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RESEARCH PAPER · Journal of Materials Chemistry C · 2021

Tuning luminescence from NIR-I to NIR-II in Cr 3+ -doped olivine phosphors for nondestructive analysis

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Tuning luminescence from NIR-I to NIR-II in Cr 3+ -doped olivine phosphors for nondestructive analysisOriginalAb initio two-sites occupancy and broadband near-infrared emission of Cr 3+ in Li 2 MgZrO 482Broadband near-infrared BaMSi 3 O 9 :Cr 3+ (M = Zr, Sn, Hf) phosphors for light-emitting diode applications38Broadband Short-Wave Infrared Light-Emitting Diodes Based on Cr 3+ -Doped LiScGeO 4 Phosphor147Cr 3+ Activated Garnet Phosphor with Efficient Blue to Far‐Red Conversion for pc‐LED175Efficient broadband near-infrared luminescence of Cr3+ doped fluoride K2NaInF6 and its NIR-LED application toward veins imaging175Controlling Cr3+/Cr4+ concentration in single-phase host toward tailored super-broad near-infrared luminescence for multifunctional applications99Efficient broadband near-infrared phosphor Sr2ScSbO6:Cr3+ for solar-like lighting146Achieving an ultra-broadband infrared emission through efficient energy transfer in LiInP2O7: Cr3+, Yb3+ phosphor80Structural Confinement toward Controlling Energy Transfer Path for Enhancing Near-Infrared Luminescence77Two Selective Sites Control of Cr3+‐Doped ABO4 Phosphors for Tuning Ultra‐Broadband Near‐Infrared Photoluminescence and Multi‐Applications124Octahedron-dependent near-infrared luminescence in Cr3+-activated phosphors99Efficient Ultra‐Broadband Ga 4 GeO 8 :Cr 3+ Phosphors with Tunable Peak Wavelengths from 835 to 980 nm for NIR pc‐LED Application134Regulating chromium ions site occupancy and enhancing near-infrared luminescence properties of Sr2P2O7:Cr3+ phosphor through synthesizing under reduction atmosphere28Consequence of optimal bonding on cation ordering and enhanced near-infrared luminescence in Cr 3+ -doped pyroxene oxides49Cr 3+ -Doped double perovskite antimonates: efficient and tunable phosphors from NIR-I to NIR-II78Cr 3+ -Doped InTaO 4 phosphor for multi-mode temperature sensing with high sensitivity in a physiological temperature range78Crystal-field induced tuning of luminescence properties of Na 3 Ga x Al 1− x F 6 :Cr 3+ phosphors with good thermal stability for NIR LEDs20Efficient and thermally stable broadband near-infrared emission in a garnet Gd 3 In 2 Ga 3 O 12 :Cr 3+ phosphor44Luminescence properties and energy transfer of the near-infrared phosphor Ca 3 In 2 Ge 3 O 12 :Cr 3+ ,Nd 3+16Multimodal dynamic color-tunable persistent luminescent phosphor Ca 3 Al 2 Ge 3 O 12 :Mn 2+ ,Cr 3+ for anti-counterfeiting and industrial inspection25The optical research progress of nanophosphors composed of transition elements in the fourth period of near-infrared windows I and II for deep-tissue theranostics47Structural Rigidity Control toward Cr3+-Based Broadband Near-Infrared Luminescence with Enhanced Thermal Stability243Novel Cr3+-activated far-red emitting phosphors with β-Ca3(PO4)2-type structure for indoor plant cultivation37Site-Selective Occupancy of Mn 2+ Enabling Adjustable Red/Near-Infrared Multimode Luminescence in Olivine for Dynamic Anticounterfeiting and Encryption70Efficient and Thermally Stable Broad-Band Near-Infrared Emission in a KAlP 2 O 7 :Cr 3+ Phosphor for Nondestructive Examination191Ultra‐Efficient GAGG:Cr 3+ Ceramic Phosphor‐Converted Laser Diode: A Promising High‐Power Compact Near‐Infrared Light Source Enabling Clear Imaging109Spectral engineering and thermometric performance of LiIn(Si2-Ge )O6: Cr3+ phosphor for multi-mode NIR thermometry26Broadband near-infrared emission in the NaInP2O7:Cr3+ phosphor for light-emitting-diode applications50Structural