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RESEARCH PAPER · Light Science & Applications · 2021

Thermally stable and highly efficient red-emitting Eu3+-doped Cs3GdGe3O9 phosphors for WLEDs: non-concentration quenching and negative thermal expansion

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Thermally stable and highly efficient red-emitting Eu3+-doped Cs3GdGe3O9 phosphors for WLEDs: non-concentration quenching and negative thermal expansionOriginalA study of negative-thermal-quenching (Ba/Ca)AlSi 5 O 2 N 7 :Eu 2+ phosphors6Construction of a novel mechanoluminescent phosphor Li 2 MgGeO 4 : x Mn 2+ by defect control32Enhancing the static green up-conversion luminescence of NaY(MoO 4 ) 2 :Yb/Er microcrystals via an annealing strategy for anti-counterfeiting applications34Luminescence property improvement and controllable color regulation of a novel Bi 3+ doped Ca 2 Ta 2 O 7 green phosphor through charge compensation engineering and energy transfer19Efficient red and broadband near‐infrared luminescence in Mn 2+ /Yb 3+ ‐doped phosphate phosphor21Desired warm white light emission from a highly photostable and single-component Gd2TiO5:Dy3+/Eu3+ nanophosphors for indoor illuminations20A novel upconversion luminescence temperature sensing material: Negative thermal expansion Y2Mo3O12:Yb3+, Er3+ and positive thermal expansion Y2Ti2O7:Yb3+, Er3+ mixed phosphor68Multifunctional Pr3+ single doped CaLaMgTaO6: Crystal structure, thermal behavior and applications25Luminescence investigation of a novel red-emitting Sr3NaSbO6:Eu3+ phosphor27A novel Eu3+-doped ScCaO(BO3) red phosphor for tricolor-composited high color rendering white light15White light emission and energy transfer mechanism of LaOCl:Tb3+/Sm3+ with 3D umbrella-like structure6Efficient white upconversion luminescence in Yb3+/Eu3+ doubly-doped transparent glass ceramic10Multichannel emissions from 5DJ metastable levels of Eu3+ in miscible-phase phosphors2Broadband excited Na 3 Tb(PO 4 ) 2 :Ce 3+ /Eu 2+ green/yellow‐emitting phosphors with high color purity for LED‐based application15Novel double-perovskite SrLaLiTeO6:Mn4+ far-red phosphor with superior thermal stability for indoor plant growth LED58Enhanced red emission from Mn4+ activated phosphor induced by fluoride to oxyfluoride phase transformation19Poly (vinyl alcohol-co-ethylene) (EVOH) modified polymer inclusion membrane in heavy rare earths separation with advanced hydrophilicity and separation property59Fluorescence regulation derived from Eu 3+ in miscible-order fluoride-phosphate blocky phosphor7Broadband, Enhanced, and Antithermally Quenched Near-Infrared Phosphors via a Cosubstitution Approach33Robust thermal performance and color purity of samarium based deep red emitting phosphor for near-UV chip-based high-color-rendering34Ca[B 8 O 11 (OH) 4 ] : Eu 2+ – A Highly Efficient Deep Blue‐Emitting Phosphor Prepared by Low‐Temperature Self‐reduction12Enhanced red emission in Li2Mg3TiO6: Mn4+ phosphor via Na+ and Ge4+ doping11Anti-thermal quenching of Eu3+ luminescence in negative thermal expansion Zr(WO4)238Constructing a Model for Tuning the Thermal Quenching Properties of Bismuth-Doped Phosphors by Energy-Gap Modulation34Enhancing luminescence intensity and improving thermostability of red phosphors Li3Ba2La3(WO4)8:Eu3+ by co-doping with Sm3+ ions59Enhancing the Photoluminescence Property of Pr3+ Ions by Understanding the Polymorphous Influence of the K3Lu(PO4)2 Host6Photoluminescence properties of Eu-doped WO3-Eu2(WO4)3 composites and single-phase Eu2(WO4)3 powders7Rare-earth-free Mn4+-doped double perovskite structure phosphor for near ultraviolet excitation of WLED and plant cultivation45Structure, optical properties and preferential site substitution of Eu3+ activated Ca8NaBi(PO4)6F2 red emitting phosphors prepared by modified Pechini process32Rare-earth single atom based luminescent composite nanomaterials: Tunable full-color single phosphor and applications in WLEDs51Full-visible-spectrum lighting enabled by site-selective occupation in the high efficient and thermal stable (Rb, K)2CaPO4F: Eu2+ solid-solution phosphors58Synthesis and spectroscopic analysis of Eu3+-doped tungsten bronze Sr5YTi3Nb7O30 phosphors for w-LED and visualization of latent fingerprint41Anti-thermal-quenching red-emitting phosphors based on lanthanide doped negative-thermal-expansion (NTE) hosts46Blue-LED-excitable NIR-II luminescent lanthanide-doped SrS nanoprobes for ratiometric thermal sensing25Photo Curing and Pressureless Sintering of Orange-emitting Glass-ceramics1Luminescence and energy transfer of color-tunable Tb3+/Sm3+co-doped BaZn2(PO4)2 glass-ceramic phosphors17Bifunctional samarium activated red-emitting and thermal resistant phosphor for simultaneous field emission displays and white light-emitting diodes32Achieving zero-thermal quenching luminescence in ZnGa2O4: 0.02Eu3+ red phosphor47Enhanced luminescence performances of BaLaMgTaO6:Mn4+ red phosphor by Bi3+, Ca2+ doping for indoor plant lighting supplementary LED23Multifunctional lanthanide ions‐doped Ba2TiGe2O8 phosphor for near-infrared ratiometric thermometer and information security10The Charge Transfer Band as a Key to Study the Site Selection Preference of Eu3+ in Inorganic Crystals56Composition and Antithermal Quenching of Noninteger Stoichiometric Eu2+-Doped Na-β-Alumina with Cyan Emission for Near-UV WLEDs37Emerging near-unity internal quantum efficiency and color purity from red-emitting phosphors for warm white LED with enhanced color rendition33Embedding red-emitting dyes in robust hydrogen-bonded organic framework for application in warm white light-emitting diodes11A novel red-emitting phosphor K 2 MgGeO 4 :Eu 3+ for WLEDs: zero-thermal quenching induced by heterovalent substitution27A novel red-emitting phosphor with an unusual concentration quenching effect for near-UV-based WLEDs40A single-component white-light-emitting fluorescent material with high color rendering index based on resonance energy transfer11Achieving stable photoluminescence by double thiacalix[4]arene-capping: the lanthanide-oxo cluster core matters10Design and tuning Cr 3+ -doped near-infrared phosphors for multifunctional applications via crystal field engineering26Efficient and thermally stable broadband near-infrared emission from near zero thermal expansion AlP 3 O 9 :Cr 3+ phosphors67High thermal stability phosphors with a rigid structure similar to the benzene ring and application in plant growth21Luminescence properties of Cr 3+ -doped near-infrared emissive fluoroyttrates for light-emitting diodes18Microstructural origin of peculiar spectra and excellent luminescence properties of Y 10 Ta 4 O 25 :Eu 3+ with a fluorite-related structure17Modulating A site compositions of europium( iii )-doped double-perovskite niobate phosphors32Multipath Luminescent Thermometry in Cs3gdge3o9:Yb3+,Er3+ Phosphor with Superior Signal Discriminability0Novel ultra-high-temperature zero-thermal quenching plant-protecting type blue-green dual-emission KAl 11 O 17 :Eu 2+ ,Mn 2+ phosphors for urban ecological lighting39Photoluminescence and Mixed-Valence Tuning of EU in Sr2(Al,Ga)2sio7 Phosphors for Sensitive Thermometric Applications9Revealing Eu 3+ -doped yttrium pyrogermanate as a soft UV excitable phosphor: retaining the pros of the commercial phosphor and compensating for the cons13Sensitization of Mn 2+ luminescence via efficient energy transfer to suit the application of high color rendering WLEDs21Splendid four-mode optical thermometry