O15:Er3+ via excitation energy confinement for a novel NIR LED with real-time chip temperature monitoring0L-isoleucine doped Creatininium Benzene Sulphonate organic single crystals: Insight into charge carrier dynamics and sensor applications1Cavity Controlled Nonlinear Optical Filtering of Second Harmonic Signal in Metal Organic Framework Single Crystals4Multifunctional chiral dinuclear DyIII enantiomeric pairs: showing single-molecule magnet behaviors with very strong third-harmonic generation responses5Two Chiral EuIII Enantiomeric Pairs with Significantly Enhanced Photophysical and Third-Harmonic Generation Performances through the Coordination Roles of Enantiopure Bi- and Tridentate N-Donors9Unravelling the impact of octahedral distortion and non-covalent interactions on the hyperpolarizabilities of Co(II) and Ni(II) coordination complexes with uridine nucleotide11Homochiral Coordination Polymers Exhibiting Second-Harmonic Generation and Photo-Induced Structural Transformation10Near‐Infrared Emitting Lanthanide Catecholate Giant Single Crystals – Morphology Control and Photon Down‐Conversion2An Amide-Functionalized Pillar-Layered Metal–Organic Framework Based on Mixed Linker Systems with Enhanced Third-Order Nonlinear Optical Performance22Nd3+ /Yb3+ co-doped Ca2Ga2SiO7 near-infrared phosphors via energy transfer for multifunctional applications3Near-infrared-emissive metal-organic frameworks as novel scaffolds for bioimaging and sensing applications6Smart Luminescent Materials Based on Rare-Earth Complexes: From Precise Syntheses to Regulable Functions9Luminescent lanthanide hybrid materials: from molecular design to anti-counterfeiting application24A high-performance temperature-sensing luminescent material of Ni 2+ -doped double perovskite structure Li 2 TiTeO 6 phosphor0Breaking the SHG-stability trade-off in UV nonlinear optical materials by polar-layer-dense-locking4Chiral Eu–K Metal–organic Framework Based on Lactate Derivative and Its Second-Order Nonlinear Optical Properties0Construction of ratiometric optical thermometers by linking chiral cyclometalated dicyanidoiridates( iii ) with europium( iii ) luminophores into cluster compounds6Lanthanide upconverting luminescence in molecular complexes and metal–organic frameworks9Lanthanide-based MOFs derived from 1,3-bis(diphenylphosphoryl)-2-oxapropane0Luminescence Thermometry of a Nd III and Nd III /Yb III Imidazole Derived‐Based MOFs: Thermally Enhanced Ytterbium Emission0Metal–organic frameworks (MOFs) for nonlinear optical properties: design principles, DFT insights, and future directions for photonic applications1Multilevel Helical Cd-based Coordination Polymers with Significant Second NLO Response Constructed from Lactic Acid Derivatives0Simultaneously switching both the magnetic behaviors and nonlinear optical processes in mononuclear DyIII complexes0Sub-attomolar-level biosensing of cancer biomarkers using SHG modulation in DNA-programmable quantum dots/MoS 2 disordered metasurfaces0Waste‐to‐MOF: Upcycling of Waste Polyimide Into Europium‐Based Metal‐Organic Framework as Efficient Fluorescence Sensor of Biogenic Amines4A uranyl carboxyphosphonate framework exhibiting luminescence intensity, luminescence lifetime and SHG triple-response2Simultaneously switching both the magnetic behavior and nonlinear optical process in mononuclear DyIII complexes via the coordination role of enantiopure N3-pincers2Photoluminescence Enhancement in Erbium Nanoparticles via Controlled Phase Transformation2Host-guest structure and tunable multicolor emission in Zn-MOFs via dye encapsulation6An Exceptionally Stable Porous Indium-Organic Framework with Enhanced Third-Order Nonlinear Optical Performance3Enantiomeric Cd-based coordination polymers with multilevel helical structures and significant second NLO response constructed from lactic acid derivatives2Enhancing Optical Limiting Performance of Vegetable Oils with MoSe2 Nanosheets for Sustainable Photonic Applications1Click Chemistry Functionalization of Harmonic Nanoparticles with Lanthanide Complexes Towards Tunable Platforms for Multimodal Imaging0Chirality transfer in helical supramolecular frameworks: Structures and SHG response modulation of Zinc(II) coordination polymers based on lactic derivatives1Covalently integrated thermochromic lanthanide MOF/polymer membranes for chemically robust dual-emission ratiometric luminescent thermometry0Metal–organic framework-based second-order nonlinear optical materials: From structural design to functional applications0Simultaneous Second Harmonic Generation (SHG) and Upconversion Luminescence Enabling Fully Non‐Linear Optical Thermometry in Ferroelectric Ceramics1Chiral dinuclear EuIII enantiomeric pairs: simultaneously showing photoluminescences, circularly polarized luminescences, second- and third-harmonic generations with enhanced performances0Multistrategy Optimization of Benzothiadiazole-Based Ln-MOF Composites for Enhanced Photocatalytic Degradation of Tetracycline0Significant second-harmonic generation enhancement in ZrCl4-BDC MOFs-CDs nanocomposite via synergistic interfacial engineering0Helical Cd‐Based Frameworks Based on Lactic Acid Derivatives and Their Second‐Order Nonlinear Optical Responses0Luminescence Thermometry 2.0: Machine-Learning Temperature Read-Out with Luminescence of YOF: Yb3+, Er3+ Nanoparticles0

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