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RESEARCH PAPER · Frontiers in Chemistry · 2020

Metal Oxysulfides: From Bulk Compounds to Nanomaterials

Clément Larquet, Sophie Carenco

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Metal Oxysulfides: From Bulk Compounds to NanomaterialsOriginalOxygen Reduction Reaction with Molybdenum-Containing Oxysulfide Nanoparticles : from Colloidal Synthesis to Surface Activity0Evolution of Non-metallic Inclusions Through Processing in Ti-V Microalloyed 316L and Al-V Microalloyed 17-4PH Stainless Steels for Hipping Applications3In situ electron-doping of MoS2 thin films by embedded MoOxSy particles during chemical vapor deposition9Ultrathin oxysulfide semiconductors from liquid metal: a wet chemical approach35From Ta2S5 Wires to Ta2O5 and Ta2O5–xSx5Size and optical versatility in rare earth oxysulfide photonic materials1Design of metastable oxychalcogenide phases by topochemical (de)intercalation of sulfur in La2O2S224An Overview of Gadolinium-Based Oxide and Oxysulfide Particles: Synthesis, Properties, and Biomedical Applications54Synthesis, structure, and magnetic properties of the quaternary oxysulfides Ln 5V3O7S6 (Ln = La, Ce)1Combining electrochemical and quantitative elemental analysis to investigate the sulfur poisoning process of ceria thin film fuel electrodes3Dual-mode vehicles with simultaneous thermometry and drug release properties based on hollow Y 2 O 3 :Er,Yb and Y 2 O 2 SO 4 :Er,Yb spheres10Liquid metals: an ideal platform for the synthesis of two-dimensional materials115Oxides free materials for photocatalytic water splitting3Synthesis of lanthanide chalcogenide nanoparticles4Ultrathin 2D silver sulphate nanosheets for visible-light-driven NO 2 sensing at room temperature9[NiFe]-(Oxy)Sulfides Derived from NiFe2O4 for the Alkaline Hydrogen Evolution Reaction7Lanthanide-doped inorganic luminescent nanoparticles : synthesis, characterizations and applications0Multianion induced out-of-plane proper polarization in oxyfluoride Aurivillius Bi2TiO4F28Heterogeneous Oxysulfide@Fluoride Core/Shell Nanocrystals for Upconversion-Based Nanothermometry43La4Ga2Se6O3: A Rare-Earth Oxyselenide Built from One-Dimensional Strips5Hollow structures with rare earths: Synthesis and electrocatalytic applications34Mixed-Anion-Oriented Design of LnMGa3S6O (Ln = La, Pr, and Nd; M = Ca and Sr) Nonlinear Optical Oxysulfides with Targeted Property Balance56Stepwise sulfurization of MoO3 to MoS2 thin films studied by real-time X-ray scattering15Recent developments on Bi-based oxychalcogenide materials with thermoelectric and optoelectronic applications: an overview33Banana peel biowaste-derived carbon composited with Zn(O,S) for solar-light photocatalytic hydrogen generation21Versatility of Tellurium in Heteroanionic Ln 2 O 2 Te (Ln = La, Ce, Pr) and Tellurate Ln 2 TeO 6 (Ln = La, Pr)8Physicochemical and optical studies of novel heterogeneous oxysulfide catalyst based on Mo for potential application in reduction reactions6Nouveaux oxysulfures fonctionnels métastables obtenus par désintercalation topochimique du soufre0Synthesis, Characterization, and Electronic Properties of ZnO/ZnS Core/Shell Nanostructures Investigated Using a Multidisciplinary Approach14Optical-Quality Thin Films with Tunable Thickness from Stable Colloidal Suspensions of Lanthanide Oxysulfide Nanoplates5Optimization of R2O2Se (R = La, Gd, Y) Synthesis for the Preparation of Optical Materials0PVP-coated ultrasmall Nd-doped Gd 2 O 2 S nanoparticles for multimodal imaging16Tb- and Eu-doped yttrium oxyselenides as novel absorber layers for superstrate thin-film photovoltaics: improved spectral optical absorption and green–red phosphor activation2Оптимизация синтеза R2O2Se для получения оптических материалов (R=La, Gd, Y)0A new class of layered Bi2O2S nanopetals by one-pot supercritical-CO2 approach: A reliable electrocatalyst for analgesic bioflavonoid detection9Comprehensive review on multiple mixed-anion ligands, physicochemical performances and application prospects in metal oxysulfides32Synthesis of uranium mixed anion compounds synthesized using the Boron-Chalcogen Mixture method: Ba6Co6U0·91S13·5O0.5 and Ba5·47K0·53Zn6US13·5O0.55Enhanced VO•• sites with substitutional defects of LiZn′ on Zn(O,S) for high-rate hydrogen generation under simulated solar-light irradiation7Crystalline S-doped TiO2 photoanodes from amorphous titanium oxysulfide (TiOxSy) for photo-oxidation reactions7A sandwiched