design based on thermochromic Cs 3 GdGe 3 O 9 :Er 3+ phosphors103Strong and pure red-emitting Eu 3+ -doped phosphor with excellent thermal stability for warm WLEDs33Strong F-F Excitation in Hafnium Germanate: Near-Uv Led and Cathode Beam Pumped Red Phosphor with Thermal Robustness4The synergism between self-activated and impurity-related emissions of LiCa 3 ZnV 3 O 12 : lattice distortion, energy transfer and temperature sensing effect6Tunable concentration/excitation-dependent deep-red and white light emission in single-phase Eu 2+ -activated Sc-based oxide phosphors for blue/UV-LEDs32Tuning of the thermal quenching performance of Bi 3+ -doped scheelite Ca(Mo/W)O 4 solid solution phosphors13Utilizing the energy transfer mechanism to realize color tunable luminescence14How to Obtain Anti‐Thermal‐Quenching Inorganic Luminescent Materials for Light‐Emitting Diode Applications252Stable Tunable Luminescence of Hetero-valent Eu Ion Activated Ba2InTaO6 Phosphors Synthesized by Defect-Induced Self-Reduction in the Molten-Salt Method16Effects of activated Sr 2+ ion content on strong blue‐emitting Ca 2 Sb 2 O 7 materials for high‐quality WLED devices5Enhanced up-conversion luminescence intensity of NaY(MoO4)2: Ho3+/Yb3+ phosphor by doping with Mg2+ ions for use in high-efficiency optical temperature sensor18An energy transfer strategy for highly luminescent green-emitting Ce3+/Tb3+ codoped Ca2LaHf2Al3O12 garnet phosphors in white light-emitting diodes21Photoluminescence spectroscopy of Mn2+ in zero-thermal expansion Zn4B6O13 green-emitting phosphor12Intense Luminescence and Good Thermal Stability in a Mn2+-Activated Mg-Based Phosphor with Self-Reduction27Strong enhancement of red photoluminescence from Eu doped Ga2O3 films by thermal annealing15Superb thermal stability purple-blue phosphor through synergistic effect of emission compensation and nonradiative transition restriction of Eu2+31Thermal enhancing photoluminescence intensities of Eu3+ doped Lu2(MoO4)311Cr3+/Yb3+/Nd3+-doped Ba2LaGa11O20 broadband NIR phosphors for NIR pc-LED and c-Si solar cells10Luminescence and structural properties of Ca1-xZrO3:Eux: An experimental and theoretical approach3A potential red-emitting phosphor Na2.5Zr2Si1.5P1.5O12: Eu3+ for WLEDs with excellent thermal stability, color purity and high quantum efficiency41Thermally boosted upconversion and downshifting luminescence in Sc2(MoO4)3:Yb/Er with two-dimensional negative thermal expansion303A novel blue-light excitable Pr3+ doped (Sr,Ba)LaMgTaO6 phosphor for plant growth lighting59A high quantum yield red phosphor NaGdSiO4: Eu3+ with intense emissions from the 5D0→7F1,2 transition44Tailoring of polychromatic emissions in Tb3+/Eu3+ codoped NaYbF4 nanoparticles via energy transfer strategy for white light-emitting diodes12Enhanced thermostability of Eu3+ ions photoluminescence by multi-level electron traps with various temperature responses4Highly-efficient double perovskite Mn4+-activated Gd2ZnTiO6 phosphors: A bifunctional optical sensing platform for luminescence thermometry and manometry197Synthesis of the Red-Emitting (Ba, Ca)2ScAlO5:Eu3+ Phosphors with Photoluminescence Properties30A novel broadband-excited LaNb2VO9:Sm3+ orange-red-emitting phosphor with zero-thermal-quenching behavior for WLEDs and personal identification22Highly efficient Ce: Lu(Mg,Al)2(Si,Al)3O12 phosphor ceramics for high-power white LEDs/LDs15Synthesis and characterization of a new double perovskite phosphor: NaCaTiTaO6:Dy3+ with high thermal stability for w-LEDs application59Hetero-valent substitution design of high thermal stability reddish-orange Sr3Ga2Sn1·5Si2·5O14:Sm3+ phosphor for healthy lighting white-light-emitting-diodes applications31Study the effect of Zn2+ co-doping on the