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RESEARCH PAPER · Chemistry of Materials · 2021

Lattice Disorder and Oxygen Migration Pathways in Pyrochlore and Defect-Fluorite Oxides

Frederick P. Marlton, Zhaoming Zhang, Yuanpeng Zhang, Thomas E. Proffen, Chris D. Ling, Brendan J. Kennedy

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Lattice Disorder and Oxygen Migration Pathways in Pyrochlore and Defect-Fluorite OxidesOriginalAverage and local ordering of Yb2(Ti2-Yb )O7-/2 ‘stuffed’ pyrochlores: The development of a robust structural model14A Comparison of Order-Disorder in Several Families of Cubic Oxides20Broad Distribution of Local Polar States Generates Large Electrothermal Properties in Pb-Free Relaxor Ferroelectrics8Electrocatalytic Studies of Coral-Shaped Samarium Stannate Nanoparticles for Selective Detection of Azathioprine in Biological Samples21Controllable sites and high-capacity immobilization of uranium in Nd 2 Zr 2 O 7 pyrochlore13Raman spectroscopy study of disorder phenomena and size effects in pyrochlores13Structure–property correlation in oxide-ion and proton conductors for clean energy applications: recent experimental and computational advancements62Attaining Low Lattice Thermal Conductivity in Half-Heusler Sublattice Solid Solutions: Which Substitution Site Is Most Effective?8Influence of Fe-substituted structural transformation on energy storage density and switchability of Bi3NbO712Discovery of a reversible redox-induced order-disorder transition in a 10-component compositionally complex ceramic15Optimization of dielectric and magnetoresistive response in Nd2-xLaxCe2O7 (0 ≤ x ≤ 2.0) for efficient energy storage applications16Understanding the Re-entrant Phase Transition in a Non-magnetic Scheelite21Improving Both the Activity and Stability for the Oxygen Evolution Reaction with Bismuth Ruthenate Epitaxially Grown on Bismuth Titanate Pyrochlore6Eutectic ceramics of the CeO2 – ZrO2 – MgO system produced by laser-assisted directional solidification2Long- and short-range orders in 10-component compositionally complex ceramics24Vacancy-Driven Disorder and Elevated Dielectric Response in the Pyrochlore Pb1.5Nb2O6.57Recent developments in oxide ion conductors: focusing on Dion–Jacobson phases41Emerging disorder in Gd 2 (Ti 1− x Zr x ) 2 O 7 pyrochlores matrices for radioactive waste disposal: symmetry lowering versus defect clustering11Gateway toward efficient and miniaturized A 2 B 2 O 7 -type fluorite structure-based energy storage devices13Oxygen–Ion Conductivity, Dielectric Properties and Spectroscopic Characterization of “Stuffed” Tm2(Ti2−xTmx)O7−x/2 (x = 0, 0.1, 0.18, 0.28, 0.74) Pyrochlores4Ab initio description of magnetic and critical properties of spin-glass pyrochlore NaSrMn2F72An exploration of lattice transformation mechanism of muscovite single crystal under EB irradiation at 0–1000 kGy2Characterizing the Structure and Radiation Resistance of Weberite-Type Complex Oxides0Effects of synthesis conditions on the crystal and local structures of high-entropy oxides Ln 2M2 O 7 (Ln = La-Yb, Y; M = Ti, Zr, Ce)15Size and orientation of polar nanoregions characterized by PDF analysis and using a statistical model in a Bi(Mg 1/2 Ti 1/2 )O 3 –PbTiO 3 ferroelectric re-entrant relaxor22Structured Catalysts and Catalytic Processes: Transport and Reaction Perspectives140Design of a pebbles-like erbium stannate integrated with graphene nanoribbons for the anti-cancer drug nilutamide detection in water and biological samples13Spectroscopic characterization of fluorite of Amba Dongar, Gujarat, India: Linking chemical composition with color11Composition-dependent spin exchange interaction for multiferroicity in perovskite Pb(Fe1/2Nb1/2)O33Phase transition in Eu 2 Zr 2– x O 7–2 x ( x = 0–1) solid solutions: A combined structural and spectroscopic study11Understanding the influence of local structure distortions on Na-ion migration in perovskite solid electrolytes6Atomic Scale Responses of High Entropy Oxides to Redox Environments15Short-range order in ion irradiated fluorite structural derivatives in Sc2O3–HfO25Pyrochlore-like Local Structure in Globally Disordered Y2Zr2O7: Evidence and Reasoning by Combined Theoretical and Experimental Study11Structural and spectroscopic insights into the cation mediated phase transitions in samarium zirconates Sm2Zr2–O7–2 (x = 0 to 1)3Tuning the radiation tolerance of titanate pyrochlore via Sn-substitution: an in situ ion irradiation study of pyrochlore-glass ceramics2Radiation-induced short-range order in ceramics1Introduction of Hexagonal-Perovskite Type Ionic Conductors and Order/Disorder in the Crystal0Exploring structural stability and bonding trends in A2B2O7 Pyrochlores using machine learning0Nonstoichiometry and realistic layered CMAS corrosion routes in Gd2-xZr2+xO7+x/20Influence of isovalent Hf substitution at the B-site on the structural evolution, dielectric relaxation, and electrical transport properties of nanocrystalline La2Sn2O7 pyrochlores0Structural and spectroscopic insights on fluorite-structured terbium zirconates Tb2Zr2−xO7−2x (x = 0–1)0Water soaking effect on conductivity of “stuffed” pyrochlores Ln2.1Zr1.9O7−δ (Ln = La, Sm, Gd)0Local ordering, defect dynamics, and phase stability in Sc–Hf oxides under ion irradiation0