induced tunable NIR luminescence of (Y,Lu)3(Mg,Al)2(Al,Si)3O12: Cr3+ phosphors37Highly efficient Fe3+-doped A2BB′O6 (A = Sr2+, Ca2+; B, B′ = In3+, Sb5+, Sn4+) broadband near-infrared-emitting phosphors for spectroscopic analysis251Modulation of Thermally Stable Photoluminescence in Cr 3+ -Based Near-Infrared Phosphors201Broadband NIR-II phosphors with Cr4+ single activated centers based on special crystal structure for nondestructive analysis64Molten Salt Synthesis of Broad-Band Near-Infrared InBO 3 :Cr 3+ Submicron Phosphor and Its Luminescent Enhancement by Lanthanide Ion Codoping23Energy Level Diagram of 3d2 Configuration in Tetrahedral Crystal Field and Its Applications to Cr4 + /Mn5 + ‐Doped Luminescent Materials43Advances in Chromium‐Activated Phosphors for Near‐Infrared Light Sources489Ultra-broadband near infrared phosphor with wide spectral range and long peak wavelength achieved by double-site occupation50Broadband near-infrared luminescence in the NaAlP2O7:Cr3+ phosphor for spectroscopy applications19Highly Efficient Broadband Near-Infrared Luminescence with Zero-Thermal-Quenching in Garnet Y3In2Ga3O12:Cr3+ Phosphors185A High-efficiency blue-LED-excitable NIR-II-emitting MgO:Cr3+,Ni2+ phosphor for future broadband light source toward multifunctional NIR spectroscopy applications178Ultra-broad NIR emission from two-site Cr3+ occupation in fluoride phosphor via composition-driven structural transformation41Ultra-broadband and high-efficiency phosphors to brighten NIR-II light source applications31Ultra-broadband of up to 200 nm near-infrared phosphors based on one-site occupation strategy for multipurpose applications in light-emitting diodes14Producing Tunable Broadband Near-Infrared Emission through Co-Substitution in (Ga1–xMgx)(Ga1–xGex)O3:Cr3+77Site-Selective Occupancy Control of Cr Ions toward Ultrabroad-Band Infrared Luminescence with a Spectral Width up to 419 nm79Highly efficient and thermally stable broadband NIR phosphors by rationally bridging Cr 3+ –Yb 3+ in LiScGe 2 O 6 for optical bioimaging69Double‐Site Occupation Triggered Broadband and Tunable NIR‐I and NIR‐II Luminescence in AlNbO4:Cr3+ Phosphors15An Efficient Perovskite‐Like Phosphor with Peak Emission Wavelength at 850 nm for High‐Performance NIR LEDs43Super Broadband Near‐Infrared Solid Solution Phosphors with Adjustable Peak Wavelengths from 1165 to 875 nm for NIR Spectroscopy Applications41Broadband emitting phosphor Sr 6 Sc 2 Al 4 O 15 :Cr 3+ for near-infrared LEDs31Composition–structure–luminescence and enhancement of Cr 3+ activated broadband near infrared phosphors for night vision, bio-imaging, and noninvasive detection19Synthesis and photoluminescent characterization of ceramic phosphors Li 2 MgGeO 4 :Ln 3+ (Ln 3+ = Pr 3+ or Tm 3+ ) under different excitation wavelengths12Understanding the broadband near-infrared luminescence in a highly distorted garnet Ca 4 HfGe 3 O 12 :Cr 3+ phosphor36Cr3+‐Facilitated Ultra‐Sensitive Luminescence Ratiometric Thermometry at Cryogenic Temperature51LaMgGa11O19:Cr3+,Ni2+ as Blue‐Light Excitable Near‐Infrared Luminescent Materials with Ultra‐Wide Emission and High External Quantum Efficiency111Manipulation of the ratio of Li + /Zn 2+ on the structure and persistent luminescence property of Li 2 Zn 0.9992 Ge 3 O 8 :0.08%Cr 3+5Energy transfer realizes efficient NIR emitting Ca2ScTaO6:Cr3+, Yb3+ perovskite-structured phosphors39Achieving High Quantum Efficiency Broadband NIR Mg4Ta2O9:Cr3+ Phosphor Through Lithium‐Ion Compensation189Introducing Jahn-Teller distortion to enhance the practicability of (Ga,Sc)2O3:Cr3+ near-infrared phosphor18Broadband near-infrared emitting Cr3+-activated InGaO3(ZnO)4 phosphor and its application in pc-LEDs10NIR Mechanoluminescence from Cr3+ Activated Y3Al5O12 