luminescent heterostructure based on lanthanide‐doped Gd 2 O 2 S@NaYF 4 core/shell nanocrystals24Topochemical Anionic Subunit Insertion Reaction for Constructing Nanoparticles of Layered Oxychalcogenide Intergrowth Structures9Fabrication of BiCuOS nanoflowers acting as nanoarrays on photonic nanoparticles for chemo-photothermal therapy17Co3O4@Ru Aggregate boosting the electrochemiluminescence for ultrasensitive and selective detection of lidocaine13Investigation of the Nano-Bio Interface by the Design and Development of Nanostructured Lanthanide Oxysulfide Thin Films using Ellipsometric and Electrochemical Techniques0Anionic Redox Topochemistry for Materials Design: Chalcogenides and Beyond9NIR II-responsive core–shell La 2 O 2 S:Er 3+ @La 2 O 2 S nanoparticles towards 1.5 μm photodetection7Structurally and surficially activated TiO 2 nanomaterials for photochemical reactions100Quaternary Rare-Earth Oxyselenides RE4Ga2Se7O2 (RE = Pr, Nd) with Trigonal Bipyramidal GaSe5 Units: Evaluation of Optical, Thermoelectric, and Electrocatalytic Properties10Controlled Synthesis of Terbium-Doped Colloidal Gd2O2S Nanoplatelets Enables High-Performance X-ray Scintillators19Burned Coal Dumps as a Source of New Compounds: The Novel Mixed-Valent Iron Oxysulfide Ca4Fe2+3Fe3+2O6S4 from the Chelyabinsk Coal Basin, South Ural2Rare-Earth Metal-Based Nanosystems for Facilitating Neural Stem Cell Differentiation into Neurons and Enhancing Axonal Stability3Rapid Synthesis and Sintering of La2O2S and Its Physical, Optical, and Mechanical Properties5Meeting the Industrial Challenges of CO 2 Photocatalytic Reduction: Moving From Molybdenum Disulfides to Oxysulfides Based Materials?6FORMIROVANIE POLUPROVODNIKOVOGO SOSTOYaNIYa V OKSISUL'FOSTIBNITAKh RSbS2O PRI R = Dy, Ho, Er0Enhanced degradation of methylene blue dye using hydrothermally synthesized Nickel-doped Strontium oxide catalysts8Single step synthesis of gadolinium oxide nanorods decorated graphene oxide nanocomposites as promising bactericidal agents for the biomedical sector4Understanding Ion-Exchange Processes in the Synthesis of ZnSx@ZnO1–x Heterostructures from Controlled Sulfidation of ZnO Nanocrystals3Enhanced two-photon absorption in hydrothermally synthesized La 2 O 6 Te nanorods for visible light photodetection18Clustering Cu-S based compounds using periodic table representation and compositional Wasserstein distance3Harnessing the electrochemical ability of a Ce 4 O 4 S 3 /Ni 3 S 2 composite as an electrode for a symmetric supercapacitor3La 2 ZnGa 2 S 6 O: a melilite-type transition metal oxysulfide achieving a well-balanced nonlinear optical behavior5Solid-State Synthesis Enables Enhanced Crystallinity and Tunable Optical Properties in Lanthanum Oxytelluride2Synthesis and Electron Dependent Properties of the Phosphor Gd 2 O 2 S:Ce 3+ , Tb 3+1Eu(II) 4 Eu(III) 2 Ge 3 S 11 O 2 : a Single‐Element Mixed‐Valence Engineering Breakthrough for Strongly Enhanced Nonlinearity and Anisotropy in Rare‐Earth Oxysulfides8Analysis of RF magnetron sputtered MoS2 thin films for electronic application: Influence of the sputter power to film growth and composition7Rare-Earth Substitution of La 3 Si 2 S 8 I for Efficient and Color-Tunable Phosphor Converted White Light Emitting Diodes14Optimization and Characterization of Dy‐ and Ce‐Doped Gadolinium Oxy Sulfate (Gd2O2SO4) Nanoparticles for Advanced Luminescent Applications0Redox‐Mediated Phosphorus Adsorption on Manganese Oxysulfide in Aqueous Solutions2Facile and scalable synthesis of Y2O2S nanoparticles via Y(OH)3 precursor preparation and CS2 sulfurization0Growth temperature effects on defect-mediated optical and photoluminescence properties of PbS x O y nanostructured thin films1Hydrazinecarbodithiolate Complex and Graphene Oxide Mediated Precursors of CoO4-xSy and NiO4-xSy Ternary Systems for Efficient Dye Degradation0A New Synthetic Method for HfS 2 Thin Films Using MOCVD0A novel europium(III) oxysulfide Eu2OS4 synthesized under high-pressure: crystal structure and spectroscopy0Investigation of spectroscopic studies of commercially useful contrast media omniscan in two biologically important fluids0Synthesis of AgBiS 2 and AgInS 2 Based on Formation Energies in Sulfur‐Rich Reducing Flame0Manganese oxysulfide particles for hexavalent chromium removal from aqueous environment: Isotherm, kinetics, thermodynamic analysis1Oxysulfide materials as emerging photocatalysts for solar water splitting: Design principles and challenges0