structural and optical properties of CdSiO3:Eu3+ phosphor1Designing tunable luminescence in Ce3+/Eu2+-codoped Ca8Zn(SiO4)4Cl2 phosphors for white light-emitting diode and optical anti-counterfeiting applications32Li+ doping induced zero-thermal quenching in Cs3Zn6––B9O21:xEu3+,yLi+ (0 ≤ x ≤ 0.10, 0.06 ≤ y ≤ 0.16)10Triple luminescent center energy transfer enables color tuning in Na3Y(PO4)2:RE3+ (RE = Tb/Eu/Tm) for w-LEDs7Eu3+-activated Sr3LaNb3O12 red-emitting phosphors with excellent color stability for high color rendering w-LEDs8Blue-light excitable red-emitting Eu3+-doped TiO2 phosphor for WLED applications: Judd-Ofelt analysis and systematic investigation on its optical properties12Thermal Enhancement of Luminescence for Negative Thermal Expansion in Molecular Materials65Microstructure and photoluminescence of Eu-doped Sr3Al2O6 phosphors calcined with and without H3BO3 flux13Continuous production of K2SiF6:Mn4+ red phosphor by green route synthesis method for warm WLEDs application9Excitation wavelength dependent photoluminescence and photochromic studies of Yb3+/Er3+ doped β−KYF4 and β−NaYF4 nanoparticles8High-Efficiency Continuous-Luminescence-Controllable Performance and Antithermal Quenching in Bi 3+ -Activated Phosphors35CaGdSbWO8:Sm3+: A deep-red tungstate phosphor with excellent thermal stability for horticultural and white lighting applications34Sol-gel synthesis and characterization of praseodymium-doped and calcium-, titanium-substituted yttrium aluminium garnets Pr:Y3-xCaxAl5-yTiyO128A Triple-Doped Phosphor Strategy for the Conversion of Cool and Warm White Light10Manganese activated narrowband red-emitting Cs2KInF6:Mn4+ phosphor with high colour purity for backlight display16Multipath luminescent thermometry inCs3GdGe3O9:Yb3+, Er3+ phosphor26Environment-Dependent Eu2+-Activated Ba3CaK(PO4)3 toward White-Light Emission by Chemical Cosubstitution of the (BO3)3– Anion Group19Luminescence and energy transfer of a novel BaCeF5: Tb3+, Eu3+ color-tunable phosphor10SrLaNaTeO6:Eu3+ red-emitting phosphors with high luminescence efficiency and high thermal stability for high CRI white LEDs36Thermal stable cyan-emitting Ba9(Lu1.5Ga0.5)Si6O24:Ce3+ for high color-rendering white LEDs7Ratiometric fluorescence detection of tetracycline for tetracycline adjuvant screening in bacteria75Perovskite A-site symmetry tuning to achieve high quantum efficiency phosphor for WLED applications18Charge transfer band excited (Sr,Ba)2YTaO6:Eu3+ reddish-orange-emitting phosphors for luminescence lifetime thermometry and flexible anti-counterfeiting labels36Luminescence properties, tunable emission and energy transfer of Ca9MgLi(PO4)7:Bi3+/Eu3+ phosphor19Complete B-site cation regulation accomplish UV-excited red phosphors in double perovskite oxides13Strategies for Enhancement Luminance of Sub‐Micrometer Phosphor: A Sub‐Micrometer Narrow‐Band Red Phosphor with Ultrahigh Thermal Stability50High-Temperature Zero Thermal Expansion in HfFe2+δ from Added Ferromagnetic Paths12One-step synthesis of multi-colored ZnO nanoparticles for white light-emitting diodes9Preparation and photoluminescence performance of BaMoO4:Sm3+ orange–red phosphor2Recent Developments of Microscopic Study for Lanthanide and Manganese Doped Luminescent Materials8Thermal, structural and optical properties of un-doped and lanthanide-doped germanate ceramics6Impact of Negative Thermal Expansion on Thermal Quenching of Luminescence of Sc2Mo3O12:Eu3+73Novel Sm3+-activated YCa4O(BO3)3 phosphors with high quantum efficiency and thermal stability for red-backlight display and indoor illumination27A novel red-emitting Na5W3O9F5:Eu3+ phosphor with high color purity for blue-based WLEDs61Enhanced Photoluminescence of Gd3Al4GaO12: Cr3+ by Energy Transfers