with Intense Zero Phonon line89Broadband near infrared luminescent properties of Cr3+ activated SrGa2Si2O8 phosphor18Research progress of rare earth/transition metal ions doped NIR luminescent materials6Ultra-broad Near-Infrared Emitting Phosphor LiInF4: Cr3+with Extremely Weak Crystal Field42Cation substitution-dependent phase transforming phosphors: A new alternative broadband NIR-II emitter for solid state lighting46Effective ratiometric optical thermometry based on inverse temperature dependent dual near infrared emission of Cr3+ doped BaAl4Sb2O12 phosphor18The ultra-wideband near-infrared luminescence properties and applications of K2SrGe8O18:Cr3+ phosphor26Long-Wavelength Near-Infrared Divalent Nickel-Activated Double-Perovskite Ba2MgWO6 Phosphor as Imaging for Human Fingers90Enabling Yb3+ Luminescence with Visible Light Response in Mg2GeO4 via Energy Transfer11Achieving Ultra-Wideband NIR-II Emission in Cr3+-Doped Li(Sc,In)(Si,Ge)O4 Phosphors Based on Host Composition Engineering35Broadband near infrared emission in Cr3+: Cs2AgBiCl6 double perovskite halides16Color Tunable Composite Phosphor Ceramics Based on SrAlSiN3:Eu2+/Lu3Al5O12:Ce3+ for High-Power and High-Color-Rendering-Index White LEDs/LDs Lighting12Luminescence characteristics of ultra-broadband near-infrared emission Li3Mg2SbO6:Cr3+ phosphors and their applications in light-emitting diodes11Six‐ and five‐coordinated Cr 3+ in Ga 2 GeO 5 invokes tunable broadband near‐infrared emission toward night‐vision applications61Valence conversion and site reconstruction in near-infrared-emitting chromium-activated garnet for simultaneous enhancement of quantum efficiency and thermal stability161How to Achieve Excellent Luminescence Properties of Cr Ion‐Doped Near‐Infrared Phosphors103High Output Power and High Quantum Efficiency in Novel NIR Phosphor MgAlGa0.7B0.3O4:Cr3+ with Profound FWHM Variation143Sr2MgWO6:Ni2+-A highly efficient and tunable photoluminescence near-infrared phosphor for NIR-II light source applications34Cooperative cationic substitution strategy triggers high blue-light absorptance and near-infrared emission with high quantum efficiency in Cr3+-activated pyroxene-type assembly11Cr3+‐Yb3+‐Ni2+ Tri‐Doped NIR Phosphors with Spectral Output Covering NIR‐I and NIR‐II Regions24Achieving Broadband NIR Emission in Fe 3+ ‐Activated ALaBB′O 6 (A = Ba, Sr, Ca; B–B′ = Li–Te, Mg–Sb) Phosphors via Multi‐Site Ionic Co‐Substitutions60CaLaLiTeO6: Mn4+, Tm3+ phosphors with multiband near-infrared emission towards multifunctional applications11From Ancient Blue Pigment to Unconventional NIR Phosphor: A Thermal-Stable Near-Infrared I/II Broadband Emission from Ca1–xSrxCuSi4O10 Solid Solution9Multifunctional applications of novel near-infrared emitting Ca2ScNbO6:Cr3+ double-perovskite phosphors35Achieving the performance luminescence of LaMg0.5Sn0.5O3:Cr3+ by [In3+-Sc3+] co-substitution [Mg2+-Sn4+] and its application to the biodetection and night vision lighting4A novel near-infrared phosphor Li 1.6 Mg 1.6 Sn 2.8 O 8 :Cr 3+ for near-infrared spectral analysis25Improvement of thermal stability and luminescence in La 3 Zr x Sn 1− x Ga 5 O 14 :0.015Cr 3+ by the substitution of Zr # Sn and its application in level detection, biomedical imaging and night vision monitoring0Long wavelength near-infrared II emitting Na3YSi3O9:x Cr3+ silicate and spectral broadening by multi-site occupancy0Site-selective occupancy of Cr 3+ enabling tunable emission from near infrared I to II in fluoride LiInF 4 :Cr 3+18Phase transition and Nd3+/Pr3+ co-doping induced enhancement of NIR emission in ScP3O9: Cr3+ phosphor15Directly Identifying Multiple Cr3+ Emitting Centers for Broad Near‐Infrared Emission in an Efficient and Near‐Zero Thermal Quenching Garnet‐Type