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  1. Oxygen Reduction Reaction with Molybdenum-Containing Oxysulfide Nanoparticles : from Colloidal Synthesis to Surface Activity

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  2. Evolution of Non-metallic Inclusions Through Processing in Ti-V Microalloyed 316L and Al-V Microalloyed 17-4PH Stainless Steels for Hipping Applications

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  3. In situ electron-doping of MoS2 thin films by embedded MoOxSy particles during chemical vapor deposition

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  4. Ultrathin oxysulfide semiconductors from liquid metal: a wet chemical approach

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  5. From Ta2S5 Wires to Ta2O5 and Ta2O5–xSx

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  6. Size and optical versatility in rare earth oxysulfide photonic materials

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  7. Design of metastable oxychalcogenide phases by topochemical (de)intercalation of sulfur in La2O2S2

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  8. An Overview of Gadolinium-Based Oxide and Oxysulfide Particles: Synthesis, Properties, and Biomedical Applications

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  16. [NiFe]-(Oxy)Sulfides Derived from NiFe2O4 for the Alkaline Hydrogen Evolution Reaction

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  18. Multianion induced out-of-plane proper polarization in oxyfluoride Aurivillius Bi2TiO4F2

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  19. Heterogeneous Oxysulfide@Fluoride Core/Shell Nanocrystals for Upconversion-Based Nanothermometry

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  20. La4Ga2Se6O3: A Rare-Earth Oxyselenide Built from One-Dimensional Strips

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  48. Quaternary Rare-Earth Oxyselenides RE4Ga2Se7O2 (RE = Pr, Nd) with Trigonal Bipyramidal GaSe5 Units: Evaluation of Optical, Thermoelectric, and Electrocatalytic Properties

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  49. Controlled Synthesis of Terbium-Doped Colloidal Gd2O2S Nanoplatelets Enables High-Performance X-ray Scintillators

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  50. Burned Coal Dumps as a Source of New Compounds: The Novel Mixed-Valent Iron Oxysulfide Ca4Fe2+3Fe3+2O6S4 from the Chelyabinsk Coal Basin, South Ural

    ACS Earth and Space Chemistry · 2024-07-10

    Andrey A. Zolotarev, Margarita S. Avdontceva, Sergey V. Krivovichev, Ella V. Sokol, Elena S. Zhitova, Jianhua Chen, Yuqiong Li, Anatoly A. Zolotarev, Natalia S. Vlasenko, Mikhail Anatolyevich Rassomakhin

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