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  1. Average and local ordering of Yb2(Ti2-Yb )O7-/2 ‘stuffed’ pyrochlores: The development of a robust structural model

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    Bryce G. Mullens, Zhaoming Zhang, Maxim Avdeev, Helen E. A. Brand, Bruce C. C. Cowie, Anita M. D’Angelo, Matilde Saura Muzquiz, Brendan J. Kennedy

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  2. A Comparison of Order-Disorder in Several Families of Cubic Oxides

    Frontiers in Chemistry · 2021-09-01

    Tamilarasan Subramani, Albert A. Voskanyan, K. Jayanthi, Mykola Abramchuk, Alexandra Navrotsky

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  3. Broad Distribution of Local Polar States Generates Large Electrothermal Properties in Pb-Free Relaxor Ferroelectrics

    Chemistry of Materials · 2021-11-05

    Frederick P. Marlton, Sanjib Nayak, Sarangi Venkateshwarlu, Ngai Hang Chan, Jing Kong, Yuanpeng Zhang, Matthew G. Tucker, Mads R. V. Jørgensen, Abhijit Pramanick

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  4. Electrocatalytic Studies of Coral-Shaped Samarium Stannate Nanoparticles for Selective Detection of Azathioprine in Biological Samples

    ACS Applied Nano Materials · 2021-12-06

    Ramachandran Rajakumaran, Balamurugan Karuppaiah, Shen‐Ming Chen, Ramaraj Sukanya, Carmel B. Breslin

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  5. Controllable sites and high-capacity immobilization of uranium in Nd 2 Zr 2 O 7 pyrochlore

    Journal of Synchrotron Radiation · 2021-12-17

    Jian Sun, Jing Zhou, Zhiwei Hu, Ting-Shan Chan, Renduo Liu, Haisheng Yu, Linjuan Zhang, Jian-Qiang Wang

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  6. Raman spectroscopy study of disorder phenomena and size effects in pyrochlores

    Elsevier eBooks · 2022-01-01

    María Luisa Sanjuán

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  7. Structure–property correlation in oxide-ion and proton conductors for clean energy applications: recent experimental and computational advancements

    Journal of Materials Chemistry A · 2022-01-01

    Mauro Coduri, Maths Karlsson, Lorenzo Malavasi

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  8. Attaining Low Lattice Thermal Conductivity in Half-Heusler Sublattice Solid Solutions: Which Substitution Site Is Most Effective?