Phosphor50Achieving ultra-broadband NIR Gd2Mg3Ge3O12:Cr3+,Yb3+ garnet phosphors through energy transfer15Efficient broad-band NIR-II emitting phosphor Mg4Ta2O9: Ni2+ with satisfactory thermal stability of luminescence59Super Broadband Emission Across NIR‐I and NIR‐II Under Blue Light Excitation of Cr 3+ , Ni 2+ Co‐Doped Sr 2 GaTaO 6 Phosphor Achieved by Two‐Site Occupation and Effective Energy Transfer178Strategies to Realize Efficient and Stable Broadband NIR Emission in Germinate Oxides25Near‐infrared emitting metal halide materials: Luminescence design and applications78Plastic Identification by Using Energy Transfer Enhanced Broadband Short-Wave Infrared Phosphor Mg3Ga2GeO8:Cr3+, Ni2+4Ultrahigh Quantum Efficiency Near-Infrared-II Emission Achieved by Cr 3+ Clusters to Ni 2+ Energy Transfer51Extending Near-Infrared Emission Beyond 900 nm in Cr3+-Activated Niobate Double Perovskites10Developing the Na2CaZr2Ge3O12:Cr3+ Garnet Phosphor for Advanced NIR pc-LEDs in Night Vision and Bioimaging87Suppressing neuroinflammation using the near-infrared light emitted by (Sr,Ba)Ga12O19: Cr3+ phosphor10Highly Efficient and Thermally Stable Broadband NIR Phosphors with Superlong Afterglow Performance and their Multifunctional Applications53Cr3+ activated Na3RESi3O9 (RE = Y, Lu, Sc) silicate broadband near-infrared phosphors for luminescence towards NIR-II region via a multi-site occupancy strategy51Enhanced near-infrared II and III emission in Ga2O3: Ni2+ phosphor via charge compensation for NIR spectroscopy application28Cr3+-Yb3+ energy transfer drives ultra-wideband thermally-stable NIR-emitting Sr3Sc2Ge3O12 garnet phosphors for pc-LED application22Simultaneously strong NIR-II and NIR-III luminescence induced by Cr3+-Yb3+-Er3+ energy transfer in KScP2O7 for NIR thermometry, NIR pc-LED and night-vision applications14Broadband near-infrared luminescence in spinel Zn4InSbO8:Cr3+ phosphor for light-emitting diodes application5Advanced luminescence applications of 3d3 transition metal ions6Realizing Ultrabroadband NIR-II Emission and Wide-Range Wavelength Tuning in Cr4+-activated ABO2 (A = Li, Na; B = Al, Ga) Phosphors10Efficient and Tunable Near-Infrared Luminescence in Cubic Phosphate K 2 AlTi(PO 4 ) 3 :Cr 3+ for Spectroscopy Applications44The Near‐Infrared Light Emitted by LiScO 2 :Cr 3+ Phosphor Used to Induce Gland Secretion for Sjogren's Syndrome5High‐Performance Tunable Near‐Infrared Emitters of Cr 3+ ‐Activated Garnet Phosphor Enabled by Chemical Unit Co‐Substitution29Cr3+ and Ni2+ Co-doped near-infrared dual-emission garnet phosphor for spectroscopic applications16A novel Cr3+-doped MgGaBO4 phosphor: Expanding the horizons in plant illumination6Laser‐Driven (Ga/Sc) 2 O 3 :Cr 3+ Luminescent Ceramics Enabling Near‐Infrared Light Source for Noninvasive Imaging and Detection42Piezoelectric-induced mechanoluminescence in centrosymmetric Lu3Al5O12: Properties of self-recoverable and tunable near-infrared luminescence19Laser-pumped high-power compact near-infrared light sources based on phosphor-in-glass films4Near-infrared luminescence in Ca3ZnMGe3O12:Cr3+ (M = Zr, Hf, Sn, Ti) garnet family for light-emitting diode applications4Tunable Broadband NIR-II Emission via Cr 4+ -Er 3+ Energy Transfer in CaMgGeO 4 :Cr 4+ ,Er 3+ Phosphors for Nondestructive Analysis16Blue light excitable efficient down-conversion photoluminescence of Yb3+ and Er3+ in ultra-wide NIR region via Cr3+-Yb3+-Er3+ energy transfer in KAlP2O7 and multifunctional applications11Efficient Near‐Infrared Luminescence in Cr 3+ Activated β ‐Alumina Structure Phosphor via Multiple‐Sites Occupancy17Unique Spectral Broadening Induced by Exchange Coupling Between Cr 3+ Ions in LiAl 5 O 8 :Cr 3+ Phosphors for Versatile Optical Applications44Near-infrared emitting