from Co-Doped Dy3+12Effect of dopant (Li+, Mg2+ and Bi3+) on the photoluminescence emission intensity of Eu3+ doped CaAl2O4 phosphor: Application to white LEDs13Unique excitation power density and pulse width-dependent multicolor upconversion emissions of Y 2 Mo 4 O 15 :Yb 3+ ,Ho 3+ for anti-counterfeiting and information encryption applications25Realization of highly efficient Ba2SrWO6:Mn4+ phosphor via La addition strategy and application for plant cultivation LED40Room-Temperature Synthesis of Highly-Efficient Eu3+-Activated KGd2F7 Red-Emitting Nanoparticles for White Light-Emitting Diode7Investigation of multicolor emitting Cs 3 GdGe 3 O 9 :Bi 3+ ,Eu 3+ phosphors via energy transfer for WLEDs10Design of Eu 2+ ‐activated broadband orange‐emitting phosphors with excellent luminescent performance for warm WLEDs10Preparation and Photoluminescent Properties of Tb3+-Doped Lu2W3O12 and Lu2Mo3O12 Green Phosphors18Blue-light activated green emitting BaY 2 Al 2 Ga 2 SiO 12 :Ce 3+ ,Bi 3+ : efficient persistent luminescence phosphors for AC-LEDs28Negative lattice expansion-induced upconversion luminescence thermal enhancement in novel Na 2 MoO 4 :Yb 3+ , Er 3+ transparent glass ceramics for temperature sensing applications39Achieving excellent thermostable red emission in singly Mn 2+ -doped near-zero thermal expansion (NZTE) material Li 2 Zn 3 (P 2 O 7 ) 26An up-conversion Ba 3 In(PO 4 ) 3 :Er 3+ /Yb 3+ phosphor that enables multi-mode temperature measurements and wide-gamut ‘temperature mapping’25Broadband-excited and green-red tunable emission in Eu 2+ -sensitized Ca 8 MnTb(PO 4 ) 7 phosphors induced by structural-confined cascade energy transfer5Cationic composition engineering in double perovskite XLaLiTeO 6 :Eu 3+ (X = Ba, Sr, Ca, and Mg) toward efficient and thermally stable red luminescence for domestic white-LEDs35Concentration quenching inhibition and fluorescence enhancement in Eu 3+ -doped molybdate red phosphors with two-phase mixing19Design of anti-thermal quenching Pr 3+ -doped niobate phosphors based on a charge transfer and intervalence charge transfer band excitation-driven strategy18Efficient red luminescence in Eu 3+ doped CdSe/CdS all-inorganic quantum dots shows great potential for wLEDs13Electronic Defect Engineering of Double-Doped Β-Kyf4:Eu3+,Bi3+ Red Phosphors: Negative Thermal Quenching and Applications for High-Efficiency White Light-Emitting Diodes0Energy transfer and tunable emission in BaSrGd 4 O 8 :Bi 3+ ,Eu 3+ phosphors for warm WLED9Enhancing upconversion via constructing local energy clusters in lanthanide-doped fluoride nanoparticles10Eu 2+ luminescence in CaYGaO 4 olivine: a new efficient red phosphor for warm illumination47High quantum efficiency and excellent color purity of red-emitting Eu 3+ -heavily doped Gd(BO 2 ) 3 -Y 3 BO 6 -GdBO 3 phosphors for NUV-pumped WLED applications24Highly efficient near-infrared solid solution phosphors with excellent thermal stability and tunable spectra for pc-LED light sources toward NIR spectroscopy applications11Highly-efficient Eu 2+ -activated Sr 8 Si 4 O 12 Cl 8 cyan-emitting phosphors with zero-thermal quenching luminescence for versatile applications16Investigation of the luminescence properties and energy transfer mechanisms in Gd 3 TaO 7 :Bi 3+ ,Eu 3+ phosphors for their potential application in full-spectrum WLEDs10Lanthanide-doped lead-free double perovskite La 2 MgTiO 6 as ultra-bright multicolour LEDs and novel self-calibrating partition optical thermometer35

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  32. Synthesis and spectroscopic analysis of Eu3+-doped tungsten bronze Sr5YTi3Nb7O30 phosphors for w-LED and visualization of latent fingerprint

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