    Electronic Materials · 2022-01-05

    Rasmus Tranås, Ole Martin Løvvik, Kristian Berland

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  9. Influence of Fe-substituted structural transformation on energy storage density and switchability of Bi3NbO7

    Applied Physics A · 2022-02-17

    Rozi Ali, Abdul Quader, Sidra Zawar, Ghulam Mustafa, Shahid Mahmood Ramay, Shahid Atiq

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  10. Discovery of a reversible redox-induced order-disorder transition in a 10-component compositionally complex ceramic

    Scripta Materialia · 2022-03-29

    Dawei Zhang, Yan Chen, Tianshi Feng, Dunji Yu, Ke An, Renkun Chen, Jian Shu Luo

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  11. Optimization of dielectric and magnetoresistive response in Nd2-xLaxCe2O7 (0 ≤ x ≤ 2.0) for efficient energy storage applications

    Materials Science in Semiconductor Processing · 2022-06-27

    Abdul Quader, Ghulam Mustafa, Saira Riaz, Shahid Mahmood Ramay, Shahid Atiq

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  12. Understanding the Re-entrant Phase Transition in a Non-magnetic Scheelite

    Journal of the American Chemical Society · 2022-08-22

    Matilde Saura Muzquiz, Frederick P. Marlton, Bryce G. Mullens, Alicia Maria Manjón-Sanz, Jöerg C. Neuefeind, Michelle S. Everett, Helen E. A. Brand, Subrata Mondal, G. Vaitheeswaran, Brendan J. Kennedy

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  13. Improving Both the Activity and Stability for the Oxygen Evolution Reaction with Bismuth Ruthenate Epitaxially Grown on Bismuth Titanate Pyrochlore

    ACS Applied Energy Materials · 2022-08-26

    Pierre‐Yves Olu, Eiko Yokomizo, Taro Kinumoto

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  14. Eutectic ceramics of the CeO2 – ZrO2 – MgO system produced by laser-assisted directional solidification

    Journal of Solid State Chemistry · 2022-08-31

    Alodia Orera, Patricia B. Oliete, Rosa Isabel Merino, María Luisa Sanjuán

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  15. Long- and short-range orders in 10-component compositionally complex ceramics

    Advanced Powder Materials · 2022-11-04

    Dawei Zhang, Yan Chen, Heidy Vega, Tianshi Feng, Dunji Yu, Michelle S. Everett, Jöerg C. Neuefeind, Ke An, Renkun Chen, Jian Shu Luo

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  16. Vacancy-Driven Disorder and Elevated Dielectric Response in the Pyrochlore Pb1.5Nb2O6.5

    Inorganic Chemistry · 2022-11-08

    Uyen T. Dang, Jake O’Hara, Hayden A. Evans, Daniel Olds, Juan R. Chamorro, Daniel Hickox-Young, Geneva Laurita, Robin T. Macaluso

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  17. Recent developments in oxide ion conductors: focusing on Dion–Jacobson phases

    Chemical Communications · 2022-11-15

    Wenrui Zhang, Masatomo Yashima

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  18. Emerging disorder in Gd 2 (Ti 1− x Zr x ) 2 O 7 pyrochlores matrices for radioactive waste disposal: symmetry lowering versus defect clustering

    Journal of Materials Chemistry A · 2023-01-01

    Armando di Biase, Carlo Castellano, Giorgia Confalonieri, Patrizia Fumagalli, Simone Tumiati, Davide Ceresoli, Marco Scavini

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  19. Gateway toward efficient and miniaturized A 2 B 2 O 7 -type fluorite structure-based energy storage devices

    RSC Advances · 2023-01-01

    Abdul Quader, Ghulam Mustafa, Shahid Mahmood Ramay, Shahid Atiq

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  20. Oxygen–Ion Conductivity, Dielectric Properties and Spectroscopic Characterization of “Stuffed” Tm2(Ti2−xTmx)O7−x/2 (x = 0, 0.1, 0.18, 0.28, 0.74) Pyrochlores

    Ceramics · 2023-04-10

    Nikolay V. Gorshkov, Egor D. Baldin, D. N. Stolbov, В. А. Рассулов, Olga K. Karyagina, A. V. Shlyakhtina

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  21. Ab initio description of magnetic and critical properties of spin-glass pyrochlore NaSrMn2F7