Ca2AlNbO6:Cr3+ double-perovskite phosphors for plant growth LEDs13Enhancement of luminescence properties of broadband NIR Cr3+-activated phosphate phosphors through cationic substitution11A novel high-efficiency near-infrared phosphor Mg 0.9 Ta 2 Zn 2.1 O 8 :Cr 3+ ,Yb 3+ for spectroscopy applications8Broadband photoluminescence toward the NIR II region and stable green ceramic pigments based on a novel NaBaScSi 2 O 7 : x Cr silicate phosphor10Ca 2 YScAl 2 Si 2 O 12 :Cr 3+ phosphor-in-glass film for laser-driven high-power near-infrared lighting7Co-doped aluminum metaphosphate-based phosphor for thermally robust and efficient broadband near-infrared-II light-emitting diodes0Highly efficient Cr 3+ -doped K 3 Ga 2 (PO 4 ) 3 NIR-I phosphors with exceptional thermal quenching resistance for night vision monitoring and biomedical imaging applications1Improving the luminescence performance of the near-infrared phosphor La 3 SnGa 5 O 14 :Cr 3+ ,Yb 3+ via energy transfer and its application in fingerprint detection and night vision6Photoluminescence properties of Ni2+-doped double perovskite A2MgTiO6 (A = La/Lu) phosphor with NIR-II emission for spectral analysis application2A novel broadband near-infrared phosphor NaBaScSi2O7: Fe3+ and its application in pc-LED and night vision32Neighboring‐Cation Substitution Engineering Strategy toward High Performance in Near‐Infrared Light Source for Multifunctional Applications13Zero Phonon Line and Near-Infrared Luminescence in Cs4CdSb2–xCrxCl12 Quadruple-Layered Halide Double Perovskite1Regulating broadband near-infrared luminescence and thermal stability of Cs2AgBiCl6 double perovskite via alkali metal ions doping3Broadband near-infrared post-perovskite phosphor MgGe0.9Si0.1O3:Cr3+, A+ (A = Li, Na, and K) with peak emission beyond 820 nm for night vision applications43Achieving blue light excitation and broadband NIR-II region emission regulation of ALaMgSbO6: Ni2+ (A=Ca, Sr, Ba) phosphors7Improving quantum efficiency and thermal stability of Cr3+-doped olivine solid-solution phosphors with ultra-broadband shortwave infrared emission beyond 1100 nm8Efficient Ba2NaNb5O15:Cr3+,Yb3+ nanocrystals embedded transparent glass-ceramics toward night-vision application7Blue-light excitable near-infrared LaMgGa11O19:Cr3+,Yb3+ phosphors with broadband emission and high thermal stability9Ultra-broadband near-infrared-I and II emission from chromium doped double perovskite for multifunction application4High-thermal-stability SrLaMgSbO6: Cr3+ phosphors for night vision and nondestructive testing13Near-unity quantum efficiency and remarkable anti-thermal quenching of Cr3+-activated Gd3AlGa4O12 garnet emitter for advanced broadband NIR light source5Simultaneously enhancing long-wavelength broadband NIR luminescence and thermal stabilities in Cr3+-activated phosphate phosphors via partial cation substitution4Valence and Site Engineering Enable Efficient Broadband Near‐Infrared Emission at 960 nm in Cr 3+ ‐Activated Forsterite48Blue-Light-Excited Y2MgTiO6:Ni2+, Cr3+ Phosphors with Ultrabroadband NIR Emission for Multifunctional Applications11Stable near-infrared luminescence from KMgF3:Cr3+ fluoroperovskite phosphor for light-emitting diodes2Multiband excited bright NIR emitter via Yb3+/Cr3+ co-doped double perovskites for multimodal anti-counterfeiting and imaging11Recent Advances and Emerging Applications of Lanthanide/Transition‐Metal‐Ion‐Doped Short‐Wave Infrared Luminescent Materials10Negative thermal expansion Sc2W3O12: Pr3+ phosphor for multi-functional applications of optical thermometry, anti-counterfeiting, and information encryption3Near-Infrared Luminescence in Mo 4+ -Activated Metal Halide for Advanced Optoelectronics5

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