    AIP Advances · 2023-05-01

    Mohammad Amirabbasi

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  22. An exploration of lattice transformation mechanism of muscovite single crystal under EB irradiation at 0–1000 kGy

    Journal of the American Ceramic Society · 2023-09-08

    Honglong Wang, Zhiguo Sun, Faming Xia, Chenguang Yang, Xiaoguang Wang, Jintang Li, Linxu Jiang

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  23. Characterizing the Structure and Radiation Resistance of Weberite-Type Complex Oxides

    Unknown journal · 2023-10-19

    Igor M. Gussev

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  24. Effects of synthesis conditions on the crystal and local structures of high-entropy oxides Ln 2M2 O 7 (Ln = La-Yb, Y; M = Ti, Zr, Ce)

    Ceramics International · 2023-11-24

    Victor V. Popov, Alexey P. Menushenkov, Alexey A. Yastrebtsev, Yan V. Zubavichus, Bulat R. Gaynanov, А. А. Иванов, S.G. Rudakov, Maria M. Berdnikova, Alexander A. Pisarev, E. Kulikova, Evgeny V. Khramov, Nickolay A. Kolyshkin, Victor Nikolaevich Khrustalev, Igor V. Shchetinin, Mikhail K. Tatmyshevskiy, Sergey M. Novikov, Valentyn S. Volkov, Н. А. Царенко, Natalia V. Ognevskaya, O.N. Seregina

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  25. Size and orientation of polar nanoregions characterized by PDF analysis and using a statistical model in a Bi(Mg 1/2 Ti 1/2 )O 3 –PbTiO 3 ferroelectric re-entrant relaxor

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  26. Structured Catalysts and Catalytic Processes: Transport and Reaction Perspectives

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  27. Design of a pebbles-like erbium stannate integrated with graphene nanoribbons for the anti-cancer drug nilutamide detection in water and biological samples

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  28. Spectroscopic characterization of fluorite of Amba Dongar, Gujarat, India: Linking chemical composition with color

    Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy · 2024-05-16

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  29. Composition-dependent spin exchange interaction for multiferroicity in perovskite Pb(Fe1/2Nb1/2)O3

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  30. Phase transition in Eu 2 Zr 2– x O 7–2 x ( x = 0–1) solid solutions: A combined structural and spectroscopic study

    Journal of the American Ceramic Society · 2024-07-23

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  31. Understanding the influence of local structure distortions on Na-ion migration in perovskite solid electrolytes

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  32. Atomic Scale Responses of High Entropy Oxides to Redox Environments

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  33. Short-range order in ion irradiated fluorite structural derivatives in Sc2O3–HfO2

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  34. Pyrochlore-like Local Structure in Globally Disordered Y2Zr2O7: Evidence and Reasoning by Combined Theoretical and Experimental Study

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  35. Structural and spectroscopic insights into the cation mediated phase transitions in samarium zirconates Sm2Zr2–O7–2 (x = 0 to 1)

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  36. Tuning the radiation tolerance of titanate pyrochlore via Sn-substitution: an in situ ion irradiation study of pyrochlore-glass ceramics

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  37. Radiation-induced short-range order in ceramics

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  38. Introduction of Hexagonal-Perovskite Type Ionic Conductors and Order/Disorder in the Crystal

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  39. Exploring structural stability and bonding trends in A2B2O7 Pyrochlores using machine learning

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  40. Nonstoichiometry and realistic layered CMAS corrosion routes in Gd2-xZr2+xO7+x/2

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  41. Influence of isovalent Hf substitution at the B-site on the structural evolution, dielectric relaxation, and electrical transport properties of nanocrystalline La2Sn2O7 pyrochlores

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  42. Structural and spectroscopic insights on fluorite-structured terbium zirconates Tb2Zr2−xO7−2x (x = 0–1)

    Journal of the Australian Ceramic Society · 2026-09-01

    Linggen Kong, Robert D. Aughterson, Inna Karatchevtseva, Maxim Avdeev, Yingjie Zhang

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  43. Water soaking effect on conductivity of “stuffed” pyrochlores Ln2.1Zr1.9O7−δ (Ln = La, Sm, Gd)

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  44. Local ordering, defect dynamics, and phase stability in Sc–Hf oxides under ion irradiation

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